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The purpose of this study is to develop a multifunctional coating layer based on nitrocellulose (NC)/acrylic resins containing precipitated silica and kaolin and investigate its suitability for use in packaging applications.

Different loading levels (1 and 5 Wt.%) of precipitated silica or kaolin particles were incorporated into NC/acrylic-based coating formulations and applied on low-density polyethylene (LDPE) films. The coatings and coated LDPE films were characterized in terms of structural, physical, mechanical, thermal, optical, surface, morphological and water vapor barrier properties.

The glossiness of the coating formulations decreased by increasing the precipitated silica and kaolin content. The incorporation of kaolin (1 and 5 Wt.%) and precipitated silica (1 Wt.%) had no significant effect on the melting temperature of LDPE film; however, with the addition of 5 Wt.% precipitated silica, the melting and crystallization temperatures were significantly changed. The incorporation of 5 Wt.% precipitated silica and kaolin also enhanced the water vapor barrier properties of LDPE films. The light transmittance declined with the precipitated silica and kaolin addition, especially in the ultraviolet (UV)-A/UV-B spectrum regions indicating an excellent UV light protection.

It was concluded that NC/acrylic resins coatings containing precipitated silica and kaolin exhibit improved thermal stability, UV and water vapor barrier properties and have the potential for use in packaging applications.

Heat exchangers (HEs) which provide heat transfer and transfer energy through direct or indirect contact between fluids have an essential role in many processes as a part of various industries from pharmaceutical production to electronic devices. Using nanofluid as working fluid and integrating different types of turbulators could be used to upgrade the thermal effectiveness of HEs. Recently, to obtain more increment in thermal effectiveness, hybrid nanofluids are used that are prepared by mixing two or more various nanoparticles. The purpose of this experimental and numerical study is investigating different scenarios for improving the effectiveness of a concentric U-tube type HE.

In the numerical section of this study, different turbulator modifications, including circular and quarter circular rings, were modeled to determine the effect of adding turbulator on thermal performance. In addition, Al₂O₃/water and SiO₂/water single and Al₂O₃–SiO₂/water hybrid nanofluids were experimentally tested in an unmodified concentric U-tube HE in two different modes, including counter flow and parallel flow. Al₂O₃–SiO₂/water hybrid nanofluid was prepared at 2% (wt./wt.) particle ratio and compared with Al₂O₃/water and SiO₂/water single type nanofluids at same particle ratios and with distilled water.

Numerical modeling findings exhibited that integrating turbulators to the concentric tube type HE caused to raise in the effectiveness by improving heat transfer area. Also, experimental results indicated that using both hybrid and single type nanofluids notably upgraded the thermal performance of the concentric U-tube HE. Integrating turbulators cannot be an effective alternative in a concentric U-tube type HE with lower diameter because of raise in pressure drop. Numerically achieved findings exhibited that using quarter circular turbulators decreased pressure drop in comparison with circular turbulators. According to the experimental outcomes, using hybrid Al₂O₃–SiO₂/water nanofluid leads to obtain more thermal performance in comparison with single type nanofluids. The highest increment in overall heat transfer coefficient of HE by using Al₂O₃–SiO₂/water nanofluid achieved as 58.97% experimentally.

The overall outcomes of the current research exhibited the positive impacts of using hybrid nanofluid and integrating turbulators. In this empirical and numerical survey, numerical simulations were performed to specify the impact of applying different turbulators and hybrid nanofluid on the flow and thermal characteristics in a concentric U-tube HE. The achieved outcomes exhibited that using hybrid nanofluid can notably increase the thermal performance with negligible pressure drop in comparison with two different turbulator modifications.

This paper aims to investigate the responses of single piles and pile groups due to tunneling-induced ground movements in a two-layered soil system. The analyses mainly focus on the additional single pile responses in terms of bending moment, lateral deflection, axial force, shaft resistance and pile settlement. Subsequently, a series of parametric studies were carried out to better understand the responses of single piles induced by tunneling. To give further understanding regarding the pile groups, a 2 × 2 pile group with two different pile head conditions, namely, free and capped, was considered.

Using the PLAXIS three-dimensional (3D) software, a full 3D numerical modeling is performed to investigate the effects of ground movements caused by tunneling on adjacent pile foundations. The numerical model was validated using centrifuge test data found in the literature. The relevance of the 3D model is also judged by comparison with the 2D plane strain model using the PLAXIS 2D code.

The numerical test results reveal that tunneling induces significant displacements and internal forces in nearby piles. The magnitude and distribution of internal forces depend mainly on the position of the pile toe relative to the tunnel depth and the distance between the pile and the vertical axis of the tunnel. As the volume loss increases from 1% to 3%, the apparent loss of pile capacity increases from 11% to 20%. By increasing the pile length from 0.5 to 1.5 times, the tunnel depth, the maximum pile settlement and lateral deflection decrease by about 63% and 18%, respectively. On the other hand, the maximum bending moment and axial load increase by about 7 and 13 times, respectively. When the pile is located at a distance of 2.5 times the tunnel diameter (Dt), the additional pile responses become insignificant. It was found that an increase in tunnel depth from 1.5Dt to 2.5Dt (with a pile length of 3Dt) increases the maximum lateral deflection by about 420%. Regarding the interaction between tunneling and group of piles, a positive group effect was observed with a significant reduction of the internal forces in rear piles. The maximum bending moment of the front piles was found to be higher than that of the rear piles by about 47%.

Soil is a complex material that shows differently in primary loading, unloading and reloading with stress-dependent stiffness. This general behavior was not possibly being accounted for in simple elastic perfectly plastic Mohr–Coulomb model which is often used to predict the behavior of soils. Thus, in the present study, the more advanced hardening soil model with small-strain stiffness (HSsmall) is used to model the non-linear stress–strain soil behavior. Moreover, unlike previous studies THAT are usually based on the assumption that the soil is homogeneous and using numerical methods by decoupled loadings under plane strain conditions; in this study, the pile responses have been exhaustively investigated in a two-layered soil system using a fully coupled 3D numerical analysis that takes into account the real interactions between tunneling and pile foundations. The paper presents a distinctive set of findings and insights that provide valuable guidance for the design and construction of shield tunnels passing through pile foundations.

This study aims to using Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and scanning electron microscope/energy dispersive Xray spectrometer to identify different automotive coatings for forensic purpose.

Two four-layered samples in a hit-and-run case were compared layer by layer with three different methods. FTIR spectroscopy was used to primarily identify the organic and inorganic compositions. Raman spectrum and scanning electron microscope/energy dispersive Xray spectrometer (SEM-EDS) were further used to complement the FTIR results.

Two weak and tiny peaks in one layer found between two samples by FTIR, Raman microscope and SEM-EDS verified the result of differences. The study used the three instruments in combination and found it’s effective in sensing coatings, especially in the inorganic additives.

Using these three instruments in combination is more accurate than individually in multilayered coating analysis for forensic purpose.

The three different instruments all present unique information on the composition, and provided similar and mutually verifiable results on the two samples.

With this method, scientists could identify and discriminate important coating evidences with tiny but characteristic differences.

This paper aims to investigation of processes for Pb²⁺ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb²⁺ ions by various nanocomposites has been explained from water/wastewaters. ZnO-based nanocomposites, as eco-friendly nanoparticles with unique physicochemical properties, have received increased attention to remove Pb²⁺ ions from water/wastewaters.

In this review, different ZnO-based nanocomposites were reviewed for their application in the removal of Pb²⁺ ions from the aqueous solution, typically for wastewater treatment using methodology, such as adsorption. This review focused on the ZnO-based nanocomposites for removing Pb²⁺ ions from water and wastewaters systems.

The ZnO-based nanocomposite was prepared by different methods, such as electrospinning, hydrothermal/alkali hydrothermal, direct precipitation and polymerization. Depending on the preparation method, various types of ZnO-based nanocomposites like ZnO-metal (Cu/ZnO, ZnO/ZnS, ZnO/Fe), ZnO-nonmetal (PVA/ZnO, Talc/ZnO) and ZnO-metal/nonmetal (ZnO/Na-Y zeolite) were obtained with different morphologies. The effects of operational parameters and adsorption mechanisms were discussed in the review.

The findings may be greatly useful in the application of the ZnO-based nanocomposite in the fields of organic and inorganic pollutants adsorption.

The present study is novel, because it investigated the morphological and structural properties of the synthesized ZnO-based nanocomposite using different methods and studied the capability of green-synthesized ZnO-based nanocomposite to remove Pb²⁺ ions as water contaminants.

The current review can be used for the development of environmental pollution control measures.

This paper reviews the rapidly developing field of nanocomposite technology.

The purpose of this study is to know the influence of palm oil fuel ash and metakaolin on the strength of concrete and crack resistance of reinforced concrete beam. An ordinary portland cement has been used in the concretes production where it is an important material to be considered due to its nature that reacts with every substance present. During the cement production, a significant amount of carbon dioxide is emitted from the clinker in rotary kiln and lot of energy is required in the production processes. Such an event can be prevented by replacing the part of cement with metakaolin (MK) and palm oil fuel ash (POFA). Aside from being a cementitious alternative, the materials can also contribute to a greener environment and more sustainable building, as POFA is available in Malaysia and may be used to substitute cement and minimize pollution.

This study assesses the effect of MK and POFA on the concrete in terms of compressive strength and cracks pattern of the reinforced concrete beam based on the relevant previous studies.

From this study, the compressive strength of concrete containing MK and POFA was higher than the control mix with the percentage of improvement in the range of 0.8%–78.2% for MK and 0.5%–14%, respectively. The optimum content of MK and POFA is between the range of 10% and 15% and 10% and 20%, respectively, to achieve high strength of concrete. Other than that, the inclusion of MK to the concrete mix improves the strength of reinforced concrete beams and reduces cracks on the surface of reinforced concrete beams, whereas the inclusion of POFA to the concrete mix increases the cracks on reinforced concrete beams. The cracks appeared within the flexure zone of every beam containing the MK and POFA.

It was found that the fineness of MK and POFA has a significant influence on the mechanical properties of concrete.

Long time ago, multistructured materials showed great interest being considered as the bridge between bulk and atomic materials. Core-shell particles are kind of composite materials that refer to multilayered structures with a core totally surrounded by shell(s) (onion-like structure). These new structures can offer an advantage of applying new adjustable parameters like shape, stoichiometry and chemical ordering, in addition to the opportunity of tailoring more complexed structures for different applications. Recently it was found that these structures can be tuned and taken for more advanced path with novel structures formed of core surrounded by multishells. The purpose of this study is to study the effect of the new anticorrosive pigments with its mutual shells and how each shell affects the performance of the pigment in protecting the metal and which shell will be more relevant in its effect.

The prepared pigments were characterized using X-ray fluorescence, X-ray diffraction, TEM and SEM/EDX to prove their core-shell structure, and then they were integrated in coating formulations to evaluate their anticorrosive activity using immersion test and electrochemical impedance spectroscopy (EIS).

The results showed that the prepared core-shell pigments possess a lot of unique characteristics and can offer improved anticorrosive performance in the generated coatings.

Core-mutual shells structured pigments were prepared for improving the corrosion resistivity of the organic coatings as a new trend in anticorrosive pigments.

This study aims to investigate the clamour by the people of Plateau State, Nigeria, for more licences to bear firearms for self-defence because of the continuous failure of the Nigerian State to defend them against the Fulani herders’ aggression. More guns less crime deterrence theory served as the framework of analysis, which posits that because criminals are rational beings, they will choose not to attack when they know many people have legitimate firearms.

Data were collected from four purposefully selected local government areas of the state. This study’s sample size was 400. Therefore, 400 copies of the Google Forms questionnaire were administered. In addition, seven key informant interviews and nine focus group discussions were also conducted.

This research results showed the following: while self-defence and issuance of more licenses were supported by 84.8% and 85.0% of respondents, respectively, they also argued that the insurgency would likely end if more people carried legally acquired firearms. Again, the study showed a positive correlation between the government’s failure in security and the demand for self-defence exercises against the Fulani herdsmen’s insurgency, this study recommends more licensed firearms for the people of Plateau State.

This study recommends more licenced firearms for the people of Plateau State.

One of the sources for the increase in the carbon footprint on the earth is the manufacturing of cement, which causes a severer environmental impact. Abundant research is going on to diminish CO₂ content in the atmosphere by appropriate utilization of waste by-products of industries. Alkali-activated slag concrete (AASC) is an innovative green new concrete made by complete replacement of cement various supplementary cementitious raw materials. Concrete is a versatile material used in different fields of structures, so it is very important to study the durability in different exposures along with the strength. The purpose of this paper is to study the performance of AASC by incorporating quartz sand as fine aggregate under different exposure conditions.

The materials for this innovative AASC are selected based on preliminary studies and literature surveys. Based on numerous trials a better performance mix proportion of AASC with quartz sand is developed with 1:2:4 mix proportion, 0.8 alkali Binder ratio, 19 M of NaOH and 50% concentration of Na₂SiO₃. Subsequently, AASC cubes are prepared and exposed for 3, 7, 14, 28, 56, 90, 112, 180, 252 and 365 days in ambient, acid, alkaline, sulfate, chloride and seawater and tested for compressive strength. In addition, to study the microstructural characteristics, scanning electron microscope (SEM), energy dispersive X-ray analysis and X-ray diffraction analysis was also performed.

Long-term performance of AASC developed with quartz sand is very good in the ambient, alkaline environment of 5% NaOH and seawater with the highest compressive strength values of 51.8, 50.83 and 64.46, respectively. A decrease in compressive strengths was observed after the age of 14, 56 and 112 days for acid, chloride and sulfate exposure conditions, respectively. SEM image shows a denser microstructure of AASC matrix for ambient, alkaline of 5% NaOH and seawater.

The proposed AASC is prepared with a mix proportion of 1:2:4, so the other proportions of AASC need to verify. In general plain, AASC is not used in practice except in few applications, in this work the effect of reinforced AASC is not checked. The real environmental exposure in fields may not create for AASC, as it was tested in different exposure conditions in the laboratory.

The developed AASC is recommended in practical applications where early strength is required, where the climate is hot, where water is scarce for curing, offshore and onshore constructions exposed to the marine environment and alkaline environment industries like breweries, distilleries and sewage treatment plants. As AASC is recommended for ambient air and in other exposures, its implementation as a construction material will reduce the carbon footprint.

The developed AASC mix proportion 1:2:4 is an economical mix, because of low binder content, but it exhibits a higher early age compressive strength value of 45.6 MPa at the age of 3 days. The compressive strength increases linearly with age from 3 to 365 days when exposed to seawater and ambient air. The performance of AASC is very good in the ambient, alkaline environment and seawater compared to other exposure conditions.

The purpose of this paper is to review cases of artificial reefs built through additive manufacturing (AM) technologies and analyse their ecological goals, fabrication process, materials, structural design features and implementation location to determine predominant parameters, environmental impacts, advantages, and limitations.

The review analysed 16 cases of artificial reefs from both temperate and tropical regions. These were categorised based on the AM process used, the mortar material used (crucial for biological applications), the structural design features and the location of implementation. These parameters are assessed to determine how effectively the designs meet the stipulated ecological goals, how AM technologies demonstrate their potential in comparison to conventional methods and the preference locations of these implementations.

The overview revealed that the dominant artificial reef implementation occurs in the Mediterranean and Atlantic Seas, both accounting for 24%. The remaining cases were in the Australian Sea (20%), the South Asia Sea (12%), the Persian Gulf and the Pacific Ocean, both with 8%, and the Indian Sea with 4% of all the cases studied. It was concluded that fused filament fabrication, binder jetting and material extrusion represent the main AM processes used to build artificial reefs. Cementitious materials, ceramics, polymers and geopolymer formulations were used, incorporating aggregates from mineral residues, biological wastes and pozzolan materials, to reduce environmental impacts, promote the circular economy and be more beneficial for marine ecosystems. The evaluation ranking assessed how well their design and materials align with their ecological goals, demonstrating that five cases were ranked with high effectiveness, ten projects with moderate effectiveness and one case with low effectiveness.

AM represents an innovative method for marine restoration and management. It offers a rapid prototyping technique for design validation and enables the creation of highly complex shapes for habitat diversification while incorporating a diverse range of materials to benefit environmental and marine species’ habitats.