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The purpose of this study is to present a novel additive manufacturing (AM) technology which is based on selective formation of cellulose-acrylate composite. Besides proposing a process that combines the benefits of fibres and photopolymers, this paper reports the development of material, characterisation of a straight line composite formation, adherence between layers and functional feasibility of the proposed concept.

For the preliminary evaluation of the proposed process, a composite material based on cellulose-photopolymer was developed, while a multi-objective optimisation study indicated the formulation which results in the maximum values of layer adherence, tensile strength of composite and the effect of the water on the mechanical strength of material. For the characterisation of the process, three main subjects were analysed: the characterisation of straight line composite formation, the effect of composite formation process on previous layers and the functional feasibility of technology.

In the material development, the tensile strength of dry composite was identified between 20 and 30 MPa, while the tensile strength of wet composite was between 5 and 12 MPa. It is important to note that the dry and wet cellulose presented tensile strength, respectively, equal to 15 and 1 MPa, indicating the possibility of residual material removal only with the use of water or other soft solvent. The values of adherence between layers (peeling test) were found to be between 0.12 and 0.15 kgf, and the photopolymer formulation which resulted in the maximum adherence has monomer/oligomer ratio equal to 1.5 and 2 per cent wt of photoinitiator percentual. As result of the optimisation study, the material formulation was compounded by monomer – 10 ml, oligomer – 4.5 ml and photoinitiator – 2 per cent, being found suitable to characterise and evaluate the proposed process. The study of composite formation along a straight line showed values of line width between 1,400 and 3,500 μm in accordance with light power, laser velocity and laser beam diameter. On the other hand, the number of previous layers affected by the composite formation varied from 0 to 4, indicating a potential process limit. In the functional feasibility study, a feasible process window which resulted in the maximum dimensional deviation equal to 0.5 mm was identified. In addition, the mean mechanical tensile strength was found to be around 30 MPa for longitudinal laser trajectory (90°) and 15 MPa for transversal laser trajectory (0°), highlighting the anisotropic behaviour of final parts according to the manufacturing strategy.

This paper proposed a novel AM technology and also described studies related to the characterisation of this concept. This work might also be useful to the development of other AM processes and applications.

During the past years, numerous market segments have increasingly adopted additive manufacturing technologies for product development and complex parts design. Consequently, recent developments have expanded the technologies, materials and applications in support of emerging needs, in addition to improving current processes. The present work aims to propose and characterise a new technology that is based on selective formation of metal-polymer composites with low power source.

To develop this project, the authors have divided this work in three parts: material development, process feasibility and process optimisation. For the polymeric material development, investigation of metallic and composite materials assessed each material’s suitability for selective composite formation besides residual material removal. The primary focus was the evaluation of proposed process feasibility. The authors applied multivariable methods, where the main responses were line width, penetration depth, residual material removal feasibility, layer adherence strength, mechanical strength and dimensional deviation of resultant object. The laser trace speed, distance between formation lines and laser diameter were the main variables. Removal agent and polymeric material formulation were constants. In the last part of this work, the authors applied a multi-objective optimisation. The optimisation objectives minimized processing time and dimensional deviation while maximizing mechanical strength in xy direction and mechanical strength in z direction.

With respect to material development, the polymeric material tensile strength was found between 30 and 45 MPa at break. It was also seen that this material has low viscosity before polymerized (between 2 and 20 cP) essential for composite formation and complete material removal. In that way, the authors also identified that the residual material removal process was possible by redox reaction. In contrast with that the final object was marked by the polymer which covers the metallic matrix, protecting the object protects against chemical reactions. For the feasibility study, the authors identified the process windows for adherence between composite layers, demonstrating the process feasibility. The composite mechanical strength was shown to be between 120 and 135 MPa in xy direction and between 35 and 45 MPa in z direction. In addition, the authors have also evidenced that the geometrical dimensional distortion might vary until 5 mm, depending on process configuration. Despite that, the authors identified an optimised configuration that exposes the potential application of this new technology. As this work is still in a preliminary development stage, further studies are needed to be done to better understand the process and market segments wherein it might be applied.

This paper proposed a new and innovative additive manufacturing technology which is based on metal-polymer composites using low power source. Additionally, this work also described studies related to the investigation of concept feasibility and proposed process characterisation. The authors have focused on material development and studied the functional feasibility, which at the same time might be useful to the development of other additive manufacturing processes.

Over the past few years, the number of related research to additive manufacturing (AM) has risen. The selective composite formation (SCF) can also be found among the new technologies that were developed. This technology was first introduced in 2013, and because of its innovative character, there are still many challenges to be overcome. Therefore, the main aim of this study is to present a finite element method which allows to investigate the processing of the material during the selective formation of a composite material based on cellulose and acrylic.

In the beginning, we introduced a brand new finite element method approach which is based on light transmittance network and photopolymerisation in transient state. This method is mainly characterised by internal light absorption, transversal reflectance, light transmittance coefficient and photopolymerisation kinetics. The authors defined experimentally the main model coefficients besides investigating the formation of composite material in six case studies. The main variables evaluated in those studies were the number of layers and the number of lines. By the end, the degree of polymer conversion and the preliminary evaluation of adherence between layers were identified in addition to the formation profile of composite material.

The presented method evidence that the SCF resulted in a profile of polymerisation which is different from profiles found in vat polymerisation processes. It was shown that the light diffraction increases polymerisation area to outside of laser limits and reduces the penetration depth. It was also exposed that the selective formation of composite material on the top layer interferes with the polymerisation of previous layers and might increase the polymerised area in about 25 per cent per layer. By the end, adherence between layers was evidenced because of a high-pass filter that limited polymer conversion to over 60 per cent. In this case, the adherence between the top layers was provided by the interface between layers, while the deeper layers resulted in a solid formed by composite.

This paper presents research results related to a very new AM technology and also proposes a new method to characterise this concept. Because of this new analytic approach, the process planning can be simulated and optimised, in addition to being a useful tool for other researches related to photocurable polymers and AM technologies.

Current methods for the preparation of composite powder feedstock for selective laser melting (SLM) rely on costly nanoparticles or yield inconsistent powder morphology. This study aims to develop a cost-effective Ti6Al4V-carbon feedstock, which preserves the parent Ti6Al4V particle’s flowability, and produces in situ TiC-reinforced Ti6Al4V composites with superior traits.

Ti6Al4V particles were directly mixed with graphite flakes in a planetary ball mill. This composite powder feedstock was used to manufacture in situ TiC-Ti6Al4V composites using various energy densities. Relative porosity, microstructure and hardness of the composites were evaluated for different SLM processing parameters.

Homogeneously carbon-coated Ti6Al4V particles were produced by direct mixing. After SLM processing, in situ grown 100–500 nm size TiC nanoparticles were distributed within the α-martensite Ti6Al4V matrix. The formation of TiC particles refines the Ti6Al4V β grain size. Relative density varied between 96.4% and 99.5% depending on the processing parameters. Hatch distance, exposure time and point distance were all effective on relative porosity change, whereas only exposure time and point distance were effective on hardness change.

This work introduces a novel, cost-effective powder feedstock preparation method for SLM manufacture of Ti6Al4V-TiC composites. The in situ SLM composites achieved in this study have high relative density values, well-dispersed TiC nanoparticles and increased hardness. In addition, the feedstock preparation method can be readily adapted for various matrix and reinforcement materials in future studies.

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti elements into GTD222 alloy.

The composite material was prepared using the selective laser melting (SLM) technology, followed by a hot isostatic pressing (HIP) treatment. Subsequently, the composite underwent a hot corrosion test in a 75% Na₂SO₄ + 25% NaCl mixed salt environment at 900 °C.

The HIP-SLMed TiC/GTD222 composite exhibits a relatively low weight loss rate. First, the addition of alloying elements facilitates the formation of multiple protective oxide films rich in Al, Ti and Cr. These oxide films play a crucial role in enhancing the material’s resistance to hot corrosion. Second, the HIP treatment results in a reduction of grain size in the composite and an increased number of grain boundaries, which further promote the formation of protective films.

The hot corrosion behavior of the TiC/GTD222 nickel-based composite material prepared through SLM and HIP processing has not been previously studied. This research provides a new approach for designing nickel-based superalloys with excellent hot corrosion resistance.

The purpose of this paper is to compare different powder metallurgy (PM) processes to produce ceramic parts through additive manufacturing (AM). This creates the potential to rapidly shape ceramic parts with an almost unlimited shape freedom. In this paper, alumina (Al₂O₃) parts are produced, as Al₂O₃ is currently the most commonly used ceramic material for technical applications.

Variants of the following PM route, with indirect selective laser sintering (indirect SLS) as the AM shaping step, are explored to produce ceramic parts: powder synthesis, indirect SLS, binder removal and furnace sintering and alternative densification steps.

Freeform-shaped Al₂O₃ parts with densities up to approximately 90 per cent are obtained.

The resulting Al₂O₃ parts contain inter-agglomerate pores. To produce higher-quality ceramic parts through indirect SLS, these pores should be avoided or eliminated.

The research is innovative in many ways. First, composite powders are produced using different powder production methods, such as temperature-induced phase separation and dispersion polymerization. Second, four different binder materials are investigated: polyamide (nylon-12), polystyrene, polypropylene and a carnauba wax – low-density polyethylene combination. Further, to produce ceramic parts with increased density, the following densification techniques are investigated as additional steps of the PM process: laser remelting, isostatic pressing and infiltration.

Additive manufacturing (AM) of thermoplastic polymers for powder bed fusion processes typically requires each layer to be fused before the next can be deposited. The purpose of this paper is to present a volumetric AM method in the form of deeply penetrating radio frequency (RF) radiation to improve the speed of the process and the mechanical properties of the polymer parts.

The focus of this study was to demonstrate the volumetric fusion of composite mixtures containing polyamide (nylon) 12 and graphite powders using RF radiation as the sole energy source to establish the feasibility of a volumetric AM process for thermoplastic polymers. Impedance spectroscopy was used to measure the dielectric properties of the mixtures as a function of increasing graphite content and identify the percolation limit. The mixtures were then tested in a parallel plate electrode chamber connected to an RF generator to measure the heating effectiveness of different graphite concentrations. During the experiments, the surface temperature of the doped mixtures was monitored.

Nylon 12 mixtures containing between 10% and 60% graphite by weight were created, and the loss tangent reached a maximum of 35%. Selective RF heating was shown through the formation of fused composite parts within the powder beds.

The feasibility of a novel volumetric AM process for thermoplastic polymers was demonstrated in this study, in which RF radiation was used to achieve fusion in graphite-doped nylon powders.

The purpose of this paper is to propose and develop PA2200-based composite powder containing 0-15 Wt.% magnesium oxide before directly using it in selective laser sintering (SLS) machine to produce end-use products for low-volume production in the engineering applications with keen focus to meet the functional requirements which rely on material properties.

The methodology reported emphasises PA2200-based composite powder containing 0-15 Wt.% magnesium oxide development for SLS process which starts with preparation and characterisation of composite material, thermal and rheological study of composite material to decide optimum process parameters for SLS process machine to get optimal part properties. Further, to verify composite material properties, a conventional casting methodology is used. The composition of composite materials those possessing good properties are further selected for processing in SLS process under optimal processing parameters.

The process parameters of SLS machine are material-dependent. The effect of temperature in X-ray diffraction profile is negligible in the case of magnesium oxide reinforced PA2200 composite material. The cyclic heating of material increases melting point temperature, this grounds to modify part bed temperature of material every time before processing on SLS machine to uphold build part properties, as well as material. With the rise in temperature, the Melt flow index and rheological property of materials change. The magnesium oxide reinforced PA2200 composite material has high thermal stability than pure PA2200 material. By the addition of small quantity of magnesium oxide, most of the mechanical property and flammability property improves while elongation at break (percentage) decreases significantly.

The proposed PA2200-based composite powder containing 0-15 Wt.% magnesium oxide material development system and casting metrology to verify developed material properties will be very useful to develop new composite material for SLS process with use of less material. The developed methodology has proven, especially in the case where non-experts or student need to develop composite material for SLS process according to the property requirement of applications.

Unlike earlier composite material development methodology, the projected methodology of polymer-based composite material and confirmation of material properties instead of commencing SLS process provides straight forward means for SLS process composite materials development with less use of the material and period of time.

This study employs Stein Rokkan's methodological approach to analyse state formation in the Greater Middle East. It develops a conceptual framework distinguishing colonial, populist and democratic pacts, suitable for analysis of state formation and nation-building through to the present period. The framework relies on historical institutionalism. The methodology, however, is Rokkan's. The initial conceptual analysis also specifies differences between European and the Middle Eastern state formation processes. It is followed by a brief and selective discussion of historical preconditions. Next, the method of plotting singular cases into conceptual-typological maps is applied to 20 cases in the Greater Middle East (including Afghanistan, Iran and Turkey). For reasons of space, the empirical analysis is limited to the colonial period (1870s to the end of World War 1). Three typologies are combined into one conceptual-typological map of this period. The vertical left-hand axis provides a composite typology that clarifies cultural-territorial preconditions. The horizontal axis specifies transformations of the region's agrarian class structures since the mid-19th century reforms. The right-hand vertical axis provides a four-layered typology of processes of external intervention. A final section presents selected comparative case reconstructions. To the authors' knowledge, this is the first time such a Rokkan-style conceptual-typological map has been constructed for a non-European region.

The main cause of aseptic inflammation after an in vivo implantation is that Poly(L-lactide) (PLLA) and Poly(D-lactide) have a slower degradation and absorption rate, while Poly(D, L-lactide) (PDLLA) has a much faster degradation rate than PLLA because of its amorphous structure. Also, the hydrolyzate of Hydroxyapatite (HA) is alkaline, which can neutralize local tissue peracid caused by hydrolysis of Polylactic acid.

In this study, the selective laser sintering (SLS) technique was chosen to prepare bone scaffolds using nano-HA/PDLLA composite microspheres, which were prepared by the solid-in-oil-in-water (S/O/W) method. First, the SLS parameters range of bulk was determined by the result of a single-layer experiment and the optimized parameters were then obtained by the orthogonal experiment. The tensile property, hydrophobicity, biocompatibility, biological toxicity and in vitro degradation of the samples with optimized SLS parameters were characterized.

As a result, the samples showed a lower tensile strength because of the many holes in their interior, which was conducive to better cell adhesion and nutrient transport. In addition, the samples retained their inherent properties after SLS and the hydrophobicity was improved after adding nano-HA because of the OH group. Furthermore, the samples showed good biocompatibility with the large number of cells adhering to the material through pseudopods and there was no significant difference between the pure PDLLA and 10% HA/PDLLA in terms of biological toxicity. Finally, the degradation rate of the composites could be tailored by the amount of nano-HA.

This study combined the S/O/W and SLS technique and provides a theoretical future basis for the preparation of drug-loaded microsphere scaffolds through SLS using HA/PDLLA composites.