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Article
Publication date: 27 February 2020

Khalid Rabaeh and Ahmed Basfar

The purpose of this paper is to propose a new dithizone solution dosimeter for high radiation applications such as polymers applications and food irradiation.

Abstract

Purpose

The purpose of this paper is to propose a new dithizone solution dosimeter for high radiation applications such as polymers applications and food irradiation.

Design/methodology/approach

Gamma-rays cell of Co-60 source with 8.4 kGy/h dose rate was used to irradiate the dithizone solutions at different irradiation temperatures. The optical measurements of unirradiated and irradiated dithizone dye solution dosimeters were performed using a UV/VIS spectrophotometer at absorption peaks of 421 and 515 nm.

Findings

The new dosimeter improved significantly with the increase of dithizone dye concentrations from 0.025 to 0.1 mM. The dosimeter shows a perfect pre- and post-irradiation stability after irradiation for five days. Because of irradiation temperature dependence, the dithizone solution dosimeter should be corrected under actual processing conditions.

Practical implications

Dosimetry is a key point in quality control of radiation processing to assure that uniform and correct radiation doses are delivered to a region of interest. Therefore, this study introduces a dithizone solution dosimeter for high-dose radiation applications such as food irradiation, polymers applications and agriculture.

Originality/value

Ionizing radiation interacted with the ethanol solvent, resulting in the formation of free radicals, then these free radicals interacted with the dithizone molecule and changed the dye color from yellow to orange.

Details

Pigment & Resin Technology, vol. 49 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 29 September 2020

Awad AL Zahrany, Khalid Rabaeh, Molham Eyadeh and Ahmed Basfar

The purpose of this paper is to present a radiochromic film dosimeter containing polyvinyl alcohol (PVA) matrix and various concentrations of methyl red (MR) dye for high dose

Abstract

Purpose

The purpose of this paper is to present a radiochromic film dosimeter containing polyvinyl alcohol (PVA) matrix and various concentrations of methyl red (MR) dye for high dose measurements.

Design/methodology/approach

The MR-PVA films were exposed to irradiation up to 60 kGy using 60Co source of gamma ray. The ultraviolet and visible regions (UV/VIS) spectrophotometry were used to examine the optical density of pre-and post-irradiated dosimeters at 424 nm.

Findings

The dose sensitivity of MR-PVA films increases significantly with increasing MR dye concentrations in the dose range of 5 to 60 kGy. The impact of relative humidity, irradiation temperature, dose rate and the stability of the films has been analyzed. The overall uncertainty of the MR-PVA film dosimeter is 6.12% (Double Standard-deviation, 95% confidence level).

Practical implications

It was found that the MR-PVA films may be used as high dose dosimeter with an acceptable overall uncertainty in routine industrial radiation processing.

Originality/value

The color bleaching of irradiated MR-PVA films in terms of specific absorbance curves increases significantly with increasing absorbed dose up to 60 kGy.

Details

Pigment & Resin Technology, vol. 50 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 March 2008

S. O'Keeffe, C. Fitzpatrick, E. Lewis and A.I. Al‐Shamma'a

The purpose of this paper is to provide a detailed review of radiation dosimetry techniques based on optical fibre dosimeters. It presents a comprehensive bibliography of the…

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Abstract

Purpose

The purpose of this paper is to provide a detailed review of radiation dosimetry techniques based on optical fibre dosimeters. It presents a comprehensive bibliography of the current research activities in the area.

Design/methodology/approach

A range of published work on optical fibre radiation dosimeters are presented, with the merits and limitations discussed. Each radiation dosimetry technique is discussed in turn, providing examples of dosimeters using such techniques reviewed. The main focus is on gamma radiation although other radiation dosimeters are considered.

Findings

This paper provides information on the wide range of research activity into radiation dosimeters. The dose ranges of these dosimeters are presented, along with the advantages and disadvantages of different dosimetry techniques.

Originality/value

A comprehensive review of published research in the area of solid radiation dosimetry is presented in this paper. It provides an individual with a review of the various techniques used and most recent research in that field.

Details

Sensor Review, vol. 28 no. 2
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 3 October 2019

Sameh Mohamed Gafar and Nehad Magdy Abdel-Kader

The purpose of this paper is to study the effect of gamma-rays on murexide (Mx) dye and its possible use as radiation dosimeters in two different dosimetry systems. The first…

Abstract

Purpose

The purpose of this paper is to study the effect of gamma-rays on murexide (Mx) dye and its possible use as radiation dosimeters in two different dosimetry systems. The first system depends on the Mx dye as a liquid dosimeter. The second dosimetry system depends also on the same dye but as in a gel form, which is more sensitive to gamma-rays.

Design/methodology/approach

The prepared Mx (solutions/gels) have a considerable two peaks at 324 and 521 nm that upon irradiation, the intensity of these peaks decreases with the increasing radiation dose.

Findings

The gamma-ray absorbed dose for these dosimeters was found to be up to 2 kGy for the solution samples and 40 Gy for the gels. Radiation chemical yield, dose response function, radiation sensitivity and before and after-irradiation stability under various conditions were discussed and studied.

Practical implications

It is expected that the radiolysis of the Mx dye can be used as radiation dosimeters in two different dosimetry systems; liquid and gel dosimeters. This can be applied in a wide range of gamma radiation practical industrial applications in water treatment, food irradiation dosimeters, radiotherapy and fresh food irradiation and seed production.

Originality/value

Both of the prepared Mx dyes, either as solutions or gel samples, can be facilely prepared from commercially, cheap, safe, available chemicals and suitable for useful applied Mx solutions and gels radiation dosimeters.

Details

Pigment & Resin Technology, vol. 48 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 23 August 2021

Mohamad Bekhit, Essam Fahim and Asmaa Sobhy

The purpose of this paper is to fall light on the possibility of using the biopolymer chitosan in gamma dose monitoring.

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Abstract

Purpose

The purpose of this paper is to fall light on the possibility of using the biopolymer chitosan in gamma dose monitoring.

Design/methodology/approach

The chitosan films were irradiated to gamma rays in the range starting from 10 to 120 kGy at a dose rate of 1.4 kGy/h using 60Co gamma source. The ultra violet and visible (UV/Vis) spectrophotometry were used to examine the optical properties of chitosan film. Also, Fourier transform infrared (FTIR) analysis was used to detect and trace any change in structural bands that may take place upon irradiation.

Findings

Increase in optical density of the chitosan film was recorded at 298 nm that correlated with increasing in the absorbed doses. Change in color of the film from pale yellow to denser yellow was detected upon increasing the absorbed doses. The close investigation for UV/Vis and FTIR analysis nominates the chitosan film to be used as a label-dosimeter in the range of 10–120 kGy depending on chitosan concentrations. The chitosan film has an excellent stability in different environmental conditions with ±3.7% uncertainty in measurements (2σ, approximately equal to a 95% confidence level).

Research limitations/implications

Chitosan film may be used as a medium and high-dose monitor with an acceptable overall uncertainty in routine radiation processing

Originality/value

The useful dose range from 10 to 80 kGy was detected for different concentrations of chitosan (0.5, 1, 1.5 Wt%) that correlated with increasing the absorbed dose, which is assigned to the linear parts in the target response curves. For the dose range 10–120 kGy, the film may be used as label dosimeter with detected color change from pale yellow to dense yellow.

Details

Pigment & Resin Technology, vol. 51 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 June 2022

Khalid Rabaeh and Molham Eyadeh

The purpose of this paper is to evaluate the dosimetric properties of N-(3-methoxypropyl) acrylamide (NMPA) polymer gel dosimeter using UV-vis spectrophotometry as a simple and…

Abstract

Purpose

The purpose of this paper is to evaluate the dosimetric properties of N-(3-methoxypropyl) acrylamide (NMPA) polymer gel dosimeter using UV-vis spectrophotometry as a simple and low-cost method.

Design/methodology/approach

The gel samples have been irradiated to various doses using a medical linear accelerator with 6 MV beam energy. The optical density of un-irradiated and irradiated NMPA polymer gel dosimeters in terms of absorbance at 500 nm was investigated by UV-vis spectrophotometry.

Findings

The absorbance values of the gel samples were increased linearly with increasing dose in the dose range between 2 and 20 Gy. A remarkable improvement in the dose response was noticed after the addition of various concentrations of glycerol. The impact of dose rate, beam energy and the post-stability of the exposed gels was studied and found consistent with the previous study using nuclear magnetic resonance results (energy independent and dose rate independent, stable up to one week).

Practical implications

The results of the independent experimental spectrophotometry and nuclear magnetic resonance analyses indicate that the NMPA polymer gel dosimeter has good and consistent dosimetric features for radiotherapy dosimetry.

Originality/value

The ionizing radiation-induced polymerization of gel samples leads to a change in the absorbance of the irradiated gel samples. This study introduces the first characterization of NMPA gel dosimeter by means of UV-vis spectrophotometer.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 August 2021

Nehad Magdy and Sameh Gafar

The purpose of this research paper is to study a comparison between two dosimetry systems, both of them based on basic violet dye (BV).

Abstract

Purpose

The purpose of this research paper is to study a comparison between two dosimetry systems, both of them based on basic violet dye (BV).

Design/methodology/approach

The first system depends on (BV) (incorporating polyvinyl alcohol) as a thin-film dosimeter. The second system also relies on (BV) as a solution dosimeter, which is more sensitive to gamma rays. The two prepared film/solutions have a considerable signal that decreases upon irradiation and the strength of the signal decreases with increasing radiation dose.

Findings

The gamma ray absorbed dose for these dosimeters was found to be up to 35 kGy for films and 1 kGy for the liquid phase. All dosimetric characteristics as radiation chemical yield, additive substance, dose-response function, radiation sensitivity, also before and after-irradiation stability under various conditions were considered.

Practical implications

It is expected the vital role of gamma radiation on this dye in its two forms or two media. This reveals their wide applications in the field of gamma irradiation processing.

Originality/value

These two dosimetry systems which depend upon the same dye are safe to handle, inexpensive, available raw materials and can be applied in various dosimetry applications as mentioned above.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 24 June 2019

Ahmad Fairuz Omar, Wan Long Chiong, Wei Yee Tan and Jia Wen Wong

This paper aims to propose an area under the curve model to represent ultraviolet (UV) exposure doses on EBT3 films (in mJ/cm2). The model was developed on a cross-section of the…

Abstract

Purpose

This paper aims to propose an area under the curve model to represent ultraviolet (UV) exposure doses on EBT3 films (in mJ/cm2). The model was developed on a cross-section of the exposed films using visible absorbance method. Ultraviolet–A light emitting diodes (UVA–LEDs) with 20° and 60° half angle with distinctive peak emission wavelengths between 365 to 405 nm are used in this experiment. No similar experimental setup or findings have been reported thus far, though the various application of EBT3 for the measurement of solar UV (A + B) have been published since EBT3 is commercially available.

Design/methodology/approach

Two sets of UVA–LEDs were used as the UV radiation source in the experiment. The first set contains of four 5 mm low power UVA–LEDs with the 20° half angle and peak emission wavelength at 365, 375, 385 and 400 nm. The second set contains of five surface mount high power UVA–LEDs with the 60° half angle and peak emission wavelength at 365, 375, 385, 305 and 400 nm. The illumination setup for the two sets of LEDs is different between each other to obtain sufficient dose distribution on the films for spectroscopy analysis. This is due to the different illumination angle and irradiance intensity by each set of LEDs.

Findings

UV–LED with a peak emission of 365, 375 and 385 nm able to produce UV doses accurately measurable using EBT3 films, UVA–LEDs with peak emission at 395 nm and above produced much lower accuracy with R2. From both set of LEDs, it can be concluded that peak emission wavelength of UVA–LED does influence the discoloration of the films. Shorter wavelength (higher energy) of UVA–LEDs discolors EBT3 films much intense compared to longer wavelength for a given UV dose exposure.

Originality/value

Despite various practical applicability and advantages of UV–LEDs, there are still no standard methods in measuring UV–LED radiation output. The proposed approach not only allows us to obtain the dose of UV–LED, where the sensitivity of measurement is wavelength (energy) depended but also allows us to visually observe the illumination pattern of invisible UV radiation through the application of EBT3 films.

Details

Sensor Review, vol. 39 no. 4
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 1 January 2006

Khalil Arshak and Olga Korostynska

Combination of a number of sensors with different response parameters into sensor arrays would enhance the overall performance of the radiation detection system. This paper…

Abstract

Purpose

Combination of a number of sensors with different response parameters into sensor arrays would enhance the overall performance of the radiation detection system. This paper presents a conceptual approach to the development of sensor arrays system with instantaneous dose and dose rate readout. A dynamic selection of multiple sensors with various sensitivity and accuracy range is implemented by applying pattern recognition (PR) analysis, which maximizes measurement accuracy. A number of relevant PR methods are discussed.

Design/methodology/approach

Thick films based on NiO, ZnO, In2O3, CeO2, TiO2, CuO and CdO are the key sensing elements in the proposed approach. Pure and carbon‐doped metal oxides were screen‐printed on Si wafers to form pn‐heterojunctions. All devices were exposed to a disc‐type 137 Cs source with an activity of 370 kBq. The values of radiation damage of pn‐junctions were estimated from changes in their current‐voltage characteristics.

Findings

Sensors showed an increase in the values of current with the increase in radiation dose up to certain levels, exceeding these levels results in unstable dosimetric characteristics.

Originality/value

The sensitivity of metal oxide films to γ‐radiation exposure depends on their composition and thickness. Mixing the oxides in different proportions and the addition of conducting particles, such as carbon, alters films susceptibility to radiation. In particular, sensors based on such films have dose response characteristics with certain level of sensitivity and working dose range, conditioned by particular sensing material properties and the device structure.

Details

Sensor Review, vol. 26 no. 1
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 1 June 1967

With the drastically changed pattern of the retail food trade in recent years in which the retailer's role has become little more than that of a provider of shelves for…

Abstract

With the drastically changed pattern of the retail food trade in recent years in which the retailer's role has become little more than that of a provider of shelves for commodities, processed, prepared, packed and weighed by manufacturers, the defence afforded by the provisions of Section 113, Food and Drugs Act, 1955 has really come into its own. Nowadays it is undoubtedly the most commonly pleaded statutory defence. Because this pattern of trade would seem to offer scope for the use of the warranty defence (Sect. 115) in food prosecutions it is a little strange that this defence is not used more often.

Details

British Food Journal, vol. 69 no. 6
Type: Research Article
ISSN: 0007-070X

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