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Aqueous zinc-ion battery has broad application prospects in smart grid energy storage, power tools and other fields. Co₃O₄ is one of the ideal cathode materials for water zinc-ion batteries due to their high theoretical capacity, simple synthesis, low cost and environmental friendliness. Many studies were concentrated on the synthesis, design and doping of cathodes, but the effect of process parameters on morphology and performance was rarely reported.

Herein, Co₃O₄ cathode material based on carbon cloth (Co₃O₄/CC) was prepared by different temperatures hydrothermal synthesis method. The temperatures of hydrothermal reaction are 100°C, 120°C, 130°C and 140°C, respectively. The influence of temperatures on the microstructures of the cathodes and electrochemical performance of zinc ion batteries were investigated by X-ray diffraction analysis, scanning electron microscopy, cyclic voltammetry curve, electrochemical charging and discharging behavior and electrochemical impedance spectroscopy test.

The results show that the Co₃O₄/CC material synthesized at 120°C has good performance. Co₃O₄/CC nanowire has a uniform distribution, regular surface and small size on carbon cloth. The zinc-ion battery has excellent rate performance and low reaction resistance. In the voltage range of 0.01–2.2 V, when the current density is 1 A/g, the specific capacity of the battery is 108.2 mAh/g for the first discharge and the specific capacity of the battery is 142.6 mAh/g after 60 charge and discharge cycles.

The study aims to investigate the effect of process parameters on the performance of zinc-ion batteries systematically and optimized applicable reaction temperature.

We present the finite element simulations of reactive mineral‐carrying fluids mixing and mineralization in pore‐fluid saturated hydrothermal/sedimentary basins. In particular we explore the mixing of reactive sulfide and sulfate fluids and the relevant patterns of mineralization for lead, zinc and iron minerals in the regime of temperature‐gradient‐driven convective flow. Since the mineralization and ore body formation may last quite a long period of time in a hydrothermal basin, it is commonly assumed that, in the geochemistry, the solutions of minerals are in an equilibrium state or near an equilibrium state. Therefore, the mineralization rate of a particular kind of mineral can be expressed as the product of the pore‐fluid velocity and the equilibrium concentration of this particular kind of mineral. Using the present mineralization rate of a mineral, the potential of the modern mineralization theory is illustrated by means of finite element studies related to reactive mineral‐carrying fluids mixing problems in materially homogeneous and inhomogeneous porous rock basins.

It is of great significance to study the influence of subgrade filling on permafrost temperature field in permafrost area for the smooth construction and safe operation of railway.

The paper builds up the model for the hydrothermal coupling calculation of permafrost using finite element software COMSOL to study how permafrost temperature field changes in the short term after subgrade filling, on which basis it proposes the method of calculation for the concave distortion of freezing front in the subgrade-covered area.

The results show that the freezing front below the subgrade center sinks due to the thermal effect of subgrade filling, which will trigger hydrothermal erosion in case of sufficient moisture inflows, leading to the thawing settlement or the cracking of the subgrade, etc. The heat output of soil will be hindered the most in case of July filling, in which case the sinking and the distortion of the freezing front is found to be the most severe, which the recovery of the permafrost temperature field, the slowest, constituting the most unfavorable working condition. The concave distortion of the freezing front in the subgrade area increases with the increase in temperature difference between the filler and ground surface, the subgrade height, the subgrade width and the volumetric thermal capacity of filler, while decreases with the increase of the thermal conductivity of filler. Therefore, the filler chose for engineering project shall be of small volumetric thermal capacity, low initial temperature and high thermal conductivity whenever possible.

The concave distortion of the freezing front under different working conditions at different times after filling can be calculated using the method proposed.

Numerical methods are used to solve double diffusion driven reactive flow transport problems in deformable fluid‐saturated porous media. In particular, the temperature dependent reaction rate in the non‐equilibrium chemical reactions is considered. A general numerical solution method, which is a combination of the finite difference method in FLAC and the finite element method in FIDAP, to solve the fully coupled problem involving material deformation, pore‐fluid flow, heat transfer and species transport/chemical reactions in deformable fluid‐saturated porous media has been developed. The coupled problem is divided into two sub‐problems which are solved interactively until the convergence requirement is met. Owing to the approximate nature of the numerical method, it is essential to justify the numerical solutions through some kind of theoretical analysis. This has been highlighted in this paper. The related numerical results, which are justified by the theoretical analysis, have demonstrated that the proposed solution method is useful for and applicable to a wide range of fully coupled problems in the field of science and engineering.

This paper addresses materials and processes for printed wiring board compatible embedded capacitors using polymer/ceramic nanocomposites and hydrothermal barium titanate. Polymers allow low temperature fabrication appropriate to the board (MCM‐L) technology. The lower dielectric constants of the commercially available polymers can be greatly compensated by incorporating higher permittivity ceramic fillers. Materials requirements for higher capacitance density (>30 nF/cm²) have been addressed through implementation of a novel low‐temperature processable hydrothermal barium titanate film on a patterned titanium foil laminated to the PWB. Application of hydrothermal grown barium titanate is currently being evaluated using a multi‐layer system‐on‐package demonstration.

Carbon dioxide (CO₂) has attracted special scientific interest over the last years mainly because of its relation to climate change and indoor air quality. Except for this, CO₂ can be used as an indicator of food freshness, patients’ clinical state and fire detection. Therefore, the accurate monitoring and controlling of CO₂ levels are imperative. The development of highly sensitive, selective and reliable sensors that can efficiently distinguish CO₂ in various conditions of temperature, humidity and other gases’ interference is the subject of intensive research with chemi-resistive zinc oxide (ZnO)-based sensors holding a privileged position. Several ZnO nanostructures have been used in sensing applications because of their versatile features. However, the deficient selectivity and long-term stability remain major concerns, especially when operating at room temperature. This study aims to encompass an extensive study of CO₂ chemi-resistive sensors based on ZnO, introducing the most significant advances of recent years and the best strategies for enhancing ZnO sensing properties.

An overview of the different ZnO nanostructures used for CO₂ sensing and their synthesis methods is presented, focusing on the parameters that highly affect the sensing mechanism and, thus, the performance of CO₂ sensors.

The selectivity and sensitivity of ZnO sensors can be enhanced by adjusting various parameters during their synthesis and by doping or treating ZnO with suitable materials.

This paper summarises the advances in the rapidly evolving field of CO₂ sensing by ZnO sensors and provides research directions for optimised sensors in the future.

In this paper, wool fibers are modified with titanate tetrabutyl by coating and grafting titanium dioxide (TiO₂) nanoparticles under low temperature hydrothermal conditions. Field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, thermal gravimetric analysis and diffuse reflectance spectroscopy are used as the characterization techniques. It is found that anatase TiO₂ nanocrystals with crystal sizes smaller than 10 nm can be synthesized and simultaneously grafted onto fiber surfaces. In comparison with pristine wool fibers, the thermal stability for the TiO₂-coated wool fibers is slightly changed. The ability to block ultraviolet radiation is improved. The volume density is slightly increased. The tensile properties are enhanced, while the crimp properties worsened. A photocatalytic degradation process of methylene blue dye and a decoloration rocess of chlorophyll are developed.

The purpose of this study is to fabricate an ultraviolet (UV) metal-semiconductor-metal (MSM) photodetector based on zinc oxide nanorods (ZnO NRs) grown on seeded silicon (Si) substrate that was prepared by a low-cost method (drop-casting technique).

The drop-casting method was used for the seed layer deposition, the hydrothermal method was used for the growth of ZnO NRs and subsequent fabrication of UV MSM photodetector was done using the direct current sputtering technique. The performance of the fabricated MSM devices was investigated by current–voltage (I–V) measurements. The photodetection mechanism of the fabricated device was discussed.

Semi-vertically high-density ZnO (NRs) were effectively produced with a preferential orientation along the (002) direction, and increased crystallinity is confirmed by X-ray diffraction analysis. Photoluminescence results show a high UV region. The fabricated MSM UV photodetector showed that the ZnO (NRs) MSM device has great stability over time, high photocurrent, good sensitivity and high responsivity under 365 nm wavelength illumination and 0 V, 1 V, 2 V and 3 V applied bias. The responsivity and sensitivity for the fabricated ZnO NRs UV photodetector are 0.015 A W-1, 0.383 A W-1, 1.290 A W-1 and 1.982 A W-1 and 15,030, 42.639, 100.173 and 334.029, respectively, under UV light (365 nm) illumination at (0 V, 1 V, 2 V and 3 V).

This paper uses the drop-casting technique and the hydrothermal method as simple and low-cost methods to fabricate and improve the ZnO NRs photodetector.

Hydrothermal waves represent the preferred mode of instability of the so-called Marangoni flow for a wide range of liquids and conditions. The related features in classical rectangular containers have attracted much attention over recent years owing to the relevance of these oscillatory modes to several techniques used for the production of single crystals of semiconductor or oxide materials. Control or a proper knowledge of convective instabilities in these systems is an essential topic from a material/product properties saving standpoint. The purpose of this study is to improve our understanding of these phenomena in less ordinary circumstances.

This short paper reports on a numerical model developed to inquire specifically about the role played by sudden changes in the available cross-section of the shallow cavity hosting the liquid. Although accounting for the spanwise dimension would be necessary to derive quantitative results, the approach is based on the assumption of two-dimensional flow, which, for high-Pr fluids, is believed to retain the essence of the involved physical processes.

Results are presented for the case of a fluid with Pr = 15 filling an open container with a single backward-facing or forward-facing step on the bottom wall or with an obstruction located in the centre. It is shown that the presence of steps in the considered geometry can lead to a variety of situations with significant changes in the local spectral content of the flow and even flow stabilization in certain circumstances. The role of thermal boundary conditions is assessed by considering separately adiabatic and conducting conditions for the bottom wall.

Although a plethora of studies have been appearing over recent years motivated, completely or in part, by a quest to identify new means to mitigate these instabilities and produce accordingly single crystals of higher quality for the industry, unfortunately, most of these research works were focusing on very simple geometries. In the present paper, the causality and interdependence among all the kinematic and thermal effects mentioned above is discussed.

Various approaches have been made to alter the vibration sensing properties of zinc oxide (ZnO) films to achieve high sensitivity. This paper aims to report the experimental study of the fabrication of precursor molar ratio concentration varied ZnO nanostructures grown on rigid substrates using the refresh hydrothermal method. The effect of these fabricated ZnO nanostructures-based vibration sensors was experimentally investigated using a vibration sensing setup.

ZnO nanostructures have been grown using low temperature assisted refresh hydrothermal method with different precursor molar concentrations 0.025 M (R1), 0.075 M (R2) and 0.125 M (R3). Poly 3,4-ethylenedioxythiophene polystyrene sulfonate, a p-type material is spun coated on the grown ZnO nanostructures. Structural analysis reveals the increased intensity of the (002) plane and better c-axis orientation of the R2 and R3 sample comparatively. Morphological examination shows the changes in the grown nanostructures upon increasing the precursor molar concentration. The optical band gap value decreases from 3.11 eV to 3.08 eV as the precursor molar concentration is increased. Photoconductivity study confirms the formation of a p-n junction with less turn-on voltage for all the fabricated devices. A less internal resistance of 0.37 kΩ was obtained from Nyquist analysis for R2 compared with the other two fabricated samples. Vibration testing experimentation showed an improved output voltage of the R2 sample (2.61 V at 9 Hz resonant frequency and 2.90 V for 1 g acceleration) comparatively. This also gave an increased sensitivity of 4.68 V/g confirming its better performance when compared to the other fabricated two samples.

Photoconductivity study confirms the formation of a p-n junction with less turn-on voltage for all the fabricated devices. A less internal resistance of 0.37 kΩ was calculated from the Nyquist plot. Vibration testing experimentation proves an increased sensitivity of 4.68 V/g confirming its better performance when compared to the other fabricated two samples.

Vibration testing experimentation proves an increased sensitivity of 4.68 V/g for R2 confirming its better performance when compared to the other fabricated two samples.