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1 – 10 of over 4000Jie Zhang, Jing Liu, Qian Hu, Feng Huang, ZhaoYang Cheng and JunTao Guo
The aim of this paper was to clarify the influence of tensile stress on the electrochemical behavior of X80 steel in a simulated acid soil solution and attempt to understand…
Abstract
Purpose
The aim of this paper was to clarify the influence of tensile stress on the electrochemical behavior of X80 steel in a simulated acid soil solution and attempt to understand mechanistic aspects of the corrosion behaviors of X80 under these conditions.
Design/methodology/approach
The electrochemical behavior of X80 steel at various tensile stresses was investigated in a simulated acid soil solution using electrochemical impedance spectroscopy, potentiodynamic scan measurements and surface analysis techniques.
Findings
The results show that as tensile stress was increased, the open-circuit potential decreased, the reaction activity increase, the reaction resistance (Rct)value became smaller by degrees, the corrosion product film resistance (Rf) first decreased and then increased and polarization current densities changed conversely. The corrosion product film was compact and continuous under the low stress, whereas it was relatively loose under high-stress conditions. Tensile stress promotes the movement of dislocations, which become active points when they move to the steel surface. The increase in the number of active points enhances the anodic dissolution rate and promotes the formation of corrosion product film whose blocking effect can decrease the dissolution rate. The corrosion rate of the specimen is determined by these two effects.
Originality/value
This research provides an essential insight into the mechanism of the electrochemical behavior of X80 steel in acid soil environments.
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Keywords
Yue Wang, Dan Wang, Meng Zhao, Fei Xie and Kaili Zhang
The purpose of this study is to find the multi-factor influence law of stress, strain rate and sulfate-reducing bacteria (SRB) on X70 pipeline steel in a simulated solution of sea…
Abstract
Purpose
The purpose of this study is to find the multi-factor influence law of stress, strain rate and sulfate-reducing bacteria (SRB) on X70 pipeline steel in a simulated solution of sea mud and the order of influence of the three factors on X70 steel to develop a scientific basis for pipeline corrosion protection.
Design/methodology/approach
This paper studied the effects of stress, strain rate and SRB on the X70 pipeline steel corrosion behavior in simulated sea mud solution through orthogonal testing, electrochemical experiments and morphological observations.
Findings
The results of this study showed that stress proved to be the most relevant element for corrosion behavior, followed by SRB and strain rate. At high stresses (301 MPa and 576 MPa), stress dominated the corrosion behavior of X70 pipeline steel. However, at low stress (82 MPa), SRB played the most important role.
Originality/value
Subsea pipelines are in a very complex environmental regime that includes stress, strain rates and SRB, which often cause pipeline pitting and perforation. However, most scholars have only looked into the influence of single factors on metal corrosion. So, the single-factor experimental results of previous studies could hardly be applied to actual working conditions. There is an urgent need to understand the multi-factor influence law of stress, strain and SRB acting together on the pipeline corrosion behavior, especially to determine the dominant factor.
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Corrosion cracking A metal fails due to corrosion fatigue if it cracks while being subjected to repeated or alternating tensile stresses in a corrosive environment. If the…
Abstract
Corrosion cracking A metal fails due to corrosion fatigue if it cracks while being subjected to repeated or alternating tensile stresses in a corrosive environment. If the corrosive environment is removed, the metal will not fail through fatigue, even after a very high number of cycles, providing the tensile stress is below the fatigue limit.
Part I of this article, published last month, was concerned chiefly with a thermodynamic approach to the subject, and covered such aspects as borderline corrosion, the corrosion…
Abstract
Part I of this article, published last month, was concerned chiefly with a thermodynamic approach to the subject, and covered such aspects as borderline corrosion, the corrosion of crystals, and the effect of stress on chemical attack. Also included was a survey of types of metal deformation, and data regarding the properties of grain boundaries and the effects of temperature and rate of loading. Now, in Part 2, the author considers the subject of stress corrosion, including the development of stress by the corrosion product.
Sixian Rao, Changwei Zhang, Fei Zhao, Lei Bao and Xiaoyi Wang
This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.
Abstract
Purpose
This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.
Design/methodology/approach
Corrosion of metals would be aggravated by CDI under applied stress. Notably, the presence of nitrogen in 316LN austenitic stainless steel (SS) would enhance the corrosion resistance compared to the nitrogen-absent 316L SS. To clarify the CDI behaviors, electrochemical corrosion experiments were performed on 316LN specimens under different applied stress levels. Complementary analyses, including three-dimensional morphological examinations by KH-7700 digital microscope and scanning electron microscopy coupled with energy dispersive spectroscopy, were conducted to investigate the macroscopic and microscopic corrosion morphology and to characterize the composition of corrosion products within pits. Furthermore, ion chromatography was used to analyze the solution composition variations after immersion corrosion tests of 316LN in a 6 wt.% FeCl3 solution compared to original FeCl3 solution. Electrochemical experiment results revealed the linear decrease in free corrosion potential with increasing applied stress. Electrochemical impedance spectroscopy results indicated that high tensile stress level damaged the integrity of passivation film, as evidenced by the remarkable reduction in electrochemical impedance. Ion chromatography analyses proved the concentrations increase of NO3− and NH4+ ion concentrations in the corrosion media after corrosion tests.
Findings
The enhanced corrosion resistance of 316LN SS is attributable to the presence of nitrogen.
Research limitations/implications
The scope of this study is confined to the influence of tensile stress on the electrochemical corrosion of 316LN at ambient temperatures; it does not encompass the potential effects of elevated temperatures or compressive stress.
Practical implications
The resistance to stress electrochemical corrosion in SS may be enhanced through nitrogen alloying.
Originality/value
This paper presents a systematic investigation into the stress electrochemical corrosion of 316LN, marking the inaugural study of its impact on corrosion behaviors and underlying mechanisms.
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J. Brettle and S. Orman
Introduction The ever increasing demands made on materials by advanced technology has led, in recent years, to a greater awareness of the importance of mechano‐chemical behaviour…
Abstract
Introduction The ever increasing demands made on materials by advanced technology has led, in recent years, to a greater awareness of the importance of mechano‐chemical behaviour. These may be defined as the synergistic effect of mechanical forces and chemical reactions on the material. Although possibly interrelated, three classes of mechano‐chemical reactions have been identified as; stress‐corrosion (SCC), corrosion fatigue (CF) and hydrogen embrittlement. SCC has become one of the ‘in’ subjects of corrosion science during the last decade, while the importance of CF has emerged comparatively recently. In a review of the national corrosion and protection scene in 1970, it was revealed that 62 postgraduate research workers, representing 21% of the total effort in the corrosion and protection field, were involved in mechano‐chemical corrosion studies1. The bulk of these were working on SCC. This large research effort has not resulted in a standardisation of test methods nor, despite several attempts, in a unifying theory for SCC2. The newcomer to the field is faced with a bewildering variety of tests of varying complexity and validity. The supporters of each type of test tend to make exaggerated claims particularly when the test they are advocating is the only one which has caused a particular alloy‐environment system to exhibit SCC.
Introduction Visual inspection or observation at low magnification with an optical microscope has been of great help in analysing fracture surfaces. Optical microscopy, however…
Abstract
Introduction Visual inspection or observation at low magnification with an optical microscope has been of great help in analysing fracture surfaces. Optical microscopy, however, has distinct limitations, such as low resolution and small depth of field. The transmission electron microscope does not have these limitations.
Gang Wang, Yue Zhang, Chen Gao, GuangTao Xu and MingHao Zhao
The purpose of this paper is to investigate, the effects of residual stress and microstructure on the corrosion behaviour of carburised 18CrNiMo7-6 steel in a 3.5% NaCl aqueous…
Abstract
Purpose
The purpose of this paper is to investigate, the effects of residual stress and microstructure on the corrosion behaviour of carburised 18CrNiMo7-6 steel in a 3.5% NaCl aqueous solution.
Design/methodology/approach
The electrochemical tests were conducted using an electrochemical workstation with a three-electrode system in a 3.5% NaCl aqueous solution, the residual stress of each working face was measured by a high-speed residual stress analyser, and microstructure of different carburised layers were observed scanning electron microscopy. Finally, the effect of carbon content, microstructure and residual stress on the corrosion behaviour of the steel was discussed.
Findings
The results showed that the residual compressive stress in the carburised layer initially increased and subsequently decreased with increasing depth of the carburised layer, reaching stability in the matrix layer. The electrochemical tests before and after stress reduction showed that the electrochemical impedance and the electrochemical potential increased with the reduction of residual compressive stress.
Originality/value
The residual compressive stress in the carburised layer initially increases and subsequently decreases with increasing carburised layer depth. The electrochemical impedance and the electrochemical potential increased with the reduction of residual compressive stress. The general relationship between electrochemical potential and residual stress was established.
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Yanbao Guo, Zhenyuan Liu, Hui Huang, Deguo Wang and Renyang He
The corrosion of buried steel pipelines is becoming more serious because of stress corrosion, stray current corrosion and other reasons. This paper aims to study the various…
Abstract
Purpose
The corrosion of buried steel pipelines is becoming more serious because of stress corrosion, stray current corrosion and other reasons. This paper aims to study the various alternating current (AC) interference densities on the stress corrosion cracking behaviors of X80 steel samples under cathodic protection (CP) in the simulated soil electrolyte environment by using an electrochemical method.
Design/methodology/approach
The change of corrosion rate and surface morphology of the X80 steel samples at various AC current densities from 0 to 150 A/m2 or CP potential between −750 and −1,200 mV in the soil-simulating environment was revealed by the electrochemical methods and slow strain rate testing methods.
Findings
The results revealed that with the increase of interference density, the corrosion potential of the X80 steel samples shifted to the negative side, and the corrosion pitting was observed on the surface of the sample, this may cause a danger of energy leak. Moreover, the corrosion rate was found to follow a corresponding change with the stress–strain curve. Besides, with the introduction of the CP system, the corrosion rate of the X80 steel working electrode decreased at a low cathodic potential, while showed an opposite behavior at high cathodic potential. In this study, the correlation between AC stray current, cathodic potential and stress was established, which is beneficial to the protection of oil and gas pipeline.
Originality/value
Investigation results are of benefit to provide a new CP strategy under the interference of AC stray current corrosion and stress corrosion to reduce the corrosion rate of buried pipelines and improve the safety of pipeline transportation.
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Wayan Sutika Ananta, Wahyu Setiawan, Hari Shuko Widodo and Dwi Kirmanto
Presents a model of how an Indonesian aircraft manufacturer, Industri Pesawat Terbang Nusantara (PT. IPTN), evaluates the causes of stress corrosion in CN‐235 aircraft and how it…
Abstract
Presents a model of how an Indonesian aircraft manufacturer, Industri Pesawat Terbang Nusantara (PT. IPTN), evaluates the causes of stress corrosion in CN‐235 aircraft and how it resolves these problems. Describes the different types of corrosion encountered and how it analyses each.