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The purpose of this paper is to explore the factors that affect the compactness of the mud filter cake, so as to prepare diaphragm wall slurry with good uniformity, small filtration loss and excellent recycling performance.

In this paper, the thickness, filtration loss and slurry viscosity of the filter cake are used as the characterization methods. The effects of pore depth, slurry specific gravity, intercalated metal ions, bridging polymer and water-soluble polymer on the compactness of the filter cake were studied.

The experimental results showed that the slurry's own pressure (pore depth) and specific gravity have little influence on the compactness of the filter cake and K⁺ can be considered as an auxiliary filtration loss reduction factor. Both the sulfonate copolymer and the potassium polyacrylate particle can significantly reduce the filtration loss of the slurry, which can effectively improve the filter cake compactness. Moreover, the composite application of potassium polyacrylate particles in the sizes of 80–100 and 150–200 meshes can exhibit a better filter cake compaction effect.

It solves the problems of high pulping cost, serious pollution of the environment, poor quality of filter cake formation and large filtration loss during the construction of the diaphragm wall, which improved the construction quality of the diaphragm wall.

The purpose of this paper is to prepare superabsorbent polymers (SAPs) based on acrylic acid, which is considered hygroscopic material to incorporate in rubber formulation, which results in producing moisten rubber that is used as roofing sheets.

SAPs were synthesized via free radical bulk polymerization technique using different content of cross-linker N, N'-methylenebisacrylamide and potassium persulfate. Differential scanning calorimeter, thermal gravimetric analysis, Fourier transform infrared spectroscopy and transmission electron microscopy were used to characterize SAPs and confirmed the formation of cross-linked hydrogel structure. The water absorbency and the gel fraction for sodium polyacrylate (NaPA) were investigated. Then, the influence of obtained NaPA on the swelling behavior of the prepared natural rubber (NR) compound has been discussed.

Absorption characteristics and gel fraction of NaPA were found to depend on the content of the cross-linker in the system. SAPs are used to improve the absorbance behavior and performance of the NR to produce, roofing sheets using in hot weather. The morphology of the obtained rubber compound was well-explained by using a scanning electron microscope.

The research provides a simple way to produce moisten rubber that can be used as a roofing sheet to overcome warm weather.

Moisten rubber roofing sheets provide a low-cost option in many developing countries with hot climates, and thus, help save the environment from global warming.

This paper aims to discuss the use of the sensor material in coating to detect defects which can cause corrosion on metal substrate. This coating consists of sodium polyacrylate (SP) to detect the presence of water and fluorescence substance 2-[4-(piperidin-1-yl)-5H-chromeno-[2,3-d]pyrimidin-2-yl]phenol [benzopyranopyrimidine (BPP)] to detect crack formation.

The coating resin is a mixture of poly(methyl methacrylate) (PMMA) and poly (methyl vinyl ether-alt-maleic anhydride). The additives are used to provide a visual indicator to the observer for when the coating exhibits any defects, so that quick action can be taken before corrosion develops further. SP has absorbent properties and expand when in contact with water, while BPP exhibits high luminous intensity in its solid form that is easily perceivable when exposed to UV. PVM/MA was used as the binder with ethanol as the solvent. The resistance of this coating towards water penetration was investigated using electrochemical impedance spectroscopy (EIS). The coating’s performance was observed in terms of visible optical appearance.

The sensor coating developed in this project serves as visual aid to the observer through the expansion of SP and high fluorescence of BPP material after the top coat is physically damaged. These findings are in provision of preventive measures that can be taken in case of top coat failure.

The resistance of the coating that contained SP could not be investigated with EIS due to its ability to expand immediately when in contact with liquids.

The coating developed in this study may be to detect corrosion.

The sensor material used has not been previously studied in applications to detect the presence of water or used to detect crack formation.

Based upon numerous assertions that a garment should be developed to maximise athletes' muscle performance while maintaining freedom of movement, this paper initially discusses the development of a perfusion suit that utilises a flexible single layer cooling system, with a view to the development of a cooling garment that does not employ a conventional tubing system which can restrict movement. The stages of the development have been described in detail, and an appropriate evaluation completed for both the initially developed perfusion suit and the subsequently developed cooling garment (modified perfusion suit). From results obtained from experiments conducted using the cooling garment, which incorporates super absorbent sodium polyacrylate pads as the cooling component, the following conclusions were drawn. First, anterior thigh temperature was reduced by 4–5°C at the end of the cooling period confirming that the developed cooling garment provides effective cooling. Second, although the difference between the skin temperature of the anterior thigh when cooling is applied to that when cooling is not applied decreased during the exercise period, the difference is still significant confirming that cooling of the anterior thigh by wearing the developed cooling garment persists throughout the duration of exercise.

Absorbent disposable products, such as diapers and sanitary napkins, are mostly one-time use items and designed to absorb and retain body fluids and solid waste. The present research work deals with the development and characterization of baby diapers made from four different fibrous compositions namely, pure bamboo, pure cotton, bamboo/cotton (70/30) and bamboo/cotton (50/50). Antibacterial activity tests have been carried out on baby diapers against S.aureus and E.coli. The strongest antibacterial activity in terms of reduction of the organism is found in diapers produced from pure bamboo fibre and the weakest antibacterial activity is found in cotton diapers. Superabsorbent polymer (SAP), namely, sodium polyacrylate is incorporated into the diapers to enhance their absorption capacity. The diapers are subjected to tests such as absorption capacity, liquid strike-through, acquisition time under load and diaper rewet under load to study their performance. Upon an analysis of the results, it is found that the performance of diapers produced from a bamboo/cotton (70/30) fibre blend is superior in comparison to the other ones.

The purpose of this paper is to investigate epoxysilane‐modified silica sols as surfactant‐free inorganic pigments dispersants and as co‐binders/reinforcing agents for silicate paints.

The performance of epoxysilane‐modified silica sols as dispersants for titania was studied using a polyacrylate‐based dispersant as reference. Furthermore, the effect of the addition of silica sols, with or without silane modification, to potassium silicate on binder properties was investigated.

Significant improvements were obtained in stability towards settling in water‐based titania pigments pastes and in light‐scattering efficiency (as much as 50 per cent) for the optimal size of the silica particle of 5 nm. The number of silane molecules per nm² silica particle surface must exceed a critical value of at least 1 molecule of epoxysilane per nm² particle surface. Additionally, improved stability towards gelling, water resistance and film‐forming properties of sol‐silicate binder mixes were achieved for epoxysilane‐modified silica sols.

Only epoxysilane‐modified silica sols were studied in this report. Titania pigment was examined but other important pigments (e.g. iron oxides) remain to be studied. In addition, only sol‐silicate mixes were investigated and not fully formulated silicate paints.

A method that produces stable, high‐performing, surfactant‐free inorganic pigments pastes. Furthermore, stable, high‐ratio, sol‐silicate binders can be obtained with improved water resistance and film properties for use in silicate paints.

The present method provides an easy route to obtain stable surfactant‐free inorganic pigments pastes, as well as makes stable, high‐ratio, sol‐silicate mixes/paints.

The purpose of this paper is to prepare poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid]s by two different routes. In the first route, poly(allyl amine-ran-acrylic acid)s were produced by radical copolymerization of a mixture of ally amine and acrylic acid, then converted into poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid]s by the Mannich reaction with a mixture of formaldehyde and phosphonic acid. In the second route, allyl amino bis(methylene phosphonic acid) monomer was synthesized and copolymerised with acrylic acid. The aim of this work is to produce low-molecular-weight copolymer with the low amount of nitrogen and phosphorous having better scale inhibiting performance than commercial low-molecular-weight poly(acrylic acid)s.

Poly(allyl amine-ran-acrylic acid)s were prepared by radical copolymerisation of a mixture of ally amine and acrylic acid, and the molecular weight of copolymers was regulated by using an effective chain transfer compound and the formed copolymer was reacted with a mixture of formaldehyde and phosphorous acid. Allyl amino bis(methylene phosphonic acid) monomer was prepared and then copolymerised with acrylic acid using radical initiators.

Poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid] produced with both routes, especially low-molecular weight ones have better anti-scaling performance than low-molecular-weight commercial poly(acrylic acid).

By using an excess of formaldehyde and phosphonic acid, a limited increase in the conversion of amine groups of poly(allyl amine-ran-acrylic acid) to amino methylene phosphonic acid groups was achieved, so unreacted amine groups were always present in the structure of the final copolymers.

The low-molecular-weight poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid] may be used as a better anti-scaling polymer in industry.

The low-molecular-weight poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid] is an alternative polymer for scale inhibition in the water boilers.

The low-molecular-weight poly[allyl amino bis(methylene phosphonic acid)-ran-acrylic acid] copolymers containing both carboxylic acid and amino bis(methylene phosphonic acid) are more effective anti-scaling additives than poly(acrylic acid)s in water boilers.

To evaluate the inhibition efficiency (IE) of polyvinyl alcohol (PVA) in controlling the corrosion of carbon steel immersed in neutral aqueous solutions containing 60 ppm of Cl⁻, in the absence and presence of Zn²⁺. To investigate the influence of sodium sulphite (Na₂SO₃), sodium dodecyl sulphate (SDS), pH and duration of immersion on the IE of PVA‐Zn²⁺ system. To analyse the protective film formed on the metal surface.

The IE has been evaluated by weight loss method. The protective film was analysed by FTIR and fluorescence spectra.

A formulation consisting of 100 ppm of PVA and 75 ppm of Zn²⁺ offered 81 per cent IE to carbon steel immersed in a solution containing 60 ppm of Cl⁻. A synergistic effect on inhibition of a combination of PVA and Zn²⁺ was observed during the tests. The protective film consisted of the Fe²⁺‐PVA complex and Zn(OH)₂. It was found to be UV‐fluorescent. When SDS was added to the PVA‐Zn²⁺ system, the mixture showed maximum IE at the critical micelle concentration (200 ppm) of SDS (an anionic surfactant). The oxygen‐scavenging effect of Na₂SO₃ increased as the concentration of Na₂SO₃ was increased. At lower concentrations of Na₂SO₃, the transport of the inhibitors played a more major role than did the removal of dissolved oxygen. As the pH value was increased, the IE of the PVA‐Zn²⁺ system decreased. As the duration of immersion was increased, the IE was observed to decrease.

Electrochemical studies such as polarization and AC impedance spectra will enlighten more on the mechanistic aspects of corrosion inhibition.

If this study is carried out at high temperature under simulated conditions, the findings may find applications in cooling water systems.

The role of transport of inhibitors towards the metal surface from the bulk of the solution, formation of micelles by surfactants, removal of dissolved oxygen by oxygen scavenger, competition between formation of insoluble iron‐inhibitor complex on metal surface and formation of soluble iron chloride in influencing the inhibitive property has been investigated. The protective film was analysed by FTIR spectra and fluorescence spectra.

The purpose of this paper is to present a new ceramic suspension to fabricate complex ceramic parts by stereolithography (SL).

The process consists of preparation of aqueous ceramic suspensions, building ceramic parts, drying, subsequent binder removal, and sintering. Highly concentrated aqueous ceramic suspensions with a suitable viscosity are prepared, then a wet green ceramic part fabricated in a SL machine according to a 3D model is dried in polyethylene glycol. After binder removal sintering in a high temperature‐sintering furnace, a complex ceramic part is obtained.

The dispersant, volume fraction of ceramic powder and powder diameter could influence the viscosity of suspension. The cured depth is inversely proportional to the scanning speed of laser spot when the laser power keeps a constant and proportional to the concentration of monomer. The penetration depth and critical exposure are 0.27 mm and 231.2 mJ/cm² from the experimental result of the windowpanes method. A new support structure could prevent the deformation of ceramic part from the suspension and improve the quality of ceramic parts. A complex impeller is fabricated at last.

The dimensional and surface accuracy of ceramic SL should be further investigated.

This paper describes a new aqueous ceramic suspension to produce complex‐shaped ceramic parts by SL.

The purpose of this paper is to develop a novel process of integral ceramic molds for investment casting of hollow turbine blades.

At first, a resin pattern of a hollow turbine blade prototype is fabricated by stereolithography (SL). And then aqueous gelcasting process is utilized to fill the resin pattern with ceramic slurry of low viscosity and low shrinkage, through in situ polymerization of the slurry a ceramic mold is formed. At last, the ceramic mold for investment casting of hollow turbine blade is obtained by vacuum drying, pyrolyzing and sintering.

An integral ceramic mold is successfully fabricated by combining SL and gelcasting process, cores and shell are connected with each other and thus high relative position accuracy is guaranteed. Properties of integral ceramic mold at room temperature and high temperature satisfy the requirements of directional casting for complex‐shaped thin‐walled blades.

Because the integral ceramic mold is a close body, it is very difficult to directly measure its inner dimensions and the relative position accuracy of cores and shell, and the further research is needed.

This method enhanced the versatility of using SL prototype in the fabrication of integral ceramic mold for investment castings. Although this paper took a hollow turbine blade as an example, this method is also capable of fabricating integral ceramic molds for other complex investment castings.