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1 – 10 of 196Photoresist imaging traditionally uses silver halide or diazo based phototools for contact exposure to an actinic UV light source. By contrast, laser direct imaging uses digital…
Abstract
Photoresist imaging traditionally uses silver halide or diazo based phototools for contact exposure to an actinic UV light source. By contrast, laser direct imaging uses digital imaging data to control a laser beam scanner to write directly on to the photoresist, therefore eliminating the need for phototools. In the past, even though the benefit of a UV system was recognised, laser direct imaging was mainly limited to the use of a visible laser as early UV lasers were low in power, unreliable and expensive. So far, no visible systems have gained commercial recognition because of the inherent deficiencies of the visible system. Recent advantages in UV laser equipment and UV sensitive photoresist have now made UV laser direct imaging a viable alternative to traditional contact imaging. As new UV laser imaging systems start to emerge, interest and attention are also growing among printed circuit board manufacturers. This paper discusses various attributes of a UV laser direct imaging system and fundamental differences in photophysics between laser direct imaging and conventional UV imaging.
The purpose of the paper is to showcase the significant achievements of Egypt's scientists in the 20th century across various fields of study such as medicine, physics, chemistry…
Abstract
Purpose
The purpose of the paper is to showcase the significant achievements of Egypt's scientists in the 20th century across various fields of study such as medicine, physics, chemistry, biology, math, geology, astronomy and engineering. The paper highlights the struggles and successes of these scientists, as well as the cultural, social and political factors that influenced their lives and work. The aim is to inspire young people to pursue careers in science and make their own contributions to society by presenting these scientists as role models for hard work and dedication. Ultimately, the paper seeks to promote the importance of science and its impact on society.
Design/methodology/approach
The purpose of this review is to present the scientific biographies of Egypt's most distinguished scientists, primarily in the field of Natural Sciences, in a balanced and comprehensive manner. The work is objective, honest and abstract, avoiding any bias or exaggeration. The author provides a clear and concise methodology, including a brief introduction to the scientist and their field of study, an explanation of their major contributions, the impact of their work on society, any challenges or obstacles faced during their career and their lasting legacy. The aim is to showcase the important achievements of these scientists, their impact on their respective fields and to inspire future generations to pursue scientific careers.
Findings
The group of outstanding scientists in 20th century Egypt were shaped by various factors, including familial upbringing, education, society, political and cultural atmosphere and state support for scientific research. These scientists made significant contributions to various academic disciplines, including medicine, physics, chemistry, biology, mathematics and engineering. Their impact on their communities and cultures has received international acclaim, making them role models for future generations of scientists and researchers. The history of these scientists highlights the importance of educational investments and supporting scientific research to foster innovation and social progress. The encyclopedia serves as a useful tool for students, instructors and education professionals, preserving Egypt's scientific heritage and honouring the scientists' outstanding accomplishments.
Research limitations/implications
The encyclopedia preserves Egypt's scientific heritage, which has been overlooked for political or other reasons. It is a useful tool for a variety of readers, including students, instructors and education professionals, and it offers insights into universally relevant scientific success factors as well as scientific research methodologies. The encyclopedia honours the outstanding scientific accomplishments of Egyptian researchers and their contributions to the world's scientific community.
Practical implications
The practical implications of this paper are several. First, it highlights the importance of education, family upbringing and societal support for scientific research in fostering innovation and social progress. Second, it underscores the need for continued funding and support for scientific research to maintain and build upon the accomplishments of past generations of scientists. Third, it encourages young people to pursue scientific careers and make their own contributions to society. Fourth, it preserves the scientific heritage of Egypt and honors the contributions of its outstanding scientists. Finally, it serves as a useful tool for students, instructors and education professionals seeking to understand the factors underlying scientific success and research methodologies.
Social implications
The social implications of the paper include promoting national pride and cultural identity, raising awareness of the importance of education and scientific research in driving social progress, inspiring future generations of scientists and researchers, reducing socioeconomic disparities and emphasizing the role of society, politics and culture in shaping scientific researchers' personalities and interests.
Originality/value
The paper's originality/value lies in its comprehensive documentation of the scientific biographies of Egypt's most prominent scientists in the 20th century, providing unique insights into the factors that contributed to their development and their impact across various academic disciplines. It preserves Egypt's scientific heritage and inspires future generations of scientists and researchers through the promotion of educational investments and scientific research. The encyclopedia serves as a useful tool for education professionals seeking to understand scientific success factors and research methodologies, emphasizing the importance of supportive and inclusive environments for scientific development.
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The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.
Abstract
Purpose
The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.
Design/methodology/approach
The polystyrene films doped with photochromic fulgide were prepared and the effect of UV irradiation were studied using spectrophotometer. The reversible reaction was effected using white light. The effect of heat was also determined.
Findings
A film of the green coloured fulgide 2‐E doped in polystyrene polymer was irradiated with UV light (366 nm), the film turned blue. The latter colour was partially switched back to the original green colour when the film was irradiated with a white light. Increasing the annealing temperatures, increases the percentage conversion of 2‐C to 2‐E. The observed large bathochromic shifts in λmax of 2‐C and the partial conversion of 2‐C to 2‐E were rationalised on the bases of electronic and steric effects. It was found that both isomers 2‐C and 2‐E absorbed white light and they interconvert. The kinetics of photocoloration and photobleaching processes were followed spectrophotometrically by monitoring the absorbance of the ring closed product 2‐C at its λmax of 620 nm. The apparent first‐order rate constants for both processes were determined. It was found that there was slight variation in the rate constant for photocoloration reaction with annealing temperature. On the other hand, the apparent first‐order rate constant of the photobleaching reaction decreases with increasing the annealing temperature.
Research limitations/implications
The polystyrene polymer doped photochromic fulgides described in the present paper was prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.
Practical implications
The photochromic materials developed can be used for different applications, such as coatings and holography.
Originality/value
The method developed may be used to enhance the performance of photochromic materials.
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S.Y. Cheng, C.W.M. Yuen, C.W. Kan and K.K.L. Cheuk
This paper investigates the effect of three different treatments, namely (i) sunlight exposures, (ii) bleaching and (iii) perming on the damage of the keratin fibres (with the use…
Abstract
This paper investigates the effect of three different treatments, namely (i) sunlight exposures, (ii) bleaching and (iii) perming on the damage of the keratin fibres (with the use of human hair). Scanning electron microscopy was applied to examine the surface morphology of the samples. Hair samples appeared to be rougher and their scales diminished after the treatments. The degree of colour change of samples was measured using a diffuse reflectance spectrophotometer. All three different treatments caused a certain degree of colour change on the samples. Urea bisulphite solubility test was also employed to investigate the alkaline damage of samples.
The results illustrated that the urea bisulphite solubility of samples conformably decreased when they were subject to these three types of treatments. With respect to the tensile strength property, the results indicate that the breaking load of treated samples decreased dramatically after undergoing three different types of treatments. On evaluating the test results, it was concluded that the bleaching process imparted the most severe damages to hair. The results of the different test methods were evaluated and discussed.
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Shimaa S.M. Elhadad, Hany Kafafy, Hamada Mashaly and Ahmed Ali El-Sayed
The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.
Abstract
Purpose
The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.
Design/methodology/approach
The newly prepared lecithin liposome was used to encapsulate dyes for the purpose of increasing dyeing affinity. Different ratios of commercially available lecithin liposomes (1%, 3%, 5% and 7%) were used simultaneously in the dyeing of cotton and wool fabrics. The treated fabrics (cotton and wool fabrics) were confirmed using different analytical procedures such as scanning electron microscope (SEM), Fourier-transition infrared spectroscopy, ultraviolet protection factor, colour strength (K|S) measurements and fastness measurements.
Findings
The results show that increasing liposome ratios in dyeing baths leads to increased dyeing affinity for cotton and wool fabrics compared with conventional dyeing without using liposomes. In addition to that, the colour strength values, infrared spectra, SEM and fastness properties of non-liposome-dyed fabrics and liposome-dyed fabrics were investigated.
Originality/value
The research paper provides broad spectrum of green encapsulation fabrics using liposome technology to perform the dye stability, dye strength and fastness.
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Abstract
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A.A. Bahajaj, A.M. Asiri, A.M. Alsoliemy and A.G. Al‐Sehemi
The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.
Abstract
Purpose
The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.
Design/methodology/approach
The poly(methyl methacrylate) PMMA and epoxy resin doped with photochromic spirooxazine (SO) are prepared and the effects of ultraviolet (UV) irradiation are studied using spectrophotometer. The reversible reaction is effected using white light. Photochemical fatigue resistance of these films is also studied.
Findings
Irradiation of colourless 7′,8′‐dichloro‐1,3,3‐trimethylspiro[indoline‐2,3′‐[3H]benzo[b][1,4]oxazine] (SO) doped in PMMA and epoxy resin with UV light (366 nm) results in the formation of an intense purple‐red coloured zwitterionic photomerocyanine (PMC). The reverse reaction is photochemically induced by irradiation with white light. Photocolouration and photobleaching reactions follow a first‐order rate equation. It is found that photocoloration rate constant of (SO) in both matrices is almost the same, which is unexpected. On the other hand, the rate of photobleaching reaction of (PMC) in PMMA is twice slower than that in the epoxy resin. It seems that the presence of the two chlorine atoms at positions 7′ and 8′ of the benzooxazine moiety destabilise the PMC in epoxy resin film and results in speeding up the fading process compared to that in PMMA. SO doped in epoxy resin shows much better fatigue resistance than that doped in PMMA.
Research limitations/implications
The PMMA and epoxy resin polymers doped photochromic spirobenzooxazine described in this paper were prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.
Practical implications
The photochromic materials developed can be used for different applications, such as coatings and holography.
Originality/value
The method developed may be used to enhance the performance of photochromic materials.
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A.A. Bahajaj and Abdullah M. Asiri
To evaluate the photochromic performance of photochromic compounds in polymer matrices.
Abstract
Purpose
To evaluate the photochromic performance of photochromic compounds in polymer matrices.
Design/methodology/approach
The epoxy resin doped with photochromic fulgide were prepared and the effect of UV irradiation were studied using spectrophotometer. The reversible reaction was effected using white light. The effect of heat was also determined.
Findings
A film of fulgide 1‐E doped in epoxy polymer was irradiated with UV light (366 nm), the film turned pink. The later colour was switched back to the original colour when the film was irradiated with a white light. The photocoloration and photobleaching obeyed first order rate equations with rate constants being 4.19×10−3 s−1 and 2.86×10−2 s−1, respectively. It was found that the film showed a good fatigue resistance. Another film was preheated at 80°C for 1‐4 h. No change in the UV absorption spectra of the film was observed. Similarly, the photocoloration and photobleaching of the annealed film showed first order rate equations with rate constants being 8.77×10−3 s−1 and 4.02×10−2s−1, respectively. Interestingly, the photocoloration and photobleaching reactions of the annealed film were faster than those of the non‐annealed film.
Research limitations/implications
The epoxy resin doped photochromic fulgides described in the present paper was prepared and studied. The principle of study established can be applied to any type of resin or to any type of photochromic compounds.
Practical implications
The photochromic materials developed can be used for different applications, such as coatings and holography.
Originality/value
The method developed may be used to enhance the performance of photochromic materials.
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To discover new photochromic molecules suitable for various applications.
Abstract
Purpose
To discover new photochromic molecules suitable for various applications.
Design/methodology/approach
The synthesis of the new photochromic pyrazole derivatives was accomplished by reaction of tetracyanoquinodimethane (TCNQ) and pyrazoles in polar solvents such as dimethylformamide (DMF).
Findings
A new photochromic system had been developed and the synthesis and photochromic properties of three pyrazole derivatives upon irradiation with ultraviolet light were studies in different solvents. The photochromic and thermochromic properties were affected markedly upon changing the solvent polarity. The new materials gave colourless to deep yellow coloration upon irradiation with ultraviolet, rendering them suitable candidates for optical storage media using the region of 400 nm.
Practical implications
A new photochromic system had been developed via a simple method. The new compounds showed photochromic, thermochromic, and solvatochromic properties making them potential candidates for many applications such as sensors, optical data storage, sensors and heat sensitive materials.
Originality/value
The photochromic system was novel and hence the photochromic molecules were novel.
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This paper aims to a newly designed photoresponsive four-armed graft copolymer was synthesised and characterised. The synthesised polymer contains photochemical group and a…
Abstract
Purpose
This paper aims to a newly designed photoresponsive four-armed graft copolymer was synthesised and characterised. The synthesised polymer contains photochemical group and a greater part of the cross-linkable functional group which is not affected by short wavelength when subject to under ultraviolet (UV) irradiation in film status.
Design/methodology/approach
The four-armed macroinitiator was prepared by reacting diethanol amine with poly [methyl-2-chloro-4-{7-(chloroacetyl) oxy]-2-oxo-2H-chromen-4-yl}-2-methylbutanoate] and acylating the product with chloroacetyl chloride. A grafting reaction with n-butyl methacrylate was carried out in the presence of the four-armed macroinitiator and the catalyst CuBr/2, 2′-bipyridyne at 90°C. All of the synthesised polymers were structurally characterised by Fourier transform infrared spectroscopy (FT-IR) and Hydrogen-1 Nuclear Magnetic Resonance (1H-NMR) spectra. Gel permeation chromatography was used to obtain the molecular weights of polymer.
Findings
1H-NMR, FT-IR and ultraviolet-visible (UV-Vis) spectroscopy demonstrated that the four-armed macroinitiator and the graft copolymer was successfully synthesised. The end-functionalised poly(methyl methacrylate) with 7-hydroxyl-4-chloromethyl coumarin was irradiated at the wavelength larger than 300 nm to create the cyclobutane ring in between the 7-hydroxyl-4-chloro methyl coumarin unities. To characterise the polymer and show the transformation of coumarin unities into photodimers, 1H-NMR, FT-IR and UV-Vis spectroscopy were used.
Research limitations/implications
Graft copolymer containing coumarin has involves photocrosslinkable functional group, in which reactive functional group has attracted great interest from both industrial and academic fields. Their synthesis provides the opportunity for a compatible modification of the graft copolymer structure to develop adapted macromolecules for a range of end practices.
Practical implications
A photoresponsive graft copolymer can have a role in an active area of polymer chemistry research due to its uses in the areas of photolithography, liquid crystal, non-linear optical materials, laser dyes, fluorescence materials and future microelectronics.
Originality/value
Graft copolymers containing a photocrosslinkable functional group, and a star polymer may be prepared using the method described in this paper and then used in technological applications. The method discussed here also allows photoinduced reversible self-healing in solid polymers.
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