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Article
Publication date: 28 July 2022

Priyanka Sakare, Saroj Kumar Giri, Debabandya Mohapatra and Manoj Kr Tripathi

This paper aims to study the color change kinetics of lac dye in response to pH and food spoilage metabolites (ammonia, lactic acid and tyramine) for its potential application in…

Abstract

Purpose

This paper aims to study the color change kinetics of lac dye in response to pH and food spoilage metabolites (ammonia, lactic acid and tyramine) for its potential application in intelligent food packaging.

Design/methodology/approach

UV-Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A528/A488) with time using zero- and first-order reaction kinetics. An indicator was prepared by incorporating lac dye in agarose membrane to validate the result of study for monitoring quality of raw milk.

Findings

Dye was orange-red in acidic medium (pH: 2 to 5) and exhibited absorbance peak at 488 nm. It turned purple in alkaline medium (pH: 7 to10) and exhibited absorbance peak at 528 nm. The change in absorbance ratio with pH followed zero-order model. Acid dissociation constant (pKa) of dye was found to be 6.3. Color change of dye in response to ammonia and tyramine followed zero-order reaction kinetics, whereas for lactic acid, the first-order model was found best. In the validation part, the color of the indicator label changed from purple to orange-red when the milk gets spoiled.

Originality/value

The study opens a new application area for lac dye. The results suggest that lac dye has potential to be used as an indicator in intelligent food packaging for detection of spoilage in seafood, meat, poultry and milk.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 29 September 2020

Awad AL Zahrany, Khalid Rabaeh, Molham Eyadeh and Ahmed Basfar

The purpose of this paper is to present a radiochromic film dosimeter containing polyvinyl alcohol (PVA) matrix and various concentrations of methyl red (MR) dye for high dose…

Abstract

Purpose

The purpose of this paper is to present a radiochromic film dosimeter containing polyvinyl alcohol (PVA) matrix and various concentrations of methyl red (MR) dye for high dose measurements.

Design/methodology/approach

The MR-PVA films were exposed to irradiation up to 60 kGy using 60Co source of gamma ray. The ultraviolet and visible regions (UV/VIS) spectrophotometry were used to examine the optical density of pre-and post-irradiated dosimeters at 424 nm.

Findings

The dose sensitivity of MR-PVA films increases significantly with increasing MR dye concentrations in the dose range of 5 to 60 kGy. The impact of relative humidity, irradiation temperature, dose rate and the stability of the films has been analyzed. The overall uncertainty of the MR-PVA film dosimeter is 6.12% (Double Standard-deviation, 95% confidence level).

Practical implications

It was found that the MR-PVA films may be used as high dose dosimeter with an acceptable overall uncertainty in routine industrial radiation processing.

Originality/value

The color bleaching of irradiated MR-PVA films in terms of specific absorbance curves increases significantly with increasing absorbed dose up to 60 kGy.

Details

Pigment & Resin Technology, vol. 50 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 September 2023

Hafsat T. Rumah, Mansur B. Ibrahim and Sani M. Gumel

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve…

Abstract

Purpose

The purpose of this research is to identify and investigate some natural dyes with halochromic properties for potential use as food spoilage indicators to reduce waste and curve the negative effects of food borne diseases.

Design/methodology/approach

Exactly 10 potential dye-yielding plants were selected based on their colour (mostly purple, red, maroon and pink). Solvent extraction was used to extract the dyes and pH differential method was used to determine the concentrations of anthocyanin in the extracted dyes. Different concentrations of hydrochloric acid and sodium hydroxide (0.1 M, 1 M and 2 M) in drops and in excess as acidic and basic solution, respectively, were used to test the halochromicity of the extracted dyes. Methyl red (a synthetic dye) was used as a reference standard/control. The pH of the dyes was recorded before and after addition of both NaOH and HCl solutions.

Findings

Five out of the 10 dyes extracted (labelled as dye A–E for Ti plant (green Cordyline fruticosa), coleus (Coleus blumei), paper flower (Bougainvillea glabra), painted nettle (Palisandra coleus) and purple heart (Setcresea purpurea), respectively, were found to be halochromic (even at low doses) by changing its colour when exposed to both acidic and basic solutions. While other dyes labelled F–J for red acalypha (Acalypha wilkesiana), golden shower (Cassia fistula), golden dew drop (Duranta repens), wild sage (Lantana camara var Aculeata) and pink oleander (Apocynaceae Nerium oleander), respectively, were either completely insensitive to the solutions in drops, slightly sensitive at high doses or the colour change is insignificant. Although some dyes were found to be more sensitive than others but in most cases, the colour changes in halochromic dyes were more stable in acidic conditions than in basic making it more sensitive to the basic than the acidic solution with the exception of dye A and E (to some extent) which was sensitive to both acidic and basic solution. The anthocyanin contents of dye A–J were found to be between the range of 2.28–10.35 mg/l with dye E having the lowest and dye J with the highest anthocyanin concentration, respectively. The initial pH of all the dyes falls within the range of 4.8–7.3 with most found within the acidic range.

Originality/value

Halochromic dye research studies are still at the infancy stage in developing world despite the vast available and abundant potential natural halochromic dye-yielding plants. The study explored this area of research and gives an opportunity for the development of smart packaging for pH-sensitive foods using natural dyes as an alternative to conventional synthetic dyes to reduce cost and also curve the negative effect of synthetic dyes as well as food borne diseases.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 7 December 2021

Khaled Mostafa

This paper aims at studying the oxygen plasma treatment and the previously prepared and fully characterized chitosan nanoparticles (CNPs) as a green and eco-friendly strategy for…

Abstract

Purpose

This paper aims at studying the oxygen plasma treatment and the previously prepared and fully characterized chitosan nanoparticles (CNPs) as a green and eco-friendly strategy for surface modification of viscose fabric. This was done to render viscose fabric dye able with two types of acid dyes that do not have direct affinity to fix on it via improving the fabric wettability.

Design/methodology/approach

To achieve the goal, viscose fabric was activated with oxygen plasma at optimum conditions and coated with different concentrations of CNPs solution via conventional pad dry cure technique. The untreated and plasma-treated fabrics with CNPs were dyed with two types of acid dyes, namely, Acid Orange 7 and Methyl Red under determined conditions. The color strength (K/S), fastness properties to light, rubbing and perspiration, add on %, tensile strength, wettability and durability of the dyed samples were determined and compared.

Findings

The results divulged that oxygen plasma-treated fabric with CNPs and the aforementioned dyes in question could improve the flowing properties in comparison with untreated fabric: (a) the fabric wettability expressed as wetting area mm2; (b) the dye ability and fastness properties of viscose fabrics expressed as K/S and fastness properties; and (c) the strength properties and add on % of the treated fabric. On the other hand, the durability of the plasma-treated fabric decreased with increasing washing cycles.

Originality/value

The novelty addressed here was using plasma treatment as an eco-friendly pre-treatment approach for attachment of CNPs as a multifunctional green bio-nano polymer onto viscose fabric, which improved the dyeing properties of the fabric with acid dyes that do not have direct affinity to fix onto it.

Details

Pigment & Resin Technology, vol. 52 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 12 September 2008

Salah Merah, Lahcene Larabi, Omar Benali and Yahia Harek

This paper aims to show the effectiveness of methyl red (MR) alone and in combination with KI as corrosion inhibitor for carbon steel in 0.5 M H2SO4.

Abstract

Purpose

This paper aims to show the effectiveness of methyl red (MR) alone and in combination with KI as corrosion inhibitor for carbon steel in 0.5 M H2SO4.

Design/methodology/approach

Corrosion rates charge transfer resistance values were determined using gravimetric and electrochemical techniques. The efficiency of inhibition was calculated by comparing corrosion rates and charge transfer resistance values in absence and presence of the inhibitor, while the mechanism of inhibition was proposed by considering temperature influence on corrosion and inhibition processes.

Findings

The inhibition efficiency of MR increased with concentration and synergistically increased in the presence of the KI. Polarisation curves reveal that MR is a mixed type inhibitor. Changes in impedance parameters were indicative of adsorption of MR on the metal surface. The trend of inhibition efficiency with temperature suggests that inhibitor molecules are physically adsorbed on the corroding metal surface in the absence of KI and chemically adsorbed in its presence. MR was found to obey Langmuir adsorption isotherm both with and without KI.

Originality/value

Electrochemical techniques have been used for the first time to study synergistic effect of MR dye and potassium iodide on inhibition of corrosion of carbon steel in H2SO4.The results suggest that the mixture (MR + KI) could find practical application in corrosion control in aqueous acidic environment.

Details

Pigment & Resin Technology, vol. 37 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 16 August 2019

Fatma Abdelghaffar, Rehab A. Abdelghaffar, Safia A. Mahmoud and Badria M. Youssef

This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater.

Abstract

Purpose

This paper aims to improve the adsorption capacity of sugarcane bagasse (SCB) as a low-cost, attractive and effective adsorbent for dye removal from wastewater.

Design/methodology/approach

SCB is a cellulosic material; it was chemically modified with compounds containing cationic groups. The adsorption efficiency of unmodified and modified SCB was investigated with anionic dyes by studying various factors that affect modified SCB and adsorption.

Findings

X-ray diffraction, FT-IR spectra and nitrogen content were used to confirm the effect of existence of quaternary ammonium groups on modified SCB. The morphological structure of the modified and unmodified SCB has been demonstrated using electronic scanning microscopy.

Research limitations/implications

The modified SCB was chemically treated by Quat 188, which is commercially available in the solution of 3-chloro-2-hydroxypropyltrimethyl ammonium chloride.

Practical implications

Grafting cationic function groups on the surface of sugarcane by cationization treatment enhances its adsorption efficiency for anionic dyes.

Originality/value

The main value of this research was indicating a clear difference in the appearance of unmodified and modified SCB surfaces. Furthermore, it can be determined that the modified SCB absorbs more of the dyes.

Details

Pigment & Resin Technology, vol. 48 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 April 2004

Amin Ismail and Emmy Hainida Khairul Ikram

This study was aimed to estimate and compare the contents of protein and amino acids in raw, boiled and fried fishes of Indian mackerel “kembong” (Rastrelliger kanagurta), sardine…

1529

Abstract

This study was aimed to estimate and compare the contents of protein and amino acids in raw, boiled and fried fishes of Indian mackerel “kembong” (Rastrelliger kanagurta), sardine (Sardina pilchardus), red tilapia (Oreochromis mossambicusx) and black tilapia (Oreochromis mossambicus). Protein contents of raw mackerel, sardine, red and black tilapia were 8.1±0.0, 8.4±0.1, 9.6±0.4 and 9.0±0.0 percent, respectively. In a boiled fish, the protein contents were 7.9±0.1, 7.7±0.0, 7.5±0.1 and 8.9±0.1 percent, respectively, and for a fried fish the values were 8.6±0.5, 8.9±0.1, 9.1±0.2 and 8.4±0.0 percent, respectively. It was found that there was a significant difference (p<0.01) in the protein content of the raw fish compared to the heat‐treated ones for all the fishes. The study detected 17 components of essential amino acids (lysine, histidine, threonine, valine, methionine, leucine, isoleucine and phenylalanine) and non‐essential amino acids (arginine, aspartic acid, serine, glutamic acid, proline, glycine, alanine, cystein and tyrosine) in all the fishes. There was no significant difference in amino acids content among the boiled and fried fishes. In conclusion, heat treatment for five minutes in boiling water (100°C) and frying for three minutes in palm oil (160°C) did not alter the quality of protein in all the fishes studied.

Details

Nutrition & Food Science, vol. 34 no. 2
Type: Research Article
ISSN: 0034-6659

Keywords

Article
Publication date: 13 April 2023

Priyanka Sakare and Saroj Kumar Giri

The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential…

Abstract

Purpose

The purpose of this paper was to study the color change kinetics of lac dye in response to aldehydes, carbon dioxide and other food spoilage metabolites for its potential application in intelligent food packaging.

Design/methodology/approach

UV–Vis spectroscopy was used to study the color change of dye solution. Ratio of absorbance of dye solution at 528 nm (peak of ionized form) to absorbance at 488 nm (peak of unionized form) was used to study the color change. Color change kinetics was studied in terms of change in absorbance ratio (A528/A488) with time using zero and first-order reaction kinetics. Lac dye-based indicator was prepared to validate the result of study for monitoring quality of strawberries.

Findings

Lac dye was orange-red in acidic medium and purple in alkaline medium. Color change of dye in response to benzaldehyde followed zero-order reaction kinetics, whereas for carbon dioxide first-order model was found best. No color change of dye solution was observed for alcohols, ketones and sulfur compounds. In the validation part, the color of the indicator label changed from purple to orange when the strawberries spoiled.

Originality/value

The study expands application area for lac dye as sensing reagent in intelligent food packaging for spoilage or ripeness detection of fruits and vegetables.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 March 2018

Amal A. Aly, Safia A. Mahmoud and Morsy Ahmed El-Apasery

This paper aims to decolorize the effluents of textile Reactive Orange 5 and Reactive Red 195 dyes by using cationized sugarcane bagasse.

168

Abstract

Purpose

This paper aims to decolorize the effluents of textile Reactive Orange 5 and Reactive Red 195 dyes by using cationized sugarcane bagasse.

Design/methodology/approach

Cationized sugarcane bagasse was prepared and used as an adsorbent for both reactive and hydrolyzed reactive dyes. Characterization of the sugarcane bagasse structure resulted by cationization was monitored using Fourier transform–infrared, while morphologically was detected using scanning electron microscopy and X-ray powder diffraction.

Findings

The maximum adsorption capacities are 805, 1,664, 1,772 and 1,596 mg/g for Hydrolyzed Red 195, Hydrolyzed Orange 5, Reactive Red 195 and Reactive Orange 5 dyes, respectively.

Research limitations/implications

Factors affecting the percentage of dye removal were optimized on different parameters such as adsorbent dose and treatment time. The data were discussed using the Langmuir and Freundlich Models of adsorption.

Practical implications

The reuse of hydrolyzed reactive dyebaths gives reasonably good fastness properties on nylon fabrics.

Social implications

The study has enabled the production of an eco-friendly and less expensive method of reactive dye effluent decolorization.

Originality/value

The study provides a potentially simple approach to decolorize dye effluents of Reactive Orange 5, Red 195 dyes and also the reuse of hydrolyzed reactive dyebaths for dyeing nylon.

Details

Pigment & Resin Technology, vol. 47 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 2 August 2013

Muhammad Saeed, Faqir Muhammad Anjum, Moazzam Rafiq Khan, Muhammad Issa Khan and Muhammad Nadeem

Whey products have conventionally been professed as a means of reducing ingredient costs. The authentic benefits of adding whey products are the enhanced worth resulting from…

Abstract

Purpose

Whey products have conventionally been professed as a means of reducing ingredient costs. The authentic benefits of adding whey products are the enhanced worth resulting from flavor, texture and nutritional improvements as well as nutraceutical or health‐enhancing payback. Therefore, the present study aims to isolate and characterize suitable starter cultures for the production of wheyghurt drink.

Design/methodology/approach

Keeping in view all the benefits of yoghurt technology this study was planned to isolate the starter cultures and optimize the conditions for the production of wheyghurt drink. The starter cultures (Lactobacillus delbruceckii ssp. Bulgaricus and Streptococcus thermophilus) were isolated from the yoghurt and further characterized on the basis of their morphological and biochemical characteristics. The wheyghurt drink prepared from starter cultures with varying starter culture concentrations (1, 1.5, 2 and 2.5 percent) was analyzed for the physicochemical and sensory characteristics to explore the potential of wheyghurt drink.

Findings

During storage, color, flavor, taste and overall acceptability were affected significantly. But the interaction between treatments and storage was found non‐significant to all the sensory parameters. At zero day maximum score (7.40) for overall acceptability was recorded for T3 and minimum score (5.60) was awarded to T4. After five, ten and 15 days of storage, judges observed a slight decline in overall acceptability in all wheyghurt drink samples. Hence it was concluded that wheyghurt drink sample T3 obtained maximum scores regarding the organoleptic evaluation and remained the best.

Practical implications

The key to growth is a continuous evaluation and modification of the product to match consumer expectations. Currently there are many apparent benefits that result from incorporating selected whey products into yogurt formulas. The starter cultures for the production of fermented whey products are not presently produced in Pakistan and are imported for industrial use. The use of LAB as starter culture may help to improve the quality and shelf life of the whey products.

Originality/value

The research is useful for food manufacturers in order to develop functional food products for consumers. Understanding consumer needs and preferences is critical to successful product development and enhancing marketing values of a product. Nutritionally improved foods, such as wheyghurt over the conventional counterpart, will be highly successful in the marketplace. Consumers will prefer such kinds of foods because they are more conscious about their health and such foods provide them with what they desire, i.e. health benefits with good nutrition.

Details

British Food Journal, vol. 115 no. 8
Type: Research Article
ISSN: 0007-070X

Keywords

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