Search results

The purpose of this paper is to evaluate the effect of antioxidant 2,6-di-tert-butyl-p-methylphenol (BHT) on the thermal stability and fatigue resistance of spirooxazine and then study the properties of photochromic polyvinyl butyral resin (PVB) films.

BHT was introduced into the spirooxazine system by blending and covalent bonding. The properties of spirooxazine solutions and photochromic PVB films were studied.

The thermal stability and fatigue resistance of spirooxazine covalently linked (BHT-SO) or mixed (BHT/SO) with BHT were higher than the system without BHT, and BHT-SO was the better one. But acidic substance would greatly impair the fatigue resistance of spirooxazine. The optimum addition amount of BHT-SO2 to PVB was 2.5 per cent, and the minimum limit was 0.01 per cent. The fading kinetic and fatigue resistance of film were similar to the solution and better. Plasticizer could accelerate the fading rate and strengthen the mechanical properties of photochromic film but had no effect on the fatigue resistance.

Spirooxazine could be grafted onto the PVB chain to make the ring closure fading reaction slower.

In addition to the wide application prospects of photochromic materials in decoration, optical storage, etc., the photochromic PVB film in the car safety glass can absorb sunlight and turn blue, then fade to colorless when the sunlight disappears, making the interior environment more comfortable.

The introduction of BHT into the spirooxazine system not only exerts its ability to capture free radicals, but its bulky volume also increases the resistance of the ring closure, making the fading process slower.

The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.

The poly(methyl methacrylate) PMMA and epoxy resin doped with photochromic spirooxazine (SO) are prepared and the effects of ultraviolet (UV) irradiation are studied using spectrophotometer. The reversible reaction is effected using white light. Photochemical fatigue resistance of these films is also studied.

Irradiation of colourless 7′,8′‐dichloro‐1,3,3‐trimethylspiro[indoline‐2,3′‐[3H]benzo[b][1,4]oxazine] (SO) doped in PMMA and epoxy resin with UV light (366 nm) results in the formation of an intense purple‐red coloured zwitterionic photomerocyanine (PMC). The reverse reaction is photochemically induced by irradiation with white light. Photocolouration and photobleaching reactions follow a first‐order rate equation. It is found that photocoloration rate constant of (SO) in both matrices is almost the same, which is unexpected. On the other hand, the rate of photobleaching reaction of (PMC) in PMMA is twice slower than that in the epoxy resin. It seems that the presence of the two chlorine atoms at positions 7′ and 8′ of the benzooxazine moiety destabilise the PMC in epoxy resin film and results in speeding up the fading process compared to that in PMMA. SO doped in epoxy resin shows much better fatigue resistance than that doped in PMMA.

The PMMA and epoxy resin polymers doped photochromic spirobenzooxazine described in this paper were prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.

The photochromic materials developed can be used for different applications, such as coatings and holography.

The method developed may be used to enhance the performance of photochromic materials.

Our previous papers (Viková & Vik, 2005) described a unique device, now patented in the Czech Republic in the author's name, for photochromic measurement in a reflectance mode together with a methodology. This device allows photochromic sensors to test the colorimetric and spectral characteristics of photochromic textiles, and also fatigue tests for control of colour change stability. This concept of colorimetric and spectral parameters also finds the dependence of colour change on the intensity of UV irradiation and temperature. In this paper, we would like to describe the dependence of colour change on temperature for the photochromic Photopia AQ Ink system (Blue, Purple and Yellow) produced by Matsui Shikiso Chemical Co.Ltd.

It is known that the reversion of photochromic compounds from coloured to colourless is promoted thermally. The photochromic structure can achieve a lower level of saturated absorbance at higher temperatures when thermo reversible photochromic systems, such as spirooxazines and chromenes, increase the rate of thermal bleaching reaction and thus decrease light stimulated coloration.

Photochromic surface coating on textiles may create new fashion opportunities. It also enhances the ultraviolet (UV) protection ability of the coated products. In this study, a spirooxazine dye and a silane that bears a long alkyl chain have been used to produce hybrid photochromic silica coatings on wool fabrics. Four stabilisers are added separately to the photochromic silica coatings to examine their influence on photostability and photochromic behaviour. It is found that the addition of UV stabilisers slightly reduces the photochromic response speed and photochromic absorption. However, the addition of UV stabilisers to the photochromic coating considerably improves the photochromic lifetime. Among the four UV stabilisers studied, the quencher results in the best improvement to photostability with the lowest reduction in photochromic absorption.

The purpose of this paper is to evaluate the photochromic performance of photochromic compounds in polymer matrices.

The poly(methyl methacrylate) (PMMA) and epoxy resin doped with photochromic spirobenzopyran were prepared and the effects of ultraviolet (UV) irradiation were studied using spectrophotometer. The reversible reaction was effected using white light. Photochemical fatigue resistance of these films was also studied.

Irradiation of colourless 1′,3′,3′‐trimethyl‐6‐nitrospiro[2H‐1‐benzopyran‐2,2′‐indoline] spiropyran (SP) doped in PMMA and epoxy resin with UV light (366 nm) results in the formation of an intense purple‐red coloured zwitterionic photomerocyanine (PMC). The reverse reaction was photochemically induced by irradiation with white light. Photocolouration of SP doped in PMMA follows a first‐order rate equation (k=0.0011 s⁻¹), while that doped in epoxy resin deviates from linearity. It was found that photobleaching follows a first‐order equation in both matrices. The photobleaching rate constant of PMC in both matrices is the same and equals 0.0043 s⁻¹. Spirobenzopyran doped in PMMA shows better fatigue resistance than that doped in epoxy resin.

The PMMA and epoxy resin polymers doped with photochromic spirobenzopyran described in the present paper were prepared and studied. The principle of study established can be applied to any type of polymer or to any type of photochromic compounds.

The photochromic materials developed can be used for different applications, such as coatings and holography.

The method developed may be used to enhance the performance of photochromic materials.

The purpose of this paper is to investigate the effect of annealing on photochromic performance of (E)‐dicyclopropylmethylene‐(2, 5‐dimethyl‐3‐furylethylid‐ene)‐succinicanhydride doped in polyacrylic acid thin film.

(E)‐dicyclopropylmethylene‐(2,5‐dimethyl‐3‐furyl‐ethylidene)‐succinic‐anhydride (DMDFS‐E) fulgide doped in polyacrylic acid thin films was prepared. DMDFS‐E fulgide doped in polyacrylic acid thin films was heated at various annealing temperatures. Photocoloration, photobleaching and photochemical fatigue resistance for the desired DMDFS‐E fulgide doped in polyacrylic acid thin films were studied.

Upon irradiation with UV light (366 nm), fulgide DMDFS‐E undergoes a conrotatory ring closure to the pinkish colored closed form C (523 nm). The later color was switched back to the original color when the films were irradiated with white light. The kinetics of photocoloration and photobleaching processes were followed spectrophotometrically by monitoring the absorbance of the ring closed product DMDFS‐C at its λmax of 523 nm. The first‐order plots of photocoloration reaction showed distinct linear line at different temperatures. The slope of these first‐order lines corresponding to the rate constants k. It was found that for photocoloration reaction, the rate constant of the photocoloration reaction was slower than the photobleaching reaction and both reactions decrease with increasing the annealing temperatures. It was found that there was almost improvement of photochemical fatigue resistance of fulgide DMDFS‐E doped in polyacrylic acid thin film at several of the annealing temperatures.

The results obtained in this work showed that the photochromic properties of DMDFS fulgide E were improved upon annealing the film at 100°C. Therefore, it would be recommended for improvement to apply fulgides as annealed polymer films.

Smart materials also called intelligent materials are gaining importance continuously in many industries including aerospace one. It is because of the unique features of these materials such as self-sensing, self-adaptability, memory capabilities and manifold functions. For a long time, there is no review of smart materials. Therefore, it is considered worthwhile to write a review on this subject.

A thorough search of the literature was carried out through SciFinder, ScienceDirect, SpringerLink, Wiley Online Library and reputed and peer-reviewed journals. The literature was critically analyzed and a review was written.

This study describes the advances in smart materials concerning their applications in aerospace industries. The classification, working principle and recent developments (nano-smart materials) of smart materials are discussed. Besides, the future perspectives of these materials are also highlighted. Much research has not been done in this area, which needs more extensive study.

Certainly, this study will be highly useful for academicians, researchers and technocrats working in aerospace industries.

The paper aims to provide an overview of the area of smart textiles.

The paper describes and discusses new and developing materials and technologies used in the textile industries.

Significant progress has been achieved in the area of technical textiles. Fibres, yarns, fabrics and other structures with added‐value functionality have been successfully developed for technical and/or high performance end‐uses. The basic building blocks are already in place in the field of smart textiles and clothing.

As progress in science and engineering research advances, and as the gap between designers and scientists narrows, the area of smart clothing is likely to keep on expanding for the foreseeable future. Growth is predicted to occur in two distinct directions: performance‐driven smart clothing and fashion‐driven smart clothing. There are challenges that have to be addressed.

The paper provides information of value to those interested in the future directions of the textile industry.

The purpose of this paper is to investigate the effects of dipentaerythritol hexaacrylate (DPHA) and 3-(trimethoxysilyl)propyl methacrylate-modified silica nanoparticles (MSiO₂) contents on the performances of the Disperse Red 1 (DR1)-grafted-silica/poly(acrylate) color hard coatings.

The organic dye DR1 was silylated by reaction with the coupling agent 3-isocyanatopropyltriethoxysilane in methyl ethyl ketone. The silylated-DR1 thus obtained was grafted on MSiO₂ to form dye-grafted silica (GSiO₂). This hybrid dye was then UV-cured with the cross-linking agent, DPHA, to yield color coatings. Thermal durability of the coatings was evaluated based on their CIE (international commission on illumination) chromaticity coordinates and UV/Vis transmittances.

The results indicated that GSiO₂-coatings could tolerate thermal attack better than pristine DR1-coatings or dye-absorbed silica (DSiO₂)-coatings because of the fact that DR1 was more finely dispersed in the polymer binder when covalently bonded to the silica particles. Under optimal conditions, coatings with very small change of saturation and hue after high-temperature treatments were obtainable. These coatings appeared transparent, had 3H-6H pencil hardness and adhered perfectly onto the poly(methyl methacrylate) substrates.

Dye-grafted color coatings may find applications such as color filter photoresists for displays, microelectronics, printed circuit boards, etc.

The performances of the coatings were evaluated in terms of mechanical strength, adherence to the substrate, transmittance and color stability against heat treatments, which have not been disclosed. Also, using a newly developed triangular composition diagram, suitable ranges for preparing useful color coatings were accessed. The present method deserves further research studies on green and blue dyes.