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Article
Publication date: 1 November 2014

C.H. Kwong, S.P. Ng and C.W. Kan

Plasma treatment is becoming increasingly popular in enhancing the hydrophobicity of synthetic textiles. In recent years, the study of surface hydrophobisation by means of plasma…

Abstract

Plasma treatment is becoming increasingly popular in enhancing the hydrophobicity of synthetic textiles. In recent years, the study of surface hydrophobisation by means of plasma treatment, under low or atmospheric pressure, has drawn a great deal of attention. A large amount of research has reported on the possibility of applying this technique with merits that include a dry process, reduced pollution, a single step treatment, etc. In this regard, this paper reviews recent approaches on enhancing the hydrophobicity of synthetic textiles by means of plasma treatment. The basic working principle of generating plasma to enhance hydrophobicity is explained. Both low and atmospheric plasma treatments are introduced. A higher cost is usually required for low pressure plasma because of the investment on a vacuum chamber. On the other hand, carrier gas is required for atmospheric plasma treatment, which is not the case for low pressure plasma. The experimental set up and the chemicals involved in the processes are discussed. In order to enhance surface hydrophobicity, fluorocarbons are always applied, such as perfluoroalkylacrylate, perfluorodecaline and tetrafluoroethylene.

Details

Research Journal of Textile and Apparel, vol. 18 no. 4
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 7 August 2021

Bochun Xu, Nan Zou, Yunhao Jia, Chao Feng, Jiajia Bu, Yu Yan and Zhipeng Xing

The purpose of this paper is to study the effect of micro-nano surface texture on the corrosion resistance of a titanium alloy and investigate the correlation between corrosion…

Abstract

Purpose

The purpose of this paper is to study the effect of micro-nano surface texture on the corrosion resistance of a titanium alloy and investigate the correlation between corrosion resistance and hydrophobicity.

Design/methodology/approach

The surface of the Ti6Al4V alloy was modified by laser processing and anodizing to fabricate micro-pits, nanotubes and micro-nano surface textures. Afterward, the surface morphology, hydrophobicity and polarization curve of the samples were analyzed by cold field scanning electron microscopy, contact angle measurement instruments and a multi-channel electrochemical workstation.

Findings

The micro-nano surface texture can enhance the hydrophobicity of the Ti6Al4V surface, which may lead to better drag reduction to ease the friction of implants in vivo. Nevertheless, no correlation existed between surface hydrophobicity and corrosion resistance; the corrosion resistance of samples with nanotubes and high-density samples with micro-nano surface texture was extremely enhanced, indicating the similar corrosion resistance of the two.

Research limitations/implications

The mechanism of micro-dimples on the corrosion resistance of the micro-nano surface texture was not studied.

Practical implications

The density of micro-pits needs to be optimized to guarantee excellent corrosion resistance in the design of the micro-nano surface texture; otherwise, it will not fulfill the requirement of surface modification.

Originality/value

The influence of the micro-nano surface texture on the corrosion resistance, as well as the relationship between hydrophobicity and corrosion resistance of the titanium alloy surface, were systematically investigated for the first time. These conclusions offer new knowledge.

Details

Anti-Corrosion Methods and Materials, vol. 68 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 31 December 2018

A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan and Nasrudin Abd Rahim

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass…

Abstract

Purpose

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass substrate.

Design/methodology/approach

Two methods have been used to enhance the hydrophobicity on glass substrates, namely, surface modification by using low surface energy isooctyltrimethoxysilane (ITMS) solution and construction of rough surface morphology using Degussa P-25 TiO2 nanoparticles with simple bottom-up approach. The prepared sol was applied onto glass substrate using dip-coating technique and stoved in the vacuum furnace 350°C.

Findings

The ITMS coating with nano TiO2 pigment has modified the glass substrate surface by achieving the water contact angle as high as 169° ± 2° and low sliding angle of 0° with simple and low-cost operation. The solid and air phase interface has created excellent anti-dirt and self-cleaning properties against dilute ketchup solution, mud and silicon powder.

Research limitations/implications

Findings will be useful in the development of self-cleaning and anti-dirt coating for photovoltaic panels.

Practical implications

Sol method provides the suitable medium for the combination of organic–inorganic network to achieve high superhydrophobicity and optimum self-cleaning ability.

Originality/value

Application of blended organic–inorganic sol as self-cleaning and anti-dirt coating film.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 22 November 2018

A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan, Syed Shahabuddin and Nasrudin Abd Rahim

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Abstract

Purpose

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Design/methodology/approach

Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace.

Findings

The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C.

Research limitations/implications

Findings will be useful to develop superhydrophobic coatings with high thermal stability.

Practical implications

Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness.

Originality/value

Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 July 2014

Sushilkumar A. Jadhav, Roberta Bongiovanni, Daniele L. Marchisio, Daniela Fontana and Christian Egger

The purpose of the present study is to use an amino-functional polysiloxane for the surface modification of red iron oxide (Fe2O3) pigment particles for their improved dispersion…

Abstract

Purpose

The purpose of the present study is to use an amino-functional polysiloxane for the surface modification of red iron oxide (Fe2O3) pigment particles for their improved dispersion stability and hydrophobicity and to study the chemical interactions of polysiloxanes with the particle surface.

Design/methodology/approach

Surface-treated red Fe2O3 pigment particles were prepared by treatment of the particles with different quantities of the (aminopropylmethylsiloxane)-dimethylsiloxane copolymer in concentrated suspensions in water. The samples were analysed with different instrumental and spectroscopic techniques to study the interaction of the polysiloxane with the particle surface and the effect of the surface treatment of the particles on their dispersion stability and hydrophobicity.

Findings

Chemisorption of the amino-polysiloxane onto the surface of Fe2O3 particles resulted in stable layers which turned out to be helpful in improving greatly the dispersion stability of the particles as shown by the Static Light Scattering and Dynamic Light Scattering results. Formation of a polysiloxane coating onto the surface of the pigment particles was confirmed by studying the interactions of the polymer molecules with Fe2O3 surfaces by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy techniques.

Practical implications

The surface-treated red Fe2O3 particles with improved dispersion stability can be important components of various formulations in applications such as the colouring of the cement or inorganic pigment-based paint formulations.

Originality/value

The study provides mechanistic insights about the interactions of amino-polysiloxane with the red Fe2O3 particles. The process of surface modification of red Fe2O3 particles with the amino-functional polysiloxane showed increased hydrophobicity and dispersion stability which is an important requirement of the pigment-based formulations in real applications.

Details

Pigment & Resin Technology, vol. 43 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 March 2022

T. Thendral Thiyaku

The purpose of this study is to develop active package films using clove essential oil (CEO) and biodegradable polybutylene adipate terephthalate (PBAT) with varying weight…

Abstract

Purpose

The purpose of this study is to develop active package films using clove essential oil (CEO) and biodegradable polybutylene adipate terephthalate (PBAT) with varying weight percentages of SiO2 nanoparticles (SiO2NPs), as well as to investigate the mechanical, barrier, thermal, optical, surface hydrophobicity and antibacterial properties of PBAT incorporated with CEO as a natural plasticizer and SiO2NPs as a nanofiller.

Design/methodology/approach

PBAT-based bio-composites films were fabricated with different weight percentage of CEO (5% and 10%) and nanosilica (1% and 3%) by solution casting method. The packaging performance was investigated using universal testing machine, spectrophotometer, contact angle goniometer, oxygen and water vapour permeability tester. The antibacterial properties of PBAT-based nanocomposite and composite films were investigated using the ISO 22196 by zone of inhibition method.

Findings

The mechanical results exhibited that the addition of 10 Wt.% of CEO into PBAT increases the percentage of elongation, whereas, the addition of 3 Wt.% of SiO2NPs increases the tensile strength of the composite film. The presence of CEO in PBAT exhibits a good barrier against water permeability and SiO2NPs in the PBAT matrix help to reduce the opacity and hydrophobicity. The antimicrobial and thermal results revealed that the inclusion of 10 Wt.% of CEO and 3 Wt.% of SiO2NPs into PBAT polymer improved antimicrobial and thermal resistance properties.

Originality/value

A new PBAT-based active packaging film developed using natural plasticizers CEO and nanofiller SiO2 with a wide range of applications in the active food packaging applications. Moreover, they have good surface hydrophobicity, thermal stability, mechanical, barrier and antibacterial properties.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 2010

A. Awal, S.B. Ghosh, M. Rana, R.D. Hund and V. Rossbach

Temporary surface modifications of cotton fabrics with different water repellent agents by wet chemical treatments were examined. The hydrophobicity of the treated substrates was…

Abstract

Temporary surface modifications of cotton fabrics with different water repellent agents by wet chemical treatments were examined. The hydrophobicity of the treated substrates was determined by contact angle. The results show that the cotton fabric became hydrophobic. Three hydrophobic finishing agents were used in this study. The fabric properties were investigated in terms of moisture regain. Significant changes in properties were observed for the different finished materials. The surface investigation conducted by scanning electron microscopy (SEM) provided distinctive features of the untreated and treated fabric samples. Elementary analysis was also carried out on the substrate through energy dispersive x-ray (EDX) to confirm the presence of hydrophobic groups. In this study, a unique approach based on the double coating method was found to be a promising technique for modifying cotton fabrics temporarily and the hydrophobic finishing agent was easily removable which in turn would be beneficial for dyeing in supercritical CO2 medium. The method therefore offers great advantages in terms of regaining natural properties of cotton fabrics after suitable modifications.

Details

Research Journal of Textile and Apparel, vol. 14 no. 1
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 2 August 2019

Fupeng Cheng, Jinglong Cui, Shuai Xu, Hongyu Wang, Pengchao Zhang and Juncai Sun

The purpose of this paper is to improve the surface electrical conductivity and corrosion resistance of AISI 430 stainless steel (430 SS) as bipolar plates for proton exchange…

Abstract

Purpose

The purpose of this paper is to improve the surface electrical conductivity and corrosion resistance of AISI 430 stainless steel (430 SS) as bipolar plates for proton exchange membrane fuel cells (PEMFCs), a protective Nb-modified layer is formed onto stainless steel via the plasma surface diffusion alloying method. The effect of diffusion alloying time on electrochemical behavior and surface conductivity is evaluated.

Design/methodology/approach

In this work, the surface electrical conductivity and corrosion resistance of modified specimen are evaluated by the potentiodynamic and potentionstatic polarization tests. Moreover, the hydrophobicity is also investigated by contact angle measurement.

Findings

The Nb-modified 430 SS treated by 1.5 h (1.5Nb) presented a lower passivation current density, lower interfacial contact resistance and a higher hydrophobicity than other modified specimens. Moreover, the 1.5 Nb specimen presents a smoother surface than other modified specimens after potentionstatic polarization tests.

Originality/value

The effect of diffusion alloying time on electrochemical behavior, surface conductivity and hydrophobicity of modified specimen is evaluated. The probable anti-corrosion mechanism of Nb-modified specimen in simulated acid PEMFC cathode environment is presented.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 12 January 2024

Gobikannan Tamilmani, Venkhatesan D., Santhosh P., Tamilselvan M., Suryappa Jayappa Pawar and Amin Hirenbhai Navinbhai

This paper aims to study the combination of photochromic microcapsules, which use the ultraviolet (UV) rays for colour changing phenomena, and titanium oxide (TiO2) nanoparticles…

65

Abstract

Purpose

This paper aims to study the combination of photochromic microcapsules, which use the ultraviolet (UV) rays for colour changing phenomena, and titanium oxide (TiO2) nanoparticles (NPs), which block the UV rays by their photocatalytic activity in the sunlight on the cotton fabric.

Design/methodology/approach

The TiO2 NPs mixed with photochromic printing paste are used for coating on cotton fabric and further curing is performed in a one-step process. The photochromic pigment printed fabric impregnated in a liquid solution is processed in a two-step process with two variables such as 1% TiO2 and 2% TiO2. The characterization of samples was done with a UV transmittance analyser, surface contact angle, antimicrobial test and fabric physical properties.

Findings

The UV protection of TiO2-treated photochromic printed fabric was high and gives the ultraviolet protection factor rating of 2,000 which denotes almost maximum blocking of UV rays. The antibacterial activity of the one-step samples shows the highest 36 mm zone of inhibition (ZOI) against S. aureus (gram-positive) and 32 mm ZOI against E. coli (gram-negative) bacteria. The one-step sample shows the highest static water contact angle of 118.6° representing more hydrophobicity, whereas the untreated fabric is fully wetted (0.4°). In two-step processes, as the concentration of TiO2 increased, the antibacterial activity, UV blocking and hydrophobicity became better.

Originality/value

This work achieves the multifunctional finishes by using photochromic microcapsules and NPs in a single process as a first attempt. The results inferred that one-step sample has achieved higher values in most of the tests conducted when compared to all other sample.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 9 May 2023

Fuping Bian and Shudong Lin

This paper aims to investigate the effects on coatings performance in the epoxy silicone resin system owing to the existence of the different chain length of open-chain epoxy…

Abstract

Purpose

This paper aims to investigate the effects on coatings performance in the epoxy silicone resin system owing to the existence of the different chain length of open-chain epoxy monomer. In this paper, [4-Methylphenyl-(4–(2-methylpropyl) phenyl)]iodonium as photoinitiator was added into epoxy silicone resin by ultraviolet (UV)-cured polymerization to investigate the effects on coatings performance owing to the existence of the different chain length of open-chain epoxy monomer.

Design/methodology/approach

A simple hydrosilylation reaction was used to synthesize epoxy-based silicone prepolymers by using hydrogen-terminated polydimethylsiloxane, 1,2-epoxy-5-hexene, 1,2-epoxy-7-octene and 1,2-epoxy-9-decene as precursors.

Findings

The results revealed that the glass transition temperatures (Tg) and hydrophobicity increased with the chain length of open-chain epoxy monomer in the UV curable epoxy-based silicone coatings, and these films had excellent heat resistance, hydrophobicity, antigraffiti and ink removal properties.

Research limitations/implications

The cationic photocuring systems are not susceptible to the effect of oxygen inhibition. However, the limitation of cationic light curing process is that it requires a long curing time.

Originality/value

The coatings prepared via the UV curing approach can provide superior antismudge effects, and thus they are promising candidates for use in various industries, especially in fields such as antismudge coatings and antigraffiti coatings.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 334