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The influence of calcium nitrite corrosion inhibitor on the durability of Portland cement mortars against sulphate solutions was investigated experimentally in the present research. For this reason, mortar specimens were produced using CEM I 42.5N cement and were immersed in different sulphate and sulphate‐chloride contaminated solutions. Sulphate resistance was evaluated according to the procedure described in ASTM C1012. The properties measured were the specimens' expansion, development of compressive strength, changes in corrosion potential and corrosion current density measurements of steel‐containing specimens.

The cementitious/chemical properties of the untreated CFA are dependent on the coal composition and previous burning conditions. The purpose of this paper is to investigate whether untreated CFA can efficiently reduce cement replacement and does not require further combustion treatment to be a viable cement replacement.

Two types of mixes: Type I concrete and PCFA (Type I and 30 per cent untreated CFA) concrete were batched and subjected to compressive strength tests and cyclic exposures of 5 per cent sodium sulphate (Na₂SO₄) and 5 per cent magnesium sulphate (MgSO₄), respectively.

PCFA mix was 41.1 and 35.21 per cent lower in strength compared to Type I at 28 and 56 days correspondingly. Continuous-sulphate-exposure resulted in slow but continued strength development for both mixes. However, the strengths of PCFA cubes exposed to cyclic sulphate and sulphate/magnesium salts continued to increase at a lower rate from their corresponding 28-day strength (rate of 18.7 per cent and strength 27.30 MPa in Na₂SO₄ and rate of 10.0 per cent and strength 25.30 MPa in MgSO₄) while Type I specimens subjected to the same exposure conditions experienced drastic reductions in strength (rate of −15.0 per cent and strength 33.21 MPa in Na₂SO₄ and rate of −23.4 per cent and strength 29.94 MPa in MgSO₄).

Results justify the need for additional tests essentially: at different percentage replacement of untreated CFA, fineness of materials, chloride environment and longer exposures, to address the cementitious properties of untreated CFA as cement replacement.

Treatment methods for fly ashes require undoubtedly additional resources, energy input and cost. This paper paves the way to define whether untreated CFA can be used as cement replacement in concrete.

The effect of chlorides on corrosion of reinforcing steel is well documented in the literature. However, few studies have focused attention on the effect of sulphates on the corrosion of low carbon steel in alkaline media. This paper aims to address this issue.

This paper describes the results of the investigation into the corrosion behaviour of low carbon steel (typically used as reinforcing steel), exposed to alkaline media at a pH of 9 and 12 with varying concentrations of sulphate and chloride ions, as well as, in sulphate only solutions. An attempt was made to inhibit corrosion of steel exposed to the corrosive media using laser surface treatment of the steel specimens. Mass loss tests and electrochemical tests were conducted to evaluate the effect of sulphate only and the combined effect of sulphate and chloride ions in an alkaline media on steel.

It was found that sulphate ions could cause corrosion of steel in alkaline media. The severity of the attack increased with increasing sulphate ion concentrations, as well as with combinations of sulphate and chloride ions. The pH 12 conditions seem to show much more critical attack with evidence of pitting corrosion as compared to uniform corrosion for test conditions at a pH of 9. The attempt to inhibit the observed corrosion of steel exposed to the corrosive high alkaline media containing sulphate ions on their own and in combination of chloride ions by laser surface treatment proved to be successful.

The research undertaken here adds to the body of knowledge relating to the effect of sulphate ions on reinforcing steel corrosion in highly alkaline media. Most literature points out that sulphate ions on their own do not have a corrosive effect, but rather, a passivating effect!

The purpose of this paper is to study the stress corrosion cracking (SCC) behaviour of anodized 1050 Al‐alloy in marine environments at different concentrations of sulphate ions.

The SCC experiments were performed by measuring the time to failure in 3.5% NaCl solution, or in the presence of three different concentrations of sulphate ions under conditions of applied anodic current. For the interpretation of the results, changes in potential during SCC tests and optical microscope micrographs of stress corrosion tested specimens at various periods of time, were obtained.

The influence of seawater composition on the SCC behaviour of the anodized 1050 Al‐alloy depends on the concentration of sulphate ions, the oxide thickness and the stress level. At the higher stress levels and low concentrations of sulphate ions, increased times to failure were observed. These results were attributed to the inhibitory action of sulphate ions. At a low stress level and higher concentration of sulphate ions, the increased times of exposure and the more intensive corrosive environment led to partial destruction of the anodic coatings and a decrease in the time to failure. Better protective properties were observed at an oxide thickness of 10 μm. The thicker oxides did not protect so well because they were more brittle, cracking under strain and allowing corrosive species to reach the metal surface.

The hypothesised mechanism of the effect of seawater composition on the SCC behaviour of anodized Al‐alloys depended on the concentration of sulphate ions and the stress level remains yet to be confirmed.

The selection of suitable anodic coatings for the protection of aluminium alloys against stress corrosion cracking depends on the composition of the marine environment.

The paper provides information regarding the influence of sulphate ions on the anticorrosive properties of electrolytically prepared anodic coatings on aluminium alloys.

Describes the analysis of the logistics system of a supplier of anhydrous sodium sulphate to the Australian market. This examination considered the total cost and customer service implications of the present supply of this bulk product from one Canadian and US west coast source, its unloading at three Australian ports and subsequent distribution to customers in major Australian markets. Examines a number of options for restructuring anhydrous sodium sulphate logistics including the use of a single inbound port and the establishment of a single centralised distribution centre. In addition to these major structural options, examines a number of possible improvements which could be applied to any of them: the installation of a centralised national order processing operation; the reduction of national inventory holdings; changes in the terms of trade; modified relations with distributors; and improved interrelationships with customers. Uses a spreadsheet model to examine these options.

The purpose of this study is to optimize single-bath dyeing process of wool and silk blend, to achieve uniform colour strength for both the fibre after the dyeing process. Due to different absorption characteristics of wool and silk, two-stage dyeing is preferred in the industry. If the fibres are dyed together, the wool fibre becomes darker and the silk fibre becomes lighter after the dyeing process. Solid dyeing effect can be achieved using a single-bath dyeing process.

The dye-acceptor sites in the wool fibre are first blocked using one commercial syntan Mesitol HWS. Then, the syntan-treated wool and silk fibres (80:20 blend ratios) are dyed with Telon Navy AMF dyes in the presence of sodium sulphate. To explore the influence of Syntan, sodium sulphate and the experimental conditions on the dyeing process and to optimize the process, central composite design (CCD) of four factors and three levels was tested.

The design process is optimized using four independent variables: Mesitol HWS concentration, sodium sulphate concentration, pH of dyebath and temperature of dyeing. Three levels of Mesitol HWS concentration (5, 10 and 15 per cent), sodium sulphate concentration (10, 20 and 30 per cent), pH (2.5, 4 and 5.5) and temperature of dyeing (70, 80 and 900°C) were selected for this study. These variables are optimized using response surface regression equation of the ratio of K/S wool and K/S silk. The predicted equation matched well with the experimental data.

This paper proposes the use of one-bath dyeing process of wool and silk blend fabric to reduce the dyeing time, process step and to save water.

Besides with a large amount of Na⁺ and Cl⁻ ions in seawater, the presence of Mg⁺² and SO₄⁻² ions builds more complex corrosion mechanism. This paper aims to investigate the corrosion of embedded reinforcement in concrete with the environment of both Cl⁻ and SO₄⁻² anions associated Mg⁺² cation.

The concrete specimens were prepared by using ordinary Portland cement (OPC), and OPC blended with metakaolin (MK) for water to cementitious material ratio (w/cm) 0.48 and 0.51. The concrete mixes were contaminated with the addition of MgCl₂ alone and combined MgCl₂ and MgSO₄ in mix water. Reinforcement corrosion was evaluated by half-cell potential and corrosion current densities (I_corr) at regular intervals. Moreover, the influence of cementitious material type, salt type and w/cm ratio on electrical resistivity of concrete was also investigated. The statistical models were developed for electrical resistivity as a function of calcium to aluminium content ratio, compressive strength, w/cm ratio and age of concrete.

Although the corrosion initiation time increases in the concomitant presence of MgSO₄ and MgCl₂ as internal source compared to MgCl₂, I_corr values are higher in both OPC and MK blended concrete. However, electrical resistivity decreased with addition of MgSO₄. MK blended concrete performed better with increased resistivity, corrosion initiation time and decreased I_corr values.

This study reports statistical distributions for scattered I_corr of rebar in different concrete mixtures. Stepwise regression models were developed for resistivity by considering the interactions among different variables, which would help to estimate the resistivity through basic information.

So far as the various British Food and Drugs Acts are concerned, the meaning of “sophistication” or “adulteration,” which includes “substitution,” is now very wide.

Investigates anaerobic two‐stage treatment of tannery wastewater. This results in a mean chemical oxygen demand (COD) removal of 60 per cent for tannery B and more than 70 per cent for tanneries A and C with COD_o = 5,710mg l^‐1 and mean detention time held at 3.5 days. Gas production was small, rating an estimated 75 l kg‐1 COD_o with COD_o = 5,710mg l^‐1. Tests simultaneously the influence of quality and quantity of wastewater on COD removal and gas production (multiple regression). Finds significant inhibitory effects were caused by chloride on gas volume and by sulphate on COD removal. Chromium showed no significant effect. Dosage of ferric chloride for removal of the toxic sulphide effected a decrease in gas volume and had no effect on COD removal (analysis of variance).

This paper aims to select a type of mordant from aluminium salts, namely, aluminium sulphate, aluminium nitrate and polyaluminium chloride (PAC) with the lowest potential for contamination so that their use will minimise pollution from natural dye waste. It also aims to determine the pollution value of natural dye immersion waste from jackfruit wood extract, secang wood, mangsi fruit and several synthetic dyes, to identify potential environmental pollution.

Dyeing with natural dyes was performed by exhaust at room temperature by the pre-mordant method, while with synthetic dyes it was performed by exhaust according to the dyeing procedure (reactive, vat and naphthol). The groundwater, mordant solutions, natural dye extract and the waste-water from the natural and synthetic dyes were then tested to determine their biological oxygen demand (BOD₅), chemical oxygen demand (COD), total suspended solids (TSS), pH, Al and heavy metal contents such as chromium (Cr), copper (Cu), cadmium (Cd), nickel (Ni), cobalt (Co) and lead (Pb).

Aluminium sulphate had the lowest pollution load while PAC had the highest, as aluminium sulphate had a higher BOD₅/COD ratio (0.62–0.67) than aluminium nitrate (0.56–0.64) or PAC (0.44–0.54). The dyeing waste from the three natural dyes contained an acidic pH of 3.5–4.2, Al of 75.280–621.34 mg/L, Cr of 0.154–0.215 mg/L and Cu of 0.035–0.072 mg/L. The values of TSS, COD and BOD₅ are higher than the quality standards of the waste but are environmentally friendly because the ratio of the BOD₅/COD values from the waste ranges from 0.44–0.67.

The findings indicate that as a mordant, aluminium sulphate results in lower pollution loads than aluminium nitrate and PAC. However, all three mordants contain Cr and Cu, albeit in negligible concentrations. Therefore, it is recommended that future studies strive to identify a mordant that has lower pollution loads and does not contain metals but can increase dyeing results to satisfy consumer requirements. It is the hope that, with the discovery of a new mordant, natural dyes will be the solution for the heavy metal pollution caused by synthetic dyes.

The use of environmentally-friendly mordants and natural dyes in the Indonesian textile and batik industry will give rise to superior quality eco-textile and eco-batik products. Such environmentally-friendly and high-quality products will not only increase competition and consumer interest but increase product sales as well which will, in turn, increase incomes and the economy. Additionally, an increase in the use of natural dyes by the textile and batik industry will serve as additional income to the communities and farmers from which the raw materials for the natural dyes are sourced thereby creating jobs and increasing welfare.

As environmentally-friendly mordants and natural dyes replace the hazardous and toxic materials currently used in the textile and batik industry, it guarantees the health and safety of its consumers and workers. Furthermore, as the waste-water produced is biodegradable, it reduces river and groundwater pollution. It is, therefore, expected that this information will not only lead to a shift in attitude within the textile and batik industries but the adoption of environmentally-friendly materials, for the sake of the environment, as well as the development of eco-textile and eco-batik products.

Aluminium sulphate is a mordant type of aluminium salt with a lower potential for contamination than aluminium nitrate and PAC. However, PAC has been discovered to be a mordant for natural dyes, as has the fruit of the mangsi shrub, which has recently been discovered as a naturally occurring blue dye.