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1 – 10 of 12Rania Abdel Gwad Eloriby, Wael Sabry Mohamed and Hamdy Mohamed Mohamed
The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating…
Abstract
Purpose
The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating archaeological glass.
Design/methodology/approach
This study focused on characterizing glass surfaces coated with two commonly used polymeric materials in archaeological glass preservation. Furthermore, the study evaluates the elimination of these coatings from the surfaces by using innovative aqueous systems composed of micellar solutions (MS) and oil-in-water (O/W) Texapon-P microemulsions (TEX). Glass samples coated with selected polymers were subjected to thermal and photochemical aging to simulate natural degradation conditions. This study aimed to evaluate the effectiveness of nanocontainer aqueous systems compared to acetone (Ac), a conventional solvent commonly used for removal procedures. The characterization procedures involved transmission electron microscopy, USB digital microscopy, scanning electron microscopy, color alteration and gravimetric measurement.
Findings
The findings indicate that the effectiveness of novel techniques using aqueous nanocontainer systems is quite promising when considering a “green approach” to preserving cultural heritage. Microscopic examination demonstrated the efficacy of MS in effectively removing acrylic and vinyl polymers from the glass surface. Furthermore, TEX proved effective in removing polyvinyl acetate (PVA) over Paraloid B72 (B-72). In addition, the measurement of color alteration values revealed a decrease after using MS compared to the standard sample before applying the polymers, with values of ΔE = 1.48 and 1.82 for B-72 polymer and PVA, respectively.
Originality/value
This research provides nanocontainer solutions for removing aged polymers from the glass surface. This makes the current study a promising step for treating archaeological glass.
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Hamdy Mohamed Mohamed and Wael Sabry Mohamed
The study aims to assess the efficiency of nanocomposite to improve the properties of gap-filling materials for pottery artifacts.
Abstract
Purpose
The study aims to assess the efficiency of nanocomposite to improve the properties of gap-filling materials for pottery artifacts.
Design/methodology/approach
Five different pastes were used in the laboratory studies. The pastes consist mainly of pottery powder (grog), dental plaster, microballoons and an adhesive of Primal AC33, nano-silica and nano kaolinite in various concentrations. The prepared samples were subjected to accelerated heat and light aging. Besides, some investigations were used to evaluate the efficacy of the additive nanomaterials, such as TEM, digital and scanning electron microscopy microscopes. Contact angle, color change, shrinkage degree, physical properties and compressive strength tests were also conducted.
Findings
The results indicated that using Nano-silica considerably improves the mechanical strength and decreases the shrinkage of gap-filling materials. According to the results, a mixture of grog, microballoons and Primal AC33/Nano-silica Nanocomposites is the optimal gap-filling paste for archaeological pottery. Moreover, this paste showed a higher contact angle (120°), lower color change (ΔE = 2.62), lower shrinkage (3.3%), lower water absorption (3.36%), lower porosity (5.05%) and higher compressive strength (5124 N/mm2).
Originality/value
This paper attains to develop an economic polymer-nanocomposite that can be used with gap-filling materials for pottery artifacts.
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Bataa Sayed Mohamed Mazen, Badawi Mohamed Ismail, Rushdya Rabee Ali Hassan, Mahmoud Ali and Wael S. Mohamed
The purpose of this study is to detect the effect of some natural cellulosic polymers in their nano forms with the addition of zinc oxide nanoparticles on restoring the lost…
Abstract
Purpose
The purpose of this study is to detect the effect of some natural cellulosic polymers in their nano forms with the addition of zinc oxide nanoparticles on restoring the lost mechanical strength of degraded papyrus without any harmful effects on the inks.
Design/methodology/approach
In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.
Findings
In the current study, the USB digital microscopy, scanning electron microscope, measurement of mechanical properties (tensile and elongation), pH measurement, color change and infrared spectroscopy were undertaken for the samples before and after treatment and aging.
Originality/value
The effect of strengthening materials was studied on cellulose and carbon ink, which makes this study closer to reality as the manuscript is the consistent structure of cellulose and inks, whereas most of the literature stated the impact of consolidation materials on the strengthening the cellulosic supports without attention to their impact on inks.
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Wael Mohamed Abdelmaksoud, Mohamed Aboaly, Said Teleb, Adel Mohy-Eldin Gabr and Mostafa Abdellah Sayed
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol…
Abstract
Purpose
The pursuit of manufacturing new inks with low financial cost is an urgent economic demand. Thus, the purpose of this paper is to synthesize some new pigments derived from Lithol Rubine (LR) via a successful simple route and to investigate their physicochemical properties for usage in the inks industry.
Design/methodology/approach
Two novel pigments were generated during the reaction of LR with Mn(II) and Co(II) salts in ethanolic solutions. The obtained pigments were isolated as solid compounds and characterized through elemental analysis, UV–vis, Fourier transform infrared, 1H NMR spectra, oil absorption, specific gravity, melting point, molar conductivity and magnetic moment measurements. Their dyeing and durability characteristics were examined using American Standard Testing Methods. The synthesized pigments were then applied in inks formulation.
Findings
The printing inks containing the two new pigments (LR–Mn and LR–Co) were compared to (GF 59-606 and GF 59-616), respectively. The results of this study showed that the performance of newly prepared pigments was comparable to that of commercial pigments currently in use in the inks industry.
Practical implications
LR and its new derivative pigments can be used in other different applications such as paper coating, crayon, rubber and paint industries.
Originality/value
The authors designed an efficient synthesis for some novel pigments. The synthesis technique is featured by a short reaction time, high yields and ease of use. The pigments developed would be good and cost-effective substitute for the original commercially available and expensive pigments used in the inks industry.
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Walaa M. Abd El-Gawad and Wael Mohamed Abdelmaksoud
This study aims to investigate the possibility of synthesizing cobalt doped willemite ceramic blue pigment by using Egyptian white sand as environmental and economical raw…
Abstract
Purpose
This study aims to investigate the possibility of synthesizing cobalt doped willemite ceramic blue pigment by using Egyptian white sand as environmental and economical raw material for multi-applications in coatings and inks.
Design/methodology/approach
After the synthesis process, the prepared blue pigment was characterized via X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray analysis technique. Then the blue pigment was integrated into both coating and ink formulations. The effect of the prepared multifunctional coatings on corrosion resistance and thermal stability was evaluated using different standard tests. Also, the effect of inclusion of blue pigment in flexographic printing ink formulation was done.
Findings
The results showed that the coating containing the cobalt doped willemite blue pigment offered good anticorrosive performance and high thermal stability. Additionally, the presented results revealed that integration of the blue pigment in flexographic printing ink formulation enhanced fineness, gloss, viscosity and color more than the commercial one “FX 430–201.”
Originality/value
In conclusion, relied on the eco-friendly principle which can be regarded as an economic and green strategy, it can be obtained that this new pigment can provide good multifunctions such as corrosion resistance and thermal stability in coatings and good fineness, gloss, viscosity and color in inks which can enable them to be widely applied in different industries.
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Eman Salim, Wael S. Mohamed and Rasha Sadek
Paper aims to evaluate the efficiency of traditional chitosan, nano chitosan, and chitosan nanocomposites for consolidating aged papyrus samples. Cellulose-based materials, such…
Abstract
Purpose
Paper aims to evaluate the efficiency of traditional chitosan, nano chitosan, and chitosan nanocomposites for consolidating aged papyrus samples. Cellulose-based materials, such as papyrus sheets and paper, which are the most common types of writing supports for works of art in many museums and archive. They are subjected to different types of deterioration factors that may lead to many conservation problems. Consolidation treatment is one of the most common conservation treatments, which should have perform after much testing to select the appropriate consolidants.
Design/methodology/approach
This research paper aims to evaluate the resistance of traditional chitosan, nanochitosan and chitosan/zinc oxide nanocomposite as an eco-friendly papyrus strengthening. Untreated and treated papyrus was thermally aged and characterized via scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR). Antimicrobial activity of the papyrus specimens was also determined against four tested pathogenic bacteria by disc diffusion method: MRSA, Staphylococcus aureus, E. coli and P. aeruginosa.
Findings
The results revealed that chitosan nanocomposite showed a remarkable enhancement of papyrus tensile properties and presence of ZnO prevents the effects of biodeterioration.
Originality/value
Zinc oxide nanoparticles enhance the optical properties and increase the chemical reactions between the consolidating material and the treated papyrus.
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Gomaa Abdel-Maksoud, Aya Abdallah, Rana Youssef, Doha Elsayed, Nesreen Labib, Wael S. Mohamed and Medhat Ibrahim
This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.
Abstract
Purpose
This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.
Design/methodology/approach
New vegetable-tanned leather samples were prepared. The consolidants used were polyacrylamide (PAM) and polymethyl methacrylate/hydroxyethyl methacrylate (MMA-HEMA). Accelerated heat aging was applied to the untreated and treated samples. Analytical techniques used were Fourier transform infrared spectroscopy (FTIR), digital microscope, scanning electron microscope (SEM), change of color and mechanical properties.
Findings
The characteristic FTIR bands showed the effect of accelerated heat aging on the molecular structure of the studied samples, but treated and aged treated samples used were better than aged untreated samples. Microscopic investigations (digital and SEM), and mechanical properties proved that 2% was the best concentration for polymers used. The change in the total color difference of the treated and aged treated samples was limited.
Originality/value
This study presents the important results obtained from PAM and poly(MMA-HEMA) used for the consolidation of vegetable-tanned leather artifacts. The best results of the studied polymers can be applied directly to protect historical vegetable-tanned leathers.
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Amir A. Abdelsalam, Salwa H. El-Sabbagh, Wael S. Mohamed and Mohsen A. Khozami
This study aims to investigate the swelling behavior, mechanical and thermal properties of ternary rubber blend composites prepared by melt blending based on carbon black…
Abstract
Purpose
This study aims to investigate the swelling behavior, mechanical and thermal properties of ternary rubber blend composites prepared by melt blending based on carbon black (CB)-filled natural rubber (NR)/styrene-butadiene rubber (SBR)/nitrile butadiene rubber (NBR) blends, containing a variety of compatibilizers. Various compatibilizers, maleic acid anhydride (MAH), prepared emulsion and adhesion system (HRH) were used. A series of NR/SBR/NBR blends at a 30/30/40 blend ratio reinforced with 45 phr of CB were prepared using the master-batch method.
Design/methodology/approach
Thermal aging properties of the composites characterized by their aging coefficient and retention in tensile and elongation at break (E.B. %). Thermal degradation of ternary rubber blend composites based on melt blending has been studied using thermogravimetric analysis.
Findings
The swelling coefficient decreased with increased compatibilizer loading. Results also showed that the tensile strength and E.B. (%) decreased with aging over the entire aging period. Additionally, the addition of compatibilizers into the ternary rubber blend composite had slightly improved the thermal stability.
Research limitations/implications
Interactions between the different components of blends at the interfaces have a high impact on the interfacial properties of the rubber blend.
Practical implications
Compatibilizers significantly improve the properties of the resulting composites with the loading of investigated compatibilizers because of the uniform dispersion of CB in the rubber matrix.
Social implications
Using blends in the rubber industry led to the high-efficiency production of low-cost products.
Originality/value
The rubber blending has a significant positive effect on a wide range of applications such as structural applications, aerospace, military, packaging, tires and biomedical, so improving the compatibility of blends will make new materials suitable for new applications.
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Yusuff Jelili Amuda and Sarah Alabdulrahman
Conventional insurance creates a gap in the financial system across the world that manifests from the global financial and economic crisis. There is an increasing demand for…
Abstract
Purpose
Conventional insurance creates a gap in the financial system across the world that manifests from the global financial and economic crisis. There is an increasing demand for insurance schemes that will bridge the gap of financial and economic crisis globally. More recently, there is an advocacy in Saudi Arabia for achieving Vision 2030 by various facets of human endeavours such as strengthening financial markets and boasting economic development. The purpose of this paper is to deeply explore policy and reinforcement of the legal framework of Islamic insurance as essential bedrocks in Islamic finance that are Shari’ah compliant to achieve Saudi Vision 2030 for overall sustainability of all spheres of human endeavours in the country.
Design/methodology/approach
Content analysis and systematic literature review are used as methodological approaches in this paper. There are various sources of accessing secondary data used in this study such as online peer review, journals and library-based sources. Through the exploration of various secondary data, five major themes were identified in this study, namely, policy, legal framework, Islamic insurance, Islamic finance and Saudi Vision 2030. Analysis of various themes were done systematically in this paper. The methodology provides theoretical and practical foundations for reinforcing policy and legal framework for Islamic insurance, specifically in Islamic finance to achieve Vision 2030 in Saudi Arabia. It is the policy and legal framework that can provide necessary dynamics for strengthening Islamic insurance in particular and Islamic finance in general towards attaining sustainable Vision 2030 in the country.
Findings
The paper demonstrated that policy period is explicitly associated with Islamic insurance, whereby Takaful insurance is regarded as policyholder rather than shareholder-oriented. Similarly, it is established that there is need to specifically mention the policy period and the nature of contract in Islamic insurance should not be limited to only mutual cooperation among the participants in connection with the losses but it should capture element of sharing income generated from investment between insurer and policyholders using predetermined ratio for such as provided with theoretical legal framework (Shari’ah) in connection with Islamic insurance model as an integral part of Islamic finance.
Research limitations/implications
It will depart completely from conventional insurance where borrowing of funds and investment are put at fixed interest (Riba), uncertainty (Gharar) and speculative ideas (Maisir). Avoidance of different elements ascribed with conventional insurance would enable Saudi Arabia to strengthen financial system and boast economic development with an emphasis on an effective policy and efficient legal framework towards attaining Vision 2030 in the country.
Practical implications
The methodology provides theoretical and practical foundations for reinforcing policy and legal framework for Islamic insurance, specifically in Islamic finance to achieve Vision 2030 in Saudi Arabia.
Social implications
Conventional insurance creates a gap in financial system across the world that manifests from the global financial and economic crisis. There is an increasing demand for insurance scheme that will bridge the gap of financial and economic crisis globally. More recently, there is an advocacy in Saudi Arabia for achieving Vision 2030 by various facets of human endeavours such as strengthening financial market and boasting economic development.
Originality/value
With this emphasis, it will depart completely from conventional insurance where borrowing of funds and investment are put at fixed interest (Riba), uncertainty (Gharar) and speculative ideas (Maisir). Avoidance of different elements ascribed with conventional insurance would enable Saudi Arabia to strengthen financial system and boast economic development with an emphasis on an effective policy and efficient legal framework towards attaining Vision 2030 in the country.
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Yousra Ghazaoui, Mohammed EL Ghzaoui, Sudipta Das, BTP Madhav and Ali el Alami
This paper aims to present the design, fabrication and analysis of a wideband, enhanced gain 1 × 2 patch antenna array with a simple profile structure to meet the desired antenna…
Abstract
Purpose
This paper aims to present the design, fabrication and analysis of a wideband, enhanced gain 1 × 2 patch antenna array with a simple profile structure to meet the desired antenna traits, such as wide bandwidth, high gain and directional patterns expected for the upcoming fifth-generation (5G) wireless applications in the millimeter wave band. To enhance these parameters (bandwidth and gain), a new antenna geometry by using a T-junction power divider is presented.
Design/methodology/approach
The theory behind this paper is connected with advancements in the 5G communications related to antennas. The methodology used in this work is to design a high gain array antenna and to identify the best possible power divider to deliver the power in an optimized way. The design methodology adopts several steps like the selection of proper substrate material as per the design specification, size of the antenna as per the frequency of operation and application-specific environment condition. The simulation has been performed on the designed antenna in the electromagnetic simulation tool (high-frequency structure simulator [HFSS]), and optimization has been done with parametric analysis, and then the final array antenna model is proposed. The proposed array contains 2-patch elements excited by one port adapted to 50 Ω through a T-junction power divider. The 1 × 2 array configuration with the suggested geometry helps to improve the overall gain of the antenna, and the implementation of the T-junction power divider provides enhanced bandwidth. The proposed array designed using a 1.6 mm thick flame retardant substrate occupies a compact area of 14 × 12.14 mm2.
Findings
The prototype of the array antenna is fabricated and measured to validate the design concept. A good agreement has been reached between the measured and simulated antenna parameters. The measured results confirm its wideband and high gain characteristics, covering 24.77–28.80 GHz for S11= –10 dB with a peak gain of about 15.16 dB at 27.65 GHz.
Originality/value
The proposed antenna covers the bandwidth requirements of the 26 GHz n258 band (24.25–27.50 GHz) to be deployed in the UK and Europe. The suggested antenna structure also covers the federal communications commission (FCC)-regulated 28 GHz n261 band (27.5–28.35 GHz) to be deployed in America and Canada. The low profile, compact size, simple structure, wide bandwidth, high gain and desired directional radiation patterns confirm the applicability of the suggested array antenna for the upcoming 5 G wireless systems.
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