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1 – 10 of 126Zhenxiao Chen, Derek Ingham, Mohammed Ismail, Lin Ma, Kevin J. Hughes and Mohamed Pourkashanian
The purpose of this paper is to investigate the effects of hydrogen humidity on the performance of air-breathing proton exchange membrane (PEM) fuel cells.
Abstract
Purpose
The purpose of this paper is to investigate the effects of hydrogen humidity on the performance of air-breathing proton exchange membrane (PEM) fuel cells.
Design/methodology/approach
An efficient mathematical model for air-breathing PEM fuel cells has been built in MATLAB. The sensitivity of the fuel cell performance to the heat transfer coefficient is investigated first. The effect of hydrogen humidity is also studied. In addition, under different hydrogen humidities, the most appropriate thickness of the gas diffusion layer (GDL) is investigated.
Findings
The heat transfer coefficient dictates the performance limiting mode of the air-breathing PEM fuel cell, the modelled air-breathing fuel cell is limited by the dry-out of the membrane at high current densities. The performance of the fuel cell is mainly influenced by the hydrogen humidity. Besides, an optimal cathode GDL and relatively thinner anode GDL are favoured to achieve a good performance of the fuel cell.
Practical implications
The current study improves the understanding of the effect of the hydrogen humidity in air-breathing fuel cells and this new model can be used to investigate different component properties in real designs.
Originality/value
The hydrogen relative humidity and the GDL thickness can be controlled to improve the performance of air-breathing fuel cells.
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Keywords
Isaac Chukwuemezu Okereke, Mohammed S. Ismail, Derek Ingham, Kevin J. Hughes, Lin Ma and Mohamed Pourkashanian
This paper aims to numerically investigate the impact of gas diffusion layer (GDL) anisotropic transport properties on the overall and local performance of polymer electrolyte…
Abstract
Purpose
This paper aims to numerically investigate the impact of gas diffusion layer (GDL) anisotropic transport properties on the overall and local performance of polymer electrolyte fuel cells (PEFCs).
Design/methodology/approach
A three-dimensional numerical model of a polymer electrolyte fuel cell with a single straight channel has been developed to investigate the sensitivity of the fuel cell performance to the GDL anisotropic transport properties – gas permeability, diffusivity, thermal conductivity and electrical conductivity. Realistic experimentally estimated GDL transport properties were incorporated into the developed PEFC model, and a parametric study was performed to show the effect of these properties on fuel cell performance and the distribution of the key variables of current density and oxygen concentration within the cathode GDL.
Findings
The results showed that the anisotropy of the GDL must be captured to avoid overestimation/underestimation of the performance of the modelled fuel cell. The results also showed that the fuel cell performance and the distributions of current density and oxygen mass fraction within the cathode GDL are highly sensitive to the through-plane electrical conductivity of the GDL and, to a lesser extent, the through-plane diffusivity, and the thermal conductivity of the GDL. The fuel cell performance is almost insensitive to the gas permeability of the GDL.
Practical implications
This study improves the understanding of the importance of the GDL anisotropy in the modelling of fuel cells and provides useful insights on improving the efficiency of the fuel cells.
Originality/value
Realistic experimentally estimated GDL transport properties have been incorporated into the PEFC model for the first time, allowing for more accurate prediction of the PEFC performance.
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Mohammed Ismail, Derek Ingham, Kevin J Hughes, Lin Ma and Mohamed Pourkashanian
The purpose of this paper is to numerically investigate the effects of the shape on the performance of the cathode catalyst agglomerate used in polymer electrolyte fuel cells…
Abstract
Purpose
The purpose of this paper is to numerically investigate the effects of the shape on the performance of the cathode catalyst agglomerate used in polymer electrolyte fuel cells (PEFCs). The shapes investigated are slabs, cylinders and spheres.
Design/methodology/approach
Three 1D models are developed to represent the slab like, cylindrical and spherical agglomerates, respectively. The models are solved for the concentration of the dissolved oxygen using a finite element software, COMSOL Multiphysics®. “1D” and “1D axisymmetric” schemes are used to model the slab like and cylindrical agglomerates, respectively. There is no one-dimensional scheme available in COMSOL Multiphysics® for spherical coordinate systems. To resolve this, the governing equation in “1D” scheme is mathematically modified to match that of the spherical coordinate system.
Findings
For a given length of the diffusion path, the variation in the performances of the investigated agglomerates is dependent on the operational overpotential. Under low magnitudes of the overpotentials, where the performance is mainly limited by reaction, the slab-like agglomerate outperforms the spherical and cylindrical agglomerates. In contrast, under high magnitudes of the overpotentials where the agglomerate performance is mainly limited by diffusion, the spherical and cylindrical agglomerates outperform the slab-like agglomerate.
Practical implications
The current advances in the nano-fabrication technology gives more flexibility in designing the catalyst layers in PEFCs to the desired structures. If the design of the agglomerate catalyst is to be assessed, the current micro-scale modelling offers an efficient and rapid way forward.
Originality/value
The current micro-scale modelling is an efficient alternative to developing a full (or half) fuel cell model to evaluate the effects of the agglomerate structure.
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Piergiorgio Alotto, Massimo Guarnieri and Federico Moro
The purpose of this paper is to optimize the performance of direct methanol fuel cells for portable applications by combining a non‐linear, fully coupled circuit model and a…
Abstract
Purpose
The purpose of this paper is to optimize the performance of direct methanol fuel cells for portable applications by combining a non‐linear, fully coupled circuit model and a stochastic optimization procedure.
Design/methodology/approach
A novel non‐linear equivalent circuit that accounts for electrochemical reactions and charge generation inside catalyst layers, electronic and protonic conduction, methanol crossover through the membrane, mass transport of reactants inside diffusion layers is presented. The discharge dynamic of the fuel cell, depending on the initial methanol concentration and on the load profile, is modelled by using the mass conservation equation. The equivalent circuit is interfaced to a stochastic optimization procedure in order to maximize the battery duration while minimizing fuel crossover.
Findings
In the proposed circuit scheme, unlike semi‐empirical models, lumped circuit parameters are derived directly from mass transport and electric equations in order to fully describe the dynamic performance of the fuel cell. Physical and geometrical parameters are optimized in order to improve the system runtime. It is shown that a combined use of fuel cells and lithium batteries can improve the runtime of portable electronic devices compared to traditional supply systems based on lithium batteries only.
Research limitations/implications
The one‐dimensional model of the micro fuel cell does not take into account possible transverse mass and electric charge flows in the fuel cell layers; most of the geometric and physics model parameters cannot be estimated from direct in situ or ex situ measurements.
Practical implications
Direct methanol fuel cells are nowadays a promising technology for replacing or complementing lithium batteries due to their high energy density. Most limiting features of direct methanol fuel cells are the fuel crossover and its slow oxidation kinetics. By using the proposed approach, fuel cell parameters can be optimized in order to enhance the discharge runtime and to reduce the methanol crossover.
Originality/value
The equivalent circuit model with optimized lumped non‐linear parameters can be used when designing power management units for portable electronic devices.
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Piergiorgio Alotto, Massimo Guarnieri and Federico Moro
The purpose of this paper is to simulate micro direct methanol fuel cells (DMFCs) for portable electronic devices by means of a non‐linear equivalent circuit based on a fully…
Abstract
Purpose
The purpose of this paper is to simulate micro direct methanol fuel cells (DMFCs) for portable electronic devices by means of a non‐linear equivalent circuit based on a fully coupled, dynamic, electrochemical model.
Design/methodology/approach
The equivalent circuit accounts for electrochemical reactions and electric current generation inside the catalyst layers, electronic and protonic conduction, fuel crossover across the membrane, mass transport of reactants inside the diffusion layers. The V‐I characteristic of the device is obtained by combining mass transport and electric equations. The transient dynamics is accounted for by an equivalent capacitance, while the slow dynamics by the mass conservation equation. The equivalent circuit is embedded in the Matlab/Simulink® dynamic model of a hybrid system, consisting of a micro fuel cell and a Li‐ion rechargeable battery.
Findings
An original equivalent circuit of a passive DMFC suitable for static and dynamic simulations under variable loading conditions is proposed and validated.
Research limitations/implications
The one‐dimensional model of the micro cell does not take into account transverse mass transfer and current density variations in the cell layers, which can be due to non‐homogeneous materials or to the complex dynamics of the convective mass flow in the reservoir and in the room air.
Practical implications
The equivalent circuit can be used for simulating the dynamic performance in realistic operating conditions when the fuel cell is used to supply the electronic equipment through a power management unit.
Originality/value
The DMFC is described from an electrical point of view as a controlled non‐linear generator; such equivalent representation is particularly suited for designing power management units for electronic portable devices.
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Nasser Baharlou-Houreh, Navid Masaeli, Ebrahim Afshari and Kazem Mohammadzadeh
This paper aims to investigate the effect of partially blocking the cathode channel with the stair arrangement of obstacles on the performance of a proton exchange membrane fuel…
Abstract
Purpose
This paper aims to investigate the effect of partially blocking the cathode channel with the stair arrangement of obstacles on the performance of a proton exchange membrane fuel cell.
Design/methodology/approach
A numerical study is conducted by developing a three-dimensional computational fluid dynamics model.
Findings
As the angle of the stair arrangement increases, the performance of the fuel cell is reduced and the pressure drop is decreased. The use of four stair obstacles with an angle of 0.17° leads to higher power density and a lower pressure drop compared to the case with three rectangular obstacles of the same size and maximum height. The use of four stair obstacles with an angle of 0.34° results in higher power density and lower pressure drop compared to the case with two rectangular obstacles of the same size and maximum height.
Originality/value
Using the stair arrangement of obstacles as an innovation of the present work, in addition to improving the fuel cell’s performance, creates a lower pressure drop than the simple arrangement of obstacles.
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Massimo Guarnieri and Federico Moro
The purpose of this paper is to simulate passive proton exchange membrane fuel cells (PEMFCs) for portable electronic devices by means of a non‐linear lumped circuit based on…
Abstract
Purpose
The purpose of this paper is to simulate passive proton exchange membrane fuel cells (PEMFCs) for portable electronic devices by means of a non‐linear lumped circuit based on electrical, mass transfer and electro‐kinetic equations.
Design/methodology/approach
Electrical, mass transfer and electro‐kinetic equations are combined in order to derive a non‐linear lumped circuit. The dynamic circuit model is tested in realistic operating conditions.
Findings
An original equivalent circuit model for simulating the transient behavior of passive PEMFCs is proposed. The PEMFC is represented as a non‐linear equivalent circuit with controlled lumped parameters depending on pressure, temperature, hydration, and system capacity.
Research limitations/implications
Lumped parameters are synthesized assuming a one‐dimensional fuel cell model since layer thicknesses are much smaller than other dimensions. Heat generation and transfer are not modeled even though lumped parameters depend on temperature.
Practical implications
The proposed circuit model can be implemented directly in circuit simulators for designing power management units needed to interface small‐passive PEMFCs and portable electronics such as PDAs, laptops, or mobile phones.
Originality/value
The fuel cell is represented as a non‐linear controlled generator whose parameters are derived directly from multiphysics equations rather than empirical relationships. The dynamic behaviour of PEMFCs can be simulated on completely different times scales, i.e. during transients or during the discharge phase.
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Jinbei Tian, Mohammed S. Ismail, Derek Ingham, Kevin J. Hughes, Lin Ma and Mohamed Pourkashanian
This paper aims to investigate the impact of three different flow channel cross sections on the performance of the fuel cell.
Abstract
Purpose
This paper aims to investigate the impact of three different flow channel cross sections on the performance of the fuel cell.
Design/methodology/approach
A comprehensive three-dimensional polymer electrolyte membrane fuel cell model has been developed, and a set of conservation equations has been solved. The flow is assumed to be steady, fully developed, laminar and isothermal. The investigated cross sections are the commonly used square cross section, the increasingly used trapezoidal cross section and a novel hybrid configuration where the cross section is square at the inlet and trapezoidal at the outlet.
Findings
The results show that a slight gain is obtained when using the hybrid configuration and this is because of increased velocity, which improves the supply of the reactant gases to the catalyst layers (CLs) and removes heat and excess water more effectively compared to other configurations. Further, the reduction of the outlet height of the hybrid configuration leads to even better fuel cell performance and this is again because of increased velocity in the flow channel.
Research limitations/implications
The data generated in this study will be highly valuable to engineers interested in studying the effect of fluid cross -sectional shape on fuel cell performance.
Originality/value
This study proposes a novel flow field with a variable cross section. This design can supply a higher amount of reactant gases to the CLs, dissipates heat and remove excess water more effectively.
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A.B. Mahmud Hasan, M.A. Wahab and S.M. Guo
The purpose of this paper is to present the results of analysis of the transport gases and liquid water between the gas diffusion layer (GDL) and gas flow channel (GFC) of proton…
Abstract
Purpose
The purpose of this paper is to present the results of analysis of the transport gases and liquid water between the gas diffusion layer (GDL) and gas flow channel (GFC) of proton exchange membrane fuel cells (PEMFCs). These results are then used to describe the effects of the GDL‐GFC interfacial conditions on the general performance of PEMFCs.
Design/methodology/approach
This analysis utilizes finite element analysis commercial codes to illustrate the transport of fluids. The gas transport data obtained from the solution are compared with the established works of others. The liquid transport processes are modeled using the Darcy equation coupled with a saturation‐capillary pressure function (the Leverett function) and assuming no phase change. In addition, the boundary conditions for the liquid transport equation are varied in order to show the extent of non‐uniformities at the GDL‐GFC interface.
Findings
Analysis shows that water dispersion from the GDL‐GFC interface extends across the GDL to its other side, and eventually reduces the performance of the PEMFC.
Research limitations/implications
It is well known that CFD simulation of fuel cells is, in general, still facing significant challenges due to the limited understanding of the complex physical and chemical processes existing within the fuel cell. The model is now under further development to improve its capabilities and undergoing further validations.
Practical implications
The simulations can provide detailed information on some of the key fluid dynamics, physical and chemical/electro‐chemical processes that exist in liquid dispersion at the interface of GDL‐GFC in fuel cells which are critical for fuel cell design and optimization.
Originality/value
The simulation can be used to understand liquid dispersion at the interface of GDL‐GFC and provide and alternative to experimental investigations in order to improve the performance of fuel cell.
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A reliable and safe operation of fuel cells (FCs) is imperative for their application in aviation, especially within the main powertrain. Moreover, performance and lifetime…
Abstract
Purpose
A reliable and safe operation of fuel cells (FCs) is imperative for their application in aviation, especially within the main powertrain. Moreover, performance and lifetime requirements for technical and economic viability are demanding compared to their stationary or road transportation counterparts, while the operating conditions are considered challenging. Prognostics and health management (PHM) could represent a powerful tool for enhancing reliability, durability and performance by detecting, predicting and/or mitigating relevant degradation and failure mechanisms. Against this backdrop, the authors consider it of high relevance to obtain an understanding of the effectiveness of PHM approaches for polymer electrolyte fuel cells (PEFCs) for future aircraft applications, which represents the aim of this paper.
Design/methodology/approach
In this study, the authors first discuss application relevant failure modes, review state-of-the-art PHM approaches and, consecutively, assess the potential of FC control strategies for aviation. Aiming for a tangible, comparable metric for this initial assessment, the authors apply a published remaining useful life prediction method to load profiles for a range of aviation-specific applications.
Findings
The authors’ analysis shows significant potentials for lifetime improvement by (partial) avoidance of high power operation and rapid load change through control strategies. Tapping into these theoretical potentials, however, requires significant developments in the field of PEFC PHM and a focus on aviation specific degradation and performance testing.
Originality/value
The novelty of this study lies in creating an understanding of the potential of avoiding or preventing certain degradation modes by means of PHM in the PEFC specifically in aviation applications.
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