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The purpose of this study is to reveal the effect of nano-Al₂O₃ particle addition on the nucleation/growth kinetics, microhardness, wear resistance and corrosion resistance of Co–P–xAl₂O₃ nanocomposite plating.

The kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating prepared by electroplating were investigated by electrochemical measurements, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Vickers microhardness measurement, SRV5 friction and wear tester and atomic force microscopy.

A 12 g/L nano-Al₂O₃ addition in the plating solution can transform the nucleation/growth kinetics of the plating from the 3D progressive model to the 3D instantaneous model. The microhardness of the plating increased with the increase of nano-Al₂O₃ content in plating. The wear resistance of the plating did not adhere strictly to Archard’s law. An even and denser corrosion product film was generated due to the finer grains, with a high corrosion resistance.

The effect of different nano-Al₂O₃ addition on the nucleation/growth kinetics and properties of Co–P–xAl₂O₃ nanocomposite plating was investigated, and an anticorrosion mechanism of Co–P–xAl₂O₃ nanocomposite plating was proposed.

This study aims to focus on numerical simulation investigations of phase transformation during cooling of 55SiMnMo steel, which is commonly applied to improve mechanical properties.

A mathematical model based on the finite element method (FEM) and the phase transformation kinetics model has been proposed to predict microstructure changes during continuous cooling of 55SiMnMo steel. This model can be employed to analyze the variation of austenite, special upper bainite and lump-like composite structure with cooling time at different cooling rates.

According to the continuous cooling experiments, when the cooling rate is lower than 0.1°C/s, the special upper bainite is the only transformation product which decreases with increasing cooling rate; when the cooling rate is above 0.5°C/s, the transformation products include special upper bainite and lump-like composite structure. Meanwhile, the results of continuous cooling experiment verified the correctness of this finite element model.

This model has a great value for proper controlling of the cooling process which can improve the quality of hollow drill steel and increase the service life of the final product.

The purpose of this paper is to study the effect of temperature on Zn–Ni alloys in ChCl–Urea.

Based on cyclic voltammetry experiments, the deposition behavior and kinetics of the Zn–Ni alloy are studied. The nucleation process of the Zn–Ni alloy is studied in detail via chronoamperometry experiments. The effects of the deposition temperature on the microstructure, Ni content and phase composition of Zn–Ni alloy coatings are investigated via scanning electron microscopy and X-ray diffraction (XRD) combined with classical thermodynamics.

The results show that with increasing temperature, the reduction peak shifts toward a more positive electric potential, which is beneficial for the co-electric deposition process, and the diffusion coefficient is estimated. With increasing temperature, the nucleation process of the Zn–Ni alloy becomes a three-dimensional instantaneous nucleation, the typical kinetic parameters are determined using the standard 3D growth proliferation control model and the Gibbs free energy is estimated. The Zn–Ni alloy coatings are prepared via normal co-deposition. With increasing temperature, the degree of crystallinity increases, the coating gradually becomes uniform and compact and the XRD peak intensity increases.

The nucleation process of the Zn–Ni alloy at different temperatures is analyzed. The diffusion coefficient D and Gibbs free energy are calculated. The contribution of the three processes at different temperatures is analyzed. The effect of temperature on the morphology of the Zn–Ni alloy coatings is studied.

The paper describes the physical phenomena which influence the electrical and mechanical characteristics of low temperature coefficient, high stability thin metal resistive films. Emphasis is placed on the Matthiensen and Arrhenius rules in respect of resistivity and time‐temperature stabilities. The phenomena outlined are highly dependent on the deposition methods used and film properties are discusssed in terms of the film formation kinetics, substrates, and deposition technologies. The production of thin metal film resistive films based on these principles readily achieves temperature coefficients of <5 ppm/°C over the temperature range −55°C to + 155°C with load stress stabilities of <300 ppm with full dissipation, 155°C, 2000 hours, which is as good as bulk nickel‐chromium alloy foil.

This paper aims to investigate the stress corrosion cracking (SCC) process of sensitized 304 stainless steel during the slow strain rate test by using the electrochemical noise (EN) technique.

EN data are interpreted based on chaos and wavelet analyses, and correlation dimension and wavelet energy distribution are used as indicators for SCC process identification.

Experimental results reveal that the corrosion potential abruptly decreases from 180 to 100 mV at 6,300 s and the current increases from 10 to 100 nA accordingly, which is attributed to passive film breakdown and crack initiation. Chaos and wavelet analyses results reveal that, as crack initiates, the correlation dimensions increase from 1.2 to 1.9, and the corresponding distribution frequencies of maximum relative wavelet energy change from high frequency to low frequency.

SCC is monitored in lab, and crack initiation and propagation are identified by chaos and wavelet analyses. This work lays the foundation for SCC detection in field using EN.

The purpose of this paper is to discuss the recently developed multi-physics computational model for the conventional Gas Metal Arc Welding (GMAW) joining process that has been upgraded with respect to its predictive capabilities regarding the spatial distribution of the mechanical properties controlling the ballistic limit (i.e. penetration resistance) of the weld.

The original model consists of five modules, each dedicated to handling a specific aspect of the GMAW process, i.e.: electro-dynamics of the welding-gun; radiation-/convection-controlled heat transfer from the electric arc to the workpiece and mass transfer from the filler-metal consumable electrode to the weld; prediction of the temporal evolution and the spatial distribution of thermal and mechanical fields within the weld region during the GMAW joining process; the resulting temporal evolution and spatial distribution of the material microstructure throughout the weld region; and spatial distribution of the as-welded material mechanical properties. The model is upgraded through the introduction of the sixth module in the present work in recognition of the fact that in thick steel GMAW weldments, the overall ballistic performance of the armor may become controlled by the (often inferior) ballistic limits of its weld (fusion and heat-affected) zones.

The upgraded GMAW process model is next applied to the case of butt-welding of MIL A46100 (a prototypical high-hardness armor-grade martensitic steel) workpieces using filler-metal electrodes made of the same material. The predictions of the upgraded GMAW process model pertaining to the spatial distribution of the material microstructure and ballistic-limit-controlling mechanical properties within the MIL A46100 butt-weld are found to be consistent with general expectations and prior observations.

To the authors’ knowledge, the present work is the first reported attempt to establish, using computational modeling, functional relationships between the GMAW process parameters and the mechanical properties controlling the ballistic limit of the resulting weld.

This study aims to analyze the shear strength and fracture mechanism of full Cu-Sn IMCs joints with different Cu₃Sn proportion and joints with the conventional interfacial structure in electronic packaging.

The Cu-Sn IMCs joints with different Cu₃Sn proportion were fabricated through soldering Cu-6 μm Sn-Cu sandwich structure under the extended soldering time and suitable pressure. The joints of conventional interfacial structure were fabricated through soldering Cu-100 μm Sn-Cu sandwich structure. After the shear test was conducted, the fracture mechanism of different joints was studied through observing the cross-sectional fracture morphology and top-view fracture morphology of sheared joints.

The strength of joints with the conventional interfacial structure was 26.6 MPa, while the strength of full Cu-Sn IMCs joints with 46.7, 60.6, 76.7 and 100 per cent Cu₃Sn was, respectively, 33.5, 39.7, 45.7 and 57.9 MPa. The detailed reason for the strength of joints showing such regularity was proposed. For the joint of conventional interfacial structure, the microvoids accumulation fracture happened within the Sn solder. However, for the full Cu-Sn IMCs joint with 46.7 per cent Cu₃Sn, the cleavage fracture happened within the Cu6Sn5. As the Cu₃Sn proportion increased to 60.6 per cent, the inter-granular fracture, which resulted in the interfacial delamination of Cu₃Sn and Cu6Sn5, occurred along the Cu₃Sn/Cu6Sn5 interface, while the cleavage fracture happened within the Cu6Sn5. Then, with the Cu₃Sn proportion increasing to 76.7 per cent, the cleavage fracture happened within the Cu6Sn5, while the transgranular fracture happened within the Cu₃Sn. The inter-granular fracture, which led to the interfacial delamination of Cu₃Sn and Cu, happened along the Cu/Cu₃Sn interface. For the full Cu₃Sn joint, the cleavage fracture happened within the Cu₃Sn.

The shear strength and fracture mechanism of full Cu-Sn IMCs joints was systematically studied. A direct comparison regarding the shear strength and fracture mechanism between the full Cu-Sn IMCs joints and joints with the conventional interfacial structure was conducted.

A multi-physics process model is developed to analyze reactive melt infiltration (RMI) fabrication of ceramic-matrix composite (CMC) materials and components. The paper aims to discuss this issue.

Within this model, the following key physical phenomena governing this process are accounted for: capillary and gravity-driven unsaturated flow of the molten silicon into the SiC/SiC CMC preform; chemical reactions between the silicon melt and carbon (either the one produced by the polymer-binder pyrolysis or the one residing within the dried matrix slurry); thermal-energy transfer and source/sink phenomena accompanying reactive-flow infiltration; volumetric changes accompanying chemical reactions of the molten silicon with the SiC preform and cooling of the as-fabricated CMC component to room temperature; development of residual stresses within, and thermal distortions of, the as-fabricated CMC component; and grain-microstructure development within the SiC matrix during RMI.

The model is validated, at the material level, by comparing its predictions with the experimental and modeling results available in the open literature. The model is subsequently applied to simulate RMI fabrication of a prototypical gas-turbine engine hot-section component, i.e. a shroud. The latter portion of the work revealed the utility of the present computational approach to model fabrication of complex-geometry CMC components via the RMI process.

To the authors’ knowledge, the present work constitutes the first reported attempt to apply a multi-physics RMI process model to a gas-turbine CMC component.

This work aims to focus on evaluation of the ability of cathodically deposited ZrO₂-based coatings to stabilise the surface of silver against tarnishing caused by S2−-based species and comparison of these coatings with Cr oxide-based coating.

The coatings were evaluated using inductively coupled plasma optical emission spectroscopy (ICP-OES), scanning electron microscopy (SEM), impedance spectroscopy (EIS) and galvanostatic reduction of specimens exposed to H₂S vapours.

The kinetics of deposition were studied and optimum conditions for coating formation were determined. The options of manual application suitable for practical use were studied also. Zr specimens showed better barrier properties than did a chromated specimen. The best properties were observed on a specimen with a manually fast-applied coating. However, Zr coating does not provide as good protection from tarnishing as chromate. The structure of the Cr coating contains species of chromate that oxidize species of S2−.

The paper provides new information regarding the anticorrosive properties of cathodically deposited ZrO₂ coating as an alternative to Cr coating for the preservation of silver surfaces.

Solid thin films have been deposited on stainless steel 314 (SS 314) substrates in a chemical vapor deposition (CVD) reactor at different flow rates of natural gas mostly methane (CH₄). The purpose of this paper was to investigate experimentally the variation of thin film deposition rate with the variation of gas flow rate.

During experiment, the effect of gap between activation heater and substrate on the deposition rate has also been observed. To do so, a hot filament thermal CVD unit is used. The flow rate of natural gas varies from 0.5 to 2 l/min at normal temperature and pressure and the gap between activation heater and substrate varies from 4 to 6.5 mm.

Results show that deposition rate on SS 314 increases with the increase of gas flow rate. It is also seen that deposition rate increases with the decrease of gap between activation heater and substrate within the observed range. These results are analyzed by dimensional analysis to correlate the deposition rate with gas flow rate, surface roughness and film thickness. In addition, friction coefficient and wear rate of SS 314 sliding against SS 304 under different normal loads are also investigated before and after deposition. The obtained results reveal that the values of friction coefficient and wear rate are lower after deposition than that of before deposition.

In this study, thin film deposition rate on SS 314 was investigated using CVD. The obtained results were analyzed by dimensional analysis to correlate the deposition rate with gas flow rate, surface roughness and film thickness. The friction coefficient and wear rate of SS 314 were also examined before and after deposition.