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1 – 10 of 353S. Manjunatha, B. Ammani Kuttan, G.K. Ramesh, B.J. Gireesha and Emad H. Aly
The purpose of this paper is to discuss the 3D micropolar hybrid (Ag-CuO/H2O) nanofluid past rapid moving surface, where porous medium has been considered.
Abstract
Purpose
The purpose of this paper is to discuss the 3D micropolar hybrid (Ag-CuO/H2O) nanofluid past rapid moving surface, where porous medium has been considered.
Design/methodology/approach
The model of problem was represented by highly partial differential equations which were deduced by using suitable approximations (boundary layer). Then, the governing model was converted into five combined ordinary differential equations applying proper similarity transformations. Therefore, the eminent iterative Runge–Kutta–Fehlberg method (RKF45) has been applied to solve the resulting equations.
Findings
Higher values of vortex viscosity, spin gradient viscosity and micro-inertia density parameters are reduced in horizontal direction, whereas opposite behaviour is noticed for vertical direction.
Originality/value
The work has not been done in the area of hybrid micropolar nanofluid. Hence, this article culminates to probe how to improve the thermal conduction and fluid flow in 3D boundary layer flow of micropolar mixture of nanoparticles driven by rapidly moving plate with convective boundary condition.
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Hong Zhang, Sheng Han, Wenjing Hu and Jiusheng Li
The purpose of this paper is to improve the properties of metal nanoparticles which are easy to agglomerate and hard to disperse evenly, thus limiting the application of metal…
Abstract
Purpose
The purpose of this paper is to improve the properties of metal nanoparticles which are easy to agglomerate and hard to disperse evenly, thus limiting the application of metal nanoparticles in grease. A novel technology was proposed for modifying metal oxide to improve the dispersibility of nanoparticles.
Design/methodology/approach
SA-TiO2 nanoparticles were synthesized using an in-situ esterification method followed by surface modification with stearic acid. The microstructure of the nanoparticles was characterized by scanning electron microscope, transmission electron microscope and Fourier transform infrared spectroscopy and their thermal stability was evaluated by thermogravimetric analyzer. The tribological properties of the SA-TiO2 nanoparticles as additives in lithium grease were evaluated with a four-ball tester and TE77 reciprocating friction tester. The worn surfaces of the steel balls were investigated by EDS and XPS.
Findings
The prepared nanoparticles can be well dispersed in the lithium grease and possess much better tribological properties compared to traditional nanoparticles. The results indicated that the excellent tribological performance of SA-TiO2 was attributed to the chemical reaction film composing of Fe2O3, iron oxide and other organic compounds.
Originality/value
This paper provides a method to prevent the agglomeration of nano-TiO2 by surface modification with stearic acid. And the prepared nanoparticles can effectively improve the tribology performance of lithium grease.
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Masume Khodsuz, Amir Hamed Mashhadzadeh and Aydin Samani
Electrical characteristics of transformer oil (TO) have been studied during normal and thermal aging conditions. In this paper, breakdown voltage (BDV), partial discharge (PD)…
Abstract
Purpose
Electrical characteristics of transformer oil (TO) have been studied during normal and thermal aging conditions. In this paper, breakdown voltage (BDV), partial discharge (PD), heat transfer results and the physical mechanisms considering the impact of varying the diameter of Al2O3 nanoparticles (NPs) have been investigated. Different quantities of the two sizes of Al2O3 were added to the oil using a two-step method to determine the positive effect of NPs on the electrical and thermal properties of TO. Finally, the physical mechanisms related to the obtained experimental results have been performed.
Design/methodology/approach
The implementation of nanoparticles in this paper was provided by US Research Nanomaterials, Inc., USA. The provided Al2O3 NPs have an average particle size of 20–80 nm and a specific surface area of 138 and 58 m2/g, respectively, which have a purity of over 99%. Thermal aging has been done. The IEC 60156 standard has been implemented to calculate the BDV, and a 500-mL volume test cell (Apar TO 1020) has been used. PD test is performed according to Standard IEC 60343, and a JDEVS-PDMA 300 device was used for this test.
Findings
BDV tests indicate that 20 nm Al2O3 is more effective at improving BDV than 80 nm Al2O3, with an improvement of 113% compared to 99% for the latter. The analysis of Weibull probability at BDV indicates that 20 nm Al2O3 performs better, with improvements of 141%, 125% and 112% at probabilities of 1, 10 and 50%, respectively. The results of the PD tests using the PDPR pattern also show that 20 nm Al2O3 is superior. For the heat transfer test, 0.05 g/L of both diameters were used to ensure fair conditions, and again, the advantage was with 20 nm Al2O3 (23% vs 18%).
Originality/value
The effect of Al2O3 NP diameter (20 and 80 nm) on various properties of virgin and aged TO has been investigated experimentally in this paper to examine the effect of proposed NP on electrical improvement of TO.
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Saadet Güler, Ahmet Yavaş, Berk Özler and Ahmet Çagri Kilinç
Three-dimensional (3D) printing is popular for many applications including the production of photocatalysts. This paper aims to focus on developing of 3D-printed…
Abstract
Purpose
Three-dimensional (3D) printing is popular for many applications including the production of photocatalysts. This paper aims to focus on developing of 3D-printed photocatalyst-nano composite lattice structure. Digital light processing (DLP) 3D printing of photocatalyst composites was performed using photosensitive resin mixed with 0.5% Wt. of TiO2 powder and varying amounts (0.025% Wt. to 0.2% Wt.) of graphene nanoplatelet powder. The photocatalytic efficiency of DLP 3D-printed photocatalyst TiO2 composite was investigated, and the effects of nano graphite powder incorporation on the photocatalytic activity, thermal and mechanical properties were investigated.
Design/methodology/approach
Methods involve 3D computer-aided design modeling, printing parameters and comprehensive characterization techniques such as structural equation modeling, X-ray diffraction, thermogravimetric analysis, Fourier-transform infrared (FTIR) and mechanical testing.
Findings
Results highlight successful dispersion and characteristics of TiO2 and graphene nanoplatelet (GNP) powders, intricate designs of 3D-printed lattice structures, and the influence of GNPs on thermal behavior and mechanical properties.
Originality/value
The study suggests applicability in wastewater treatment and environmental remediation, showcasing the adaptability of 3 D printing in designing effective photocatalysts. Future research should focus on practical applications and the long-term durability of these 3D-printed composites.
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Sanjeev Kumar, Narendra K. Verma and Madan L. Singla
The purpose of this paper is to investigate the reflective properties of titania (TiO2) nanoparticle‐based coating.
Abstract
Purpose
The purpose of this paper is to investigate the reflective properties of titania (TiO2) nanoparticle‐based coating.
Design/methodology/approach
TiO2 nanoparticles, synthesised by sol‐gel method, were characterised by X‐ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and ultraviolet‐visible absorption spectroscopy (UV‐vis). The coating material has been prepared by dispersing titania nanoparticles in an acrylic binder with different pigment to binder weight ratio. The reflectors were prepared by applying this coating material to different coating thicknesses to aluminium sheets.
Findings
In the study reported here, the coating material could produce reflectors with diffuse reflectance, ∼99 per cent, using coating material, having binder by weight ratio between 14 and 20 per cent, and thickness, 0.15 mm. On exposing the developed reflectors to different levels of illumination (upto 20,000 lux), they were still found to have diffuse reflectance of more than 96 per cent almost throughout the visible spectrum.
Practical implications
The fabricated reflectors find applications in commercial optical products, such as: reflective panels, luminaries, etc.
Originality/value
As of today, the reflective coatings used are of conventional type, which employ bulk TiO2 particles. In this study, we are reporting TiO2 nanoparticle‐based highly reflective coating. This is an original work, and, to the best of our knowledge, no one has ever reported on “TiO2 nanoparticle‐based reflective coatings”.
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In recent times, there has been a growing interest in buoyancy-induced heat transfer within confined enclosures due to its frequent occurrence in heat transfer processes across…
Abstract
Purpose
In recent times, there has been a growing interest in buoyancy-induced heat transfer within confined enclosures due to its frequent occurrence in heat transfer processes across diverse engineering disciplines, including electronic cooling, solar technologies, nuclear reactor systems, heat exchangers and energy storage systems. Moreover, the reduction of entropy generation holds significant importance in engineering applications, as it contributes to enhancing thermal system performance. This study, a numerical investigation, aims to analyze entropy generation and natural convection flow in an inclined square enclosure filled with Ag–MgO/water and Ag–TiO2/water hybrid nanofluids under the influence of a magnetic field. The enclosure features heated slits along its bottom and left walls. Following the Boussinesq approximation, the convective flow arises from a horizontal temperature difference between the partially heated walls and the cold right wall.
Design/methodology/approach
The governing equations for laminar unsteady natural convection flow in a Newtonian, incompressible mixture is solved using a Marker-and-Cell-based finite difference method within a customized MATLAB code. The hybrid nanofluid’s effective thermal conductivity and viscosity are determined using spherical nanoparticle correlations.
Findings
The numerical investigations cover various parameters, including nanoparticle volume concentration, Hartmann number, Rayleigh number, heat source/sink effects and inclination angle. As the Hartmann and Rayleigh numbers increase, there is a significant enhancement in entropy generation. The average Nusselt number experiences a substantial increase at extremely high values of the Rayleigh number and inclination.
Practical implications
This numerical investigation explores advanced applications involving various combinations of influential parameters, different nanoparticles, enclosure inclinations and improved designs. The goal is to control fluid flow and enhance heat transfer rates to meet the demands of the Fourth Industrial Revolution.
Originality/value
In a 90° tilted enclosure, the addition of 5% hybrid nanoparticles to the base fluid resulted in a 17.139% increase in the heat transfer rate for Ag–MgO nanoparticles and a 16.4185% increase for Ag–TiO2 nanoparticles compared to the base fluid. It is observed that a 5% nanoparticle volume fraction results in an increased heat transfer rate, influenced by variations in both the Darcy and Rayleigh numbers. The study demonstrates that the Ag–MgO hybrid nanofluid exhibits superior heat transfer and fluid transport performance compared to the Ag–TiO2 hybrid nanofluid. The simulations pertain to the use of hybrid magnetic nanofluids in fuel cells, solar cavity receivers and the processing of electromagnetic nanomaterials in enclosed environments.
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Chao Ye, Xiufang Wen, Jia-ling Lan, Zhi-qi Cai, Pi-hui Pi, Shou-ping Xu and Yu Qian
The purpose of this paper is to modify light hollow polymer microsphere (LHPM) with titanium dioxide nanoparticles (nano-TiO2) to improve its compatibility with latex and apply…
Abstract
Purpose
The purpose of this paper is to modify light hollow polymer microsphere (LHPM) with titanium dioxide nanoparticles (nano-TiO2) to improve its compatibility with latex and apply the obtained nano-TiO2/LHPM composite particles in external wall thermal insulation coatings.
Design/methodology/approach
The nano-TiO2/LHPM composite particles were prepared via vigorous stirring. The morphology and chemical composition of the produced nano-TiO2/LHPM composite particles were characterized using scanning electron microscopy, energy dispersion spectrum, thermo-gravimetric analyzer and Fourier transform infrared. The performance of this new composite coating was evaluated by checking its stability, density, radiation reflectivity, thermal conductivity and the resulting insulation temperature difference when forming coating film.
Findings
It was found that a 9:1 mass ratio of nano-TiO2/LHPM with total 10 weight per cent composite particles in the thermal insulation paint showed low density, good stability, low thermal conductivity (0.1687 W/m·K) and high insulation temperature difference (5.8°C).
Research limitations/implications
The LHPM can be modified by other nanoparticles to improve its insulation performance in thermal insulation coatings.
Practical implications
This work provides a simple, robust, but effective approach to produce new thermal insulation coatings with nano-TiO2/LHPM composite particles.
Originality/value
This method for surface modification of LHPMs is novel and the modified hollow polymer microspheres could be applied to external wall insulation coatings.
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Amirul Syafiq, Lilik Jamilatul Awalin, Syukri Ali and Mohd Arif
The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create…
Abstract
Purpose
The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.
Design/methodology/approach
TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.
Findings
T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.
Research limitations/implications
The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.
Practical implications
The developed coating shows high potential for glass window application.
Originality/value
The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.
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Md Mehedi Hasan Rubel, Syed Rashedul Islam, Abeer Alassod, Amjad Farooq, Xiaolin Shen, Taosif Ahmed, Mohammad Mamunur Rashid and Afshan Zareen
The main purpose of this study was to prepare the cotton fibers and cellulose powder by a layer of nano-crystalline-titanium dioxide (TiO2) using the sol-gel sono-synthesis method…
Abstract
Purpose
The main purpose of this study was to prepare the cotton fibers and cellulose powder by a layer of nano-crystalline-titanium dioxide (TiO2) using the sol-gel sono-synthesis method to clean the wastewater containing reactive dye. Moreover, TiO2 nano-materials are remarkable due to their photoactive properties and valuable applications in wastewater treatment.
Design/methodology/approach
In this research, TiO2 was synthesized and deposited effectively on cotton fibers and cellulose powder using ultrasound-assisted coating. Further, tetra butyl titanate was used as a precursor to the synthesis of TiO2 nanoparticles. Reactive dye (red 195) was used in this study. X-ray Diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy were performed to prove the aptitude for the formation of crystal TiO2 on the cotton fibers and cellulose powder along with TiO2 nanoparticles as well as to analyze the chemical structure. Decoloration of the wastewater was investigated through ultraviolet (UV-Visible) light at 30 min.
Findings
The experimental results revealed that the decolorization was completed at 2.0 min with the cellulose nano TiO2 treatment whereas cotton nano TiO2 treated solution contained reactive dyestuffs even after the treatment of 2 min. This was the fastest method up to now than all reported methods for sustainable decolorization of wastewater by absorption. Furthermore, this study explored that the cellulose TiO2 nano-composite was more effective than the cotton TiO2 nano-composite of decoloration wastewater for the eco-friendly remedy.
Research limitations/implications
Cotton fibers and cellulose powder with nano-TiO2, and only reactive dye (red 195) were tested.
Practical implications
With reactive dye-containing wastewater, it seems to be easier to get rid of the dye than to retain it, especially from dyeing of yarn, fabric, apparel, and as well as other sectors where dyestuffs are used.
Social implications
This research would help to reduce pollution in the environment as well as save energy and cost.
Originality/value
Decoloration of wastewater treatment is an essential new track with nano-crystalline TiO2 to fast and efficient cleaning of reactive dyes containing wastewater used as a raw material.
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Zaker Bahreini, Vahid Heydari, Ali N. Hekmat, Minoo Taheri, Behrouz Vahid and Leila Moradkhannejhad
This paper aims to introduce two methods for immobilisation of TiO2 nanoparticles on a glass plate by means of silicon resin as a medium. Then, to ensure the effectiveness of…
Abstract
Purpose
This paper aims to introduce two methods for immobilisation of TiO2 nanoparticles on a glass plate by means of silicon resin as a medium. Then, to ensure the effectiveness of these stabilisation methods, the photocatalytic degradation and mineralisation of the dye C.I. Reactive Blue 21 (RB21), as a model organic pollutant, were compared using these immobilised systems and the suspended one utilizing UV and sunlight irradiations individually.
Design/methodology/approach
TiO2 nanoparticles were supported onto a glass support by silicon resin as an adhesion agent by spraying of TiO2 nanoparticles on the resin surface, which covered the glass plate or brushing the mixture of TiO2 and the resin onto the glass. The characteristics of the applied nano-TiO2 were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and Brunauer
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Emmett–Teller. Photocatalytic degradation and mineralisation of C.I. Reactive Blue 21 (RB21) by two immobilised systems were compared with suspended system in a batch mode under UV and sunlight irradiations after 2 h of treatment.
Findings
The results showed that these immobilised modes had efficiencies, including 82-87 per cent degradation of RB21 and 52-58 per cent decrease in chemical oxygen demand (COD) for the operational time of 120 min, comparable to that of the suspended mode (91 per cent degradation of RB21 and, consequently, COD is decreased by 65 per cent). Comparison between photocatalytic efficiencies of two immobilised systems revealed that coating by spraying method performed better than brushing one due to more available surface area of TiO2. Finally, the results obtained from the mentioned supported systems under sunlight indicated the efficiencies about 87 to 89 per cent in comparison of the suspension system regardless of the reaction time enhancement up to 15 h compared to the UV irradiation.
Research limitations/implications
In this research, the fixation of TiO2 nanoparticles on a substrate such as normal glass by an easy, inexpensive, durable, repairable and repeatable technique for wastewater treatment was introduced. Due to the simplicity and cheapness of these stabilisation methods and as these stabilisation methods are applicable on other substrates such as concrete, ceramics, etc., you can use these methods in major scales for purification of contaminated water, for example for stabilisation of TiO2 nanoparticles on wall pool utilized for water purification can be used.
Originality/value
Two introduced immobilisation methods in this study are novel. The photocatalytic efficiency of these immobilised systems in degradation of water contaminants was investigated by using these systems in degradation and mineralisation of the dye C.I. Reactive Blue 21 (RB21), as a model organic pollutant compared with same TiO2 nanoparticles in an aqueous suspension system under UV light. Furthermore, this paper investigated replacing of inexpensive sources of UV light instead of UV lamps, and then the same photocatalytic reactions were carried out under sunlight as a UV source and degradation efficiencies by two UV sources were compared.
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