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1 – 10 of 30Shuchen Tian, Hui Cao, Zhou Yang, Yuzhen Zhao, Wanli He and Hong Gao
Currently, conjugated nonlinear optical (NLO) materials suffer from the drawbacks of complex manufacturing process and high cost. To further study the NLO materials with…
Abstract
Purpose
Currently, conjugated nonlinear optical (NLO) materials suffer from the drawbacks of complex manufacturing process and high cost. To further study the NLO materials with cost-effective, it is necessary to prepare new NLO materials with satisfactory performance.
Design/methodology/approach
Pyrene derivatives with good third-order NLO properties were synthesized by combining pyrene compounds with TCNE, TCNQ, F4-TCNQ and other molecular systems by clicking chemical method.
Findings
The pyrene derivatives were characterized by ultraviolet spectrum and Z-scan. The charge-transfer of the D-p-A structures plays a key role in the absorption peak shifts. And the third-order nonlinear absorption of the products revealed good third-order NLO susceptibilities.
Research limitations/implications
The synthesis technology of pyrene derivatives is not mature enough and is in the preliminary exploration stage. So, the authors produced a relatively small number of samples and did not conduct a very comprehensive test.
Practical implications
This novel pyrene derivative is suggestive and can promote the exploration and development of the third-order nonlinear materials.
Originality/value
Four new pyrene derivatives were synthesized by selecting new molecular systems. Because of its good chemical properties and stable properties, it can be a reference for the development of third-order nonlinear materials in the future.
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Yuzhen Zhao, Mingxu Zhao, Huimin Zhang, Xiangrong Zhao, Yang Zhao, Zhun Guo, Jianjing Gao, Cheng Ma and Yongming Zhang
This paper aims to prepare third-order nonlinear optical (NLO) organic materials with large nonlinear optimization value, high damage threshold and ultrafast response time.
Abstract
Purpose
This paper aims to prepare third-order nonlinear optical (NLO) organic materials with large nonlinear optimization value, high damage threshold and ultrafast response time.
Design/methodology/approach
A series of novel symmetric and asymmetric compounds possessing third-order NLO properties were synthesized using 1,3,5-tribromobenzene as the basis. The photophysical and electrochemical properties, as well as the click reactions, were characterized by means of UV–VIS–NIR absorption spectroscopy and cyclic voltammetry.
Findings
The donor–acceptor chromophores were inserted into compound, making the molecule to have a broader absorption in the near-infrared regions and a narrower optical and electrochemical band gap. It also formed an electron-delocalized organic system, which has larger effects on achieving a third-order NLO response. The third-order NLO phenomenon of benzene ring complexes was experimentally studied at 532 nm using Z-scan technology, and some compounds showed the expected NLO properties.
Originality/value
The click products exhibit more NLO phenomena by performing different click combinations to the side groups, opening new perspectives on using the system in a variety of photoelectric applications.
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The purpose of this paper is to study stability analysis, solition solutions and Gaussian solitons of the generalized nonlinear Schrödinger equation with higher order terms, which…
Abstract
Purpose
The purpose of this paper is to study stability analysis, solition solutions and Gaussian solitons of the generalized nonlinear Schrödinger equation with higher order terms, which can be used to describe the propagation properties of optical soliton solutions.
Design/methodology/approach
The authors apply the ansatz method and the Hamiltonian system technique to find its bright, dark and Gaussian wave solitons and analyze its modulation instability analysis and stability analysis solution.
Findings
The results imply that the generalized nonlinear Schrödinger equation has bright, dark and Gaussian wave solitons. Meanwhile, the authors provide the graphical analysis of such solutions to better understand their dynamical behavior. Some constraint conditions are provided which can guarantee the existence of solitons. The authors analyze its modulation instability analysis and stability analysis solution.
Originality/value
These results may help us to further study the local structure and the interaction of solutions in generalized nonlinear Schrödinger -type equations. The authors hope that the results provided in this work can help enrich the dynamic behavior of the generalized nonlinear Schrödinger--type equations.
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Gives introductory remarks about chapter 1 of this group of 31 papers, from ISEF 1999 Proceedings, in the methodologies for field analysis, in the electromagnetic community…
Abstract
Gives introductory remarks about chapter 1 of this group of 31 papers, from ISEF 1999 Proceedings, in the methodologies for field analysis, in the electromagnetic community. Observes that computer package implementation theory contributes to clarification. Discusses the areas covered by some of the papers ‐ such as artificial intelligence using fuzzy logic. Includes applications such as permanent magnets and looks at eddy current problems. States the finite element method is currently the most popular method used for field computation. Closes by pointing out the amalgam of topics.
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F. Aziz, K. Sulaiman, Wissam Khayer Al-Rawi, Z. Ahmad, M.H. Sayyad, Kh. S. Karimov, L.L. Wei and M. Tahir
The purpose of this paper is to investigate the effect of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) on improvement of physical and electrical properties of vanadyl…
Abstract
Purpose
The purpose of this paper is to investigate the effect of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) on improvement of physical and electrical properties of vanadyl phthalocyanine derivative. The correlation between the physical characteristics of the active layers, comprising vanadyl 2,9,16, 23-tetraphenoxy-29H,31H-phthalocyanine (VOPcPhO) and PCBM, and the electrical properties of metal/organic/metal devices have been studied. The use of soluble vanadyl phthalocyanine derivative makes it very attractive for a variety of applications due to its tunable properties and high solubility.
Design/methodology/approach
The sandwich type structures Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al were fabricated by spin casting the active organic layers between the top and bottom (aluminum) electrodes. The stand-alone (VOPcPhO) and composite (VOPcPhO:PCBM) thin films were characterized by X-ray diffraction, atomic force microscopy, UV/Vis and Raman spectroscopy. The electronic properties of the metal/organic/metal devices were studied using current-voltage (I-V) characteristics in dark at room temperature.
Findings
The values of barrier height for Al/VOPcPhO/Al and Al/VOPcPhO:PCBM/Al devices were obtained from the forward bias I-V curves and were found to be 0.7 eV and 0.62 eV, respectively. The present study indicates that the device employing VOPcPhO:PCBM composite film as the active layer, with better structural and morphological characteristics, results in reduced barrier height at the metal-organic film interface as compared to the one fabricated with the stand-alone film.
Research limitations/implications
It is shown that doping VOPcPhO with PCBM improves the crystallinity, morphology and junction properties.
Practical implications
The spin coating technique provides a simple, less expensive and effective approach for preparing thin films. The soluble VOPcPhO is conveniently dissolved in a number of organic solvents.
Originality/value
The physical properties of the VOPcPhO:PCBM composite thin film and the electrical properties of the composite thin-film-based metal/organic/metal devices have not been reported in the literature, as far as our knowledge is concerned.
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Ruben B.O. Acevedo, Klaudia Kantarowska, Edson Costa Santos and Marcio C. Fredel
This paper aims to generate a review of available techniques to measure Residual Stress (RS) in Ti6Al4V components made by Ti6Al4V.
Abstract
Purpose
This paper aims to generate a review of available techniques to measure Residual Stress (RS) in Ti6Al4V components made by Ti6Al4V.
Design/methodology/approach
State of the art; literature review in the field of Residual Stress measurement of Ti6Al4V parts made by selective laser melting (SLM).
Findings
Different Residual Stress measurement techniques were detailed, regarding its concept, advantages and limitations. Regarding all researched references, hole drilling (semi destructive) and X-ray diffraction (nondestructive) were the most cited techniques for Residual Stress measurement of Ti6Al4V parts made by SLM.
Originality/value
An extensive analysis of RS measurement techniques for Ti6Al4V parts made by SLM.
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Ionut Nicolae, Dana Miu and Cristian Viespe
The detection of H2 concentrations in concentrations undetectable by the conventional detection method of surface acoustic wave (SAW) sensors based on frequency shift, by…
Abstract
Purpose
The detection of H2 concentrations in concentrations undetectable by the conventional detection method of surface acoustic wave (SAW) sensors based on frequency shift, by correlating analyte presence with Fourier spectra components.
Design/methodology/approach
Fast Fourier Transform (FFT) and autocorrelation analysis of phase noise in a SnO2-coated SAW sensor was performed. Fourier spectra were obtained by FFT from the SAW sensor resonance frequency instability, in the absence of analyte, and for H2 concentrations between 0.08 and 0.4 per cent.
Findings
All analyte concentrations are below the sensor limit of detection, which is 0.8 per cent for H2. Although these analyte concentrations caused no significant change in the resonance frequency of the SAW resonator, the FFT spectra presented several modifications, namely, the appearance of a new peak and the decrease of randomness. The authors consider that the effect is because of the chaotic behavior of the temporal dependence of the SAW resonance frequency. This explanation is substantiated by the decrease observed in the SAW oscillator autocorrelation function, which is an indication for a chaotic behavior.
Practical implications
As chaotic systems are extremely sensitive to perturbation, measurement methods based on chaos diagnosis could potentially greatly improve the SAW detection.
Originality/value
Fourier spectra components were correlated with analyte presence in concentrations undetectable by the conventional SAW detection method based on frequency shift.
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Adha Imam Cahyadi and Yoshio Yamamoto
The purpose of this paper is to present a design and verification through experiments of teleoperation of the 3 degrees‐of‐freedom micromanipulation system (MMS), in laboratory…
Abstract
Purpose
The purpose of this paper is to present a design and verification through experiments of teleoperation of the 3 degrees‐of‐freedom micromanipulation system (MMS), in laboratory conditions.
Design/methodology/approach
The MMS is constructed from piezoelectric actuators sited in a flexure hinge mechanism. The nonlinearity, especially hysteresis, due to a voltage steering scheme is compensated for, via a second‐order Dahl friction model. A simple mechanical model is then constructed to capture the behavior of the MMS. Redundant force feedback sensors are applied to the MMS in order to achieve flexible operation via the so‐called fault‐tolerancing mechanism. Finally, a teleoperation scheme based on passivity formalism is proposed to achieve a stable teleoperation system.
Findings
The hysteresis curve due to voltage steering can be minimized. The fault‐tolerancing concept using redundant sensors for comfortable use of the MMS has been successfully performed. The teleoperated MMS via a commercially available PHANToM® has been conducted under ineligible telecommunication channel delay.
Originality/value
The details of design, modelling and experimentations of the teleoperation of the MMS should promote the applicability of similar systems in the future.
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