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1 – 10 of over 2000Soo‐Min Oh, In‐Young Kim and Wha‐Soon Song
To explore the effect of acrylic acid polymerization and NaOH treatment of nylon‐6 on hemoglobin washability.
Abstract
Purpose
To explore the effect of acrylic acid polymerization and NaOH treatment of nylon‐6 on hemoglobin washability.
Design/methodology/approach
The nylon‐6 was chemically grafted with acrylic acid and treated with NaOH for the purpose to improve the washability of hemoglobin as a blood protein soil. The structural change before and after graft polymerization was analyzed by X‐ray photoelectron spectroscopy and scanning electron microscopy. The moisture regain, the contact angle, and the washability were each measured.
Findings
Graft polymerization and NaOH treatment of nylon‐6 changed the surface energy and structure of nylon‐6 causing the washability of hemoglobin to improve. Compared to ungrafted nylon‐6, the hydrophilic properties were increased remarkable by graft polymerization and NaOH treatment, which reulted in the improvement of washability.
Practical implications
Hemoglobin is one of the most difficult soils to remove from the fabric. The paper might be of interest to those who would consider purchasing fabrics that are good at both hydrophilic properties and washability.
Originality/value
The study on washability of hemoglobin as a blood protein soil for grafted fabric has not been reported so far. The results of this research may be used in a basic research for the development of new process which is capable of improving of hemoglobin washability.
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Briefly reviews previous literature by the author before presenting an original 12 step system integration protocol designed to ensure the success of companies or countries in…
Abstract
Briefly reviews previous literature by the author before presenting an original 12 step system integration protocol designed to ensure the success of companies or countries in their efforts to develop and market new products. Looks at the issues from different strategic levels such as corporate, international, military and economic. Presents 31 case studies, including the success of Japan in microchips to the failure of Xerox to sell its invention of the Alto personal computer 3 years before Apple: from the success in DNA and Superconductor research to the success of Sunbeam in inventing and marketing food processors: and from the daring invention and production of atomic energy for survival to the successes of sewing machine inventor Howe in co‐operating on patents to compete in markets. Includes 306 questions and answers in order to qualify concepts introduced.
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Yi Fu, Chunze Yan, Xiao Yang, Zhufeng Liu, Peng Chen and Zhaoqing Li
The purpose of this paper is to prepare metal/polymer composite materials prepared by additive manufacturing (AM) technology.
Abstract
Purpose
The purpose of this paper is to prepare metal/polymer composite materials prepared by additive manufacturing (AM) technology.
Design/methodology/approach
The effect of sintering parameters including laser power, scanning speed and slice thickness on strength and accuracy of selective laser sintering (SLS) parts were analyzed experimentally. Then, the laser sintering mechanism of nylon-12 coated copper was discussed through analyzing the interfacial reaction of nylon-12 and copper. The SLS parts were infiltrated with epoxy resin to meet the strength requirements of injection molding.
Findings
In this study, mechanical mixed nylon-12/copper and nylon-12 coated copper composite powders were investigated and compared as SLS materials. An effective dissolution–precipitation method was proposed to prepare nylon-12 coated copper powders with better processing and mechanical properties. The bending strength and modulus of fabricated parts after infiltration with epoxy reach 65.3 MPa and 3,200 MPa, respectively.
Originality/value
The composite materials can be used in the manufacture of injection molds with a conformal cooling channel for the production of common plastics in prototype quantities, showing a broad application prospect in rapid tooling.
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Yunsong Shi, Wei Zhu, Chunze Yan, Jinsong Yang and Zhidao Xia
This study aims to report the preparation, selective laser sintering (SLS) processing and properties of a new nylon elastomer powder. The effects of solvent, dissolution…
Abstract
Purpose
This study aims to report the preparation, selective laser sintering (SLS) processing and properties of a new nylon elastomer powder. The effects of solvent, dissolution temperature and time and cooling method and speed on the particle size and morphologies of the prepared nylon elastomer powder are investigated.
Design/methodology/approach
The prepared nylon elastomer power possesses the particle size of around 50 mm and is spherical in shape, indicating that this study provides the feasible dissolution-precipitation process, a distillation cooling method and a suitable solvent to prepare nylon elastomer powders.
Findings
Compared to pure nylon 12, the nylon elastomer has a lower part bed temperature and a wider sintering window for the SLS process. The wider sintering window indicates the better SLS processibility. The lower part bed temperature is beneficial to the recycling of material and the decrease in the requirement of SLS equipment.
Originality/value
The nylon elastomer in this study has a lower part bed temperature and a wider sintering window for the SLS process. The wider sintering window indicates better SLS processibility. The lower part bed temperature is beneficial to the recycling of material and the decrease in the requirement of SLS equipment.
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Davood Rouholamin and Neil Hopkinson
The purpose of this study was to assess the suitability of micro-computed tomography as a non-destructive method to investigate the morphology of nylon 12 parts produced by…
Abstract
Purpose
The purpose of this study was to assess the suitability of micro-computed tomography as a non-destructive method to investigate the morphology of nylon 12 parts produced by high-speed sintering (HSS). The investigation of the effect of changes in the lamp power on the properties of the fabricated parts was another purpose of this study.
Design/methodology/approach
Nylon 12 parts were manufactured using HSS with various lamp powers. Morphological properties of the parts were measured using micro-computed tomography. Ultimate tensile strength, elongation at break and Young’s modulus of the prepared parts were determined and compared. The effect of lamp power on the properties of the parts was then studied.
Findings
This paper proposes micro-computed tomography as a suitable technique to study the 3D structure of the parts produced by HSS. The effects of lamp power on the properties of the produced parts were also discussed.
Practical implications
The findings could result in an improvement in customisation of the parts for various applications through varying the lamp power. The level of lamp power could be tailored to obtain suitable part properties for a target application.
Originality/value
This study strengthens the fact that HSS is a promising additive manufacturing technique to produce nylon 12 parts, and the properties of the parts could be maximised using a suitable level of lamp power. The results showed that micro-computed tomography could be used as an efficient technique to investigate the morphology of the sintered parts.
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Abstract
Purpose
The purpose of this paper is to report a new method, the dissolution‐precipitation process, to prepare nylon‐coated metal powders for the indirect selective laser sintering (SLS) process.
Design/methodology/approach
The nylon‐12 coated carbon steel powders were prepared by the dissolution‐precipitation process. The powder characteristics are examined by scanning electron microscope (SEM) and laser diffraction particle size analysis. The effect of the applied laser energy density on the three‐point bend strength and dimensional accuracy of the SLS specimens are studied. The influence of nylon‐12 content on the bend strength are also investigated.
Findings
The SEM and laser diffraction particle size analysis results indicate that the steel particles are well coated by nylon‐12 resin. The bend strength of the SLS specimens increases with increasing the applied energy density until it reaches a maximum value, and then further increasing energy density will cause the decrease in the bend strength. The bend strength of the SLS specimens increases with increasing the nylon‐12 content over the investigated range. The dimensional errors in the X‐Y‐and Z‐directions are all increased with the increase in energy density.
Research limitations/implications
This paper only concerns the preparation and SLS of the coated powders. Further investigations are planned into post‐processing, such as binder decomposition and high‐temperature sintering, of the green parts made from the coated powders.
Originality/value
This paper provides a useful method for preparing nylon‐coated metal powders for making metal parts by the indirect SLS process.
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Abstract
Purpose
The purpose of this paper is to reinforce the selective laser sintering (SLS) parts of nylon‐12 using organically modified montmorillonite (OMMT).
Design/methodology/approach
A dissolution‐precipitation process is developed to prepare an OMMT/nylon‐12 composite powder (3 wt% OMMT). X‐ray diffraction (XRD) was used to characterize nanostructure features. The dispersion of OMMT in the nylon‐12 matrix was observed by scanning electron microscope (SEM). The effect of OMMT on the thermal properties of nylon‐12 was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The mechanical properties of the SLS parts made from the composite powder and neat nylon‐12 powder were measured and compared.
Findings
The X‐ray diffraction and SEM results indicate that the OMMT is intercalated by nylon‐12 molecular chains and uniformly dispersed in the nylon‐12 matrix during the dissolution‐precipitation process, and thus the OMMT/nylon‐12 intercalated nanocomposites are formed. The DSC and TGA results show that the OMMT can increase the melting enthalpy, relative crystalline content, crystallization temperature and thermal stability of nylon‐12. The tensile strength, tensile modulus, flexural strength, flexural modulus and impact strength of the SLS specimens made from the composite powder are 23.2, 31.7, 18.7, 32.4 and 8.4 percent higher than those of neat nylon‐12 SLS specimens, respectively, while the elongation at break decreases by 17.5 percent.
Research limitations/implications
The conclusion of forming intercalated nanocomposites was drawn from the XRD results in the present work. Further work should be done to observe the nanostructures of the materials by transmission electron microscope.
Originality/value
A dissolution‐precipitation process was used to prepare OMMT/nylon‐12 composite powders for SLS process. During the preparation process the OMMT could be intercalated by nylon‐12 molecular chains and uniformly dispersed in the nylon‐12 matrix, thus forming the OMMT/nylon‐12 intercalated nanocomposites. Therefore, the mechanical and thermal properties of nylon‐12 SLS parts were enhanced.
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Huseyin Unal, Salih Hakan Yetgin and Fehim Findik
– The purpose of the study was to find the best performance polymer material to be used in railway car bogies.
Abstract
Purpose
The purpose of the study was to find the best performance polymer material to be used in railway car bogies.
Design/methodology/approach
Wear tests and optical and scanning electron microscopy were used.
Findings
The friction coefficients of ultra-high-molecular-weight polyethylene (UHMWPE) and Nylon 6 polymers, as opposed to AISI 4140 steel, reduced with the increment of applied loads. With the increment of sliding speed, the friction coefficient increased in both UHMWPE and Nylon 6 polymers. The specific wear rate of the UHMWPE polymer was determined to be about 10-14 m2/N, whereas the rate of Nylon 6 was determined to be 10-13 m2/N.
Practical implications
The aim of the study was to find the best performance polymer material to be used in railway car bogies.
Originality/value
The friction and wear performance of UHMWPE and Nylon 6 engineering polymers were studied and compared to their AISI 4140 steel counterparts. It is an original work and it is not published in any media.
Mingwei Tian, Zongqian Wang, Lijun Qu, Ke Wang, Shifeng Zhu, Xiansheng Zhang and Ruichao Liu
Nylon 6 filaments have weak light and heat resistance in terms of stability, which restrict its application in engineering field. The purpose of this paper is to prepare a new…
Abstract
Purpose
Nylon 6 filaments have weak light and heat resistance in terms of stability, which restrict its application in engineering field. The purpose of this paper is to prepare a new photo-stabilization functional nanocomposite inks by using graphene nanosheet as UV light-resisting functional materials incorporated with polyurethane.
Design/methodology/approach
Sunlight-resisting functional nylon filaments were produced by the continuous solution dip coating technology, through which the functional inks was coated on the surface of nylon 6 filament. The surface morphology of the coated filaments was characterized by scanning electron microscopy and the graphene/polyurethane nanocomposite inks as the coating agent was confirmed and well dispersed on the fiber’s surface.
Findings
Under UV exposure, the strength loss rate of the graphene-modified nylon filaments was less than 50 percent, while that of the control nylon filament was over 85 percent, which indicated that graphene remarkably enhanced the light-resistant property of nylon. Besides, graphene/polyurethane-coated Nylon 6 filaments exhibited reasonable electrical properties and the electrical conductivity could reach 10–4 S/cm.
Originality/value
Graphene inks was first proposed as the UV photo-stabilization in this paper.
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Pradeep Kumar Mishra and Jagadesh T.
The tensile behavior of additively manufactured nylon-based carbon fiber-reinforced composites (CFRP) is an important criterion in aerospace and automobile structural design. So…
Abstract
Purpose
The tensile behavior of additively manufactured nylon-based carbon fiber-reinforced composites (CFRP) is an important criterion in aerospace and automobile structural design. So, this study aims to evaluate and validate the tensile stiffness of printed CFRP composites (low- and high-volume fraction fiber) using the volume average stiffness (VAS) model in consonance with experimental results. In specific, the tensile characterization of printed laminate composites is studied under the influence of raster orientations and process-induced defects.
Design/methodology/approach
CFRP composite laminates of low- and high-volume fraction carbon fiber of different raster orientations (0°, ± 45° and 0/90°) were fabricated using the continuous fiber 3D printing technique, and tensile characteristics of laminates were done on a universal testing machine with the crosshead speed of 2 mm/min. The induced fracture surface of laminates due to tensile load was examined using the scanning electron microscopy technique.
Findings
The VAS model can predict the tensile stiffness of printed CFRP composites with different raster orientations at an average prediction error of 5.94% and 10.58% for low- and high-volume fiber fractions, respectively. The unidirectional CFRP laminate composite with a high-volume fraction (50%) of carbon fiber showed 50.79% more tensile stiffness and 63.12% more tensile strength than the low-volume fraction (26%) unidirectional composite. Fiber pullout, fiber fracture and ply delamination are the major failure appearances observed in fracture surfaces of laminates under tensile load using scanning electron microscopy.
Originality/value
This investigation demonstrates the novel methodology to study specific tensile characteristics of low- and high-volume fraction 3D printed CFRP composite.
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