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This paper aims to focus on the development and study properties of bisphenol-A glycidyldimethacrylate (BisGMA) and ethylene–propylene–diene monomer (EPDM) blend-based nanocomposites containing amine-functionalised multi-walled carbon nanotubes (MWCNT-NH2) as a compatibiliser.

First, BisGMA was synthesised from epoxy and methacrylic acid followed by the amine functionalisation of MWCNTs. A novel two-roll milling technique was then conducted to prepare nanocomposite specimens with MWCNT-NH2 as compatibiliser. Effect of MWCNT-NH2 content on the mechanical, thermal, electrical, corrosive and water absorption properties of the nanocomposites was investigated and results have been reported.

The results of the present work reveal that MWCNT-NH2 acts as a potential compatibiliser and nanofiller in BisGMA/EPDM blend-based nanocomposites. The authors report here that the nanocomposites exhibit improved mechanical, thermal and electrical properties with increased addition of MWCNT-NH2. Moreover, desirable results are obtained at 5 phr of nanofiller loading beyond which the properties deteriorate due to particle agglomeration. The nanocomposites display negligible corrosion and water absorption characteristics. Thus, the above fabricated nanocomposites with optimum compatibiliser content can serve as low-cost structural, thermal and electrical materials which can also be utilised in corrosive and moist environments.

The present investigation has come up with the successful and cost-effective fabrication of BisGMA/EPDM blend-based nanocomposites with optimum nanofiller/compatibiliser (MWCNT-NH2) content that can be used for a wide range of structural, thermal and electrical projects, as it is corrosion and moisture resistant. It is also the most durable from the mechanical point of view.

The above nanocomposites have never been designed before.

The purpose of this paper is to analyze the effect of driver size and number of shells on propagation delay and power for multi‐walled carbon nanotubes (MWCNT) interconnects at 22 nm technology node.

An equivalent circuit model of MWCNT is used for estimation and analysis of propagation delay and power. The delay and power through MWCNT and Cu interconnects are compared for various driver sizes and number of MWCNT shells.

The SPICE simulation results show that the MWCNT interconnect has lower propagation delay than Cu interconnects. The delay ratio of MWCNT to Cu decreases with increase in length for different driver size and number of MWCNT shells. However, the delay ratio increases with reduction in number of MWCNT shells. The ratio of average power consumption (MWCNT/Cu) also decreases with the variation in driver size and numbers of shells with respect to the length of interconnect. The theoretical study proves CNTs to be better alternatives against copper on the ground of performance parameters.

Several challenges remain to be overcome in the areas of fabrication and process integration for CNTs. Lowering of metal nanotube contact resistance would be vital, especially for local interconnect and via applications. Moreover, rigorous characterization and modeling of electromagnetic interactions in CNT bundles; 3‐D (metal) to 1‐D (CNT) contact resistance; impact of defects on electrical and thermal properties; and high‐frequency effects are being seen as additional challenges.

This paper investigates, assesses and compares the performance of carbon nanotubes (CNT) based interconnects as prospective alternatives to copper wire interconnects in future VLSI chips. Multi walled CNTs assure for long/global interconnect applications.

Pipelines are subject to pits, holes and cracks after staying in service for a while, especially in harsh environments. To repair the pipelines, composite materials are used, due to composite materials' low cost, high-corrosion resistance and easy handling. This study aims to investigate the reliability of the blister test for evaluating the bonding strength of multiwall carbon nanotube (MWCNT) on woven carbon-reinforced epoxy.

Flexural, hardness and Izod impact tests were used to evaluate MWCNT effect on the epoxy by adding different amounts, 0.2, 0.4, 0.6, 0.8 and 1 wt. %, of MWCNT, to be compared with pure epoxy.

The results showed that 0.8 wt.% gives the highest strength. The experimental results of 0.8 wt.% MWCNT reinforced carbon composite was compared with the finite element model under blister test, and the results showed high similarities.

Evaluation of the reliability and the advantages of MWCNT considering the high aspect ratio and high tensile strength, which is more than 15 times compared to steel, MWCNT enhances the strength, stiffness and toughness of epoxy used as a matrix in repairing pipelines, which leads to an increase in the resistance of composite materials against oil internal pressure before delamination.

The purpose of this paper is to study the effects of multi-walled carbon nanotubes (MWCNTs) loading on the thermal conductivity of nanocomposites.

In this paper, the polymer nanocomposite of MWCNT nanoparticles incorporated with PLA and LNR as compatibilizer were prepared via melt blending method.

The result has shown that the sample with 3.5 wt.% of MWCNT content provided higher thermal conductivity which is believed to be the optimum loading that formed the suitable percolated network for phonon conduction facilitation because of better dispersion in the PLA/LNR matrix as confirmed by SEM micrograph.

Thermal conductivity of polylactic acid (PLA)/liquid natural rubber (LNR) matrix improved with MWCNT.

With the technological progress, high-performance materials are emerging in the market of additive manufacturing to comply with the advanced requirements demanded for technical applications. In selective laser sintering (SLS), innovative powder materials integrating conductive reinforcements are attracting much interest within academic and industrial communities as promising alternatives to common engineering thermoplastics. However, the practical implementation of functional materials is limited by the extensive list of conditions required for a successful laser-sintering process, related to the morphology, powder size and shape, heat resistance, melt viscosity and others. The purpose of this study is to explore composite materials of polyamide 12 (PA12) incorporating multi-walled carbon nanotubes (MWCNT) and graphene nanoplatelets (GNP), aiming to understand their suitability for advanced SLS applications.

PA12-MWCNT and PA12-GNP materials were blended through a pre-optimized process of mechanical mixing with various percentages of reinforcement between 0.50 wt.% and 3.00 wt.% and processed by SLS with appropriate volume energy density. Several test specimens were produced and characterized with regard to processability, thermal, mechanical, electrical and morphological properties. Finally, a comparative analysis of the performance of both carbon-based materials was performed.

The results of this research demonstrated easier processability and higher tensile strength and impact resistance for composites incorporating MWCNT but higher tensile elastic modulus, compressive strength and microstructural homogeneity for GNP-based materials. Despite the decrease in mechanical properties, valuable results of electrical conductivity were obtained with both carbon solutions until 10^–6 S/cm.

The carbon-based composites developed in this research allow for the expansion of the applicability of laser-sintered parts to advanced fields, including electronics-related industries that require functional materials capable of protecting sensitive devices against electrostatic discharge.

Epoxy resins are widely used in a variety of engineering applications, including composite wind turbine blades used in the renewable energy industry, highly complex structural components for aircraft, paints, coatings, industrial tooling, biomedical systems, adhesives, electronics and automotive. Epoxies' low fracture toughness is one of the key obstacles preventing its adoption in a wider range of applications. To address epoxy's low fracture toughness, this paper aims to examine the roles of intra-ply hybridization and nano reinforcing.

This paper investigates the role of intra-ply hybridization of glass-carbon woven fibers and adding 0.8 wt.% of multiwall carbon nanotube (MWCNT) nano reinforcement to overcome the low fracture toughness of epoxy. A bending test is used to calculate the composites elastic parameters, and a notched sample three-point bending test is used to show crack behavior in addition to using materials characterization methods to reveal the effect of the MWCNT on structure, bonding, glass transition temperature (Tg) and dispersion of MWCNT in the matrix. Furthermore, this paper suggests using the finite element method to overcome the difficulty in calculating the crack extension.

Intra-ply hybridization and MWCNT reinforcement decrease the crack extension of epoxy with time. The inclusion of high-strength carbon fiber increased the fracture toughness of glass composite. Furthermore, the existence of MWCNT in the surrounding area of the notch in epoxy composites hinders crack propagation and provides stiffness at the interface by bridging the crack and eventually enhancing its fracture toughness.

Studying the role of intra-ply hybridization of glass-carbon woven fibers and adding 0.8 wt.% of MWCNT nano reinforcement to overcome the low fracture toughness of epoxy. Additionally, this research recommends using the finite element method to overcome the challenge of computing the crack extension.

This study aims to fabricate a multifunctional electromagnetic interference (EMI) shielding composite fabric with simultaneous high-efficiency photothermal conversion and Joule heating performances.

A multifunctional polypyrrole (PPy) hydrogel/multiwalled carbon nanotube (MWCNT)/cotton EMI shielding composite fabric (hereafter denoted as PHMC) was prepared by loading MWCNT onto tannin-treated cotton fabric, followed by in situ crosslinking-polymerization to synthesize three-dimensional (3D) conductive networked PPy hydrogel on the surface of MWCNT-coated cotton fabric.

Benefiting from the unique interconnected 3D networked conductive structure of PPy hydrogel, the obtained PHMC exhibited a high EMI-shielding effectiveness vale of 48 dB (the absorbing electromagnetic wave accounted for 84%) within a large frequency range (8.2–12.4 GHz). Moreover, the temperature of the laminated fabric reached 54°C within 900 s under 15 V, and it required more than 100 s to return to room temperature (28.7°C). When the light intensity was adjusted to 150 mW/cm², the PHMC temperature was about 38.2°C after lighting for 900 s, indicating high-efficiency electro-photothermal effect function.

This paper provides a novel strategy for designing a type of multifunctional EMI shielding composite fabric with great promise for wearable smart garments, EMI shielding and personal heating applications.

The present research investigates tailoring the physical properties of stereolithography (SL) epoxy‐based resins by dispersing controlled small amounts of multi‐walled carbon nanotubes (MWCNTs) directly in SL resins prior to layered manufacturing.

A modified 3D Systems 250/50 SL multi‐material machine was used where the machine was equipped with a solid‐state (355 nm) laser, unique ∼ 500 ml vat, overfill drain vat design that continuously flowed resin into the vat via a peristaltic pump, and 8.89 by 8.89 cm² platform. The vat did not include a recoating system. Pumping the composite resin assisted in maintaining the MWCNTs dispersed over long periods of time (with MWCNT settling times on the order of one week). The research approach required developing a method for dispersing the MWCNTs in SL resin, determining new SL build parameters for the modified resin and SL machine, and building and testing tensile specimens.

Mechanical mixing and ultrasonic dispersion provided simple means for dispersing MWCNTs in the SL resin. However, MWCNT agglomerates were observed in all the parts fabricated using the filled resins. Each concentration of MWCNTs resulted in a “new” resin requiring modifications to the SL build parameters, E_C and D_P. Once characterized, the modified resins performed similar to traditional resins in the SL process. Small dispersions of MWCNTs resulted in improvements in the tensile strength (TS) (or ultimate tensile stress) and fracture stress (FS) of tensile specimens as 0.025 percent (w/v) MWCNTs in DSM Somos^® WaterShed™ 11120 resin resulted in increases in TS and FS of 5.7 percent and 26 percent, respectively, when compared to unfilled resin. Increasing the concentration of MWCNTs to 0.10 percent (w/v) resulted in increases in TS and FS of 7.5 percent and 33 percent, respectively, over the unfilled resin. Transmission and scanning electron microscopy showed strong affinity between the epoxy resin and the MWCNTs.

Additional MWCNT type and concentrations in various SL resins should be investigated along with additional means for dispersion to provide sufficient information on developing new SL resins for unique functional applications.

It is anticipated that the methods described here will provide a basis for further development of advanced nanocomposite SL resins for end‐use applications.

This research successfully illustrated the dispersion and use of MWCNTs as a reinforcement material in a commercially available SL resin.

The synergistic effect of functionalization of multi-walled carbon nanotubes (CNT) using KMnO4 oxidation and initial tensile deformation on the electrical resistance of nanotube network/polyurethane composite subjected to elongation was studied.

Though the initial deformation irreversibly changed the arrangement of carbon nanotube network, subsequent cyclic elongation confirmed stable resistance values. The increased strain-dependent resistance of stimulated nanotube network/polyurethane composite was demonstrated by monitoring vibration of tambour leather after a bead impact and finger flexion.

The results showed a tenfold composite resistance increase for the composite prepared from KMnO₄ oxidized nanotubes, quantified by a so-called gauge factor, from a value of about 20 in comparison to the network prepared from pristine nanotubes. This is a substantial increase, which ranks the stimulated composite among materials with the highest electromechanical response.

The results in this paper are new and have not been published yet. The paper combines different ideas which are developed together. It presents a new concept of synergistic effect of CNT oxidation and application of pre-strain simulation. Oxidation and pre-strain increases by several times the sensitivity of the tested composites which are predetermined for use as strain sensors of various sizes and shapes.

In many of today’s manufacturing industries, such as automobile, aerospace, defence, die and mould making, medical and electrical discharge machining (EDM) has emerged as an effective material removal process. In this process, a series of discontinuous electric discharges is used for removing material from the workpiece in the form of craters generating a replica of the tool into the workpiece in a dielectric environment. Appropriate selection of the tool electrode material and combination of input parameters is an important requirement for performance enhancement of an EDM process. This paper aims to optimize an EDM process using single-valued neutrosophic grey relational analysis using Cu-multi-walled carbon nanotube (Cu-MWCNT) composite tool electrode.

This paper proposes the application of grey relational analysis (GRA) in a single-valued neutrosophic fuzzy environment to identify the optimal parametric intermix of an EDM process while considering Cu-MWCNT composite as the tool electrode material. Based on Taguchi’s L9 orthogonal array, nine experiments are conducted at varying combinations of four EDM parameters, i.e. pulse-on time, duty factor, discharge current and gap voltage, with subsequent measurement of two responses, i.e. material removal rate (MRR) and tool wear rate (TWR). The electrodeposition process is used to fabricate the Cu-MWCNT composite tool.

It is noticed that both the responses would be simultaneously optimized at higher levels of pulse-on time (38 µs) and duty factor (8), moderate level of discharge current (5 A) and lower level of gap voltage (30 V). During bi-objective optimization (maximization of MRR and minimization of TWR) of the said EDM process, the achieved values of MRR and TWR are 243.74 mm³/min and 0.001034 g/min, respectively.

Keeping in mind the type of response under consideration, their measured values for each of the EDM experiments are expressed in terms of linguistic variables which are subsequently converted into single-valued neutrosophic numbers. Integration of GRA with single-valued neutrosophic sets would help in optimizing the said EDM process with the Cu-MWCNT composite tool while simultaneously considering truth-membership, indeterminacy membership and falsity-membership degrees in a human-centric uncertain decision-making environment.