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Article
Publication date: 2 April 2019

Xiaohong Yuan, Qufu Wei, Huizhen Ke, Zujian Huang and Dongsheng Chen

The purpose of this paper is to prepare structural colors of fabrics coated with Silver/Zinc Oxide (Ag/ZnO) composite films by magnetron sputtering and analyze the relationship…

Abstract

Purpose

The purpose of this paper is to prepare structural colors of fabrics coated with Silver/Zinc Oxide (Ag/ZnO) composite films by magnetron sputtering and analyze the relationship between the colors and the thickness of Zinc Oxide (ZnO) film in Ag/ZnO composite film and the photocatalytic property of the fabrics coated with Ag/ZnO composite film.

Design/methodology/approach

Ag/ZnO composite films deposited on polyester fabrics were prepared by magnetron sputtering technology. The structural colors of textiles coated with Ag/ZnO composite films and the relationship between the colors and Ag/ZnO composite films were analyzed, and the photocatalytic property of Ag/ZnO composite films was also discussed.

Findings

The results indicated that the colors varied with the thicknesses of the ZnO film in Ag/ZnO composite films. The reactive sputtering time of ZnO film was 5, 8, 10 and 14 min, respectively, and the colors of the corresponding fabrics were purple, blue, blue-green and yellow. Meanwhile, the polyester fabrics coated with Ag/ZnO composite films showed the excellent photocatalytic properties, and silver (Ag) films deposited under the ZnO films in Ag/ZnO composite films could also improve the photocatalytic activities of ZnO films, and the formaldehyde degradation rates was 77.5%, which was higher than the 69.9% for the fabrics coated only with the ZnO film.

Originality/value

The polyester fabrics coated with Ag/ZnO composite films not only created various structural colors using change the thicknesses of the ZnO film, but also achieved the multifuctionality, which will have a broad application prospect in textile fields.

Details

International Journal of Clothing Science and Technology, vol. 31 no. 4
Type: Research Article
ISSN: 0955-6222

Keywords

Article
Publication date: 21 October 2022

Longxiao Zhang and Ting Xie

The purpose of this paper is to explore the geometric parameter difference of the terrace-like structural transfer film under different working parameters [pressure and velocity…

93

Abstract

Purpose

The purpose of this paper is to explore the geometric parameter difference of the terrace-like structural transfer film under different working parameters [pressure and velocity (PV) values] and filled particle types (three fillers: SiO2, TiO2 and ZnO), and find the geometric parameter related to the wear of polytetrafluoroethylene (PTFE)-based composites.

Design/methodology/approach

PTFE composites were filled with SiO2, TiO2 and ZnO particles, and the morphology parameter of the PTFE composite transfer film under different PV values obtained from the rotary reciprocating pin-on-disk frictional tester was quantified by using a three-dimensional laser scanning microscope.

Findings

The results showed that the effective layer coverage rate and effective thickness of the transfer film had a good relationship with the wear of the three PTFE composites. On the whole, increasing the speed or load was helpful to increase the effective thickness of the three PTFE composite transfer films, but reduced the effective layer coverage rate. The greater the effective layer coverage rate and effective thickness of the transfer film, the better the wear resistance of the PTFE composites in the entire speed and load range.

Originality/value

This work will promote further understanding of the transfer film and lay a foundation for realizing its morphology regulation and improving the wear of the PTFE composites.

Details

Industrial Lubrication and Tribology, vol. 75 no. 1
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 5 January 2015

N. Patil, N.B. Velhal, R. Pawar and Vijaya Puri

The purpose of this article is to study the effect of ferrite content on electric, magnetic and microwave properties of screen-printed y(Ni0.4Co0.2Cd0.4Fe2O4) + (1 …

Abstract

Purpose

The purpose of this article is to study the effect of ferrite content on electric, magnetic and microwave properties of screen-printed y(Ni0.4Co0.2Cd0.4Fe2O4) + (1 − y)Pb(Zr0.52Ti0.48)O3 (y = 0.0, 0.15, 0.30, 0.45, 1.0) thick films on alumina.

Design/methodology/approach

Thick films of ferrite–ferroelectric composite on alumina substrate have been delineated using screen printing technique. The structural analysis was carried out using X-ray diffraction method and scanning electron microscopy. The DC electrical resistivity was measured using the two-probe method. The magnetic measurement was carried out using a vibrating sample magnetometer. Microwave absorption was studied in the 8-18 GHz frequency range by using the vector network analyzer (N5230A). The permittivity in the 8-18 GHz frequency range was measured by using voltage standing wave ratio slotted section method.

Findings

The formation of two individual ferrite–ferroelectric phases in composite thick films was confirmed by the X-ray diffraction patterns. The scanning electron microscope morphologies show the growth of cobalt-substituted nickel cadmium ferrite grains which are well dispersed in lead zirconium titanate matrix. The DC electrical resistivity increases with increase in ferrite content and decreases with increase in temperature. The present ferrite shows ferromagnetic nature and it increases saturation magnetization and coercivity of the composite thick films. Tuning properties are observed in the Ku-band and broadband X-band microwave absorption is observed in the composite thick films. The imaginary part of permittivity increases with an increase in ferrite content, which increases microwave absorption. The real part of microwave permittivity varied from 17 to around 22 with an increase in ferrite content and it decreases with frequency. The microwave conductivity, which increases with an increase in ferrite content, reveals the loss of polaron conduction, which supports the dielectric loss in the microwave region.

Originality/value

Electric, magnetic and microwave properties of screen-printed y(Ni0.4Co0.2Cd0.4Fe2O4) + (1 − y)Pb(Zr0.52Ti0.48)O3 (y = 0.0, 0.15, 0.30, 0.45, 1.0) composite thick films on alumina substrate is reported for the first time.

Details

Microelectronics International, vol. 32 no. 1
Type: Research Article
ISSN: 1356-5362

Keywords

Article
Publication date: 5 March 2018

Shu-hao Deng, Yu Wang and Xi Yang

The purpose of this paper is to improve the conductivity and processability of polyaniline (PANI).

Abstract

Purpose

The purpose of this paper is to improve the conductivity and processability of polyaniline (PANI).

Design/methodology/approach

The study opted for synthesis of the conductive PANI/polyvinyl alcohol (PVA) composite film, co-doped with 5-sulphosalicylic acid and sulphuric acid. Using an electrochemical method, a small amount of silver (Ag) was electrodeposited on the film. The PVA/PANI and PVA/PANI/Ag composite films were characterised by scanning electron microscope, X-ray diffraction and infrared. The composite deposition mechanism of the composite film was investigated by cyclic voltammetry for the first time.

Findings

The conductivity of the optimum PVA/PANI composite film reached 21.2 S · cm−1.Then, a small amount of Ag was deposited on the PVA/PANI film, and the conductivity significantly increased by 1250 S · cm−1. Through appropriate degree of stretching, the conductivity of the films was enhanced. The results indicate that uniform PVA/PANI fibres and dendritic Ag can combine to form complete three-dimensional conductive networks that exhibit better conductivity and mechanical properties. The cyclic voltammetry curves reveal that the dedoping potential of PANI was more negative than the reduction potential of Ag. Therefore, the procedure for the deposition of Ag on the PANI/PVA composite film cannot decrease the conductivity.

Practical implications

This paper for the first time described and revealed the effective and practical synthesis approach and composite mechanism to prepare multi-types metal-conductive polymer composites and improve the conductivity of a conductive polymer with a less expense and one-step electrochemical method.

Originality/value

This paper first explored galvanostatic oxidation to synthesise a PANI composite film to resolve the processability and conductivity of PANI by co-doped with mixed acids and deposited Ag on film. Furthermore, for the first time, the composite mechanism of metal and conductive polymer was studied.

Details

Pigment & Resin Technology, vol. 47 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 January 2016

M.Y. Zhang, L.Z. Liu, L. Weng, W.W. Cui and K.S. Hui

– The aim of this study was to fabricate polyimide (PI)/Al2O3 composite films via surface modification and ion exchange techniques, and examine their properties.

368

Abstract

Purpose

The aim of this study was to fabricate polyimide (PI)/Al2O3 composite films via surface modification and ion exchange techniques, and examine their properties.

Design/methodology/approach

The method involves hydrolyzing the PI film double surface layers in an aqueous potassium hydroxide (KOH) solution and incorporating aluminium ions (Al3+) into the hydrolyzed layers of the PI film via subsequent ion exchange, followed by a treatment of the Al3+-loaded PI films with an aqueous ammonia solution, which leads to the formation of Al(OH)3 in the surface-modified layers. After a final thermal annealing treatment in ambient air, the Al(OH)3 decomposes to Al2O3, and forms composite layers on both surfaces of the re-imidized PI film.

Findings

The PI/Al2O3 composite film obtained with a 6 hours of KOH treatment exhibited excellent thermal stability, good mechanical properties and better electric breakdown strength and corona-resistance properties than the pristine PI film.

Practical implications

The method for obtaining the composite films in this paper is worth consideration, but additional research will be needed. Furthermore, this method is of general importance for the fabrication of composite PI films with tailored properties.

Originality/value

This study showed that surface modification and ion-exchange techniques are powerful methodologies for the fabrication of PI/Al2O3 composite films.

Details

Pigment & Resin Technology, vol. 45 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 September 2013

Shibo Wang

– The purpose of this paper is to investigate the distribution and surface characteristic of transfer film of polyamide composites filled with ZnOw during traction rolling.

Abstract

Purpose

The purpose of this paper is to investigate the distribution and surface characteristic of transfer film of polyamide composites filled with ZnOw during traction rolling.

Design/methodology/approach

In this paper, the traction rolling tribological behavior of polyamide composites filled with ZnOw was studied with a twin-disc traction rolling tester. The topography of transfer film was observed with a three dimensional profiler. Meantime the thickness of transfer film was measured. The chemistry elements of transfer film were analyzed with EDS and XRD.

Findings

The results indicated that transfer film of composites patchily covered on the surface of counter disc, the amount of which increased with increasing cycles. The coverage and thickness of pure PA film increased against rolling cycles. However, the thickness of 15 wt.% ZnOw/PA film remained at 6 μm as the coverage rose against rolling cycles. Fe element was found in pure PA transfer film, which existed in Fe0 and FeO for chemical reaction between Fe and atmospheric oxygen. Transfer film of 15 wt.% ZnOw/PA composites included a little Zn and Fe element. Fe element existed as Fe0. Zn element existed as ZnO.

Originality/value

This paper presented the distribution and surface characteristic of transfer film during traction rolling.

Details

Industrial Lubrication and Tribology, vol. 65 no. 6
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 4 February 2022

Mona Saied, Abeer Reffaee, Shimaa Hamieda, Salwa L. Abd- El- Messieh and Emad S. Shafik

This study aims to get rid of non-degradable polyvinyl chloride (PVC) waste as well as sunflower seed cake (SSC) waste by preparing eco-friendly composites from both in different…

Abstract

Purpose

This study aims to get rid of non-degradable polyvinyl chloride (PVC) waste as well as sunflower seed cake (SSC) waste by preparing eco-friendly composites from both in different proportions to reach good mechanical and insulating properties for antimicrobial and antistatic applications.

Design/methodology/approach

Eco-friendly composite films based on waste polyvinylchloride (WPVC) and SSC of concentrations (0, 10, 20, 30 and 40 Wt.%) were prepared using solution casting method. Further, the effect of sunflower seed oil (SSO) on the biophysical properties of the prepared composites is also investigated. Fourier transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscope, mechanical, thermal, dielectric properties were assessed. Besides, the antimicrobial and biodegradation tests were also studied.

Findings

The crystallinity increases by rising SSC concentration as revealed by XRD results. Additionally, the permittivity (ε′) increases by increasing SSC filler and SSO as well. A remarkable increase in dc conductivity was attained after the addition of SSO. While raw WPVC has very low bacterial activity. The composite films are found to be very effective against staphylococcus epidermidis, staphylococcus aureus bacteria and against candida albicans as well. On the other hand, the weight loss of WPVC increases by adding of SSC and SSO, as disclosed by biodegradation studies.

Originality/value

The study aims to reach the optimum method for safe and beneficial disposal of PVC waste as well as SSC for antistatic and antimicrobial application.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 March 2022

T. Thendral Thiyaku

The purpose of this study is to develop active package films using clove essential oil (CEO) and biodegradable polybutylene adipate terephthalate (PBAT) with varying weight…

Abstract

Purpose

The purpose of this study is to develop active package films using clove essential oil (CEO) and biodegradable polybutylene adipate terephthalate (PBAT) with varying weight percentages of SiO2 nanoparticles (SiO2NPs), as well as to investigate the mechanical, barrier, thermal, optical, surface hydrophobicity and antibacterial properties of PBAT incorporated with CEO as a natural plasticizer and SiO2NPs as a nanofiller.

Design/methodology/approach

PBAT-based bio-composites films were fabricated with different weight percentage of CEO (5% and 10%) and nanosilica (1% and 3%) by solution casting method. The packaging performance was investigated using universal testing machine, spectrophotometer, contact angle goniometer, oxygen and water vapour permeability tester. The antibacterial properties of PBAT-based nanocomposite and composite films were investigated using the ISO 22196 by zone of inhibition method.

Findings

The mechanical results exhibited that the addition of 10 Wt.% of CEO into PBAT increases the percentage of elongation, whereas, the addition of 3 Wt.% of SiO2NPs increases the tensile strength of the composite film. The presence of CEO in PBAT exhibits a good barrier against water permeability and SiO2NPs in the PBAT matrix help to reduce the opacity and hydrophobicity. The antimicrobial and thermal results revealed that the inclusion of 10 Wt.% of CEO and 3 Wt.% of SiO2NPs into PBAT polymer improved antimicrobial and thermal resistance properties.

Originality/value

A new PBAT-based active packaging film developed using natural plasticizers CEO and nanofiller SiO2 with a wide range of applications in the active food packaging applications. Moreover, they have good surface hydrophobicity, thermal stability, mechanical, barrier and antibacterial properties.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 December 2018

Zhen Yan, Dong Jiang, Xiaoming Gao, Can Zhang, Ming Hu, Dapeng Feng, Jiayi Sun, Lijun Weng and Chao Wang

This paper aims to study the tribological behavior of the WS2/oil-impregnated porous polyimide (PPI) solid/liquid composite system, in which both PFPE (perfluoropolyether) and…

Abstract

Purpose

This paper aims to study the tribological behavior of the WS2/oil-impregnated porous polyimide (PPI) solid/liquid composite system, in which both PFPE (perfluoropolyether) and SiCH (silahydrocarbons) oils with different hydrocarbon chains were used, respectively. Lubricating mechanism of the composite system was also explored.

Design/methodology/approach

The tribological behaviors of the WS2 films against the PPI cylindrical pins before and after immersing oil were evaluated under different loads by a reciprocating-type ball-on-disc tribometer.

Findings

The composite system exhibited the low and stable friction coefficient after the running-in stage, and the lubricant oil played a positive effect. It was found that the WS2/PFPE composite system exhibited more excellent lubricating property, although sole SiCH far exceeds PFPE in lubrication. The abnormal phenomenon mainly resulted from the influence of the oil amount. XRD results on the wear track surfaces indicated that PFPE and SiCH oils with different hydrocarbon chains were likely to preferentially adsorb to the edge plane and basal plane of the WS2 crystals, respectively.

Originality/value

In previous studies, liquid lubricants were directly dripped or spin-coated on the solid lubricant surface. Based on its potential advantage in application, the tribological behavior and mechanism of the solid lubricating film/oil-impregnated PPI composite system were investigated in this study.

Details

Industrial Lubrication and Tribology, vol. 71 no. 3
Type: Research Article
ISSN: 0036-8792

Keywords

Article
Publication date: 5 July 2011

L.Z. Liu, L. Weng, Y.X. Song, L. Gao, H. Zhao and Q.Q. Lei

The purpose of this paper is to investigate the effects of coupling agents on the structure and properties of the nanocomposite films and clarify their mechanism. Polyimide (PI)/Al…

Abstract

Purpose

The purpose of this paper is to investigate the effects of coupling agents on the structure and properties of the nanocomposite films and clarify their mechanism. Polyimide (PI)/Al2O3 nanocomposite films were prepared using different coupling agents.

Design/methodology/approach

Poly(amic acid) (PAA) was firstly synthesised from appropriate pyromellitic diannanocomposite and oxydianiline in N‐dimethylacetamide. Calculated amount of nano‐Al2O3 particles modified by different coupling agents (KH550, KH560, KH570 and AE3012) were added to PAA solution by an ultrasonic‐mechanical method and PI/nano‐Al2O3 film was fabricated by heat curing. The microstructure, thermal stability, mechanical properties and electric breakdown strength of the films were characterised.

Findings

The addition of coupling agents could greatly improve the dispersion homogeneity of Al2O3 nano‐particles in PI matrix. Results of corresponding characterisations indicated that both the thermal stability and mechanical properties of PI/Al2O3 nanocomposite film with KH550 were greater/better than others, while AE3012 could improve the electric breakdown strength.

Research limitations/implications

In the present discussion, the effects of different coupling agents, KH550, KH560, KH570 and AE3012, were investigated. Results of this research work would be beneficial to an in‐depth understanding on the relationship between microstructure and properties of PI composites, and further promote the development of the high‐performance PI insulating materials.

Originality/value

The four coupling agents, KH550, KH560, KH570 and AE3012, were firstly used to disperse the nano‐Al2O3 particles in PI matrix. The effects of coupling agents on microstructure and properties of composites were discussed by the authors in detail.

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