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Article
Publication date: 2 March 2022

Maryam Khashij, Mohammad Hossein Salmani, Arash Dalvand, Hossien Fallahzadeh, Fatemeh Haghirosadat and Mehdi Mokhtari

This paper aims to investigation of processes for Pb2+ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb2+ ions by…

Abstract

Purpose

This paper aims to investigation of processes for Pb2+ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb2+ ions by various nanocomposites has been explained from water/wastewaters. ZnO-based nanocomposites, as eco-friendly nanoparticles with unique physicochemical properties, have received increased attention to remove Pb2+ ions from water/wastewaters.

Design/methodology/approach

In this review, different ZnO-based nanocomposites were reviewed for their application in the removal of Pb2+ ions from the aqueous solution, typically for wastewater treatment using methodology, such as adsorption. This review focused on the ZnO-based nanocomposites for removing Pb2+ ions from water and wastewaters systems.

Findings

The ZnO-based nanocomposite was prepared by different methods, such as electrospinning, hydrothermal/alkali hydrothermal, direct precipitation and polymerization. Depending on the preparation method, various types of ZnO-based nanocomposites like ZnO-metal (Cu/ZnO, ZnO/ZnS, ZnO/Fe), ZnO-nonmetal (PVA/ZnO, Talc/ZnO) and ZnO-metal/nonmetal (ZnO/Na-Y zeolite) were obtained with different morphologies. The effects of operational parameters and adsorption mechanisms were discussed in the review.

Research limitations/implications

The findings may be greatly useful in the application of the ZnO-based nanocomposite in the fields of organic and inorganic pollutants adsorption.

Practical implications

The present study is novel, because it investigated the morphological and structural properties of the synthesized ZnO-based nanocomposite using different methods and studied the capability of green-synthesized ZnO-based nanocomposite to remove Pb2+ ions as water contaminants.

Social implications

The current review can be used for the development of environmental pollution control measures.

Originality/value

This paper reviews the rapidly developing field of nanocomposite technology.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 May 2020

Anh Thi Le and Swee-Yong Pung

This paper aims to investigate the reusability of metal/metal oxide-coupled ZnO nanorods (ZnO NRs) to degrade rhodamine B (RhB).

Abstract

Purpose

This paper aims to investigate the reusability of metal/metal oxide-coupled ZnO nanorods (ZnO NRs) to degrade rhodamine B (RhB).

Design/methodology/approach

ZnO NRs particles were synthesized by precipitation method and used to remove various types of metal ions such as Cu2+, Ag+, Mn2+, Ni2+, Pb2+, Cd2+ and Cr2+ ions under UV illumination. The metal/metal oxide-coupled ZnO NRs were characterized by scanning electron microscope, X-ray diffraction and UV-Vis diffuse reflectance. The photodegradation of RhB dye by these metal/metal oxide-coupled ZnO NRs under UV exposure was assessed.

Findings

The metal/metal oxide-coupled ZnO NRs were successfully reused to remove RhB dye in which more than >90% of RhB dye was degraded under UV exposure. Furthermore, the coupling of Ag, CuO, MnO2, Cd and Ni particles onto the surface of ZnO NRs even enhanced the degradation of dye. The dominant reactive species involved in the degradation of RhB dye were OH- and O2-free radicals.

Research limitations/implications

The coupling of metal/metal oxide onto the surface of ZnO NRs after metal ions removal could affect the photocatalytic performance of ZnO NRs in the degradation of organic pollutants in subsequent stage.

Practical implications

A good reusability performance of metal/metal oxide-coupled ZnO NRs make ZnO NRs become a desirable photocatalyst material for the treatment of wastewater, which consists of both heavy metal ions and organic dyes.

Originality/value

Metal/metal oxide coupling onto the surface of ZnO NRs particles improved subsequent UV-assisted photocatalytic degradation of RhB dye.

Details

Pigment & Resin Technology, vol. 50 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 October 2022

Marina Stramarkou, Achilleas Bardakas, Magdalini Krokida and Christos Tsamis

Carbon dioxide (CO2) has attracted special scientific interest over the last years mainly because of its relation to climate change and indoor air quality. Except for this, CO2

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Abstract

Purpose

Carbon dioxide (CO2) has attracted special scientific interest over the last years mainly because of its relation to climate change and indoor air quality. Except for this, CO2 can be used as an indicator of food freshness, patients’ clinical state and fire detection. Therefore, the accurate monitoring and controlling of CO2 levels are imperative. The development of highly sensitive, selective and reliable sensors that can efficiently distinguish CO2 in various conditions of temperature, humidity and other gases’ interference is the subject of intensive research with chemi-resistive zinc oxide (ZnO)-based sensors holding a privileged position. Several ZnO nanostructures have been used in sensing applications because of their versatile features. However, the deficient selectivity and long-term stability remain major concerns, especially when operating at room temperature. This study aims to encompass an extensive study of CO2 chemi-resistive sensors based on ZnO, introducing the most significant advances of recent years and the best strategies for enhancing ZnO sensing properties.

Design/methodology/approach

An overview of the different ZnO nanostructures used for CO2 sensing and their synthesis methods is presented, focusing on the parameters that highly affect the sensing mechanism and, thus, the performance of CO2 sensors.

Findings

The selectivity and sensitivity of ZnO sensors can be enhanced by adjusting various parameters during their synthesis and by doping or treating ZnO with suitable materials.

Originality/value

This paper summarises the advances in the rapidly evolving field of CO2 sensing by ZnO sensors and provides research directions for optimised sensors in the future.

Details

Sensor Review, vol. 42 no. 6
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 8 February 2011

Rabindra N. Das, How T. Lin, John M. Lauffer and Voya R. Markovich

There has been increasing interest in the development of printable electronics to meet the growing demand for low‐cost, large‐area, miniaturized, flexible and lightweight devices…

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Abstract

Purpose

There has been increasing interest in the development of printable electronics to meet the growing demand for low‐cost, large‐area, miniaturized, flexible and lightweight devices. The purpose of this paper is to discuss the electronic applications of novel printable materials.

Design/methodology/approach

The paper addresses the utilization of polymer nanocomposites as it relates to printable and flexible technology for electronic packaging. Printable technology such as screen‐printing, ink‐jet printing, and microcontact printing provides a fully additive, non‐contacting deposition method that is suitable for flexible production.

Findings

A variety of printable nanomaterials for electronic packaging have been developed. This includes nanocapacitors and resistors as embedded passives, nanolaser materials, optical materials, etc. Materials can provide high‐capacitance densities, ranging from 5 to 25 nF/in2, depending on composition, particle size, and film thickness. The electrical properties of capacitors fabricated from BaTiO3‐epoxy nanocomposites showed a stable dielectric constant and low loss over a frequency range from 1 to 1,000 MHz. A variety of printable discrete resistors with different sheet resistances, ranging from ohm to Mohm, processed on large panels (19.5×24 inches) have been fabricated. Low‐resistivity materials, with volume resistivity in the range of 10−4‐10−6 ohm cm, depending on composition, particle size, and loading, can be used as conductive joints for high‐frequency and high‐density interconnect applications. Thermosetting polymers modified with ceramics or organics can produce low k and lower loss dielectrics. Reliability of the materials was ascertained by (Infrared; IR‐reflow), thermal cycling, pressure cooker test (PCT) and solder shock testing. The change in capacitance after 3× IR‐reflow and after 1,000 cycles of deep thermal cycling between −55°C and +125°C was within 5 per cent. Most of the materials in the test vehicle were stable after IR‐reflow, PCT, and solder shock.

Research limitations/implications

The electronic applications of printable, high‐performance nanocomposite materials such as adhesives (both conductive and non‐conductive), interlayer dielectrics (low‐k, low‐loss dielectrics), embedded passives (capacitors and resistors), and circuits, etc.. are discussed. Also addressed are investigations of printable optically/magnetically active nanocomposite and polymeric materials for fabrication of devices such as inductors, embedded lasers, and optical interconnects.

Originality/value

A thin film printable technology was developed to manufacture large‐area microelectronics with embedded passives, Z‐interconnects and optical waveguides, etc. The overall approach lends itself to package miniaturization because multiple materials and devices can be printed in the same layer to increase functionality.

Details

Circuit World, vol. 37 no. 1
Type: Research Article
ISSN: 0305-6120

Keywords

Article
Publication date: 13 October 2022

Ziyan Wang, Xueli Yang, Caixuan Sun, Hongyan Liu, Junkai Shao, Mengjie Wang, Junyi Dong, Guanlong Cao and Guofeng Pan

This paper aims to successfully synthesize three-dimensional spindle-like Au functionalized Co3O4-ZnO nanocomposites; characterize the structure, morphology and surface chemical…

Abstract

Purpose

This paper aims to successfully synthesize three-dimensional spindle-like Au functionalized Co3O4-ZnO nanocomposites; characterize the structure, morphology and surface chemical properties of the products; study the effect of Au NPs doping concentration, operating temperature different gas to, sensing properties; and introduce an attractive gas sensor for acetone detection.

Design/methodology/approach

Au NPs functionalized Co3O4-ZnO nanocomposite was prepared by coprecipitation and impregnation methods; the structure and surface chemical property of the products were characterized by XRD, SEM, TEM, UV-Vis, BET and XPS. The sensing ability of Au@Co3O4-ZnO for acetone and mechanism was analyzed systematically.

Findings

The results of gas sensing tests show that the unique component structure, Schottky junction and catalytic effect of Au functionalization make it have low operating temperature, excellent selectivity, high response (10 ppm, 56) and rapid response recovery time.

Research limitations/implications

All the characterization and test data of the prepared materials are provided in this paper and reveals the gas sensing mechanism of the gas sensor.

Practical implications

The detection limit is 2.92–100 ppb acetone. It is promising to be applied in low-power, micro detection and miniature acetone gas sensors.

Social implications

The gas sensor prepared has a lower working temperature and low detection limit, so it has promising application prospects in low-concentration acetone detection and early warning.

Originality/value

The unique component structure, Schottky junction and catalytic effect of Au functionalization Co3O4-ZnO make it have low operating temperature, excellent selectivity and rapid response recovery time.

Details

Sensor Review, vol. 42 no. 6
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 8 July 2022

Syafiqah Ishak, Shazlina Johari, Muhammad Mahyiddin Ramli and Darminto Darminto

This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film…

Abstract

Purpose

This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film are preferred for sensing applications because of their modifiable surface morphology, very large surface-to-volume ratio and superior stability due to better crystallinity. The gas detection mechanism involves surface reaction, in which the adsorption of gas molecules on the ZnO thin film affects its conductivity and reduces its electrical properties. One way to enhance the gas sensing properties is by doping ZnO with other elements. A few of the common and previously used dopants include tin (Sn), nickel (Ni) and gallium (Ga).

Design/methodology/approach

In this brief review, previous works on doped-ZnO formaldehyde sensing devices are presented and discussed.

Findings

Most devices provided good sensing performance with low detection limits. The reported operating temperatures were within the range of 200̊C –400̊C. The performance of the gas sensors can be improved by modifying their nanostructures and/or adding dopants.

Originality/value

As of yet, a specific review on formaldehyde gas sensors based on ZnO metal semiconductors has not been done.

Details

Sensor Review, vol. 42 no. 5
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 8 January 2018

Yuxin Miao, Guofeng Pan, Caixuan Sun, Ping He, Guanlong Cao, Chao Luo, Li Zhang and Hongliang Li

The purpose of this paper is to study the effect of doping, annealing temperature and visible optical excitation on CuO-ZnO nanocomposites’ acetone sensing properties and…

Abstract

Purpose

The purpose of this paper is to study the effect of doping, annealing temperature and visible optical excitation on CuO-ZnO nanocomposites’ acetone sensing properties and introduce an attractive candidate for acetone detection at about room temperature.

Design/methodology/approach

ZnO nanoparticles doped with CuO were prepared by sol-gel method, and the structure and morphology were characterized via X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy and Brunauer-Emmett-Teller. The photoelectric responses of CuO-ZnO nanocomposites to cetone under the irradiation of visible light were investigated at about 30°C. The photoelectric response mechanism was also discussed with the model of double Schottky.

Findings

The doping of CuO enhanced performance of ZnO nanoparticles in terms of the photoelectric responses and the gas response and selectivity to acetone of ZnO nanoparticles, in addition, decreasing the operating temperature to about 30ºC. The optimum performance was obtained by 4.17% CuO-ZnO nanocomposites. Even at the operating temperature, about 30ºC, the response to 1,000 ppm acetone was significantly increased to 579.24 under the visible light irradiation.

Practical implications

The sensor fabricated by 4.17% CuO-ZnO nanocomposites exhibited excellent acetone-sensing characteristics at about 30ºC. It is promising to be applied in low power and miniature acetone gas sensors.

Originality/value

In the present research, a new nanocomposite material of CuO-ZnO was prepared by Sol-gel method. The optimum gas sensing properties to acetone were obtained by 4.17% CuO-ZnO nanocomposites at about 30ºC operating temperature when it was irradiated by visible light with the wavelength more than 420 nm.

Details

Sensor Review, vol. 38 no. 3
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 10 June 2014

Shaohong Wei, Youjuan Zhang and Meihua Zhou

The purpose of this paper is to synthesize SnO2–ZnO hollow nanofibers, study their sensing properties and introduce an attractive candidate for formaldehyde detection in practice…

Abstract

Purpose

The purpose of this paper is to synthesize SnO2–ZnO hollow nanofibers, study their sensing properties and introduce an attractive candidate for formaldehyde detection in practice.

Design/methodology/approach

Pure and SnO2–ZnO hollow nanofibers were synthesized by electrospinning method and characterized via X-ray diffraction, field-emission scanning electron microscopy and Fourier transform infrared spectroscopy. The formaldehyde-sensing properties were investigated.

Findings

The optimum performance was obtained at 260°C by the 14 at.% SnO2–ZnO hollow nanofiber sensor. The sensor could detect formaldehyde down to 0.1 ppm with rapid response–recovery time (4-6 s and 7-9 s, respectively), high sensitivity, good selectivity and stability. The relationship between the sensor’s sensitivity and formaldehyde concentration suggests that the adsorbed oxygen species on the sensor’s surface is O2−. The prominent sensing properties are attributed to the one dimensional hollow nanofiber structures and the promoting effects of SnO2.

Practical implications

The sensor fabricated from 14 at.% SnO2–ZnO fibers exhibits excellent formaldehyde-sensing characteristics. It can be used for formaldehyde detection in practice.

Social implications

The electrospinning method is a very simple and convenient method for fabricating hollow nanofibers and the sensing material is of low cost.

Originality/value

To the best of the authors’ knowledge, studies on formaldehyde sensing of SnO2–ZnO hollow nanofibers have not been reported before.

Details

Sensor Review, vol. 34 no. 3
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 22 February 2024

Thien Vuong Nguyen, Vy Do Truc, Tuan Anh Nguyen and Dai Lam Tran

This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First…

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Abstract

Purpose

This study aims to explore the synergistic effect of oxide nanoparticles (ZnO, Fe2O3, SiO2) and cerium nitrate inhibitor on anti-corrosion performance of epoxy coating. First, cerium nitrate inhibitors are absorbed on the surface of various oxide nanoparticles. Thereafter, epoxy nanocomposite coatings have been fabricated on carbon steel substrate using these oxide@Ce nanoparticles as both nano-fillers and nano-inhibitors.

Design/methodology/approach

To evaluate the impact of oxides@Ce nanoparticles on mechanical properties of epoxy coating, the abrasion resistance and impact resistance of epoxy coatings have been examined. To study the impact of oxides@Ce nanoparticles on anti-corrosion performance of epoxy coating for steel, the electrochemical impedance spectroscopy has been carried out in 3% NaCl solution.

Findings

ZnO@Ce3+ and SiO2@Ce3+ nanoparticles provide more enhancement in the epoxy pore network than modification of the epoxy/steel interface. Whereas, Fe2O3@Ce3+ nanoparticles have more to do with modification of the epoxy/steel interface than to change the epoxy pore network.

Originality/value

Incorporation of both oxide nanoparticles and inorganic inhibitor into the epoxy resin is a promising approach for enhancing the anti-corrosion performance of carbon steel.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 September 2021

Iyappan Gunasekaran, Govindaraj Rajamanickam, Santhosh Narendiran, Ramasamy Perumalsamy, Kiruthika Ramany and Radha Sankararajan

Various approaches have been made to alter the vibration sensing properties of zinc oxide (ZnO) films to achieve high sensitivity. This paper aims to report the experimental study…

Abstract

Purpose

Various approaches have been made to alter the vibration sensing properties of zinc oxide (ZnO) films to achieve high sensitivity. This paper aims to report the experimental study of the fabrication of precursor molar ratio concentration varied ZnO nanostructures grown on rigid substrates using the refresh hydrothermal method. The effect of these fabricated ZnO nanostructures-based vibration sensors was experimentally investigated using a vibration sensing setup.

Design/methodology/approach

ZnO nanostructures have been grown using low temperature assisted refresh hydrothermal method with different precursor molar concentrations 0.025 M (R1), 0.075 M (R2) and 0.125 M (R3). Poly 3,4-ethylenedioxythiophene polystyrene sulfonate, a p-type material is spun coated on the grown ZnO nanostructures. Structural analysis reveals the increased intensity of the (002) plane and better c-axis orientation of the R2 and R3 sample comparatively. Morphological examination shows the changes in the grown nanostructures upon increasing the precursor molar concentration. The optical band gap value decreases from 3.11 eV to 3.08 eV as the precursor molar concentration is increased. Photoconductivity study confirms the formation of a p-n junction with less turn-on voltage for all the fabricated devices. A less internal resistance of 0.37 kΩ was obtained from Nyquist analysis for R2 compared with the other two fabricated samples. Vibration testing experimentation showed an improved output voltage of the R2 sample (2.61 V at 9 Hz resonant frequency and 2.90 V for 1 g acceleration) comparatively. This also gave an increased sensitivity of 4.68 V/g confirming its better performance when compared to the other fabricated two samples.

Findings

Photoconductivity study confirms the formation of a p-n junction with less turn-on voltage for all the fabricated devices. A less internal resistance of 0.37 kΩ was calculated from the Nyquist plot. Vibration testing experimentation proves an increased sensitivity of 4.68 V/g confirming its better performance when compared to the other fabricated two samples.

Originality/value

Vibration testing experimentation proves an increased sensitivity of 4.68 V/g for R2 confirming its better performance when compared to the other fabricated two samples.

Details

Circuit World, vol. 49 no. 2
Type: Research Article
ISSN: 0305-6120

Keywords

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