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Enzymes play a pivotal role in orchestrating essential biochemical processes and influencing various cellular activities in tissue. This paper aims to provide the process of enzyme diffusion within the tissue matrix and enhance the nano system performance by means of the effectiveness of enzymatic functions. The diffusion phenomena are also documented, providing chemical insights into the complex processes governing enzyme movement.

A computational analysis is used to develop and simulate an optimal control model using numerical algorithms, systematically regulating enzyme concentrations within the tissue scaffold.

The accompanying videographic footages offer detailed insights into the dynamic complexity of the system, enriching the reader’s understanding. This comprehensive exploration not only contributes valuable knowledge to the field but also advances computational analysis in tissue engineering and biomimetic systems. The work is linked to biomolecular structures and dynamics, offering a detailed understanding of how these elements influence enzymatic functions, ultimately bridging the gap between theoretical insights and practical implications.

A computational predictive model for nanozyme that describes the reaction diffusion dynamics process with enzyme catalysts is yet not available in existing literature.

Material extrusion (ME) is a low-cost additive manufacturing (AM) technique that is capable of producing metallic components using desktop 3D printers through a three-step printing, debinding and sintering process to obtain fully dense metallic parts. However, research on ME AM, specifically fused filament fabrication (FFF) of 316L SS, has mainly focused on improving densification and mechanical properties during the post-printing stage; sintering parameters. Therefore, this study aims to investigate the effect of varying processing parameters during the initial printing stage, specifically nozzle temperatures, T_n (190°C–300°C) on the relative density, porosity, microstructures and microhardness of FFF 3D printed 316L SS.

Cube samples (25 x 25 x 25 mm) are printed via a low-cost Artillery Sidewinder X1 3D printer using a 316L SS filament comprising of metal-polymer binder mix by varying nozzle temperatures from 190 to 300°C. All samples are subjected to thermal debinding and sintering processes. The relative density of the sintered parts is determined based on the Archimedes Principle. Microscopy and analytical methods are conducted to evaluate the microstructures and phase compositions. Vickers microhardness (HV) measurements are used to assess the mechanical property. Finally, the correlation between relative density, microstructures and hardness is also reported.

The results from this study suggest a suitable temperature range of 195°C–205°C for the successful printing of 316L SS green parts with high dimensional accuracy. On the other hand, T_n = 200°C yields the highest relative density (97.6%) and highest hardness (292HV) in the sintered part, owing to the lowest porosity content (<3%) and the combination of the finest average grain size (∼47 µm) and the presence of Cr23C6 precipitates. However, increasing T_n = 205°C results in increased porosity percentage and grain coarsening, thereby reducing the HV values. Overall, these outcomes suggest that the microstructures and properties of sintered 316L SS parts fabricated by FFF AM could be significantly influenced even by adjusting the processing parameters during the initial printing stage only.

This paper addresses the gap by investigating the impact of initial FFF 3D printing parameters, particularly nozzle temperature, on the microstructures and physical characteristics of sintered FFF 316L SS parts. This study provides an understanding of the correlation between nozzle temperature and various factors such as dimensional integrity, densification level, microstructure and hardness of the fabricated parts.

This paper aims to contribute to the performance improvement and the broader application of hot-dip galvanized coating.

First, the ability to provide barrier protection, galvanic protection, and corrosion product protection provided by hot-dip galvanized coating is introduced. Then, according to the varying Fe content, the growth process of each sublayer within the hot-dip galvanized coating, as well as their respective microstructures and physical properties, is presented. Finally, the electrochemical corrosion behaviors of the different sublayers are analyzed.

The hot-dip galvanized coating is composed of η-Zn sublayer, ζ-FeZn13 sublayer, δ-FeZn10 sublayer, and Γ-Fe3Zn10 sublayer. Among these sublayers, with the increase in Fe content, the corrosion potential moves in a noble direction.

There is a lack of research on the corrosion behavior of each sublayer of hot-dip galvanized coating in different electrolytes.

It provides theoretical guidance for the microstructure control and performance improvement of hot-dip galvanized coatings.

The formation mechanism, coating properties, and corrosion behavior of different sublayers in hot-dip galvanized coating are expounded, which offers novel insights and directions for future research.

This study examines how different stacking sequences of bamboo and flax fibers, treated with 5% aqueous sodium hydroxide (NaOH) and filled with 6wt% titanium oxide (TiO₂), affect the physical, mechanical and dry sliding wear resistance properties of a hybrid composite.

Composites with different fiber stacking arrangements were developed and tested per American Society for Testing and Materials (ASTM) standards to evaluate physical, mechanical and wear resistance properties, focusing on the impact of flax fiber mats at intermediate and outer layers.

The hybrid composite significantly outperformed composites reinforced solely with bamboo fibers, showing a 65.95% increase in tensile strength, a 53.29% boost in flexural strength and a 91.01% improvement in impact strength. The configuration with multiple layers of flax fiber mat at intermediate and outer levels also demonstrated superior wear resistance.

This study highlights the critical role of stacking order in optimizing the mechanical properties and wear resistance of hybrid composites. The findings provide valuable insights for the design and application of advanced composite materials, particularly in industries requiring high performance and durability.

The purpose of this paper is to analyze the mechanism of nanofluid enhanced heat transfer in microchannels and promote the application of nanofluids in industrial processes such as solar collectors, electronic cooling and automotive batteries.

The two-phase lattice Boltzmann method was used to calculate the flow and heat transfer characteristics of Al₂O₃ nanofluids in a microchannel at Re = 50. By comparing the simulation results of pure water, nanofluids without calculated nanoparticle-fluid interaction forces and nanofluids with calculated nanoparticle-fluid interaction forces, the effects of physical properties improvement and interaction forces on flow and heat transfer are quantified.

The findings show that the nanofluid (φ = 3%, R = 10 nm) increases the average Nusselt number by 22.40% at Re = 50. In particular, 16.16% of the improvement relates to nanoparticles optimizing the thermophysical parameters of the base fluid. The remaining 6.24% relates to the disturbance of the thermal boundary layer caused by the interaction between nanoparticles and the base fluid. Moreover, the nanoparticle has a negligible effect on the average Fanning friction factor. Ultimately, we conclude that the nanofluid is an excellent heat transfer working medium based on its performance evaluation criterion, PEC = 1.225.

To the best of the authors' knowledge, this research quantifies for the first time the contribution of nanoparticle-liquid interactions and nanofluids physical properties to enhanced heat transfer, advancing the knowledge of the nanoparticle's behavior in liquid systems.

The current study aims to develop a 3D-printed continuous metal fiber-reinforced recycled thermoplastic composite using an in-nozzle impregnation technique.

Recycled acrylonitrile butadiene styrene (RABS) plastic was blended with virgin ABS (VABS) plastic in a ratio of 60:40 weight proportion to develop a 3D printing filament that was used as a matrix material, while post-used continuous brass wire (CBW) was used as a reinforcement. 3D printing was done by using a self-customized print head to fabricate the flexural, compression and interlaminar shear stress (ILSS) test samples to evaluate the bending, compressive and ILSS properties of the build samples and compared with VABS and RABS-B samples. Moreover, the physical properties of the samples were also analyzed.

Upon three-point bend, compression and ILSS testing, it was found that RABS-B/CBW composite 3D printed with 0.7 mm layer width exhibited a notable improvement in maximum flexural load (L_max), flexural stress at maximum load (sf_max), flex modulus (E_f) and work of fracture (WOF), compression modulus (E_c) and ILSS properties by 30.5%, 49.6%, 88.4% 13.8, 21.6% and 30.3% respectively.

Limited research has been conducted on the in-nozzle impregnation technique for 3D printing metal fiber-reinforced recycled thermoplastic composites. Adopting this method holds the potential to create durable and high-strength sustainable composites suitable for engineering applications, thereby diminishing dependence on virgin materials.

Toronto's heritage program is reporting year over year growth in both the number of listed and designated properties and the amount of money secured for heritage projects. At the same time, it is widely recognized that heritage trade skills are in decline. The purpose of this research is to examine Toronto's heritage policy in its regulatory and economic context to understand why heritage trades are struggling while the heritage program and the market for heritage professional services flourish and to suggest solutions based on existing policy tools.

This research looks at the policy documents at the federal, provincial and municipal level that determine the minimum standard for heritage conservation in Toronto. It refers to secondary research on the economic context for these regulations to understand how they are applied and why they tend to produce certain outcomes. It introduces the regulatory context set by Canada's Standards and Guidelines for the Conservation of Historic Places and the Ontario Heritage Act. It goes on to analyse Toronto's local policy in more detail including density bonusing programs, the Toronto Official Plan and Heritage Conservation District planning standards.

Toronto's heritage policy creates asymmetrical opportunities for heritage professionals and heritage specializing tradespeople. While the work that heritage professionals do is required or strongly encouraged by policy and increases reliably with the amount of funding secured for heritage projects, heritage tradespeople do not enjoy similar advantages. Their work is not required in the same way as heritage professionals' or encouraged to the same degree, and money secured for heritage projects does not necessarily go towards work that would engage the building trades necessary to maintain heritage structures.

The value of job creation in heritage trades is a mainstay of heritage economic advocacy, and there is growing interest in the value of these trades skills as a resource for sustainable building practices. There is relatively little research considering how heritage policy and theory affect career opportunities for workers with these trades skills, and none that addresses those systemic pressures in the context of municipal heritage programs in Canada.

One of the often-employed building constituents in the construction sector is concrete, which involves hydration of cement, leading to the generation of carbon footprints during its production. Also, massive amount of natural aggregate is illegally mined, which poses serious environmental issues along with ecological misbalance. Researchers are in continuous search of appropriate substitutes to mitigate those challenges and develop innovative concrete mix. Consequently, depletion of natural resources, the disturbances to the environmental and ecological imbalance will reduce. The purpose of this study is to develop a Portland Slag Cement based novel sustainable concrete incorporating Alccofine and Recycled Refractory Brick as fractional replacement of cement and fine aggregate, respectively and evaluate its destructive, non-destructive and microstructural properties.

M25 grade of concrete adopting 0.45 water-binder proportion, with diverse percentage of Alccofine as fractional substitution of cement and 20% of recycled refractory brick (RRB) as fine aggregate, has been cast and evaluated for diverse mechanical strength following a curing of 7, 14 and 28 days. Scanning electron microscopic analysis has been carried out to study the microstructural changes in the specimens.

Supplementary use of Alccofine enhanced normal compressive strength of sustainable concrete mix blended with Portland Slag Cement by a large amount at all levels of 7, 14 and 28 days of curing. Test results indicated development of a favourable high-strength sustainable concrete mix by substituting cement with Alccofine.

This manuscript has demonstrated the possibility of developing sustainable concrete blends by incorporating Alccofine 1203 and RRB as partial replacement of Portland Slag Cement and natural fine aggregate, respectively. The strength and potential of concrete incorporating RRB for wider and special application in adverse environmental conditions having higher thermal gradient, as RRB is a valuable waste from high temperature kiln and furnaces. Alccofine 1203 has been included in the concrete mix as an alternative to Portland Slag Cement to improve the mechanical strength properties and durability of concrete intended for adverse environmental application.

The aim was not to perform a systematic review but firstly to search in PubMed, Science Direct, Scopus and Web of Science databases on the papers published in the last five years using tools for reviewing the statement of preferred information item for systematic reviews without focusing on a randomized analysis and secondly to perform a bibliometric analysis on the properties of films and coatings added of tocopherol for food packaging.

On January 24, 2022, information was sought on the properties of films and coatings added of tocopherol for use as food packaging published in PubMed, Science Direct, Scopus and Web of Science databases. Further analysis was performed using bibliometric indicators with the VOSviewer tool.

The searches returned 33 studies concerning the properties of films and coatings added of tocopherol for food packaging, which were analyzed together for a better understanding of the results. Data analysis using the VOSviewer tool allowed a better visualization and exploration of these words and the development of maps that showed the main links between the publications.

In the area of food science and technology, the development of polymers capable of promoting the extension of the shelf life of food products is sought, so the knowledge of the properties is vital for this research area since combining a biodegradable polymeric material with a natural antioxidant active is of great interest for modern society since they associate environmental preservation with food preservation.

The purpose of this study include analyzing the conformity between the General Guidelines for the Governance of the Indonesian Sharia Entities (GGG-ISE) and the implementation in the field and proposing a model of corporate governance for Islamic property developers.

This research uses a qualitative method with a case study approach. The researcher used a structured interview method and chose a purposive technique to determine the interviewees. This study has seven interviewees representing three Islamic property developer companies in Jember Regency, East Java, Indonesia. Data collection was conducted from June to July 2023, with a duration of about 60 min for each interviewee. The interviews were conducted face-to-face in each interviewee’s residential office.

The results showed that the companies had implemented several principles of GGG-ISE, namely, ethical and responsible actors, risk management, internal control, compliance, disclosure and transparency by making financial reports, shareholder rights and stakeholder rights, both internal and external stakeholders. Furthermore, this study found that GGG-ISE does not comply with the components of the organizing organ group. This study also found that governance reports have not been implemented in GGG-ISE components. In addition, this study identified a new component that must be present and not found in GGG-ISE, namely, a statement of the use of contracts for mudharib owners and between mudharib owners and stakeholders. Based on these findings, this study proposes a governance model for Islamic property developer companies called the GGG-IPDE.

This research is a pioneer in proposing a corporate governance model for Islamic property developers.