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1 – 10 of 450Yuzhen Zhao, Mingxu Zhao, Huimin Zhang, Xiangrong Zhao, Yang Zhao, Zhun Guo, Jianjing Gao, Cheng Ma and Yongming Zhang
This paper aims to prepare third-order nonlinear optical (NLO) organic materials with large nonlinear optimization value, high damage threshold and ultrafast response time.
Abstract
Purpose
This paper aims to prepare third-order nonlinear optical (NLO) organic materials with large nonlinear optimization value, high damage threshold and ultrafast response time.
Design/methodology/approach
A series of novel symmetric and asymmetric compounds possessing third-order NLO properties were synthesized using 1,3,5-tribromobenzene as the basis. The photophysical and electrochemical properties, as well as the click reactions, were characterized by means of UV–VIS–NIR absorption spectroscopy and cyclic voltammetry.
Findings
The donor–acceptor chromophores were inserted into compound, making the molecule to have a broader absorption in the near-infrared regions and a narrower optical and electrochemical band gap. It also formed an electron-delocalized organic system, which has larger effects on achieving a third-order NLO response. The third-order NLO phenomenon of benzene ring complexes was experimentally studied at 532 nm using Z-scan technology, and some compounds showed the expected NLO properties.
Originality/value
The click products exhibit more NLO phenomena by performing different click combinations to the side groups, opening new perspectives on using the system in a variety of photoelectric applications.
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Ervina Bečić, Miroslav Šober, Belma Imamović, Davorka Završnik and Selma Špirtović‐Halilović
The purpose of this paper is to test absorption characteristics of some newly synthesised 4‐hidroxycoumarins, containing phenyl‐prop‐2‐enoyl group at the 3‐position. Change in…
Abstract
Purpose
The purpose of this paper is to test absorption characteristics of some newly synthesised 4‐hidroxycoumarins, containing phenyl‐prop‐2‐enoyl group at the 3‐position. Change in spectral characteristics in solvents of different polarity (chloroform and acetonitrile) was followed in regard to the influence of the substitution at the phenyl ring and influence of concentration H+ ions. Effectiveness of tested substances was compared with well‐known UV absorbers such as benzophenone‐3 and butyl methoxydibenzoylmethane (BMDM).
Design/methodology/approach
All the tested substances were dissolved in chloroform and acetonitrile, with 10‐3 mmol concentration range. The pH was adjusted using 0.1 mol/l HCl, glacial acetic acid, 0.1 mol/l NaOH (aqueous solution) and 0.1 mol/l NaOH (methanolic solution). Spectrophotometric measurement was recorded in the range of 200‐800 nm, using 1‐cm quartz cells.
Findings
The tested 4‐hydroxycoumarin derivatives showed good UV absorption properties in the range 280‐380 nm. Substitution on the phenyl ring changes the shape of the absorption maxima. The changes depend on the properties of the substituent as well as the acidity of the solution.
Research limitations/implications
Introducing an electron‐donating substituent on the phenyl‐prop‐2‐enoyl group can shift absorption maximums to longer wavelength. In addition, the variation in substituents on the synthesised substances and pH of the solution could also be studied.
Practical implications
The new compounds showed good UV absorption, making them potential candidates for many applications. The practical importance of the tested substances are derived from their stability, relatively easy synthesis and good UV absorption properties.
Originality/value
The paper shows that the tested coumarins derivatives were new compounds with good UV absorption properties, making them good UV absorbers of commercial potential. The tested coumarins showed good UV absorption properties in the range 280‐380 nm, making them potential candidates for many applications.
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Usama Afzal, Kanza Maryam, Fatima Afzal and Muhammad Aslam
The purpose of this study is to fabricate a highly sensitive humidity sensor for observing the humidity effect on a robot’s body as an application of the Internet of Things. The…
Abstract
Purpose
The purpose of this study is to fabricate a highly sensitive humidity sensor for observing the humidity effect on a robot’s body as an application of the Internet of Things. The sensor has been fabricated by depositing a thin sensing layer of nickel phthalocyanine (NiPc) between two silver electrodes.
Design/methodology/approach
The structure of the thin film was observed by X-ray diffraction, optical properties by UV Vis and surface morphology by scanning electron microscope. The capacitance and the resistance with respect to change in relative humidity from 0 to 100%RH have been measured by LCR meter at 1 kHz.
Findings
The sensor’s response time is 7.5 s and its recovery time is 3.7 s, with high sensitivity of 127,259 pF/%RH and 332.287 MΩ/%RH. The authors have also used a proposed sensor on a steel body and observed humidity values. The analysis of all measured values was performed through the classical and neutrosophic approaches. By comparing, the authors have observed that the neutrosophic approach is more efficient in analyzing the sensor data.
Originality/value
In this work, the authors will fabricate a capacitive and resistive-type humidity sensor using the thin film of NiPc. The structural, optical and morphological properties of NiPc thin film will be investigated with different characterization techniques. The electric properties, i.e. capacitance and resistance, will be measured at intervals with an LCR meter by changing relative humidity (%RH). Moreover, the measured data will be analyzed through different statistical approaches, as already used in [12].
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Shuchen Tian, Hui Cao, Zhou Yang, Yuzhen Zhao, Wanli He and Hong Gao
Currently, conjugated nonlinear optical (NLO) materials suffer from the drawbacks of complex manufacturing process and high cost. To further study the NLO materials with…
Abstract
Purpose
Currently, conjugated nonlinear optical (NLO) materials suffer from the drawbacks of complex manufacturing process and high cost. To further study the NLO materials with cost-effective, it is necessary to prepare new NLO materials with satisfactory performance.
Design/methodology/approach
Pyrene derivatives with good third-order NLO properties were synthesized by combining pyrene compounds with TCNE, TCNQ, F4-TCNQ and other molecular systems by clicking chemical method.
Findings
The pyrene derivatives were characterized by ultraviolet spectrum and Z-scan. The charge-transfer of the D-p-A structures plays a key role in the absorption peak shifts. And the third-order nonlinear absorption of the products revealed good third-order NLO susceptibilities.
Research limitations/implications
The synthesis technology of pyrene derivatives is not mature enough and is in the preliminary exploration stage. So, the authors produced a relatively small number of samples and did not conduct a very comprehensive test.
Practical implications
This novel pyrene derivative is suggestive and can promote the exploration and development of the third-order nonlinear materials.
Originality/value
Four new pyrene derivatives were synthesized by selecting new molecular systems. Because of its good chemical properties and stable properties, it can be a reference for the development of third-order nonlinear materials in the future.
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This study aimed the synthesis and theoretical/experimental characterization of novel benzofuran-based acrylamide monomer.
Abstract
Purpose
This study aimed the synthesis and theoretical/experimental characterization of novel benzofuran-based acrylamide monomer.
Design/methodology/approach
Novel N-substituted acrylamide monomer, i.e. N-[2–(4-Bromo-benzoyl)-benzofuran-3-yl]-acrylamide (BBFA), was synthesized by reacting (3-Amino-benzofuran-2-yl)-(4-bromophenyl) methanone with acryloylchloride at 0–5oC. Nuclear magnetic resonance (1H-NMR), infrared (FT-IR) and UV-Visible spectrophotometer were used to elucidate the chemical structure of BBFA. Computational studies were performed using the DFT (B3LYP) method on the basis of 6-31 + G (d, p) using Gaussian 09 W and Gauss View 5.0 package in addition to the VEDA program, gauge-independent atomic orbital (GIAO) and time-dependent density functional theory (TD-DFT) methods.
Findings
Molecular geometry and vibration assignments of the BBFA monomer were calculated. The molecular structure of the monomer was examined. Both longest and shortest bonds were determined in the structure. The nucleophilic and electrophilic regions of the monomer were determined. The theoretical spectroscopic data of the monomer were compared with the experimental data; both were consistent with each other. The chemical reactivity of the monomer was also determined.
Originality/value
The synthesized BBFA monomer can be evaluated in many areas; from medicine to industry (such as textiles) owing to the presence of various active functional groups. Indeed, acrylamide copolymers are remarkable materials for polymer science and industry. The data produced in this study is original and adds to the scientific community.
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Fatma A. Mohamed, Saadia A. Abd El-Megied, Mahmoud S. Bashandy and Hassan M. Ibrahim
This study aims to synthesise and characterise new reactive dyes based on thiazole derivatives which act as chromophoric moieties. These dyes were applied to cotton fabric…
Abstract
Purpose
This study aims to synthesise and characterise new reactive dyes based on thiazole derivatives which act as chromophoric moieties. These dyes were applied to cotton fabric, resulting in the dyed fabrics exhibiting good colour strength, light fastness and other fastness properties. The antibacterial activity of the dyed cotton fabric was evaluated against gram-negative and gram-positive bacteria.
Design/methodology/approach
The dyes were synthesised in two steps. First, the coupling compound was formed by adding H-acid solution to cyanuric chloride in an ice bath at pH 5 then adding 4-aminobenzenesulphonic acid portion-wise at room temperature and at pH 6-7. Second, different diazonium salts 4-phenylthiazol-2-amine (2a) and 4-(4-methoxyphenyl) thiazol-2-amine (2b) were coupled with the coupling compound at pH 5. The resultant monochlorotriazine (MCT)-reactive dyes (6a, 6b) were formed. The synthesised dyes were applied onto cotton fabric under typical exhaust dyeing conditions and their dyeing properties were investigated.
Findings
High antimicrobial activity, dye exhaustion and fixation yield on cotton fabric were recorded for each dye. All dyes showed high stability against washing, rubbing, perspiration and light fastness.
Research limitations/implications
Dyeing of cotton fabric with these dyes which have higher fastness, higher exhaustion and higher antibacterial activity is considered one of the most important reactive dyes species.
Practical implications
The preparation procedure showed the synthesis of the novel MCT-reactive dyes derived from thiazole derivatives followed by the application of these dyes on cotton fabrics.
Social implications
Use of reactive dyes will bring a number of benefits to society including higher fastness and higher antibacterial activity so, and these dyes can be used for dyeing cotton.
Originality/value
In this work, the new reactive dyes derived from thiazole derivatives were synthesised and their structures were confirmed by the analytical and spectral data. Such compounds are considered to be excellent reactive dyes with different colour shades and higher antibacterial activity.
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Rui Huang, Kangni Shen, Teng Xu and Yongjia Shen
The purpose of this paper is to explore the optic performance of extended stilbene derivative.
Abstract
Purpose
The purpose of this paper is to explore the optic performance of extended stilbene derivative.
Design/methodology/approach
Five steps were adopted to synthesise novel 4, 4′-bis (2-cyanostyryl) stilbene, which contained three vinyl units in the skeleton (S3E). The structure of S3E was characterised by 1H NMR and EI-MS. Its absorption and emission spectra were also given.
Findings
Compared to C.I. Fluorescent Brightener 199, which contains two vinyl units in the skeleton, S3E showed obvious bathochromic shifts in both UV-VIS and FL spectra. The maximum absorption wavelength and fluorescent wavelength were at 390 nm and 464 nm, respectively, with Stoke’s shift of 74 nm. The absolute fluorescence quantum yield was 0.42. Thermogravimetric analysis (TGA) revealed that the weight loss of S3E was less than 5 per cent at 300 °C. Moreover, the light resistance test showed that S3E in PVC plate can keep the good fluorescent intensity for more than seven days exposed to xenon light. Therefore, it is believed that S3E could satisfy the requirements of colouring PVC as a fluorescent dye.
Practical implications
S3E can be used as a candidate of fluorescent dye in the development of thermoplastics.
Originality/value
The present paper designed and synthesised a new derivative of stilbene, which showed its preference to be a colourant of thermoplastics.
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Fatemeh Mollaamin and Majid Monajjemi
The purpose of this paper is to investigate the ability of transition metals (TMs) of iron-, nickel- and zinc-doped graphene nanosheet for adsorption of toxic gas of nitric oxide…
Abstract
Purpose
The purpose of this paper is to investigate the ability of transition metals (TMs) of iron-, nickel- and zinc-doped graphene nanosheet for adsorption of toxic gas of nitric oxide (NO). The results of this paper have provided a favorable understanding of the interaction between TM-doped graphene nanosheet and NO molecule.
Design/methodology/approach
A high performance of TM-doped graphene nanosheet as a gas sensor is demonstrated by modeling the material’s transport characteristics by means of the Langmuir adsorption and three-layered ONIOM/ density functional theory method. The Langmuir adsorption model has been done with a three-layered ONIOM using CAM-B3LYP functional and LANL2DZ and 6–311G (d, p) basis sets by Gaussian 16 revision C.01 program towards the formation of of NO→TM(Mn, Co, Cu)-doped on the Gr nanosheet.
Findings
The changes of charge density for Langmuir adsorption of NO on Mn-, Co- and Cu-doped graphene nanosheet orderly have been achieved as: ΔQCo-doped = +0.309 >> ΔQMn-doped = −0.074 > ΔQCu-doped = −0.051. Therefore, the number of changes of charge density have concluded a more remarkable charge transfer for Mn-doped graphene nanosheet. However, based on nuclear magnetic resonance spectroscopy, the sharp peaks around Cu doped on the surface of graphene nanosheet and C19 close to junction of N2 and Co17 have been observed. In addition, Cu-doped graphene sheet has a large effect on bond orbitals of C8–Cu 17, C15–Cu 17 and C16–Cu17 in the adsorption of NO on the Cu-doped/Gr which has shown the maximum occupancy. The amounts of
Originality/value
This research aims to explore the adsorption of hazardous pollutant gas of “NO” by using carbon nanostructure doped by “TM” of iron, nickel and zinc to evaluate the effectiveness of adsorption parameters of various TM-doped graphene nanosheets.
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Sinchan Biswas, Debabrata Sircar, Adinpunya Mitra and Bratati De
The purpose of this paper is to determine the antioxidant properties and phenol content of methanolic extracts of six white varieties and six purple/brown varieties of Indian rice…
Abstract
Purpose
The purpose of this paper is to determine the antioxidant properties and phenol content of methanolic extracts of six white varieties and six purple/brown varieties of Indian rice and to find some relationship between the antioxidant properties, phenolic content in the varieties analyzed.
Design/methodology/approach
Methanolic extracts of different rice varieties were analyzed for their superoxide radical scavenging activity, 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) radical scavenging activity, total antioxidant capacity, reducing power and ferrous ion chelating properties. The extracts were analyzed for determination of total phenol content, anthocyanin content, oryzanol content. Phenolic acids were determined by HPLC.
Findings
All the rice varieties (white and purple/brown) showed activity in a dose‐dependent manner. Free phenolic acids, e.g. protocatechuic acid, caffeic acid, vanillic acid, p‐coumaric acid (PCA), ferulic acid and sinapic acid and the phenolic aldehyde vanillin could be detected in all the rice samples analyzed. No relationship could be established between activity and metabolite content. Principal component analysis and classification shows that superoxide radical scavenging activity, total phenolic acid, protocatechuic acid and ferulic acid are the components to differentiate the varieties from each other.
Originality/value
Little work has been done on the antioxidant activity of white rice. The authors report superoxide radical scavenging activity, DPPH radical scavenging activity, total antioxidant activity, reducing power and ferrous ion chelating properties and phenolic contents of six white varieties and six purple/brown varieties of Indian rice. Free phenolic acids like protocatechuic acid, caffeic acid, vanillic acid, PCA, ferulic acid and sinapic acid are reported from all the 12 varieties of rice.
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Abdul Lateef, Zulfiqar Ali Raza, Muhammad Aslam, Muhammad Shoaib Ur Rehman, Asma Iftikhar and Abdul Zahir
This study aims to fabricate multiwalled carbon nanotubes (MWCNTs)-mediated polyvinyl alcohol (PVA) composite films using the solution casting approach.
Abstract
Purpose
This study aims to fabricate multiwalled carbon nanotubes (MWCNTs)-mediated polyvinyl alcohol (PVA) composite films using the solution casting approach.
Design/methodology/approach
The prepared films were evaluated for diverse structural, surface, optical and electrical attributes using advanced analytical techniques, i.e. electron microscopy for surface morphology, Fourier transform infrared spectroscopy for tracing chemical functionalities, x-ray diffraction (XRD) for crystal patterns, water contact angle (WCA) analysis for surface wettability and UV visible spectroscopy for optical absorption parameters. The specimens were also investigated for certain rheological, mechanical and electrical properties, where applicable.
Findings
The surface morphology results expressed a better dispersion of MWCNTs in the resultant PVA-based nanocomposite film. The XRD analysis exhibited that the nanocomposite film was crystalline. The surface wettability analysis indicated that with the inclusion of MWCNTs, the WCA of the resultant nanocomposite film improved to 89.4° from 44° with the pristine PVA film. The MWCNTs (1.00%, w/w) incorporated PVA-based film exhibited a tensile strength of 54.0 MPa as compared to that of native PVA as 25.3 MPa film. There observed a decreased bandgap (from 5.25 to 5.14 eV) on incorporating the MWCNTs in the PVA-based nanocomposite film.
Practical implications
The MWCNTs’ inclusion in the PVA matrix could enhance the AC conductivity of the resultant nanocomposite film. The prepared nanocomposite film might be useful in designing certain optoelectronic devices.
Originality/value
The results demonstrated the successful MWCNTs mediation in the PVA-based composite films expressed good intercalation of the precursors; this resulted in decreased bandgap, usually, desirable for optoelectronic applications.
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