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This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti elements into GTD222 alloy.

The composite material was prepared using the selective laser melting (SLM) technology, followed by a hot isostatic pressing (HIP) treatment. Subsequently, the composite underwent a hot corrosion test in a 75% Na₂SO₄ + 25% NaCl mixed salt environment at 900 °C.

The HIP-SLMed TiC/GTD222 composite exhibits a relatively low weight loss rate. First, the addition of alloying elements facilitates the formation of multiple protective oxide films rich in Al, Ti and Cr. These oxide films play a crucial role in enhancing the material’s resistance to hot corrosion. Second, the HIP treatment results in a reduction of grain size in the composite and an increased number of grain boundaries, which further promote the formation of protective films.

The hot corrosion behavior of the TiC/GTD222 nickel-based composite material prepared through SLM and HIP processing has not been previously studied. This research provides a new approach for designing nickel-based superalloys with excellent hot corrosion resistance.

This study aims to optimise the effect of pre-oxidation on hot corrosion behaviour of Tribaloy T-900 at 900 °C in mixed Na₂SO₄ and K₂SO₄.

Prior to hot corrosion experiment, pre-oxidation treatments were carried in ambient air at 900 °C for 1, 5 and 10 h, respectively. The hot corrosion experiments were performed in a box type furnace at 900 °C. Both surfaces of specimens were brushed with saturated salt solution of 75 wt.% Na₂SO₄ + 25 wt.% K₂SO₄. After brushing, the salt-coated specimens were placed in electric stove to ensure drying of salt. After drying, presence of 3 mg/cm² salt on specimen’s surface was ensured through weighting.

The 1-h pre-oxidation treatment prior to hot corrosion showed superior hot corrosion resistance against molten salt attack. An optimum pre-oxidation time of 1 h helped timely formation of protective Cr₂O₃ layer and inhibited the formation of less stable and porous surface oxides of Ni and Mo during hot corrosion.

Pre-oxidation effect on hot corrosion behaviour of refractory metal (such as Mo in investigated alloy) containing alloy has never been reported previously. Refractory metals oxide (e.g. MoO3) could transform the corrosion phenomena to catastrophic failure through acidic fluxing.

This paper aims to study the feasibility of using machine learning in hot corrosion prediction of Inconel 617 alloy.

By examination of the experimental studies on hot corrosion of Inconel 617, a data set was built for machine learning models. Apart from the alloy composition, this paper included the condition of hot corrosion like time and temperature, and the composition of the saline medium as independent features, while the specific mass change is set as the target feature. In this paper, linear regression, random forest and XGBoost are used to predict the specific mass gain of Inconel 617.

XGBoost yields the coefficient of determination (R²) of 0.98, which was highest among models. Also, this model recorded the lowest value of mean absolute error (0.20). XGBoost had the best performance in predicting specific mass gain of the alloy in different times at temperature of 900°C. In sum, XGBoost shows highest accuracy in predicting specific mass gain for Inconel 617.

Using machine learning to predict hot corrosion in Inconel 617 marks a substantial progress in this domain and holds promise for simplifying the development and evaluation of novel materials featuring enhanced hot corrosion resilience.

This paper aims to study the microstructural hot corrosion behaviour of the sintered Y₂SiO₅ ceramic silicate under a Na₂SO₄ + V₂O₅ mixture at an engine representative temperature of 1150°C. Y₂SiO₅ is a promising candidate for thermal barrier coatings (TBC) due to its excellent chemical stability at high temperatures. As a continuous source of Y₃+, it is expected that Y₂SiO₅ environmental barrier coating may prolong the lifetime of TBC systems by stopping the degradation caused by the loss of the Y₂O₃ stabilizer.

Two routes were chosen for the yttria silicate powder synthesis by sol-gel from TEOS and APTES precursors as the difference in Si source changed the ratio of Y₂SiO₅/Y₂Si₂O₇ phases. Hot corrosion studies using Na₂SO₄ and V₂O₅ mixtures were conducted on both surfaces of APTES and TEOS tablets at 1150°C for 8 h in atmospheric air. The morphology and microstructure analyses of the silicate samples after hot corrosion tests were carried out using a SEM and X-ray diffraction analyse techniques.

Based on the degradation, the general status of the APTES tablet after hot corrosion presents a better hot corrosion resistance at a temperature of 1150°C than does that of the TEOS tablet. In the TEOS tablet, the crystal morphology of NaY9Si60O26 woodchip shapes with a size of 60 µm is developed on the surface for finally initiating some cracks. In the APTES case, the crystal morphology of rod-like shapes with a size of 100 µm is developed; hence, a dense thick layer predominately postpones the reaction of V₂O₅ and Na₂SO₄ with yttria silicate, and consequently, less damage is observed.

Coating yttria silicate preparation is very complicated; the problems of a high synthesis temperature, long production period and low yield still need to be solved. Under these perspectives, ceramics prepared via spark plasma sintering (SPS) can reach theoretical high densities and a fine grain size can be retained after the SPS process; hence, well resistance to the corrosion in molten salts is expected to obtain for the sintered yttria silicate tablets.

In Indian thermal power plants, the main cause of boiler tube failure is the presence of molten sulphates and vanadates, which deteriorate the tube material at high temperatures. To combat the hot corrosion failure of metals, thermal spray technology is adopted. This study aims to investigate and study the effect of hot corrosion behaviour of carbon nanotube (CNT)-reinforced ZrO₂-Y₂O₃ composite coatings on T-91 boiler tube steel in a molten salt environment at 900 °C for 50 cycles.

A plasma spray technique was used for development of the coatings. The samples were exposed to hot corrosion in a silicon tube furnace at 900 °C for 50 cycles. After testing, the test coupons were analysed by X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy and cross-sectional analysis techniques to aid understanding the kinetics of the corrosion reaction.

CNT-based reinforced coatings showed lower weight gain along with the formation of protective oxide scales during the experimentation. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.

It is pertinent to mention here that the high temperature behaviour of CNT-reinforced ZrO₂-Y₂O₃ composite on T-91 steel at 900°C temperature in molten salt environment has never been studied. Thus, the present research was conducted to provide useful results for the application of CNT-reinforced composite coatings at elevated temperature.

To evaluate the corrosion resistance of four different stainless steels often employed in hot end exhaust components.

This paper evaluated the outcomes of the hot salt test and the cyclic oxidation test on four different stainless steels, used as hot end exhaust components. The specimens were analyzed by means of SEM for surface changes and the weight loss was considered.

The general corrosion rate and pitting resistance under all the test conditions for hot end exhaust components indicated that 434 was by far the most corrosion resistant alloy, followed by 1.4509 and 321, and lastly 304 was the least corrosion resistant. In general, the ferritic stainless steels, especially 434, outperformed the austenitic ones under all the test conditions.

The comparison of the corrosion resistance and rate, between the frequently used ferritic and austenitic stainless steels used in the exhaust system, gave a clear indication that the ferritic steels will provide prolonged service and this could be beneficial information to the manufacturers.

A new approach to summarise the materials' behaviour and their relative performance in the tests performed was developed. This proposed summary of a number of corrosion indicators could serve as a relative guide to alloy selection for use in hot end automotive exhaust systems for both manufacturers and users.

This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.

The “two-step” hot-dip coating process for cable steel wires was developed, which involved first hot-dip galvanizing and then hot-dip galvanizing of aluminum magnesium alloy. The corrosion rate, polarization curve and impedance of Zn–6Al–1Mg and Zn–10Al–3Mg alloy-coated steel wires were compared through acetate spray test and electrochemical test, and the corrosion mechanism of Zn–Al–Mg alloy-coated steel wires was revealed.

The corrosion resistance of Zn–10Al–3Mg alloy-coated steel wires had the best corrosion resistance, which was more than seven times that of pure zinc-coated steel wires. The corrosion current of Zn–10Al–3Mg alloy-coated steel wires was lower than that of Zn–6Al–1Mg alloy-coated steel wires, whereas the capacitive arc and impedance value of the former were higher than that of the latter, making it clear that the corrosion resistance of Zn–10Al–3Mg was better than that of Zn–6Al–1Mg alloy coating. Moreover, the Zn–Al–Mg alloy-coated steel wires for bridge cables had the function of coating “self-repairing.”

Controlling the temperature and time of the hot dip galvanizing stage can reduce the thickness of transition layer and solve the problem of easy cracking of the transition layer in the Zn–Al–Mg alloy coating due to the Sandelin effect.

High temperature oxidation and hot corrosion behaviour of some ceramic‐based coatings, e.g. borate, silicate‐chromate and carbide‐oxide on mild steel has been investigated in the temperature range of 400–850°C. The coated steel in general shows much better oxidation and hot corrosion resistance than the uncoated steel specially at higher temperatures. The borate coating has better hot corrosion resistance performance between 700 and 800°C whereas silicate‐chromate is suitable at temperatures above 800°C. The coated steels show parabolic behaviour during oxidation. In presence of Na2SO4, the corrosion rate increases with increasing salt concentration till a maxima is reached. The amount of Na2SO4 corresponding to the maximum corrosion rate decreases with increasing temperature. A self‐sustained fluxing cum sulphidation mechanism has been proposed to explain hot corrosion behaviour of uncoated or coated mild steel.

The purpose of this paper is to obtain a single setting (optimal setting) of various input parameters of pack cementation process, i.e. halide salt activator, powder of master alloy and wt% of Y₂O₃ to obtain a single output characteristic as a whole namely resistance of hot corrosion for T91 steel.

The multi-criterion methodology based on Taguchi approach and utility concept has been used for optimization of the multiple performance characteristics namely hot corrosion rate K_P1, K_P2 and K_P3 for pack cementation coated T91 steel in chlorine and vanadium environment.

All the three pack cementation parameters, namely, halide salt activator, powder of master alloy and wt% of Y₂O₃ had a significant effect on the utility function based on analysis of variance for multiple performances. The percentage contribution of halide activator (1.54 percent), master alloy powder (4.66 percent) and wt% Y₂O₃ (93.79 percent). The results indicated the beneficial influence of yttrium on the chemical stability of the protective layer in presence of chlorine and vanadium environments. The optimal parameter settings obtained in this study is A2B2C1, i.e. halide salt activator (NaCl), powder of master alloy (92Cr-8Al) and 1wt% of Y₂O₃.

The outcome of this study shall be useful to explore the possible use of the developed coating for high temperature components. Unfortunately, the pack cementation was normally limited by the diffusion and reaction kinetics involved, which has a detrimental effect on the mechanical properties of work pieces. Therefore, reducing pack cementation temperature is required for widespread application of the pack coatings.

Pack coating at optimum conditions can be used for surface coating technologies to economically improve high temperature oxidation, corrosion resistance of components.

The multi-criterion methodology based on Taguchi approach and utility concept has been used for first time for parametric optimization of wt% Y₂O₃ modified chromium- aluminide coatings for T91 steel.

This paper aims to investigate hot corrosion behaviour of different Cr₃C₂–NiCr coatings on boiler tube steel.

High velocity oxy fuel technique has been used to deposit different coatings on commercially available ASTM-SA213-T22 boiler tube steel. The hot corrosion studies have been performed in molten salt environment at 900°C temperature in silicon tube furnace in laboratory.

The results showed that uncoated superalloy suffered intense spalling and the weight change was massive during each cycle on studies of hot corrosion 900°C. The 100 per cent NiCr and 10 per cent (Cr₃C₂) – 90 per cent (NiCr) coatings provided better protection to T22 steel against the hot corrosion because of the formation of Ni and Cr₃C₂ layers.

In this research a variety of coatings have been used. This research work has been aimed to investigate the hot corrosion behavior of Boiler Steel b with different Cr₃C₂–NiCr coatings, under molten salt environment in Silicon tube furnace at 900°C, under cyclic conditions.