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This paper aims to quantify atmospheric corrosion by image analyses. The corrosion extent, form and distribution of corrosion product on Q235B and T91 steels exposed to a Zhoushan marine atmosphere over one year are characterized by image analysis.

Image analysis of corrosion images were achieved using the gray value, wavelet analysis and fuzzy Kolmogorov–Sinai (K–S) entropy.

As corrosion becomes extensive, the gray value of corrosion images decreases, and the energy value of nine subimages after wavelength decomposition decreases. Fuzzy K–S entropy increases as localized corrosion propagates but decreases as uniform corrosion spreads.

The methods proposed in this work open a new way for fast corrosion evaluation of metallic materials exposed to atmospheric conditions.

The salinity of the oilfield produced water has a significant effect on steel corrosion. The purpose of this paper is to study the influence of salinity on corrosion behavior of X60 steel and it also provides basic for material selection of gas wells with high salinity.

The weight loss experiment was carried out on steel with high temperature and high pressure autoclave. The surface morphology and composition of corrosion scales were studied by means of scanning electron microscopy, energy dispersive spectroscopy and X-ray diffractometry.

The results show that as salinity increases, the corrosion rate of X60 steel will gradually experience a rapid decline stage and then a slow decline stage. X60 steel is mainly exhibiting uniform corrosion in the first rapid decline stage and pitting corrosion in the second slow decline stage. The increase in salinity reduces gas solubility, which, in turn, changes the morphology and density of the corrosion scales of X60 steel. At low salinity, loose iron oxides generated on the surface of the steel, which poorly protects the substrate. At high salinity, surface of the steel gradually forms protective films. Chloride ions in the saline solution mainly affect the structure of the corrosion scales and initiate pitting corrosion. The increased chloride ions lead to more pitting pits on the surface of steel. The recrystallization of FeCO₃ in pitting pits causes the corrosion scales to bulge.

The investigation determined the critical concentration of pitting corrosion and uniform corrosion of X60 steel, and the new corrosion mechanism model was presented.

This paper aims to investigate the effect of alternating current (AC) on corrosion, it is not yet clear about the exact mechanism of the corrosion induced by AC. Previous reports indicated that AC corrosion was similar to the effect of continuous cathodic and anodic polarization on the corrosion process of the metals. Wan et al. studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution.

This study attempted to understand the AC-induced corrosion by imposing the half-cycle AC on the X80 pipeline steel in an acid bicarbonate solution. The AC corrosion mechanism was determined by weight loss and potentiodynamic polarization curve measurements, as well as surface characterization.

The results show that the positive half-cycle AC accelerated the uniform corrosion in the NaHCO3 solution, the negative half-cycle AC would decrease the uniform corrosion and local corrosion was increased and some Ca and Mg deposited on the surface of X80 steel, so the corrosion rate decreased by negative half-cycle AC. The corrosion product was composed of α-FeOOH under the application of positive half-cycle AC. The oxygen reduction led to a local increase of pH near the electrode surface and led to the formation of α-FeOOH, which enhanced the protectability of corrosion products.

Researchers studied the effect of negative half-wave AC on stress corrosion cracking behavior and mechanism of X80 pipeline steel in near-neutral solution. However, the AC behavior and corrosion mechanism in acid solution are unknown. So to make clear about the corrosion behavior of metals in different polarization states and the mechanism involved, diode technology was used to research the AC corrosion, half-wave AC was applied on the metals after the full-wave rectified.

The purpose of this paper is to investigate the effects of incorporating SiC nanoparticles into ZA-27 alloy on the corrosion behavior of the produced nanocomposites.

The nanocomposites were fabricated by a double-step stir casting technique. The corrosion behavior of the produced ZA-27 nanocomposites was investigated using potentiodynamic polarization test in a 3.5% NaCl medium. The surfaces of the fabricated metal matrix nanocomposites (MMNCs) before and after corrosion tests were imaged and analyzed using an optical microscope and scanning electron microscope (SEM) to examine the microstructure of the produced MMNCs and morphology of its surface before and after corrosion.

The corrosion test results reveal that the fabricated nanocomposites have an improved uniform corrosion resistance when compared with the corresponding monolithic matrix alloy. On the other hand, the base monolithic alloy is less susceptible to the pitting phenomenon than the nanocomposites. The electrochemical results are consistent with the pits morphology of the corroded MMNCs.

This study highlights the use of SiC nano-particulates for controlling of ZA alloy corrosion behavior and enhancing its anti-corrosion characteristics which will open a new route for industrial applications. The corrosion behavior of ZA-27 alloy-based composite reinforced with different weight fractions of nano-SiC particles have an improved uniform corrosion behavior as compared with the corresponding matrix alloy.

Reliable estimations of the extent of corrosion and time required to reach specific safety limits are crucial for assessing the reliability of aging reinforced concrete (RC) bridges. Engineers and decision-makers can use these figures to plan suitable inspection and maintenance operations.

Analytical, empirical and numerical approaches for estimating the service life of corroded RC structures were presented and compared. The concrete cover cracking times, which were predicted by the previously proposed analytical models, were compared with the experimentally obtained cracking times to identify the model/s for RC bridges. The shortcomings and limitations of the existing models are discussed.

The empirical models typically depend on the rate of corrosion, diameter of steel reinforcement and concrete cover depth and based on basic mathematical formula. In contrast, the analytical and numerical models contain the strength and stiffness properties of concrete as well as type of corrosion products and incorporate more complex mechanical factors. Four existing analytical models were analyzed and their performance was evaluated against existing experimental data in literature. All the considered analytical models were assumed thick-walled cylinder models. The maximum difference between observed cracking time from different test data and calculated cracking time using the developed models is 36.5%. The cracking times extend with increase in concrete cover and decrease with corrosion current density. The development of service life prediction models that considers factors such as heterogeneity of concrete, non-uniform corrosion along rebar, rust production rate and a more accurate representation of the corrosion accommodating region are some of the areas for further research.

Outcome of this paper partially bridge the gap between theory and practice, as it is the basis to estimate the serviceability of corrosion-affected RC structures and to propose maintenance and repair strategies for the structures. For structural design and evaluation, the crack-width criterion is the greatest practical importance, and structural engineers, operators and asset managers should pay close attention to it. Additionally, repair costs for corrosion-induced serviceability failures, particularly concrete cracking and spalling, are significantly higher than those for strength failures. Therefore, to optimize the maintenance cost of RC structures, it is essential to precisely forecast the serviceability of corrosion-affected concrete structures. The lifespan of RC structures may be extended by timely repairs. This helps stake holders to manage the resources.

In order to improve modeling of corrosion-induced cracking, important areas for future research were identified. Heterogeneity properties of concrete, concept of porous zone (accommodation effect of pores should be quantified), actual corrosion morphology (non-uniform corrosion along the length of rebar), interaction between sustain load and corrosions were not considered in existing models. Therefore, this work suggested for further researches should consider them as input and develop models which have best prediction capacity.

This work has positive impact on society and will not affect the quality of life. Predicting service life of structures is necessary for maintenance and repair strategy plans. Optimizing maintenance strategy is used to extend asset life, reduce asset failures, minimize repair cost, and improve health and safety for society.

The degree of accuracy and applicability of the existing service life prediction models used for RC were assessed by comparing the predicted cracking times with the experimentally obtained times reported in the literature. The shortcomings of the models were identified and areas where further research is required are recommended.

The purpose of this study is to investigate the initial corrosion behavior of pure Mg, AZ31 and AZ91 alloys in phosphate buffer solution (PBS) and to characterize the features in corrosion type and resistance of the corrosion product layer.

The scanning electron microscopy, equipped with energy-dispersive spectroscopy, X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy have been used to characterize the as-corroded samples. Besides, the Mg²⁺ concentration in PBSs has been determined by inductively coupled plasma atomic emission spectrum.

It has been found that pure Mg suffers pit corrosion, and AZ31 initially undergoes pit corrosion and then uniform corrosion dominates with an extended immersion duration. However, AZ91 exhibits the uniform corrosion with the highest corrosion rate among the three materials. Besides, the corrosion product layer on AZ31 has the best compactness and corrosion resistance.

The findings add depth in understanding the corrosion of pure Mg and its alloys in PBS and also have guiding significance in exploring the effects by alloyed elements to develop new biomaterials with better performance.

The purpose of this study is to explore the corrosion behaviors of tube pile steel with the addition of 0.2 per cent Cu and 0.2 per cent Cu-0.2 per cent Cr in half-immersion environment.

The electrochemical corrosion behaviors of tube pile steel with different alloy-elements addition were identified using the polarization curve method and electrochemical impedance spectroscopy technique. Corrosion product and its morphology were analyzed by X-ray diffraction, optical microscope and scanning electron microscopy.

Results indicate that the most serious corrosion occurred in the liquid-air interface zone due to the higher oxygen and water concentration. With the addition of Cu and Cu-Cr, pits were getting smaller and denser, transforming the corrosion type from pitting corrosion to uniform corrosion gradually. Rust layer containing Cu/Cr tended to compact and inhibited the anodic process, while the enrichment of Cu/Cr in rust layer decelerated the dissolution of substrate, thus the expanding of pits was suppressed.

This paper studied the corrosion behaviors of liquid-air interface zone of tube pile steel and verified the transformation of corrosion type with adding Cu, Cu/Cr elements.

Pipelines are seriously corroded due to the close distance between pipelines and high voltage transmission lines. The purpose of this paper is to study the influence of alternating current (AC) on corrosion behavior of X80 pipeline steel in coastal soil solution.

The corrosion behavior of X80 steel under different AC densities in coastal soil solution was investigated by electrochemical measurements and image processing technology. Furthermore, a quantitative description model of AC corrosion through fractal dimension of corrosion image was established.

The results show that under low AC density the X80 steel is mainly uniform corrosion, and once AC density reaches 150 A/m², the corrosion morphology gradually turns to pitting corrosion with irregular circle. For another aspect, the fractal dimension of corrosion images shows that the two/three-dimensional fractal dimension increase with the increase of AC density, presenting a linear and an exponential relationship respectively. In addition, the variation of the three-dimensional fractal dimension is the same as that of average corrosion rate. The threshold of the increasing trend of fractal dimension as well as corrosion type is 150 A/m².

The investigation provides a quantitative method to describe AC corrosion morphology through fractal dimension. Furthermore, the method is of benefit to process corrosion images automatically.

The purpose of this investigation was to study the function mechanisms of a corrosion inhibitor package used for martensitic stainless steel tubulars in acid solution at high temperatures.

The inhibition performance was evaluated by means of an acid corrosion test at high temperature and high pressure, and the functional mechanism of the inhibitor package at different temperatures was investigated using polarization curve and electrochemical impedance spectroscopy measurements.

The results showed that the corrosion inhibitor package chosen for high-temperature and high-pressure gas well applications was very suitable for use with 13Cr super martensitic stainless steel. At lower temperatures, the function mechanism of the corrosion inhibitor package was characterized as a type of negative catalytic effect. As the temperature was increased, the effect of the intensifier in the package became more significant and the function mechanism changed to be the geometric covering effect type.

This study has the important practical value for guiding the oil field to conduct reasonable screening and using the acidizing corrosion inhibitor for martensite stainless steel tubulars.

Several experimental and numerical studies were performed in the past to estimate buckling capacity of corroded tubular members. However, the effect of initial imperfections has not been properly considered in most of these earlier proposed formulas. Therefore, the main objective of this paper is to propose an accurate analytical formula to determine the buckling capacity of patched corroded tubular members.

Tubular members with initial geometrical imperfections can be regarded as beam-columns because of the combination of axial load and bending moment. The proposed formula is derived for a rectangular corrosion patch. The proposed formula is verified with results from finite element analysis of corroded tubular members and experimental results. The formula is also applied to an existing offshore jacket structure to highlight its significance and applicability. It is found that the buckling capacity of jacket members in splash zone reduces significantly with ageing. This reduction is around 29 and 14% for the selected brace and leg member respectively, during the design life. Finally, it is concluded that corrosion reduces the buckling capacity significantly and the proposed formula can be easily applied by practicing engineers to give an accurate and slightly conservative estimate the remaining buckling capacity.

The main finding is the new formula which accurately and conservatively estimate the buckling capacity of corroded tubular members. The proposed formula considers the secondary effect of both initial geometrical imperfections and shifting of centroid because of corrosion.

The proposed new formula is unique and original in that it considers both secondary effects from geometrical imperfections, reduction of cross-section from corrosion wastage and shifting of centroid because of corrosion. Finally, it is concluded that corrosion reduces the buckling capacity significantly and the proposed formula can be easily applied by practicing engineers to conservatively estimate the remaining buckling capacity and verify if further, more advanced estimations are needed.