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This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace.

The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C.

Findings will be useful to develop superhydrophobic coatings with high thermal stability.

Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness.

Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.

The purpose of this investigation was to study the corrosion protection and structural characteristics of a hybrid organic-inorganic thin film preloaded with green corrosion inhibitor for anticorrosive protection of stainless steel 304L.

An ethanol solution of the polymerized 3-methacryloxypropyltrimethoxysilan and tetraethylorthosilicate was mixed with henna extract to give homogeneous sols. The morphology, composition and adhesion of hybrid sol-gel coatings were examined by SEM, EDX and pull-off tests, respectively. The surface chemistry of the hybrid sol-gel coatings was investigated with polarization scans and electrochemical impedance spectroscopy (EIS) in the physiological saline solution.

The polarization curves and EIS data were in agreement. Henna extract additions significantly increased the corrosion protection capability of the sol-gel thin film to greater than 85 percent in the physiological saline solution. In addition, the doped hybrid coating on stainless steel 304L was useful in 3.5 percent NaCl solution.

There have been few reports on the hybrid organic-inorganic thin films preloaded with corrosion inhibitor, as described in the paper, and this environmentally friendly coating on stainless steel 304L was found to be highly effective for industrial applications.

The purpose of this paper is to focus on the corrosion protection of magnesium alloy ZK10 by applying via the dip‐coating process an hybrid organic‐inorganic coating that contains nanocontainers of TiO₂ loaded with corrosion inhibitor.

The coating consists of cross‐linked polymers containing epoxy groups, conductive polymer polypyrrole as well as organic modified silicates. The morphology and the composition of the coating were examined with scanning electron microscopy and energy dispersive X‐ray analysis, respectively.

Corrosion tests via electrochemical impedance spectroscopy denoted that the incorporation of loaded nanocontainers improved the anticorrosion properties of the coating by increasing the impedance values in the low frequency range. Moreover, the surface of the aforementioned coating remained crack free after the exposure of the sample to corrosive environment.

The paper presents a new system which has been developed for the corrosion protection of magnesium alloy ZK10.

The purpose of this paper is to fabricate an ethanol sensor which has bio-friendly and eco-friendly properties compared to the commercially available ethanol sensors.

This paper describes the construction of a highly sensitive ethanol sensor with low ppm level detection at room temperature by integrating three techniques. The first deals with the formation of organic/inorganic p-n heterojunction. Second, tuning of structural parameters such as length, diameter and density of Zinc Oxide (ZnO) nanostructure was achieved through introduction of the Fe dopant into a pure ZnO seed layer. Furthermore, ultra-violet (UV) light photoactivation approach was used for enhancing the sensing performance of the fabricated sensors. Four different sensors were fabricated by combing the above approaches. The structural, morphological, optical and material compositions were characterized using different characterization techniques. Sensing behavior of the fabricated sensors toward ethanol was experimented at room temperature with and without UV illumination combined with stability studies. It was observed that all the fabricated sensors showed enhanced sensing performance for 10 ppm of ethanol. In specific, FNZ (Fe-doped ZnO seeded Ni-doped Zn nanorods) sensor exhibited a higher response at 2.2 and 13.5 s for 5 ppm and 100 ppm of ethanol with UV light illumination at room temperature, respectively. The photoactivated FNZ sensor showed quick response and speedy recovery at 18 and 30 s, respectively, for 100 ppm ethanol.

In this study, the authors have experimentally analyzed the effect of Fe (in ZnO seed layer and ZnO NRs) and Ni (in ZnO NRs) dopants in the room temperature sensing performance (with and without UV light) of the fabricated ethanol sensors. Important sensing parameters like sensitivity, recovery and response time of all the fabricated sensors are reported.

The Fe doped ZnO seeded Ni doped Zn nanorods (FNZ sample) showed a higher response at 2.2 s and 13.5 s for very low 5 ppm and 10 ppm of ethanol at room temperature under UV light illumination when compared to the other fabricated sensors in this paper. Similarly, this sensor also had quick response (18 s) and speedy recovery (30 s) for 100 ppm ethanol.

The purpose of this paper is to enhance the anticorrosion property of aluminium pigments and to improve their compatibility with polymers in coating.

Aluminium pigments encapsulated by organic‐inorganic layer were prepared by hydrolysis and condensation of organic silane acrylate resin and tetraethoxy silane (TEOS) on the surface of pigments via sol‐gel method. TEOS and poly (methyl methacryalte‐n‐butyl acrylate‐vinyl triethoxysilane) (PMBV) formed in advance by co‐polymerisation of methyl methacrylate (MMA), n‐butyl acrylate (BA) and vinyl triethoxysilane (VTES) were used as precursors. The adhesion property of the aluminium pigments was measured by peel test, and the loss of silvery appearance after encapsulation and acid soaking were both evaluated by colour lightness difference (ΔL) measurement. The encapsulated aluminium pigments were further characterised by means of FTIR, SEM, TG and XPS.

It was found that PMBV‐SiO2 thin films could be formed on the surface of aluminium pigments smoothly and uniformly, and the adhesion and anticorrosion performances of encapsulated aluminium pigments were improved significantly.

The organic silane acrylate resin used as a precursor in the sol‐gel process could be synthesised from other aclyate monomers. In addition, the hydrolysis and condensation mechanism of organic silane acrylate resin on the surface of aluminium pigments need further studies.

The method developed provided a good solution to the two problems of aluminium pigments and increased their application values.

The method of improving adhesion and anticorrosion properties of aluminium pigments was novel and could find numerous applications in surface coatings and adhesives.

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO₂) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass substrate.

Two methods have been used to enhance the hydrophobicity on glass substrates, namely, surface modification by using low surface energy isooctyltrimethoxysilane (ITMS) solution and construction of rough surface morphology using Degussa P-25 TiO₂ nanoparticles with simple bottom-up approach. The prepared sol was applied onto glass substrate using dip-coating technique and stoved in the vacuum furnace 350°C.

The ITMS coating with nano TiO₂ pigment has modified the glass substrate surface by achieving the water contact angle as high as 169° ± 2° and low sliding angle of 0° with simple and low-cost operation. The solid and air phase interface has created excellent anti-dirt and self-cleaning properties against dilute ketchup solution, mud and silicon powder.

Findings will be useful in the development of self-cleaning and anti-dirt coating for photovoltaic panels.

Sol method provides the suitable medium for the combination of organic–inorganic network to achieve high superhydrophobicity and optimum self-cleaning ability.

Application of blended organic–inorganic sol as self-cleaning and anti-dirt coating film.

The purpose of this paper was to prepare a hybrid organic/inorganic coating with interesting barrier properties against the corrosion of plain carbon steel sheets in 3.5 per cent NaCl solution. The search for replacing chromates in protective coatings has led to the development of hybrid sol-gel anticorrosive coatings. Appropriate functionalization can dramatically enhance the chemical durability and mechanical strength of these coatings.

To prepare the targeted coating, 1,2-epoxybutane (EB) was mixed with 2 to 4 per cent aminoethylaminopropyl-methylsiloxane dimethylsiloxane (APDMS) copolymer and 1,6-diaminohexane. The above coating (EBAC) has been further mixed with three different corrosion inhibitors “Moly-white® 101-ED, Heucophos Zapp® and cerium ammonium nitrate”, yielding the coatings EBAC-M, EBAC-Z and EBAC-Ce, respectively. The corrosion characteristics of all coatings on the steel panels immersed in 3.5 per cent NaCl solution were obtained using different electrochemical methods such as electrochemical impedance spectroscopic and Tafel polarization measurements.

The newly prepared coatings showed interesting protection properties for protecting the steel substrate against corrosion in chloride-containing media.

The results provide a good approach for the modification of polydimethylsiloxane coatings using a simple organic modifier.

The purpose of this work was to prepare a hybrid organic/inorganic coating with interesting barrier properties against the corrosion of plain carbon steel sheets in 3.5 per cent NaCl solution. The search for replacing chromates in protective coatings has led to the development of hybrid sol-gel anticorrosive coatings. Appropriate functionalization can dramatically enhance the chemical durability and mechanical strength of these coatings.

To prepare the targeted coating, 1,2-epoxybutane (EB) was mixed with 2-4 per cent aminoethylaminopropyl-methylsiloxane dimethylsiloxane copolymer and 1,6-diaminohexane. The above coating (EBAC) was further mixed with three different corrosion inhibitors “Moly-white® 101-ED, Hfucophos Zapp®” and Cerium Ammonium Nitrate, yielding the coatings (EBAC-M), (EBAC-Z) and (EABC-Ce), respectively. The corrosion characteristics of all coatings on carbon steel panels immersed in 3.5 per cent NaCl solution were obtained using different electrochemical methods such as electrochemical impedance spectroscopic and Tafel polarization measurements.

The newly prepared coatings showed interesting properties for protecting the steel substrate against corrosion in chloride containing media.

The results provide a good approach for the modification of polydimethylsiloxane coatings using a simple organic modifier.

The purpose of this paper is to develop hybrid organic‐inorganic silica‐based nanocomposite films, by sol‐gel method, for corrosion protection of AA2024 alloy. Also, cerium nitrate corrosion inhibitor is introduced into the optimized coating in the next step of the investigations in order to study the improvement in the corrosion protection properties of the organically modified silicate (Ormosil) films.

The sol‐gel films have been synthesized from 3‐glycidoxypropyltrimethoxysilane and tetraethylorthosilicate precursors. In order to investigate the effective factors on the properties of Ormosils films, different coatings with different organic and hydrolysis water content were developed. Then, cerium nitrate corrosion inhibitor was added to the coatings. The structure of the hybrid sol‐gel films was studied by scanning electron microscopy. The corrosion protection properties of the films were studied by potentiodynamic scanning, and electrochemical impedance spectroscopy, respectively.

The results indicate that the hybrid films provided exceptional barrier and corrosion protection in comparison with untreated aluminium alloy substrate. Moreover, improvement of the protection properties of the films containing cerium nitrate corrosion inhibitor occurred with immersion time. This would imply that cerium ions could reach the defects, and reduce the corrosion rate.

This paper provides the development of Ormosils coating, which exceptionally improves the corrosion protection of 2024 aluminium alloy.