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Purpose – This work aims to study the treatment of adsorbant on the increasing liquid hydrocarbon quality produced by pyrolysis low density polyethylene (LDPE) plastic waste at low temperature. The hydrocarbon distribution, physicochemical properties and emission test were also studied due to its application in internal combustion engine. This research uses pure Calcium carbonate (CaCO₃) and pure activated carbon as adsorbant, LDPE type clear plastic samples with control variable that is solar gas station.

Design/Methodology/Approach – LDPE plastic waste of 10 kg were vaporized in the thermal cracking batch reactor using LPG 12 kg as fuel at range temperature from 100 to 300°C and condensed into liquid hydrocarbon. Furthermore, this product was treated with the mixed CaCO₃ and activated carbon as adsorbants to decrease contaminant material.

Findings – GC-MS identified the presence of carbon chain in the range of C6–C44 with 24.24% of hydrocarbon compounds in the liquid. They are similar to diesel (C6–C14). The 30% of liquid yields were found at operating temperature of 300°C. The calorific value of liquid was 46.021 MJ/Kg. This value was 5.07% higher than diesel as control.

Originality/Value – Hydrocarbon compounds in liquid produced by thermal cracking at a low temperature was similar to liquid from a catalytic process.

Government appointed and sponsored committees of every description—select, ad hoc, advisory, inquiry—such a prominent feature of the public scene since the last War, are understandable, even acceptable, reflect the urgency of the times in which we live. In the gathering gloom of more recent twilight years, they have flourished inordinately, especially in the socio‐political field, where most of their researches have been conducted. Usually embellished with the name of the figure‐head chairman, almost always expensively financed, they have one thing in common—an enormous output of words, telling us much of what we already know. So much of it seems dull, meaningless jargon, reflecting attitudes rather than sound, general principles.

The purpose of this paper is to present a detailed algorithm for simulating three-dimensional hydrocarbon reservoirs using the blackoil model.

The numerical algorithm uses a cell-centred structured grid finite volume method. The blackoil formulation is written in a way that an Implicit Pressure Explicit Saturation approach can be used. The flow field is obtained by solving a general gas pressure equation derived by manipulating the governing equations. All possible variations of the pressure equation coefficients are given for different reservoir conditions. Key computational details including treatment of non-linear terms, expansion of accumulation terms, transitions from under-saturated to saturated states and vice versa, high gas injection rates, evolution of gas in the oil production wells and adaptive time-stepping procedures are elaborated.

It was shown that using a proper linearization method, less computational difficulties occur especially when free gas is released with high rates. The computational performance of the proposed algorithm is assessed by solving the first SPE comparative study problem with both constant and variable bubble point conditions.

While discretization is performed and implemented for unstructured grids, the numerical results are presented only for structured grids, as expected, the accuracy of numerical results are best for structured grids. Also, the reservoir is assumed to be non-fractured.

The proposed algorithm can be efficiently used for simulating a wide range of practical problems wherever blackoil model is applicable.

A complete and detailed description of ingredients of an efficient finite volume-based algorithm for simulating blackoil flows in hydrocarbon reservoirs is presented.

IT is well known that gas mains which carry petroleum gases containing hydrogen sulphide are subject to strong corrosion by the latter; their normal life is of the order of a few years but, in places where condensate collects, the main may show penetration within a few months.

A new site survey service, for the detection and measurement of toxic gases, is being introduced by Hazard Control Ltd, 61 High St, Barnet, Herts, the gas detection and atmospheric safety engineering specialists.

‘Saksham’, a corporate social responsibility (CSR) initiative of one of the largest public sector companies in India, the Gas Authority of India Limited (GAIL), provides specific training in skills required for plastic industry to low-income communities potentially affected by GAIL's business operations. Unlike a typical GAIL CSR programme, which directly targets communities affected by GAIL's operations, the Saksham programme serves the needs of one of GAIL's main customers - the small and medium scale plastic industry. Although the programme is a huge success and has completed three batches, all the students of which were placed in plastic manufacturing companies, Shamasundara, Zonal General Manager of GAIL is still not sure about the future of the programme. He wondered what should be the metrics to evaluate whether a programme can be classified as a CSR initiative by a firm.

The purpose of this paper is to study the corrosion process by examining the deterioration of X80 steel exposed to a real petroleum sample containing condensed hydrocarbon plus oilfield-produced water, which were subjected to stimulated emulsions in flowing media at 50°C.

The impedance and polarization spectra were used to assess the aggressiveness of the petroleum sample and tried to find a washing process using condensed hydrocarbon with deionized water. Mössbauer technique was used to identify the phases in precipitated ions obtained during an oven-drying procedure of the oilfield produced water.

The emulsion, chloride, sulphur compounds, heavy metals and the use of a double hydrodynamic system were the most important factors affecting the corrosion of X80 steel. The corrosion rate of this steel increased when oilfield-produced water was stimulated by a double hydrodynamic system (4.56 mm/year). It was determined to be 7.66 mm/year and 4.01 mm/year when steel was exposed to a stimulated emulsion using the petroleum sample and condensed hydrocarbon with deionized water at 24 h, respectively, suggesting that a significant process of hydrocarbon washing could occur and a more corrosive solution was highlighted. Mössbauer results showed that the ions precipitates included the following phases at Wt.%: magnetite (20.0), greigeite (22.8), siderite (3.2), pyrite (2.9), marcasite (26.7) and mackinawite (24.4).

A stimulated hydrocarbon/water emulsions with a more homogeneous solution containing high concentrations of saline compounds and heavy metals were used to simulate the susceptibility to corrosion on the internal pipeline steels exposed to any type of immiscible liquids such as condensed hydrocarbon, or crude oil, containing water. A practical application of the presented research could provide a novel framework for understanding the internal corrosion in pipelines from the simulation of washed hydrocarbons after the stimulated emulsions that can be found in the field. Because more susceptibility to corrosion for pipeline steels would be expected at the end of the transportation of the fluid. It is possible to investigate the possible corrosion mechanisms by using a dried oilfield-produced water sample interacting with the pipeline steels.

The evolution in developed countries has taken a role in global warming and natural disasters such as flash flood, El-Nino, earthquake and groundwater contamination. The underground storage tank leakage problems and spillage of hydrocarbon liquid leading to the contamination of non-aqueous phase liquids (NAPLs) into the groundwater could reduce the quality of groundwater. This chapter is intended to investigate the behaviour and the pattern of NAPL migrations in double-porosity soil under vibration and intact conditions. The experimental model is developed by using kaolin soil type S300 and toluene as NAPLs. The kaolin soil was mixed with 25% of moisture content to produce kaolin granules in the soil column and vibrate under 0.98 Hz of frequency within 60 seconds. As a result, both specimen liquids completely migrated to the bottom of soil column: sample 1 has higher permeability compared to sample 2. This is due to the fracture in double-porosity soil under vibration effect and loosened the soil structure in sample 1 compared to good intact soil sample 2 with stronger and compact soil structure. In conclusion, this study proves that the dangerous hydrocarbon NAPL migration in fractured double-porosity soil has very harmful effect on the environment and groundwater resources.

THE considerable increase in the number of resin, synthetic rubber, tar, solvent and oil refining installations in recent years, together with the expansion of the plastics industry and rapid growth of the synthetic fibre plants has brought in its train numerous problems in the lubrication field. Many of the liquids produced, or used in the processes are strong solvents for the more conventional types of lubricating greases. If these liquids cannot be prevented from coming into contact with the lubricants used in the fuel pumps, bearings, glands, cocks and valves etc. on the plant lines by the use of suitable seals of the “Teflon” type (for example), then the lubricant has to be formulated with appropriate fluids or gelling materials which are comparatively immiscible in the solvents used. This has resulted in a search for better solvent resistant lubricants particularly where these are used on equipment handling gasoline and oil fractions, ketones, chlorinated solvents and aliphatic or aromatic hydrocarbons in liquid or vapour form.

This paper aims to study the tribological behavior of the WS2/oil-impregnated porous polyimide (PPI) solid/liquid composite system, in which both PFPE (perfluoropolyether) and SiCH (silahydrocarbons) oils with different hydrocarbon chains were used, respectively. Lubricating mechanism of the composite system was also explored.

The tribological behaviors of the WS2 films against the PPI cylindrical pins before and after immersing oil were evaluated under different loads by a reciprocating-type ball-on-disc tribometer.

The composite system exhibited the low and stable friction coefficient after the running-in stage, and the lubricant oil played a positive effect. It was found that the WS2/PFPE composite system exhibited more excellent lubricating property, although sole SiCH far exceeds PFPE in lubrication. The abnormal phenomenon mainly resulted from the influence of the oil amount. XRD results on the wear track surfaces indicated that PFPE and SiCH oils with different hydrocarbon chains were likely to preferentially adsorb to the edge plane and basal plane of the WS2 crystals, respectively.

In previous studies, liquid lubricants were directly dripped or spin-coated on the solid lubricant surface. Based on its potential advantage in application, the tribological behavior and mechanism of the solid lubricating film/oil-impregnated PPI composite system were investigated in this study.