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The purpose of this study is to investigate the presence of silicon dioxide (SiO₂) nanoparticles in o-toluidine monomer as a reactant and ammonium persulfate as an oxidant to obtain the poly(o-toluidine) (POT)/SiO₂ nanocomposites by oxidative polymerization method.

Fourier transformation infrared spectroscopy, X-ray diffraction and field emission scanning electron microscopy were used to characterize the structural properties of the composite. POT/SiO₂ nanocomposites were mixed with acrylic resin through a solution mixing method and the composites were coated onto the surface of mild steel. Electrochemical measurements were used to determine the corrosion protection efficiency (P.E.%) of polymer composite coatings using 3.5% NaCl solution as corrosion environment.

The results obtained reveals that the POT/SiO₂/acrylic resin composite coatings have got higher corrosion P.E.% than that of POT/acrylic resin coatings.

The formation of uniformly passive layer in the POT/SiO₂ composite was used to enhance the P.E.% on mild steel surface. The POT/SiO₂/acrylic resin nanocomposites showed effective anticorrosive behavior on mild steel in 3.5% NaCl solution.

Some thermally stable epoxy coatings have been developed using functional aminosl.ilanes viz, N‐[3‐(trimethoxysilyl) propyl] ethylenediamine and copolymer of aminopropylmethyl dimethylsiloxane in different ratio. It has been observed that use of silicon compounds invariably enhances the thermal stabililty, chemical resistance and corrosion resistance of epoxy coating. It has also been observed that silane bearing triethoxy group gave better adherence properities whereas silicone gave better thermal stability. The degradation kinetics showed that the reactions were of first order.

Fluorinated silicon polymers are expected to be adopted in specific coatings to afford outstanding advantages, such as high chemical and photochemical resistance, low surface tension and low refractive index. The modified acrylate resin is prepared via solution polymerization of fluorine and silicon monomers, acrylate monomers and other functional monomers. The purpose of this paper is that the fluorine and silicon monomers such as vinyltriethoxysilane (VTES) and hexafluorobutyl methacrylate (HFMA) and some cheap monomers such as styrene are used to prepare the cationic acrylic resin.

The fluorine and silicon modified cationic acrylic resin is prepared via solution polymerization technology, which uses butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), HFMA, VTES, dimethylaminoethyl methacrylate (DMAEMA) and hydroxypropyl methacrylate (HPMA) as the co-polymerized monomers, propylene glycol monomethyl ether (PGME) as solvent and 2,2-Azo-bis-iso-butyronitrile (AIBN) as the initiator to create a resin to introduce the Si–O and C–F into the polymer chains. The cathodic electrodeposition (CED) coatings were prepared by mixing the synthetic resin and blocked isocyanate.

The influence of the amounts of HFMA and VETS on the resin and the resultant CED coatings is investigated in detail. The optimum amounts of HFMA and VETS are obtained, which is 7–8% and 4–5%, respectively. The hydrophobicity and the acid and alkaline resistance of the film are improved when VETS and HFMA are introduced to co-polymerize with other monomers.

The fluorine and silicon monomers such as VTES and HFMA and some cheap monomers such as styrene, which are used to prepare the cationic acrylic resin, are seldom reported in the open literature.

The purpose of this paper is to investigate the effects of nano‐titanium dioxide and nano‐silicon dioxide particles on the mechanical and antimicrobial properties of denture base resin.

Nano‐titanium dioxide and nano‐silicon dioxide particles were introduced to heat‐curing denture base resin to prepare composites. Electronic universal testing machine and friction tester were used to test tensile strength and frictional resistance properties of the samples prepared, respectively; also, film adhesion method was used to test the in vitro antimicrobial activity against Candida albicans and Streptococcus mutans.

Addition of nano‐titanium dioxide particles could improve the antimicrobial property of denture base resin, and addition of nano‐silicon dioxide particles could improve the tensile strength and frictional resistance of denture base resin. Mixture of the two nano‐particles, at a certain ratio, could improve the tensile strength, frictional resistance and antimicrobial property of denture base resin to a certain extent.

Nano‐titanium dioxide and nano‐silicon dioxide denture base resin composites were obtained. The mechanical and antimicrobial properties of the composites were improved compared to the raw denture base resin.

Nano‐titanium dioxide and nano‐silicon dioxide denture base resin composites with excellent performance could be obtained. Longer service life, greater hardness and clearness helped improve the patients' quality of life. Limited work with respect to the improved denture base resin was performed, which could form the theme of a future study. The outcomes of the research reported here set a new milestone in the field of denture base resin.

An introduction to the topic of aqueous silicone resin coating systems for exterior masonry. Concentrates on applications in the construction industry.

The purpose of this paper is to prepare new economical thermal resistant coatings containing white sand (WS) and kaolin (K) fillers, which are cheap natural ores in Egypt and are sources for ceramic materials such as SiO₂ and Al₂O₃.

This paper investigates the effect of heat at 500°C on the durability of mild steel samples coated with silicon coatings. The coated plates were exposed to elevated temperatures according to ASTM D 2485 to determine their stability. Thermal gravimetric analysis and scanning electron microscopy were used to investigate the thermal stability of the modified films.

It was revealed that the composite fillers can enhance the thermal stability of silicon coatings. Another advantage of using the prepared composite fillers is promoting the dryness of silicon resin without heat.

Different natural ores were used as ceramic filler to enhance the thermal stability of silicon coatings.

New economical thermal-resistant coatings containing white sand and kaolin were prepared to replace the expensive thermal coatings; also, they can be used in industries other than coatings, e.g. paper, rubber and plastics composites.

This paper aims to introduce two methods for immobilisation of TiO₂ nanoparticles on a glass plate by means of silicon resin as a medium. Then, to ensure the effectiveness of these stabilisation methods, the photocatalytic degradation and mineralisation of the dye C.I. Reactive Blue 21 (RB21), as a model organic pollutant, were compared using these immobilised systems and the suspended one utilizing UV and sunlight irradiations individually.

TiO₂ nanoparticles were supported onto a glass support by silicon resin as an adhesion agent by spraying of TiO₂ nanoparticles on the resin surface, which covered the glass plate or brushing the mixture of TiO₂ and the resin onto the glass. The characteristics of the applied nano-TiO₂ were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and Brunauer

Emmett–Teller. Photocatalytic degradation and mineralisation of C.I. Reactive Blue 21 (RB21) by two immobilised systems were compared with suspended system in a batch mode under UV and sunlight irradiations after 2 h of treatment.

The results showed that these immobilised modes had efficiencies, including 82-87 per cent degradation of RB21 and 52-58 per cent decrease in chemical oxygen demand (COD) for the operational time of 120 min, comparable to that of the suspended mode (91 per cent degradation of RB21 and, consequently, COD is decreased by 65 per cent). Comparison between photocatalytic efficiencies of two immobilised systems revealed that coating by spraying method performed better than brushing one due to more available surface area of TiO₂. Finally, the results obtained from the mentioned supported systems under sunlight indicated the efficiencies about 87 to 89 per cent in comparison of the suspension system regardless of the reaction time enhancement up to 15 h compared to the UV irradiation.

In this research, the fixation of TiO₂ nanoparticles on a substrate such as normal glass by an easy, inexpensive, durable, repairable and repeatable technique for wastewater treatment was introduced. Due to the simplicity and cheapness of these stabilisation methods and as these stabilisation methods are applicable on other substrates such as concrete, ceramics, etc., you can use these methods in major scales for purification of contaminated water, for example for stabilisation of TiO₂ nanoparticles on wall pool utilized for water purification can be used.

Two introduced immobilisation methods in this study are novel. The photocatalytic efficiency of these immobilised systems in degradation of water contaminants was investigated by using these systems in degradation and mineralisation of the dye C.I. Reactive Blue 21 (RB21), as a model organic pollutant compared with same TiO₂ nanoparticles in an aqueous suspension system under UV light. Furthermore, this paper investigated replacing of inexpensive sources of UV light instead of UV lamps, and then the same photocatalytic reactions were carried out under sunlight as a UV source and degradation efficiencies by two UV sources were compared.

Conventional investment casting of turbine blades is a time consuming and expensive process due to the complications in wax injection steps and the complex shape of airfoil surfaces. By using rapid investment casting, a substantial improvement in the gas turbine blade manufacturing process can be expected. However, this process needs to be able to compete with conventional investment casting from a dimensional accuracy view of point. The purpose of this paper is to investigate the manufacture of gas turbine blades via two indirect rapid tooling (RT) technologies, namely epoxy (EP) resin tooling and silicon rubber molding.

The second stage blade of a Ruston TA 1750 gas turbine (rated at 1.3 MW) was digitized by a coordinate measuring machine. The aluminum‐filled EP resin and silicon rubber molds were fabricated using StereoLithography master models. Several wax patterns were made by injection in the EP resin and silicone rubber molds. These wax patterns were utilized for ceramic shell fabrication and blade casting.

Dimensional inspection of cast blades showed that silicone rubber molding was not a suitable approach for production of blade wax patterns. The maximum deviation for the final cast blade made using the silicone rubber mold was +0.402 mm. The maximum deviation for the final cast blade made using the EP resin mold was lower at −0.282 mm. This showed that EP resin tooling could enable new cost‐effective solutions for small batch production of gas turbine blades.

The research results presented will give efficient industrial approach and scientific insight of the gas turbine blade manufacturing by use of rapid technologies.

There are some general research works related to utilization of rapid technologies for manufacturing of gas turbine blade. However, this paper presents a unique procedure of integrated reverse engineering and RT technologies for rapid investment casting of gas turbine blade through presenting comprehensive comparison between two techniques from dimensional accuracy view of point.

Recycling technology for printed wiring boards (PWBs) with mounted electronic components was studied for the purpose of disassembling the boards, recovering useful materials, and reusing these materials. An automatic removal method was developed for the electronic components on the basis of a combination of heating to above the solder melting temperature and applying impacting the shearing forces. Most of the electronic components were recovered undamaged and the solder was able to be recovered as particles. The solder remaining on the board was recovered by abrading the board surface and by using a heating‐impacting process. After these processes, the resin board (a cured epoxy resin board reinforced with glass fibre)was pulverised and separated into a copper‐rich powder (copper: 82 Wt%) and a glass fibre and resin mixture powder (glass fibre‐resin powder) by gravimetric and electrostatic methods. The recovered electronic components, solder and copper‐rich powder were used as valuable metal resources for refining. Moreover, the recovered glass fibre‐resin powder was found to be a useful filler for plastic products such as epoxy resin and ABS (acrylonitrile/butadiene/styrene copolymer) resin.