Search results

The purpose of this paper is to investigate the effect of the replacement of natural coarse aggregate (NCA) with different percentages of recycled coarse aggregate (RCA) on properties of low calcium fly ash (FA)-based geopolymer concrete (GPC) cured at oven temperature. Further, this paper aims to study the effect of partial replacement of FA by ground granulated blast slag (GGBS) in GPC made with both NCA and RCA cured under ambient temperature curing.

M25 grade of ordinary Portland cement (OPC) concrete was designed according to IS: 10262-2019 with 100% NCA as control concrete. Since no standard guidelines are available in the literature for GPC, the same mix proportion was adopted for the GPC by replacing the OPC with 100% FA and W/C ratio by alkalinity/binder ratio. All FA-based GPC mixes were prepared with 12 M of sodium hydroxide (NaOH) and an alkalinity ratio, i.e. sodium hydroxide to sodium silicate (NaOH:Na₂SiO₃) of 1:1.5, subjected to 90^°C temperature for 48 h of curing. The NCA were replaced with 50% and 100% RCA in both OPC and GPC mixes. Further, FA was partially replaced with 15% GGBS in GPC made with the above percentages of NCA and RCA, and they were given ambient temperature curing with the same molarity of NaOH and alkalinity ratio.

The workability, compressive strength, split tensile strength, flexural strength, water absorption, density, volume of voids and rebound hammer value of all the mixes were studied. Further, the relationship between compressive strength and other mechanical properties of GPC mixes were established and compared with the well-established relationships available for conventional concrete. From the experimental results, it is found that the compressive strength of GPC under ambient curing condition at 28 days with 100% NCA, 50% RCA and 100% RCA were, respectively, 14.8%, 12.85% and 17.76% higher than those of OPC concrete. Further, it is found that 85% FA and 15% GGBS-based GPC with RCA under ambient curing shown superior performance than OPC concrete and FA-based GPC cured under oven curing.

The scope of the present paper is limited to replace the FA by 15% GGBS. Further, only 50% and 100% RCA are used in place of natural aggregate. However, in future study, the replacement of FA by different amounts of GGBS (20%, 25%, 30% and 35%) may be tried to decide the optimum utilisation of GGBS so that the applications of GPC can be widely used in cast in situ applications, i.e. under ambient curing condition. Further, in the present study, the natural aggregate is replaced with only 50% and 100% RCA in GPC. However, further investigations may be carried out by considering different percentages between 50 and 100 with the optimum compositions of FA and GGBS to enhance the use of RCA in GPC applications. The present study is further limited to only the mechanical properties and a few other properties of GPC. For wider use of GPC under ambient curing conditions, the structural performance of GPC needs to be understood. Therefore, the structural performance of GPC subjected to different loadings under ambient curing with RCA to be investigated in future study.

The replacement percentage of natural aggregate by RCA may be further enhanced to 50% in GPC under ambient curing condition without compromising on the mechanical properties of concrete. This may be a good alternative for OPC and natural aggregate to reduce pollution and leads sustainability in the construction.

Reports results from studies conducted on a polyfunctional amine adduct epoxy curing agent (EPI‐CURE DPC‐3293) as a means to design low temperature cure coatings. Through the judicious choice of epoxide resins and amine‐functional curing agents, relatively fast reaction rates and resistance to moisture and humidity are maintained under low‐temperature cure conditions, and that is evidenced by a good balance of performance properties of coating films. We have used differential scanning calorimetry (DSC) to study the extent of reaction as well as the glass transition temperatures (T_g). Electrochemical impedance spectroscopy (EIS) has been used to predict the barrier properties of coating films. These results are compared with epoxide resins cured with a phenalkamine curing agent to illustrate some of the unique advantages of using multifunctional amine adduct curing agents for the curing of epoxide resins under sub‐ambient cure conditions for a multitude of end‐use applications.

Concrete is a building material widely used for the infrastructural development. Cement is the binding material used for the development of concrete. It is the primary cause of CO₂ emission globally. The purpose of this study is to develop sustainable concrete material to satisfy the present need of construction sector. Geopolymer concrete (GPC) is a sustainable concrete developed without the use of cement. Therefore, investigations are being conducted to replace the cement by 100% with high calcium fly ash (FA) as binding material.

High calcium FA is used as cementitious binder, sodium hydroxide (NaOH) and sodium silicates (Na₂SiO₃) are used as alkaline liquids for developing the GPC. Mix proportions with different NaOH molarities of 4, 6, 8 and 10 M are considered to attain the appropriate mix. The method of curing adopted is ambient and oven curing. Workability, compressive strength and microstructure characteristics of GPC are analysed and presented.

An increase of NaOH in the mix decreases the workability. Compressive strength of 29 MPa is obtained for Mix-I with 8 M under ambient curing. A polynomial relationship is obtained to predict the compressive strength of GPC. Scanning electron microscope analysis is used to confirm the geo-polymerisation process in the microstructure of concrete.

This research work focuses on finding some alternative cementitious material for concrete that can replace ordinary portland cement (OPC) to overcome the CO₂ emission owing to the utilisation of cement in the construction industry. An attempt has been made to use the waste material (high calcium FA) from thermal power plant for the production of GPC. GPC concrete is the novel building material and alternative to conventional concrete. It is the ecofriendly product contributing towards the improvement of the circular economy in the construction industry. There are several factors that affect the property of GPC such as type of binder material, molarity of activator solution and curing condition. The novelty of this work lies in the approach of using locally available high calcium FA along with manufactured sand for the development of GPC. As this approach is rarely investigated, to prove the attainment of compressive strength of GPC with high calcium FA, an attempt has been made during the present investigation. Other influencing parameter which affects the strength gain has also been analysed in this paper.

This study aims to develop geopolymer concrete (GPC) using manufactured sand (M-sand) and recycled concrete aggregate (RCA) under different curing conditions. GPC is a sustainable construction material developed with industrial waste products such as fly ash to eliminate the use of cement in the production of concrete. GPC requires heat curing for the attainment of early age strength. The development of GPC under heat curing conditions is a hard process in practice. To overcome such circumstances, an attempt was made to develop the GPC under different curing conditions with the aid of coarse aggregate (CA) and RCA. The influence of different curing conditions on strength gain and microstructural characteristics of GPC is investigated. Mechanical properties of GPC such as compressive strength, tensile strength, flexural strength and elastic modulus are reported and discussed.

This study focuses on the assessment of mechanical and microstructure characterization of eco-efficient GPC developed with natural CA and RCAs. The required optimum quantity of binder, alkali activator, alkaline liquid to binder ratio and aggregates was determined by appropriate trials. Three types of curing methods, namely, ambient, oven and water, were used for the development of GPC mixes. Following the properties of RCA, it is realistic to substitute up to 40% of coarser aggregates as the resulting aggregate mix falls within the requirements of the analyzed mix.

Special attention is required for the mix with RCA because the mix’s consistency is affected by the high water absorption of the RCA mix. GPC specimens cured at ambient and water conditions exhibited marginal variation in the compressive strength for both CA and RCA. The compressive strength of GPC mixes prepared with RCA was marginally higher than that of the GPC made with CA under different curing regimes. RCA can be used as a sustainable material in lieu of CA in GPC.

The main significance of this research work is to develop the optimal mix design with appropriate mix proportion. The present study proposes a satisfactory methodology that enhances the mechanical strength of GPC as the guidelines are not available in the standards to address this problem. Effective use of waste materials such as fly ash and recycled aggregate for the development of GPC is another major research focus in the proposed investigation.

The effects of polyol types, polyol molecular weights, NCO/OH molar ratio, solvent types, and resin solid contents of the one‐part ambient temperature curing adhesives were studied. The results showed that the one‐part ambient temperature curing polyurethane prepared had fast rate of setting and good bonding, meeting the requirements of a typical structural adhesive.

Concrete, the second most used material in the world, surpassed only by water, relies on a vast amount of cement. The process of cement production emits substantial amounts of carbon dioxide (CO₂). Consequently, it is crucial to search for cement alternatives. Geopolymer concrete (GC) uses industrial by-product material instead of traditional cement, which not only reduces CO₂ emissions but also enhances concrete durability. On the other hand, the disposal of concrete waste in the landfills represents a significant environmental challenge, emphasising the urgent need for sustainable solutions. This study aimed to investigate waste concrete's best form and rate as the alternative aggregates in self-compacting and ambient-cured GC to preserve natural resources, reduce construction and demolition waste and decrease pertinent CO₂ emissions. The binding material employed in this research encompasses fly ash, slag, micro fly ash and anhydrous sodium metasilicate as an alkali activator. It also introduces the best treatment method to improve the recycled concrete aggregate (RCA) quality.

A total of25%, 50% and 100% of coarse aggregates are replaced with RCAs to cast self-compacting geopolymer concrete (SCGC) and assess the impact of RCA on the fresh, hardened and water absorption properties of the ambient-cured GC. Geopolymer slurry was used for coating RCAs and the authors examined the effect of one-day and seven-day cured coated RCA. The mechanical properties (compressive strength, splitting tensile strength and modulus of elasticity), rheological properties (slump flow, T500 and J-ring) and total water absorption of RCA-based SCGC were studied. The microstructural and chemical compositions of the concrete mixes were studied by the methods of energy dispersive X-Ray and scanning electron microscopy.

It is evident from the test observations that 100% replacement of natural aggregate with coated RCA using geopolymer slurry containing fly ash, slag, micro fly ash and anhydrous sodium metasilicate cured for one day before mixing enhances the concrete's quality and complies with the flowability requirements. Assessment is based on the fresh and hardened properties of the SCGC with various RCA contents and coating periods. The fresh properties of the mix with a seven-day curing time for coated RCA did not meet the requirements for self-compacting concrete, while this mix demonstrated better compressive strength (31.61 MPa) and modulus of elasticity (15.39 GPa) compared to 29.36 MPa and 9.8 GPa, respectively, for the mix with one-day cured coated RCA. However, incorporating one-day-cured coated RCA in SCGC demonstrated better splitting tensile strength (2.32 MPa) and water absorption (15.16%).

A potential limitation of this study on SCGC with coated RCAs is the focus on the short-term behaviour of this concrete. This limited time frame may not meet the long-term requirements for ensuring the sustained durability of the structures throughout their service life.

This paper highlights the treatment technique of coating RCA with geopolymer slurry for casting SCGC.

The purpose of this study is to advance the application of pulverised cow bone ash (PCBA) as a partial replacement of cement in soil stabilisation for the production of bricks. The study investigated the impact of PCBA substitution on the characteristic strength of clay bricks under variant curing media.

Dried cow bones were pulverised, and an energy-dispersive X-ray fluorescence test was conducted on PCBA samples to determine the chemical constituents and ascertain the pozzolanic characteristics. Ordinary Portland cement (OPC) and PCBA were blended at 100%, 75%, 50%, 25% and 0% of cement substitution by mass to stabilise lateritic clay at 10% total binder content for the production of bricks. The binder-to-lateritic clay matrixes were used to produce clay bricks and cylinders for compressive and splitting tensile strength tests, respectively.

The study found that PCBA and OPC have similar chemical compositions. The strength of the clay bricks increased with curing age, and the thermal curing of clay bricks positively impacted the strength development. The study established that PCBA is a suitable substitute for cement, up to 25% for stabilisation in clay brick production.

Construction stakeholders can successfully use a PCBA-OPC binder blend of 1:3 to stabilise clay at 10% total binder content for the production of bricks. The stabilised clay bricks should be cured at an elevated temperature of approximately 90°C for 48 h to achieve satisfactory performance.

The PCBA-OPC binder blend provides adequate soil stabilisation for the production of clay bricks and curing the clay bricks at elevated temperature. This aspect of the biomass/OPC binder blend has not been explored for brick production, and this is important for the reduction of the environmental impacts of cement production and waste from abattoirs.

Introduction Most corrosion protection systems used for maintenance, as well as binders for the building and civil engineering industries, are cold‐curing formulations. Elevated temperature cure is usually excluded by the size and shape of the substrate to be coated. Consequently, the selection of binders that are suitable for these surface protection systems is limited to those that combine the following properties:

The durability of concrete structures, especially built-in corrosive environments, starts to deteriorate after 20–30 years, even though they have been designed for more than 60 years of service life. The durability of concrete depends on its resistance against a corrosive environment. Inorganic Polymer concrete, or geopolymer concrete, has been emerging as a new engineering material with the potential to form an alternative to conventional concrete for the construction industry. The purpose of this paper is to conduct the investigation on corrosion of the geopolymer materials prepared using GGBS blended with low calcium fly ash in different percentages and sodium hydroxide, sodium silicate as activators and cured in ambient conditions (25±5°C).

GGBS was replaced by fly ash at different levels from 0 to 50 percent in a constant concentration of 12M. The main parameters of this study are the evaluation of strength characteristics of geopolymer concrete and resistance against corrosion by conducting accelerated corrosion test (Florida method).

From the test results it is observed that the strength of the geopolymer concrete with GGBS in ambient curing performs well compared to geopolymer concrete with GGBS blended with fly ash. The GPCE sample (40 percent replacement of fly ash to GGBS) shows better results and the resistance against corrosion was good, compared to all other mixes.

The outcomes of this investigation will be useful for the researchers and the construction industry.

This paper results that optimum percentage of fly ash should be blended with GGBS against the corrosion attack. This investigation indicates that GGBS without the combination of fly ash can be utilized in a normal environment. These findings will definitely be useful for the ready-mix concrete manufacturers and the construction Industry.

Disposal of industrial wastes causes pollution to the environment. Industrial wastes are utilized for the production of geopolymer concrete, which is the alternative material for the construction industry.

From the observation of the previous literature, till now there was no investigation on geopolymer concrete for corrosion under ambient curing conditions, as such this investigation could be considered as the new investigation.

One of the sources for the increase in the carbon footprint on the earth is the manufacturing of cement, which causes a severer environmental impact. Abundant research is going on to diminish CO₂ content in the atmosphere by appropriate utilization of waste by-products of industries. Alkali-activated slag concrete (AASC) is an innovative green new concrete made by complete replacement of cement various supplementary cementitious raw materials. Concrete is a versatile material used in different fields of structures, so it is very important to study the durability in different exposures along with the strength. The purpose of this paper is to study the performance of AASC by incorporating quartz sand as fine aggregate under different exposure conditions.

The materials for this innovative AASC are selected based on preliminary studies and literature surveys. Based on numerous trials a better performance mix proportion of AASC with quartz sand is developed with 1:2:4 mix proportion, 0.8 alkali Binder ratio, 19 M of NaOH and 50% concentration of Na₂SiO₃. Subsequently, AASC cubes are prepared and exposed for 3, 7, 14, 28, 56, 90, 112, 180, 252 and 365 days in ambient, acid, alkaline, sulfate, chloride and seawater and tested for compressive strength. In addition, to study the microstructural characteristics, scanning electron microscope (SEM), energy dispersive X-ray analysis and X-ray diffraction analysis was also performed.

Long-term performance of AASC developed with quartz sand is very good in the ambient, alkaline environment of 5% NaOH and seawater with the highest compressive strength values of 51.8, 50.83 and 64.46, respectively. A decrease in compressive strengths was observed after the age of 14, 56 and 112 days for acid, chloride and sulfate exposure conditions, respectively. SEM image shows a denser microstructure of AASC matrix for ambient, alkaline of 5% NaOH and seawater.

The proposed AASC is prepared with a mix proportion of 1:2:4, so the other proportions of AASC need to verify. In general plain, AASC is not used in practice except in few applications, in this work the effect of reinforced AASC is not checked. The real environmental exposure in fields may not create for AASC, as it was tested in different exposure conditions in the laboratory.

The developed AASC is recommended in practical applications where early strength is required, where the climate is hot, where water is scarce for curing, offshore and onshore constructions exposed to the marine environment and alkaline environment industries like breweries, distilleries and sewage treatment plants. As AASC is recommended for ambient air and in other exposures, its implementation as a construction material will reduce the carbon footprint.

The developed AASC mix proportion 1:2:4 is an economical mix, because of low binder content, but it exhibits a higher early age compressive strength value of 45.6 MPa at the age of 3 days. The compressive strength increases linearly with age from 3 to 365 days when exposed to seawater and ambient air. The performance of AASC is very good in the ambient, alkaline environment and seawater compared to other exposure conditions.