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Incineration strengths of hazardous (2.8×10⁸μg/s) and nonhazardous (6.31×10⁸μg/s) materials were found from the quantities to be incinerated, chemical formulas, and the incineration time. The smoke stack geometry, exhaust dynamics, and different atmospheric stability conditions were used in the Gaussian model to predict the maximum concentration distances of 0.5 to about 6 km at the ground level in the downwind direction. However, trailing edges of some of exhaust distributions were found to extend beyond 120 km under some atmospheric stability conditions. The counties of Jefferson, Lonoke, Pulaski, Dallas, Cleveland, Calhoun, and Grant in the state of Arkansas are more likely to be affected than others. The possible major products in the hazardous incineration exhaust are chlorinated compounds. The results of this study are important to know the areas that fall under comparatively higher concentrations of incineration exhaust for further observations because of its inherent impact upon living beings, crop production, and environmental conditions.

The purpose of this paper is to investigate the effect of annealing on photochromic performance of (E)‐dicyclopropylmethylene‐(2, 5‐dimethyl‐3‐furylethylid‐ene)‐succinicanhydride doped in polyacrylic acid thin film.

(E)‐dicyclopropylmethylene‐(2,5‐dimethyl‐3‐furyl‐ethylidene)‐succinic‐anhydride (DMDFS‐E) fulgide doped in polyacrylic acid thin films was prepared. DMDFS‐E fulgide doped in polyacrylic acid thin films was heated at various annealing temperatures. Photocoloration, photobleaching and photochemical fatigue resistance for the desired DMDFS‐E fulgide doped in polyacrylic acid thin films were studied.

Upon irradiation with UV light (366 nm), fulgide DMDFS‐E undergoes a conrotatory ring closure to the pinkish colored closed form C (523 nm). The later color was switched back to the original color when the films were irradiated with white light. The kinetics of photocoloration and photobleaching processes were followed spectrophotometrically by monitoring the absorbance of the ring closed product DMDFS‐C at its λmax of 523 nm. The first‐order plots of photocoloration reaction showed distinct linear line at different temperatures. The slope of these first‐order lines corresponding to the rate constants k. It was found that for photocoloration reaction, the rate constant of the photocoloration reaction was slower than the photobleaching reaction and both reactions decrease with increasing the annealing temperatures. It was found that there was almost improvement of photochemical fatigue resistance of fulgide DMDFS‐E doped in polyacrylic acid thin film at several of the annealing temperatures.

The results obtained in this work showed that the photochromic properties of DMDFS fulgide E were improved upon annealing the film at 100°C. Therefore, it would be recommended for improvement to apply fulgides as annealed polymer films.

The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.

The poly(methyl methacrylate) (PMMA) and epoxy resin doped with photochromic spirobenzopyran were prepared and the effects of ultraviolet (UV) irradiation were studied using spectrophotometer. The reversible reaction was effected using white light. Photochemical fatigue resistance of these films was also studied.

Irradiation of colourless 1′,3′,3′‐trimethyl‐6‐nitrospiro[2H‐1‐benzopyran‐2,2′‐indoline] spiropyran (SP) doped in PMMA and epoxy resin with UV light (366 nm) results in the formation of an intense purple‐red coloured zwitterionic photomerocyanine (PMC). The reverse reaction was photochemically induced by irradiation with white light. Photocolouration of SP doped in PMMA follows a first‐order rate equation (k=0.0011 s⁻¹), while that doped in epoxy resin deviates from linearity. It was found that photobleaching follows a first‐order equation in both matrices. The photobleaching rate constant of PMC in both matrices is the same and equals 0.0043 s⁻¹. Spirobenzopyran doped in PMMA shows better fatigue resistance than that doped in epoxy resin.

The PMMA and epoxy resin polymers doped with photochromic spirobenzopyran described in the present paper were prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.

The photochromic materials developed can be used for different applications, such as coatings and holography.

The method developed may be used to enhance the performance of photochromic materials.

To evaluate the photochromic performance of fulgide 1‐E with ferrocene in polymer matrices.

The fulgide 1‐E with ferrocene dye 2 doped in polymethylmethacrylate was prepared and the effects of UV irradiation were studied using spectrophotometer. The reversible reaction was effected using white light. The effect of heat was also determined.

A film of the brown coloured fulgide 1‐E with ferrocene doped in PMMA polymer was irradiated with ultraviolet light (365 nm), the film turned red. The later colour was partially switched back to the original brown colour when the film was irradiated with a white light. It was found that the rate constants of photocoloration reaction at initial stages are faster than those at late stages. Similarly, the photocoloration reaction was slower than the photobleaching reaction. Photocoloration reaction decreased with the increase of the annealing temperatures, but for photobleaching reaction, the rates were almost similar (at 46 and 82°C). The fatigue resistance of the film was greatly improved when the annealing temperature increased to 82°C.

The polymethylmethacrylate polymer doped photochromic fulgide 1‐E and ferrocene 2 described in the present paper was prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.

The photochromic materials developed can be used for different applications, such as coatings and holography.

The method developed may be used to enhance the performance of photochromic materials.

The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.

The poly(methyl methacrylate) PMMA and epoxy resin doped with photochromic spirooxazine (SO) are prepared and the effects of ultraviolet (UV) irradiation are studied using spectrophotometer. The reversible reaction is effected using white light. Photochemical fatigue resistance of these films is also studied.

Irradiation of colourless 7′,8′‐dichloro‐1,3,3‐trimethylspiro[indoline‐2,3′‐[3H]benzo[b][1,4]oxazine] (SO) doped in PMMA and epoxy resin with UV light (366 nm) results in the formation of an intense purple‐red coloured zwitterionic photomerocyanine (PMC). The reverse reaction is photochemically induced by irradiation with white light. Photocolouration and photobleaching reactions follow a first‐order rate equation. It is found that photocoloration rate constant of (SO) in both matrices is almost the same, which is unexpected. On the other hand, the rate of photobleaching reaction of (PMC) in PMMA is twice slower than that in the epoxy resin. It seems that the presence of the two chlorine atoms at positions 7′ and 8′ of the benzooxazine moiety destabilise the PMC in epoxy resin film and results in speeding up the fading process compared to that in PMMA. SO doped in epoxy resin shows much better fatigue resistance than that doped in PMMA.

The PMMA and epoxy resin polymers doped photochromic spirobenzooxazine described in this paper were prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.

The photochromic materials developed can be used for different applications, such as coatings and holography.

The method developed may be used to enhance the performance of photochromic materials.

The present study aims at shedding some light on the serious effect of insecure pesticides to the surface ozone as a secondary pollutant resulting from some photochemical reactions during the sunny days. The temporal variation in O₃ concentrations due to pesticide spray, the corresponding temperature and relative humidity have been monitored and discussed. The air quality index (AQI) for the maximum concentrations of O₃ within each day of study has also been deduced. The obtained results illustrated that O₃ concentrations had been increased after pesticide spray with different values from hour to hour and then began to decay after one day or more according to its concentrations. The second day had the highest concentrations of the O₃ including the maximum concentration, which was recorded at hour 14 local time. Furthermore, most of AQI values were restricted between harmful and very harmful index during the second days and only the third day of the first experiment. Moreover, temperature and relative humidity have significantly influenced ozone concentrations with positive and negative correlation coefficients, respectively.

A new fabrication process for rapid prototyping is proposed in this paper. Optical and thermal effects are simultaneously used in this process to locally induce a phase change in a liquid resin. This phase change phenomena is used to “write” three‐dimensional shapes or patterns. Such objects or patterns can involve macroscopic engineering prototypes through to nanostructures for exploitation in waveguiding and photonic crystals. Several advantages can be achieved through this new process, in terms of accuracy, cost and time.

PART II Analysis of the examination syllabuses Sixth‐form school chemistry is closely tied to the syllabuses of the GCE at ‘A/S’ level and in consequence the most practical method of judging whether textbooks provide the requirements of sixth‐form work is to compare them with the examination syllabuses. Recently this has been made difficult because of rather revolutionary changes in some of the GCE Boards syllabuses. Oxford, Oxford and Cambridge, and the Joint Matriculation Board of the Northern Universities, introduced modifications for the 1964 examination, the Southern Universities for the 1965 examination, and recently Cambridge has introduced an alternative syllabus (T) for the 1966 examination. The other Cambridge examination, now known as ‘Alternative N’, was modified to its present form in 1954. London are in the process of revision.

The purpose of this paper is to present a novel manufacturing process that aims to pattern metal tracks onto polyimide at atmospheric pressure and ambient environment. The process can be scaled up for industrial applications.

From a thorough literature survey, different approaches were carried out for processing polyimide. Following a design of experiments for the processing and various characterisation techniques, a micro‐coil was manufactured as a test demonstrator.

The characteristics of some main formaldehyde‐based electroless copper baths were compared. The quality of the sidewalls was characterised and the performance of the process was assessed.

This paper demonstrates a high‐value manufacturing technique that is mass manufacturable, low cost and suitable for use on 3D surfaces. Criteria required for the development of a direct‐writing process have been described. The issues surrounding electroless plating on polyimide have been explained.