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This paper attempted to study the alkali-activated (AA) binder consisting of 94% of ground granulated blast furnace slag (GGBFS) and 6% of blended powder of alkali metal hydroxide and metal sulfate, which acted as an activator.

Several concrete specimens (cubes, cylinders and prisms), which were casted using AA binders, were further tested for mechanical properties after exposure to elevated temperatures of 200 °C, 400 °C, 600 °C and 800 °C. Additionally, to understand the structural behavior in uniaxial compressive load, reinforced concrete short columns were cast, cured and tested at ambient temperature as well as after exposure to 300 °C, 600 °C and 900 °C, to know the residual strength after exposure to elevated temperature.

The findings for the residual strength of alkali-activated slag binder concrete (AASBC) indicated a substantial agreement with the results obtained for the residual strength of Portland slag cement (PSC) concrete, thereby showing the effectiveness of binder when used as a replacement of cement.

The study clearly indicates that the binder developed is an effective approach for the 100% replacement of cement in the concrete.

This paper aims to present an experimental investigation on the performances of alkali-activated slag (AAS) concrete and Portland slag cement (PSC) concrete under the influence of elevated temperature. In the present study, the alkali-activated binder contains 85% of ground granulated blast furnace slag (GGBFS) and 15% of powder blended as chemical activators.

For the purpose, standard size of cube, cylinder and prism have been cast for a designed mix of concrete. The AAS concrete specimens were kept for water as well as air curing. After attaining the maturity of 28 days, the samples were first exposed to different elevated temperatures, i.e. 100°C, 200°C, 300°C, 400°C, 500°C, 600°C, 700°C and 800°C. Later on, the tests were conducted on these samples to find the change in weight and the residual strength of the concrete.

After 500°C exposure, a considerable amount of the strength loss has been observed for AAS concrete. It has been evaluated that the performance of AAS concrete is better than that of the PSC concrete at elevated temperature.

The present research work is being applied on the material for which the experimental result has been obtained.

The author has tried to develop a new type of binder by using steel industry waste material and then tested at elevated temperature to sustain at high temperatures.

This research may give a social impact for developing mass housing project with a lower cost than that of using a conventional binder, i.e. cement.

A new type of binder material is being developed.

To reduce environmental impact caused by excessive use of ordinary Portland cement (OPC) and to mitigate scarcity of base materials such as natural coarse aggregate (NCA), industrial by-products can be carefully used as alternatives to OPC and NCA, in production of concrete. This paper aims to describe the performance of using ground granulated blast furnace slag (GGBS), fly ash (FA) as a complete replacement to OPC and ferrochrome slag (FCS) as replacement to NCA in production of novel FCS based alkali activated slag/fly ash concretes (AASFC) and evaluate their performance at elevated temperatures.

Two control factors with three levels each i.e. FA (0, 25 and 50 per cent by weight) and FCS (0, 50 and 100 per cent by volume) as a GGBS and NCA replacement, respectively, were adopted in AASFC mixtures. Further, AASFC mixture specimens were subjected to different levels of elevated temperature, i.e. 200°C, 400°C, 600°C and 800°C. Compressive strength and residual compressive strength were considered as responses. Three different optimization techniques i.e. gray relational analysis, technique for order preference by similarity to ideal solution and Desirability function approach were used to optimize AASFC mixtures subjected to elevated temperatures.

As FA replacement increases in FCS based AASFC mixtures, workability increases and compressive strength decreases. The introduction of FCS as replacement to NCA in AASFC mixture did not show any significant change in compressive strength under ambient condition. AASFC produced with 75 per cent GGBS, 25 per cent FA and 100 per cent FCS was found to have excellent elevated temperature enduring properties among all other AASFC mixtures studied.

Although several studies are available on using GGBS, FA and FCS in production of OPC-based concretes, present study reports the performance of novel FCS based AASFC mixtures subjected to elevated temperatures. Further, GGBS, FA and FCS used in the present investigation significantly reduces CO₂ emission and environmental degradation associated with OPC production and NCA extraction, respectively.

One of the sources for the increase in the carbon footprint on the earth is the manufacturing of cement, which causes a severer environmental impact. Abundant research is going on to diminish CO₂ content in the atmosphere by appropriate utilization of waste by-products of industries. Alkali-activated slag concrete (AASC) is an innovative green new concrete made by complete replacement of cement various supplementary cementitious raw materials. Concrete is a versatile material used in different fields of structures, so it is very important to study the durability in different exposures along with the strength. The purpose of this paper is to study the performance of AASC by incorporating quartz sand as fine aggregate under different exposure conditions.

The materials for this innovative AASC are selected based on preliminary studies and literature surveys. Based on numerous trials a better performance mix proportion of AASC with quartz sand is developed with 1:2:4 mix proportion, 0.8 alkali Binder ratio, 19 M of NaOH and 50% concentration of Na₂SiO₃. Subsequently, AASC cubes are prepared and exposed for 3, 7, 14, 28, 56, 90, 112, 180, 252 and 365 days in ambient, acid, alkaline, sulfate, chloride and seawater and tested for compressive strength. In addition, to study the microstructural characteristics, scanning electron microscope (SEM), energy dispersive X-ray analysis and X-ray diffraction analysis was also performed.

Long-term performance of AASC developed with quartz sand is very good in the ambient, alkaline environment of 5% NaOH and seawater with the highest compressive strength values of 51.8, 50.83 and 64.46, respectively. A decrease in compressive strengths was observed after the age of 14, 56 and 112 days for acid, chloride and sulfate exposure conditions, respectively. SEM image shows a denser microstructure of AASC matrix for ambient, alkaline of 5% NaOH and seawater.

The proposed AASC is prepared with a mix proportion of 1:2:4, so the other proportions of AASC need to verify. In general plain, AASC is not used in practice except in few applications, in this work the effect of reinforced AASC is not checked. The real environmental exposure in fields may not create for AASC, as it was tested in different exposure conditions in the laboratory.

The developed AASC is recommended in practical applications where early strength is required, where the climate is hot, where water is scarce for curing, offshore and onshore constructions exposed to the marine environment and alkaline environment industries like breweries, distilleries and sewage treatment plants. As AASC is recommended for ambient air and in other exposures, its implementation as a construction material will reduce the carbon footprint.

The developed AASC mix proportion 1:2:4 is an economical mix, because of low binder content, but it exhibits a higher early age compressive strength value of 45.6 MPa at the age of 3 days. The compressive strength increases linearly with age from 3 to 365 days when exposed to seawater and ambient air. The performance of AASC is very good in the ambient, alkaline environment and seawater compared to other exposure conditions.

The purpose of this paper is to develop an alternative new ternary geopolymer mortar (MKSP) to resolve a traditional mortar problem which exhibits several disadvantages, including poor strengths and surface microcracks and the CO₂ air pollution.

The MKSP ternary binder was produced using metakaolin (MK), slag (S), and palm oil fuel ash (POFA) activated with an alkaline mixture of sodium silicate (Na₂SiO₃) and 10 M NaOH in a mass ratio of 2.5. Seven different mix proportions of MK, slag, and POFA were used to fabricate MKSP mortars. The water-to-binder ratio was varied between 0.4 and 0.5. The mortars were heat cured for 2 h at 80°C and then aged in air. Flexural stress and strain, mortars flow and compressive strength were tested. Furthermore, the mortars were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses.

The results showed that the sample MKSP6, which contained 40 percent MK, 40 percent slag, and 20 percent POFA, exhibited high compressive strength (52 MPa) without any cracks and flexural strength (6.9 MPa) at 28 days after being cured for 2 h at 80°C; however, the MKSP7 mortar with optimal strength of 55 MPa showed some surface cracks . Further, the results of the XRD, SEM, and FTIR analyses indicated that the MKSP mortars primarily consisted of a crystalline (Si+Al) phase (70 percent) and a smaller amorphous (Si+Ca) phase (30 percent).

The MKSP ternary geopolymer mix has three limitations as an importance of heat curing for development early strength, POFA content less than 20 percent to gain high normal strength and delaying the sitting time by controlling the slag content or the alkali activator type.

The use of geopolymer materials binder in a real building is limited and it still under research, Thus, the first model of real applied geopolymer cement in 2008 was the E-Crete model that formed by Zeobond company Australia to take the technology of geopolymer concrete to reality. Zeobond Pty Ltd was founded by Professor Jannie S.J. van (van Deventer et al., 2013), it was used to product precast concrete for the building structure. The second model was PYRAMENT model in 2002 by American cement manufacturer Lone Star Industries which was produced from the development carried out on inorganic alumino-silicate polymers called geopolymer (Palomo et al., 1999). In 2013 the third model was Queensland’s University GCI building with three suspended floors made from structural geopolymer concrete containing slag/fly ash-based geopolymer (Pathak, 2016). In Australia, 2014, the newly completed Brisbane West Wellcamp airport becomes the greenest airport in the world. Cement-free geopolymer concrete was used to save more than 6,600 tons of carbon emissions in the construction of the airport. Therefore, the next century will see cement companies developing alternative binders that are more environmentally friendly from a sustainable development point of view.

Production of new geopolymer binder of mortar as alternative to traditional cement binder with high early and normal strength from low cost waste materials, less potential of cracking, less energy consumption need and low carbon dioxide emission.

The alkali-activated slag (AAS) cement is an interesting building material, confronting to the new economical and ecological challenges. In order to enhance its physical properties in comparison with ordinary Portland cement (OPC), we used natural pozzolana as a mineral addition. The parameters studied are: the fineness of the addition (5350 and 5650 cm²/g), and its percentage (0 to 30%). The activator used is NaOH (5M) and the curing temperature was fixed at 20°C. The results show the possibility to obtain compound alkali-activated slag cement with better stability and a compressive strength higher than 35 MPa.

The aim of this paper is to determine the thermal conductivity of a protective layer of alkali-activated cement and the possibility of performing fire protection with fireclay sand and Lightweight mortar. Unprotected steel structures have generally low fire resistance and require surface protection. The design of passive protection of a steel element must consider the service life of the structure and the possible need to replace the fire protection layer. Currently, conventional passive protection options include intumescent coatings, which are subject to frequent inspection and renewal, gypsum and cement-based fire coatings and gypsum and cement board fire protection.

Alkali-activated cements provide an alternative to traditional Portland clinker-based materials for specific areas. This paper presents the properties of hybrid cement, its manufacturability for conventional mortars and the development of passive fire protection. Fire experiments were conducted with mortar with alkali-activated and fireclay sand and lightweight mortar with alkali-activated cement and expanded perlite. Fire experiment FE modelling.

The temperatures of the protected steel and the formation of cracks in the protective layer were investigated. Based on the experiments, the thermal conductivities of the two protective layers were determined. Conclusions are presented on the applicability of alkaline-activated cement mortars and the possibilities of applicability for the protection of steel structures. The functionality of the passive fire layer was confirmed and the strengths of the mortar used were determined. The use of alkali-activated cements was shown to be a suitable option for sustainable passive fire protection of steel structures.

Eco-friendly fire protection based on hybrid alkali-activated cement of steel members.

Important differentiating attributes in the procedures used, the characteristic mineral composition of the binders, and the implications these have on the final long term stability and physico-mechanical performance of the concretes produced are identified and discussed, with the intent to improve transparency and clarity in the field of geopolymer concrete technologies.

This state-of-the-art review covers the area of geopolymer concrete, a class of sustainable construction materials that use a variety of alternative powders in lieu of cement for composing concrete, most being a combination of industrial by-products and natural resources rich in specific required minerals. It explores extensively the available essential materials for geopolymer concrete and provides a deeper understanding of its underlying chemical mechanisms.

This is a state-of-the-art review introducing the essential characteristics of alternative powders used in geopolymer binders and the effectiveness these have on material performance.

With the increase of need for alternative cementitious materials, identifying and understanding the critical material components and the effect they may have on the performance of the resulting mixes in fresh as well as hardened state become a critical requirement to for short- and long-term quality control (e.g. flash setting, efflorescence, etc.).

The topic explored is significant in the field of sustainable concrete technologies where there are several parallel but distinct material technologies being developed, such as geopolymer concrete and alkali-activated concrete. Behavioral aspects and results are not directly transferable between the two fields of cementitious materials development, and these differences are explored and detailed in the present study.

Self-healing concrete is a revolutionary building material that will generally reduce the maintenance cost of concrete constructions. Self-healing of cracks in concrete structure would contribute to a longer service life of the concrete and would make the material more durable and more sustainable. The cementitious mortar with/without incorporating encapsulates at different percentages of slag replacement with the cement mix improves autogenous healing at different ages. Therefore, this study’s aim is to develop a self-healing cementitious matrix for repair and retrofitting of concrete structures.

In the present work, waste straw pipes are used as a capsule, filled with the solution of sodium hydroxide (NaOH), sodium silicate (Na₂SiO₃) and colloidal nano-silica as self-healing activators. An artificial micro-crack on the control and blended mortar specimens at different percentages of slag replacement with cement (with/without encapsulation) is developed by applying a compressive load of 50% of its ultimate load-carrying capacity. The mechanical strength and ultrasonic pulse velocity, water absorption and chloride ion penetration test are conducted on the concrete specimen before and after the healing period. Finally, the self-healing activity of mortar mixes with/without encapsulation is analysed at different ages.

The encapsulated mortar mix with 10% of slag content has better self-healing potential than all other mixes considering mechanical strength and durability. The enhancement of the self-healing potential of such mortar mix is mainly due to hydration of anhydrous slag on the crack surface and transformation of amorphous slag to the crystalline phase in presence of encapsulated fluid.

The self-healing activities of the slag-based cementitious composite are studied for a healing period of 90 days only. The strength and durability performance of the cracked specimen may be increased after a long healing period.

The outcome of the work will help repair the cracks in the concrete structure and enhances the service life.

This study identifies the addition encapsulates with a self-healing activator fluid that can recover its strength after minor damage.

Demand for Geopolymer concrete (GPC) has increased recently because of its many benefits, including being environmentally sustainable, extremely tolerant to high temperature and chemical attacks in more dangerous environments. Like standard concrete, GPC also has low tensile strength and deformation capacity. This paper aims to analyse the utilization of incinerated bio-medical waste ash (IBWA) combined with ground granulated blast furnace slag (GGBS) in reinforced GPC beams and columns. Medical waste was produced in the health-care industry, specifically in hospitals and diagnostic laboratories. GGBS is a form of industrial waste generated by steel factories. The best option to address global warming is to reduce the consumption of Portland cement production and promote other types of cement that were not a pollutant to the environment. Therefore, the replacement in ordinary Portland cement construction with GPC is a promising way of reducing carbon dioxide emissions. GPC was produced due to an alkali-activated polymeric reaction between alumina-silicate source materials and unreacted aggregates and other materials. Industrial pollutants such as fly ash and slag were used as raw materials.

Laboratory experiments were performed on three different proportions (reinforced cement concrete [RCC], 100% GGBS as an aluminosilicate source material in reinforced geopolymer concrete [GRGPC] and 30% replacement of IBWA as an aluminosilicate source material for GGBS in reinforced geopolymer concrete [IGRGPC]). The cubes and cylinders for these proportions were tested to find their compressive strength and split tensile strength. In addition, beams (deflection factor, ductility factor, flexural strength, degradation of stiffness and toughness index) and columns (load-carrying ability, stress-strain behaviour and load-deflection behaviours) of reinforced geopolymer concrete (RGPC) were studied.

As shown by the results, compared to Reinforced Cement Concrete (RCC) and 100% GGBS based Reinforced Geopolymer Concrete (GRGPC), 30% IBWA and 70% GGBS based Reinforced Geopolymer Concrete (IGRGPC) (30% IBWA–70% GGBS reinforced geo-polymer concrete) cubes, cylinders, beams and columns exhibit high compressive strength, tensile strength, flexural strength, load-carrying ability, ultimate strength, stiffness, ductility and deformation capacity.

All the results were based on the experiments done in this research. All the result values obtained in this research are higher than the theoretical values.