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This paper aims to investigate the effect of solder alloying with a small amount of La and Y on bond formation with the Si and Cu substrates.

Bi₂La and Bi₂Y solders were studied. Soldering was performed using a fluxless method in air and with ultrasonic activation.

It was found that in the process of ultrasonic soldering, the La and Y were distributed at the interface with Si and Cu substrates, which enhanced the bond formation. Addition of La or Y elements in a Bi-based solder also ensured wetting of non-metallic materials such as Si, Al₂O₃ and SiC ceramics.

The addition of lanthanides offers a method for ensuring wetting of non-metallic materials. The bond with Si was of an adhesive character without the formation of a new contact interlayer. This resulted in lower shear strength of the bond with Si (8-10 MPa). The shear strength of the bond with a Cu substrate was 22-30 MPa.

This study aims to investigate soldering of SiC ceramics by using Zn-Al-In-based solders and ultrasonic soldering. The focus was on the quality of soldered joints, examining the boundary of the solder/substrate joint and the strength of the fabricated joints. Moreover, the fractured surfaces of joints were assessed.

The Zn-5Al base, which is considered for eutectic solder, was used in experiments. When manufacturing this solder, In was also added to at 1 Wt.%. The soldering of SiC substrates on a hot plate with ultrasonic assistance was performed.

The solder at room temperature consists of a primary segregated solid solution (Zn) and the binary eutectics (Zn) + (Al) with a high Al content and binary lamellar eutectic with a high Zn and In content non-uniformly distributed on the grain boundaries. The average tensile strength of the Zn5Al1In solder was 52 MPa. The ceramic material was wetted during soldering via reaction between the solder and the SiC substrate, with the formation of Al-Si reaction products. The thickness of the reaction layer on the boundary was 0.5–1.1 µm. The average strength of the soldered joint was 59 MPa. The obtained results confirmed the high efficiency of ultrasonic soldering in air.

This work has characterised Zn5Al1In soldering alloy and examining soldering SiC ceramics by a flux-less ultrasonic process. The analyses were oriented to assess the strength and structure of the solder and the soldered joints. Based on the achieved results, it is possible to predict the suitability of the solder alloy for flux-free soldering of SiC ceramics.

This study aims to solder AlN ceramics with a Cu substrate using an active type Sn-Ag-Ti solder. Soldering was performed with power ultrasound. The Sn3.5Ag2Ti alloy was first studied.

It was found to contain a Sn matrix, where both Ag phase – ɛ-Ag₃Sn – and Ti phases ɛ-Ti₆Sn₅ and Ti₂Sn₃ – were identified. Ti contained in these phases is distributed to the interface with ceramic material. A reaction layer was thus formed. This layer varies in thickness from 0.5 to 3.5 µm and ensures the wettability of an active solder on the surfaces of ceramic materials.

X-ray diffraction analysis proved the presence of new NTi and AlTi₂ phases on the fractured surface. Sn plays the main role in bond formation when soldering the Cu substrate with Sn-Ag-Ti solder. The Cu₃Sn and Cu₆Sn₅ phases, which grow in direction from the phase interface to solder matrix, were found in all cases within the solder/Cu substrate interface. The combination of AlN ceramics/Cu joint maintained a shear strength of 29.5 MPa, whereas the Cu/Cu joint showed a somewhat higher shear strength of 39.5 MPa.

The present study was oriented towards soldering of AlN ceramics with a Cu substrate by the aid of ultrasound, and the fluxless soldering method was applied. Soldering alloy type Sn-Ag-Ti was analysed, and the interactions between the solder and ceramic and/or Cu substrate were studied. The shear strength of fabricated soldered joints was measured.

The work aims to study the direct bonding of silicon substrate with solders type Sn-Ag-Ti.

During the bonding process with ultrasound assistance, the active element (Ti,Ce,Mg) is distributed from the solder to interface with a silicon substrate, where it supports the bond formation.

Formation of a reaction layer, 1-2 μm in thickness, was observed. The new Si2Ti phases and Mg2Si phase were identified in the reaction layer.

The results of analysis suggest that the Si/Sn-Ag-Ti joint is of diffusion character. The highest average strength on silicon substrate (39 MPa) was achieved with Sn-Ag-Ti(Mg) solder.

The purpose of this paper is to investigate the wettability of an active Sn2Ti solder on an Al₂O₃ ceramic material at temperatures of 700°C and higher. Based on the results of the wettability study, soldered joints of Al₂O₃ ceramics/Sn2Ti solder/steel type AISI 321 were fabricated and the variation of shear strength with time was determined.

For determining melting points, differential scanning calorimetry analysis was performed. The wetting angle of Sn2Ti solder on Al₂O₃ ceramics was measured using specially developed equipment with a 10‐3 Pa vacuum at temperatures of 700, 800, 850 and 900°C. The wetting angle on AISI 321 steel at a temperature of 850°C was also determined. The joints of Al₂O₃ ceramics/Sn2Ti solder/steel type AISI 321 were prepared at 900°C, in a vacuum for times 5, 10, 15 and 20 min.

The best wettability of Sn2Ti solder was achieved at a temperature of 900°C. The wetting angle at the parameter of 900°C/ for 15 min was 47.5°. The joints of Al₂O₃ ceramics/Sn2Ti solder/steel type AISI 321 attained a strength of 18.3 MPa. It was found that the microstructure of Sn2Ti solder consists of a tin matrix with the presence of a αTi6Sn5 phase.

The results of the work are of significance for the further development of soldering with active solders in a vacuum, as well as with the application of power ultrasound. The possibility of soldering Al₂O₃ ceramics with SnTi‐based solders was thus demonstrated.

The purpose of this paper is to study Bi‐11Ag solder for higher application temperatures. The aim of the research work was to determine the soldering, thermal and mechanical properties of Bi‐11Ag solder.

To determine the melting point interval of experimental Bi‐11Ag solder, DSC analysis was performed. The contact angles were studied on a copper, nickel and silver substrate by use of a sessile drop method. Wettability tests were realised at a temperature of 380°C in a shielding atmosphere (90% N₂+10% H₂). Based on experience achieved with wetting angle measurements, the specimens for measurement of shear strength of Cu, Ni and Ag/Bi‐11Ag joints were fabricated. EDX analysis was used for the study of the solder interaction with the surface of the three metallic substrates.

The best wettability at soldering in a shielding atmosphere was achieved with silver. The wetting angle at 30 min attained the value of 23°. The worst wettability was observed on copper, where at 30 min the wetting angle was 55°. Average shear strength varied from 31 to 45 MPa. The highest strength was obtained with the Cu substrate whereas the lowest was with the Ni substrate. The lowest strength achieved with the Ni substrate was caused by formation of brittle intermetallic phase NiBi₃. Joint formation is realised by eutectic reaction at the contact of Bi with the surface of the copper substrate. Similar joint formation by eutectic reaction occurs also at Bi interaction with the surface of the Ag substrate. At Bi interaction with the nickel substrate a new intermetallic phase (NiBi₃) is formed.

Wettability of Bi‐11Ag solder on Cu, Ag and Ni substrates was determined at application of a shielding atmosphere (90% N₂+10% H₂). Wettability was determined also at application of ZnCl₂‐NH₄Cl flux. The shear strength of Bi‐11Ag on different substrates was determined. The mechanism of joint formation was analysed.

The purpose of this paper is to study the effect of the addition of a small amount of Al (0.1 percent) on the properties of lead‐free solder type Sn‐4Ag‐0.5Cu (SAC 405).

The soldering properties of wettability and spreadability on a Cu substrate were studied, and the effect of Al on the growth of intermetallic compounds (IMCs) was observed. The shear strength of soldered joints was assessed. For comparison, soldering and strength tests were carried out on SAC 405 and SAC 405+ Al solders. Soldering was performed with an activated flux type ZnCl₂‐NH₄Cl, with non‐activated flux (rosin), and without flux in the air.

Experimental results show that Al addition slightly reduces the wettability and spreadability of SAC 405 solder. Also, the shear strength is moderately reduced, dropping by 8 MPa on average. Differential scanning calorimetry (DSC) analysis showed that the melting point of SAC 405+0.1%Al solder was increased to 221°C.

The positive effect of a small Al addition is due to the fact that it hinders the growth of IMCs formed on the contact surface with Cu substrate. The width of the transition zone of IMC was reduced by approximately 2 to 3 μm, depending on the soldering temperature.