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Surface modification of light hollow polymer microspheres and its application in external wall thermal insulation coatings

Chao Ye (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Xiufang Wen (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Jia-ling Lan (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Zhi-qi Cai (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Pi-hui Pi (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Shou-ping Xu (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)
Yu Qian (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 4 January 2016

500

Abstract

Purpose

The purpose of this paper is to modify light hollow polymer microsphere (LHPM) with titanium dioxide nanoparticles (nano-TiO2) to improve its compatibility with latex and apply the obtained nano-TiO2/LHPM composite particles in external wall thermal insulation coatings.

Design/methodology/approach

The nano-TiO2/LHPM composite particles were prepared via vigorous stirring. The morphology and chemical composition of the produced nano-TiO2/LHPM composite particles were characterized using scanning electron microscopy, energy dispersion spectrum, thermo-gravimetric analyzer and Fourier transform infrared. The performance of this new composite coating was evaluated by checking its stability, density, radiation reflectivity, thermal conductivity and the resulting insulation temperature difference when forming coating film.

Findings

It was found that a 9:1 mass ratio of nano-TiO2/LHPM with total 10 weight per cent composite particles in the thermal insulation paint showed low density, good stability, low thermal conductivity (0.1687 W/m·K) and high insulation temperature difference (5.8°C).

Research limitations/implications

The LHPM can be modified by other nanoparticles to improve its insulation performance in thermal insulation coatings.

Practical implications

This work provides a simple, robust, but effective approach to produce new thermal insulation coatings with nano-TiO2/LHPM composite particles.

Originality/value

This method for surface modification of LHPMs is novel and the modified hollow polymer microspheres could be applied to external wall insulation coatings.

Keywords

Acknowledgements

The authors are grateful for the financial support from National Natural Science Foundation of China (Grant No. 21176091), Fundamental Research Funds for the Central Universities (Grant No. 2013ZZ074) and team project of Natural Science Foundation of Guangdong Province (Grant No. S2011030001366).

Citation

Ye, C., Wen, X., Lan, J.-l., Cai, Z.-q., Pi, P.-h., Xu, S.-p. and Qian, Y. (2016), "Surface modification of light hollow polymer microspheres and its application in external wall thermal insulation coatings", Pigment & Resin Technology, Vol. 45 No. 1, pp. 45-51. https://doi.org/10.1108/PRT-01-2015-0006

Publisher

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Emerald Group Publishing Limited

Copyright © 2016, Emerald Group Publishing Limited

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