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In this research, the effect of graphene nanosheets and graphene quantum dots (GQDs) as carbon-based nanofillers on corrosion protection performance of epoxy coatings is considered.

Graphene nanosheets are synthesized via chemical vapor deposition method, and GQDs are synthesized by a simple and gram scale procedure from carbon black. The prepared nanofillers are characterized by X-ray diffraction technique, Fourier transform infrared spectroscopy and transmission electron microscopy. Further, solvent-based epoxy coatings containing 0.1 Wt.% graphene nanosheets and GQDs are prepared, and the corrosion resistance of nanocomposite coatings is considered by electrochemical impedance spectroscopy.

The results indicate that both epoxy/graphene nanosheets and epoxy/GQDs samples have significantly higher corrosion resistance than pure epoxy coating. Meanwhile, GQDs can more effectively enhance the corrosion protection performance of epoxy coatings compared to graphene sheets, which can be attributed to the presence of functional groups on GQDs and improving the dispersion quality in polymer matrice.

In this research, for the first time, the graphene quantum dots (GQDs) prepared by a “top-down” method from carbon black are used as nanofiller in epoxy coatings, and the potential application of graphene nanosheets and GQDs as anti-corrosion nanofiller in epoxy coatings is investigated.

As a high-performance engineering plastic, polyimide (PI) is widely used in the aerospace, electronics and automotive industries. This paper aims to review the latest progress in the tribological properties of PI-based composites, especially the effects of nanofiller selection, composite structure design and material modification on the tribological and mechanical properties of PI-matrix composites.

The preparation technology of PI and its composites is introduced and the effects of carbon nanotubes (CNTs), carbon fibers (CFs), graphene and its derivatives on the mechanical and tribological properties of PI-based composites are discussed. The effects of different nanofillers on tensile strength, tensile modulus, coefficient of friction and wear rate of PI-based composites are compared.

CNTs can serve as the strengthening and lubricating phase of PI, whereas CFs can significantly enhance the mechanical properties of the matrix. Two-dimensional graphene and its derivatives have a high modulus of elasticity and self-lubricating properties, making them ideal nanofillers to improve the lubrication performance of PI. In addition, copolymerization can improve the fracture toughness and impact resistance of PI, thereby enhancing its mechanical properties.

The mechanical and tribological properties of PI matrix composites vary depending on the nanofiller. Compared with nanofibers and nanoparticles, layered reinforcements can better improve the friction properties of PI composites. The synergistic effect of different composite fillers will become an important research system in the field of tribology in the future.

This paper aims to focus on the development and study properties of bisphenol-A glycidyldimethacrylate (BisGMA) and ethylene–propylene–diene monomer (EPDM) blend-based nanocomposites containing amine-functionalised multi-walled carbon nanotubes (MWCNT-NH2) as a compatibiliser.

First, BisGMA was synthesised from epoxy and methacrylic acid followed by the amine functionalisation of MWCNTs. A novel two-roll milling technique was then conducted to prepare nanocomposite specimens with MWCNT-NH2 as compatibiliser. Effect of MWCNT-NH2 content on the mechanical, thermal, electrical, corrosive and water absorption properties of the nanocomposites was investigated and results have been reported.

The results of the present work reveal that MWCNT-NH2 acts as a potential compatibiliser and nanofiller in BisGMA/EPDM blend-based nanocomposites. The authors report here that the nanocomposites exhibit improved mechanical, thermal and electrical properties with increased addition of MWCNT-NH2. Moreover, desirable results are obtained at 5 phr of nanofiller loading beyond which the properties deteriorate due to particle agglomeration. The nanocomposites display negligible corrosion and water absorption characteristics. Thus, the above fabricated nanocomposites with optimum compatibiliser content can serve as low-cost structural, thermal and electrical materials which can also be utilised in corrosive and moist environments.

The present investigation has come up with the successful and cost-effective fabrication of BisGMA/EPDM blend-based nanocomposites with optimum nanofiller/compatibiliser (MWCNT-NH2) content that can be used for a wide range of structural, thermal and electrical projects, as it is corrosion and moisture resistant. It is also the most durable from the mechanical point of view.

The above nanocomposites have never been designed before.

Polymeric parts produced by 3D stereolithography (SL) process have poorer mechanical properties as compared to their counterparts fabricated via conventional methods, such as injection or compression molding. Adding nanofillers in the photopolymer resin for SL could help improve mechanical properties. This study aims to achieve enhancement in mechanical properties of parts fabricated by SL, for functional applications, by using well-dispersed nanofillers in the photopolymers, together with suitable post-processing.

Carbon nanotubes (CNTs) have high strength and Young’s modulus, making them attractive nanofillers. However, dispersion of CNTs in photopolymer is a critical challenge, as they tend to agglomerate easily. Achieving good dispersion is crucial to improve the mechanical properties; thus, suitable dispersion mechanisms and processes are examined. Solvent exchange process was found to improve the dispersion of multiwalled carbon nanotubes in the photopolymer. The UV-absorbing nature of CNTs was also discovered to affect the curing properties. With suitable post processing, coupled with thermal curing, the mechanical properties of SL parts made from CNTs-filled resin improved significantly.

With the addition of 0.25 wt.% CNTs into the photopolymer, tensile stress and elongation of the 3D printed parts increased by 70 and 46 per cent, respectively. With the significant improvement, the achieved tensile strength is comparable to parts manufactured by conventional methods.

This allows functional parts to be manufactured using SL.

In this paper, an improved procedure to incorporate CNTs into the photopolymer was developed. Furthermore, because of strong UV-absorption nature of CNTs, curing properties of photopolymer and SL parts with and without CNT fillers were studied. Optimized curing parameters were determined and additional post-processing step for thermal curing was discovered as an essential step in order to further enhance the mechanical properties of SL composite parts.

This study aims to fabricate multiwalled carbon nanotubes (MWCNTs)-mediated polyvinyl alcohol (PVA) composite films using the solution casting approach.

The prepared films were evaluated for diverse structural, surface, optical and electrical attributes using advanced analytical techniques, i.e. electron microscopy for surface morphology, Fourier transform infrared spectroscopy for tracing chemical functionalities, x-ray diffraction (XRD) for crystal patterns, water contact angle (WCA) analysis for surface wettability and UV visible spectroscopy for optical absorption parameters. The specimens were also investigated for certain rheological, mechanical and electrical properties, where applicable.

The surface morphology results expressed a better dispersion of MWCNTs in the resultant PVA-based nanocomposite film. The XRD analysis exhibited that the nanocomposite film was crystalline. The surface wettability analysis indicated that with the inclusion of MWCNTs, the WCA of the resultant nanocomposite film improved to 89.4° from 44° with the pristine PVA film. The MWCNTs (1.00%, w/w) incorporated PVA-based film exhibited a tensile strength of 54.0 MPa as compared to that of native PVA as 25.3 MPa film. There observed a decreased bandgap (from 5.25 to 5.14 eV) on incorporating the MWCNTs in the PVA-based nanocomposite film.

The MWCNTs’ inclusion in the PVA matrix could enhance the AC conductivity of the resultant nanocomposite film. The prepared nanocomposite film might be useful in designing certain optoelectronic devices.

The results demonstrated the successful MWCNTs mediation in the PVA-based composite films expressed good intercalation of the precursors; this resulted in decreased bandgap, usually, desirable for optoelectronic applications.

The purpose of this paper is related with the comparative study between graphene-based glass fiber–reinforced polymer composites and without graphene composite on polymer matrix. The current study explains the result of amalgamation of 4 Wt.% graphene oxide (GO), in comparison to without graphene, on the mechanical strength of glass fiber/epoxy (GE).

A hand layup technique is used for the experimental study. For this, chemical synthesis process is approached based on Hummer’s theory. For mechanical testing of glass fiber–reinforced graphene composites and without graphene composites, American Society for Testing and Materials-3039 (ASTM3039) standards was adopted. Furthermore, comparatively, composites were characterized by field emission scanning electron microscopy.

Reinforcement of 4.0 Wt.% GO in epoxy matrix material showed 7.46% and 12.31% improvement in mechanical strength and elongation, respectively. Scanning electron microscopy results showed the influence of graphene cumulations in the failure of GO-reinforced GE (GO-GE) composites.

The inimitable things of graphene grounded nanofillers have encouraged in the world of material for their thinkable manipulation in glass fiber polymeric composites. In this work, for the first time, graphene is used as nanofiller in glass fiber epoxy coatings, and their fractography study is investigated.

The purpose of this paper is to investigate the fretting wear performance of ultra-high-molecular-weight-polyethene (UHMWPE) with addition of GO and SiO₂.

In this study, GO were synthesized and SiO₂ nanoparticles were grafted onto GO. The effect of nanofiller on fretting wear performance of UHMWPE was investigated.

The results indicated that GO was successfully synthesized and SiO₂ nanoparticles successfully grafted onto GO. Incorporation of GS was beneficial for the reduction in friction and the improvement in wear resistance of UHMWPE. GO was beneficial for reducing friction coefficient, while SiO₂ was good for improving wear resistance. There existed a tribological synergistic effect between GO nanosheet and SiO₂ nanoparticles.

The hybrids of GS were promising nanofiller for improving the fretting wear performance of UHMWPE.

The main originality of the research is to reveal the effect of GO and SiO₂ nanoparticles on fretting behavior of UHMWPE. The result indicated hybrids of GS were promising nanofiller for improving the fretting wear performance of UHMWPE.

The purpose of this study was to investigate the effects of CaCO₃ nanoparticles on the mechanical properties, and mixed-mode fracture behavior of acrylonitrile butadiene styrene 3D printed samples with different internal architectures.

The nanocomposite filaments have been fabricated by a melt-blending technique. The standard tensile, compact tension and special fracture test samples, named Arcan specimens, have been printed at constant extrusion parameters and at four different internal patterns. A special fixture was used to carry out the mixed-mode fracture tests of Arcan samples. Finite element analyses using the J-integral method were performed to calculate the fracture toughness of such samples. The fractographic observations were used to evaluate the mechanism of fracture at different concentrations of nanoparticles.

The addition of CaCO₃ nanoparticles has resulted in a significant increase in the fracture loading of the samples, although this increase was not consistent for all the filling patterns, being more significant for samples with linear and triangular structures. According to the fractographic observations, the creation of uniformly distributed microvoids due to the blunting effect of nanoparticles and 3D stress state at the crack tip in the samples with linear and triangular structures justify the enhancement in the fracture loading by the addition of CaCO₃ nanoparticles in the matrix.

There is a significant gap in the knowledge of the effects of different nanoparticles in the polymer samples produced by the fused filament fabrication process. One of such nanoparticles is an inorganic CaCO₃ nanoparticle that has been frequently used as nanofillers to improve the thermomechanical properties of thermoplastic polymers. Here, experimental and numerical studies have been conducted to investigate the effects of such nanoadditives on the mechanical and fracture behavior of 3D printed samples.

The purpose of this paper is the computation of the elastic mechanical behaviour of the fullerene C₆₀ reinforced polyamide-12 (PA-12) via a two-stage numerical technique which combines the molecular dynamics (MD) method and the finite element method (FEM).

At the first stage, the proposed numerical scheme utilizes MD to characterize the pure PA-12 as well as a very small cubic unit cell containing a C₆₀ molecule, centrally positioned and surrounded by PA-12 molecular chains. At the second stage, a classical continuum mechanics (CM) analysis based on the FEM is adopted to approximate the elastic mechanical performance of the nanocomposite with significantly lower C₆₀ mass concentrations. According to the computed elastic properties arisen by the MD simulations, an equivalent solid element with the same size as the unit cell is developed. Then, a CM micromechanical representative volume element (RVE) of the C₆₀ reinforced PA-12 is modelled via FEM. The matrix phase of the RVE is discretized by using solid finite elements which represent the PA-12 mechanical behaviour predicted by MD, while the C₆₀ neighbouring location is meshed with the equivalent solid element.

Several multiscale simulations are performed to study the effect of the nanofiller mass fraction on the mechanical properties of the C₆₀ reinforced PA-12 composite. Comparisons with other corresponding experimental results are attempted, where possible, to test the performance of the proposed method.

The proposed numerical scheme allows accurate representation of atomistic interfacial effects between C₆₀ and PA-12 and simultaneously offers a significantly lower computational cost compared with the MD-only method.

The purpose of this study is to develop active package films using clove essential oil (CEO) and biodegradable polybutylene adipate terephthalate (PBAT) with varying weight percentages of SiO₂ nanoparticles (SiO₂NPs), as well as to investigate the mechanical, barrier, thermal, optical, surface hydrophobicity and antibacterial properties of PBAT incorporated with CEO as a natural plasticizer and SiO₂NPs as a nanofiller.

PBAT-based bio-composites films were fabricated with different weight percentage of CEO (5% and 10%) and nanosilica (1% and 3%) by solution casting method. The packaging performance was investigated using universal testing machine, spectrophotometer, contact angle goniometer, oxygen and water vapour permeability tester. The antibacterial properties of PBAT-based nanocomposite and composite films were investigated using the ISO 22196 by zone of inhibition method.

The mechanical results exhibited that the addition of 10 Wt.% of CEO into PBAT increases the percentage of elongation, whereas, the addition of 3 Wt.% of SiO2NPs increases the tensile strength of the composite film. The presence of CEO in PBAT exhibits a good barrier against water permeability and SiO2NPs in the PBAT matrix help to reduce the opacity and hydrophobicity. The antimicrobial and thermal results revealed that the inclusion of 10 Wt.% of CEO and 3 Wt.% of SiO₂NPs into PBAT polymer improved antimicrobial and thermal resistance properties.

A new PBAT-based active packaging film developed using natural plasticizers CEO and nanofiller SiO₂ with a wide range of applications in the active food packaging applications. Moreover, they have good surface hydrophobicity, thermal stability, mechanical, barrier and antibacterial properties.