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This paper aims to study the ability of laccase for decolourisation of reactive dyes in presence and absence of natural and synthetic mediators.

Box–Behnken design was used to optimize the parameters to achieve optimum response value. Preliminary screening using several mediators was performed to evaluate extent of decolourisation for the purpose followed by selection of effective mediators only.

Laccase performs in acidic pH; increase in temperature enhances its activity. Rate of decolourisation depends on laccase and dye concentration, temperature, pH and treatment time. Out of five mediators studied, HBT, BT and VA showed promising results.

Study on decolourisation was conducted for individual dyes. In some cases, dyes are applied in combination which requires further study for authentication of data.

Decolourisation with laccase has been found to be a promising technology in waste water treatment. However, selection of mediator remains a crucial factor.

Reactive dyes are self-hydrolysed over time under natural conditions and extent of decolourisation depends on concentration of dye discharged and time spent. If not decolourised quickly, it imposes restriction on use of river water for irrigation.

In this work, activity of various natural and synthetic mediators alongwith laccase was studied to achieve maximum decolourisation which was not studied earlier.

In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical oxygen demand and biochemical oxygen demand of the indigo wastewater after degradation were evaluated and optimized treatment conditions being obtained.

The single factor method was first used to select the electrolyte system and electrode materials. Then the response surface analysis based on Box–Behnken Design was chosen to determine the influence of four independent variables such as FeCl₃ concentration, NaCl concentration, decolourization time and voltage on the degradation efficiency.

On the basis of single factor experiment, the electrode material of stainless steel was selected in the double cell, and the indigo wastewater was electrolyzed with FeCl₃ and NaCl electrolytes. The process conditions of electrochemical degradation of indigo wastewater were optimized by response surface analysis: the concentration of FeCl₃ and NaCl was of 16 and 9 g/L, respectively, with a decolourization time of 50 min, voltage of 10 V and decolourization percentage of 98.94. The maximum removal rate of chemical oxygen demand reached 75.46 per cent. The highest ratio of B/C was 3.77, which was considered to be more biodegradable.

Dyeing wastewater is bringing out more and more pollution problems to the environment. However, there are some shortcomings in traditional technologies such as adsorption and filtration. As a kind of efficient and clean water treatment technology, electrochemical oxidation has been applied to the treatments of various types of wastewater. The decolourization and degradation of indigo wastewater is taken as an example to provide reference for the treatment of wastewater in actual plants.

The developed method provided a simple and practical solution for efficiently degrading indigo wastewater.

The method for the electrochemical oxidation technology was novel and could find numerous applications in the degradation of printing and dyeing wastewater.

This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.

The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.

Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.

In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.

It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.

Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.

This paper aims to evaluate the bioremediation [chemical oxygen demand (COD) and color removal] of the effluent from the cardboard recycling industry in Yazd, central province of Iran, using mixed fungal culture.

First, the effluent samples from the cardboard recycling industry were cultured on potato dextrose agar medium to isolate native fungal colonies. The grown colonies were then identified using morphological macroscopic and microscopic characteristics to choose the dominant fungi for bioremediations. The mixed cultures of Aspergillus niger, Aspergillus flavus and Penicillium digitatum were finally used for bioremediation experiments of the cardboard recycling industry. A suspension containing 1 × 10⁶ CFU/ml of fungal spores was prepared from each fungus, separately and their homogenous mixture. Sewage samples were prepared and sterilized and used at 25%, 50% and 90% dilutions and pH levels of 5, 7 and 8 for bioremediation tests using mixed fungal spores. Following that, 10 ml of the mixed fungal spores were inoculated into the samples for decolorization and COD removal and incubated for 10 days at 30°C. The amount of COD removal and decolorization were measured before incubation and after 3, 6 and 10 days of inoculation. In this research, the color was measured by American Dye Manufacturer Institute and COD by the closed reflux method. The results of the present study were analyzed using SPSS 21 statistical software and one-way ANOVA tests at p-value < 0.05.

The results of this research showed that the mean decolorization by mixed fungal culture over 10 days at pH levels of 5, 7 and 8 were 44.40%, 45.00% and 36.84%, respectively, and the mean COD removal efficiency was 71.59%, 73.54% and 16.55%, respectively. Moreover, the mean decolorization at dilutions of 25%, 50% and 90% were 45.00%, 31.93% and 30.53%, respectively, and the mean COD removal efficiency was 73.54%, 62.38% and 34.93%, respectively. Therefore, the maximal COD removal and decolorization efficiency was obtained at dilution of 25% and pH 7.

Given that limited studies have been conducted on bioremediation of the effluent from the cardboard recycling industry using fungal species, this research could provide useful information on the physicochemical properties of the effluent in this industry.

As a natural fiber, yakwool has attracted much attention in textile processing due to its excellent properties and wearabilities. However, the main colors of yakwool are black and brown. Therefore, for extending the application scopes of the fiber, the decolorization of the yakwool fiber is usually needed, especially for the black fiber. The paper aims to discuss this issue.

In the paper, the properties of the yakwool fiber were tested first, especially the melanin granules in the fiber. Then, the decolorization of the yakwool fiber was studied using the oxidation–reduction decolorization method, and corresponding optimal process of the decolorization was given. Then, the properties of the decolorized yakwool fiber were tested and compared with those of the original fiber.

It is shown that, after decolorization, the physical and mechanical properties of the fiber were deteriorated, especially in terms of the strength and elongation. Therefore, the fiber became shorter and thinner, and the scales were damaged. When compared with the yarn spun from the original yakwool fiber, it was observed that the properties of the yarn spun from the decolorized yakwool fiber deteriorated because of the deterioration in the properties of the original fiber.

In the paper, for extending the application scopes of the yakwool fiber, the decolorization of the yakwool fiber was studied.

Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.

The degradation efficiency of indigo wastewater in single-cell and double-cell were investigated. Based on the previous single factor experiments, the oxidative degradation conditions of indigo wastewater in single cell were optimized by response surface methodology (RSM). The decolorization rate, chemical oxygen demand (COD) removal rate, the contents of flocculation precipitation and indigo were measured and analyzed.

The degradation efficiency in single cell was higher than in double cell. The electrolysis conditions were optimized by RSM and the decolorization rate was 99.01% with COD removal rate of 60.34% and conductivity of 89.75 mS/cm. The amount of flocculated precipitation decreased by 53.33% and the indigo increased by 86.34%. The content of Na and S decreased by 12.13 and 6.49%, respectively. The ratio of Fe3+ to Fe2+ in the solution was 4.62:1, indicating that most of the iron dropped on the electrode sheet was converted to Fe3+.

The one-step electrochemical oxidation and flocculation method with the advantages of simple operation and environmental protection, provided a reference for the actual treatment of dyeing wastewater.

Combining the electrochemical flocculation and oxidation provided an efficient and practical solution for degradation of indigo wastewater.

Combining the advantages of electrochemical oxidation and electroflocculation, the application of electrochemistry in printing and dyeing wastewater treatment technology has been expanded.

This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to optimize the treatment system.

For effective purging, various types of metal electrodes (graphite, pure aluminum and stainless steel) and supporting electrolytes (sodium chloride and sodium sulfate) were selected for electroflocculation experiments. The decolorization rate and chemical oxygen demand (COD) removal rate were characterized.

The treatment effects of stainless steel and aluminum were similar, but the dissolution loss of aluminum and the production of flocs greatly limit its application. Electrolytes gave obvious effects to these systems. Sodium sulfate was better than sodium chloride, the decolorization rate was increased by 3.31%, the removal rate of COD in the solution was increased by 28.65% and the weight of flocculation precipitation was reduced by 0.214 g.

The electrochemical treatment system was constructed to compare and analyze the influence of experimental parameters and to provide a reference for the actual treatment of indigo wastewater.

Electrochemical flocculation can remove the insoluble indigo solids and it plays a key role in wastewater treatment.

It is novel to optimize the combination of electrode and electrolyte to improve the efficiency of electroflocculation, which can be widely used in the actual wastewater treatment process.

This paper aims to decolorize the effluents of textile Reactive Orange 5 and Reactive Red 195 dyes by using cationized sugarcane bagasse.

Cationized sugarcane bagasse was prepared and used as an adsorbent for both reactive and hydrolyzed reactive dyes. Characterization of the sugarcane bagasse structure resulted by cationization was monitored using Fourier transform–infrared, while morphologically was detected using scanning electron microscopy and X-ray powder diffraction.

The maximum adsorption capacities are 805, 1,664, 1,772 and 1,596 mg/g for Hydrolyzed Red 195, Hydrolyzed Orange 5, Reactive Red 195 and Reactive Orange 5 dyes, respectively.

Factors affecting the percentage of dye removal were optimized on different parameters such as adsorbent dose and treatment time. The data were discussed using the Langmuir and Freundlich Models of adsorption.

The reuse of hydrolyzed reactive dyebaths gives reasonably good fastness properties on nylon fabrics.

The study has enabled the production of an eco-friendly and less expensive method of reactive dye effluent decolorization.

The study provides a potentially simple approach to decolorize dye effluents of Reactive Orange 5, Red 195 dyes and also the reuse of hydrolyzed reactive dyebaths for dyeing nylon.

Five different structural reactive dyes (Reactive Brilliant Blue K-3R, Everacion Blue H-ERD, Moderzol Blue FBR, Atuzol Black B and Moderzol Blue HEGN) were treated with laccase (Denilite II US) in order to determine the optimum decolouration conditions. The experiments showed that laccase had distinct decolouration effects on these five dyes. Under optimum conditions, the colour removal rates of Everacion Blue H-ERD and Moderzol Blue HEGN were over 90%. Furthermore, the effects of different additives, such as acid ion, metal ion, and surfactants on the decolouration rate of Reactive Brilliant Blue K-3R were discussed. The results show that the decolouration rate is significantly promoted through the addition of Cu²⁺ and Al³⁺, while it is inactivated with Fe²⁺ and ion surfactants. Moreover, the COD removal rates of the five dyes are more than 75%.

This paper aims to find a suitable solution to degrade the C.I. Reactive Red 24 (RR24) dyeing wastewater by using sodium persulphate to recycle water and inorganic salts.

The effects of temperature, the concentration of inorganic salts and Na₂CO₃ and the initial pH value on the degradation of RR24 were studied. Furthermore, the relationship between free radicals and RR24 degradation effect was investigated. Microscopic routes and mechanisms of dye degradation were further confirmed by testing the degradation karyoplasmic ratio of the product. The feasibility of the one-bath cyclic dyeing in the recycled dyeing wastewater was confirmed through the properties of dye utilization and color parameters.

The appropriate conditions were 0.3 g/L of sodium persulphate and treatment at 95°C for 30 min, which resulted in a decolorization rate of 98.4% for the dyeing wastewater. Acidic conditions are conducive to rapid degradation of dyes, while ·OH or SO₄⁻· have a destructive effect on dyes under alkaline conditions. In the early stage of degradation, ·OH played a major role in the degradation of dyes. For sustainable cyclic dyeing of RR24, inorganic salts were reused in this dyeing process and dye uptake increased with the times of cycles. After the fixation, some Na₂CO₃ may be converted to other salts, thereby increasing the dye uptake in subsequent cyclic staining. However, it has little impact on the dye exhaustion rate and color parameters of dyed fabrics.

The recommended technology not only reduces the quantity of dyeing wastewater but also enables the recycling of inorganic salts and water, which meets the requirements of sustainable development and clean production.