Search results

The purpose of this paper is to study the corrosion process by examining the deterioration of X80 steel exposed to a real petroleum sample containing condensed hydrocarbon plus oilfield-produced water, which were subjected to stimulated emulsions in flowing media at 50°C.

The impedance and polarization spectra were used to assess the aggressiveness of the petroleum sample and tried to find a washing process using condensed hydrocarbon with deionized water. Mössbauer technique was used to identify the phases in precipitated ions obtained during an oven-drying procedure of the oilfield produced water.

The emulsion, chloride, sulphur compounds, heavy metals and the use of a double hydrodynamic system were the most important factors affecting the corrosion of X80 steel. The corrosion rate of this steel increased when oilfield-produced water was stimulated by a double hydrodynamic system (4.56 mm/year). It was determined to be 7.66 mm/year and 4.01 mm/year when steel was exposed to a stimulated emulsion using the petroleum sample and condensed hydrocarbon with deionized water at 24 h, respectively, suggesting that a significant process of hydrocarbon washing could occur and a more corrosive solution was highlighted. Mössbauer results showed that the ions precipitates included the following phases at Wt.%: magnetite (20.0), greigeite (22.8), siderite (3.2), pyrite (2.9), marcasite (26.7) and mackinawite (24.4).

A stimulated hydrocarbon/water emulsions with a more homogeneous solution containing high concentrations of saline compounds and heavy metals were used to simulate the susceptibility to corrosion on the internal pipeline steels exposed to any type of immiscible liquids such as condensed hydrocarbon, or crude oil, containing water. A practical application of the presented research could provide a novel framework for understanding the internal corrosion in pipelines from the simulation of washed hydrocarbons after the stimulated emulsions that can be found in the field. Because more susceptibility to corrosion for pipeline steels would be expected at the end of the transportation of the fluid. It is possible to investigate the possible corrosion mechanisms by using a dried oilfield-produced water sample interacting with the pipeline steels.

WATERMIX fluids are formulated to combine the lubricating properties of oil with the cooling properties of water. They are essentially blends of mineral oil, emulsifier, corrosion inhibitor and, possibly, biocide.

The purpose of this paper is to develop a volatile organic component‐free water‐based binder with improved coating properties from urethane‐alkyd acrylate by emulsion polymerisation.

Alkyd resin based on interesterification of sardine fish and linseed oil (50:50 w/w) was synthesised and reacted with isophorone diisocyanate to form urethane alkyd. The resultant urethane alkyd and acrylic monomers in different ratios were polymerised by emulsion polymerisation to form air‐drying water‐based binders and studied for physicochemical and other coating properties.

Urethane alkyd, co‐polymerised with acrylates by emulsion polymerisation process, can be used to prepare water‐based air‐drying binders with excellent coating and application performance. The increase in acrylate component in the system resulted in improvement of performance properties.

In the present study, refined fish oil (FO) was obtained from sardine fish. Different FOs can be used to produce alkyd resin. Urethane alkyd and acrylic monomers in different ratios can be polymerised by emulsion polymerisation techniques.

The emulsion polymerisation is the most effective technique used to produce water‐based binders with excellent coating properties.

Water‐based binders can be widely used in exterior coatings and waterproofing of cement and roofs.

To explore compatibility of natural resin shellac with acrylic resin in order to make a more eco‐friendly coating composition and also to open a new avenue for consumption of shellac.

Different compositions of paint were prepared by varying the contents of shellac and acrylic resin. Selection was made for the composition yielding the best combination of properties like water resistance, alkali resistance, washability, etc.

Modification of shellac with acrylic resin showed improved film performance. The modified product showed good adhesion, finish; the films were smooth, flexible and no flaking/detachment was observed from the surfaces. This resulted in from esterification linkages between shellac and acrylic resin.

The concentration of shellac in the composition was limited to a certain extent. Increase in shellac content impairs the film performance of the composition, especially with regard to alkali resistance.

Shellac was found to be very compatible with acrylic resin at all concentrations, this may be adopted in developing other shellac‐acrylic based products.

The modification of shellac with acrylic resin has been done, for the first time, to open a new vista for the consumption of shellac in surface coating.

This paper aims to synthesize new terpolymers by the emulsion polymerization technique composed of acrylamide-based polyurethane monomers (TPM and MPM) with different vinyl acetate copolymer systems, such as vinyl acetate/butyl acrylate (VAc/BA), vinyl acetate/ethylhexyl acrylate (VAc/2-EHA) and vinyl acetate/vinyl ester of versatic acid (VAc/VEOVA 10) systems. The performance of the prepared terpolymers as binders in emulsion coatings and textile industries was investigated and compared with the analogous commercial ones.

New waterborne polyurethane-vinyl ester-vinyl acetate terpolymers with high solid content and nano-scale emulsions have been successfully synthesized in two steps. The polyurethane oligomers were prepared by the prepolymer method as the first step. The second step involved polymerization with different vinyl monomers. The synthesized terpolymers were characterized using FTIR, scanning electron microscope, thermogravimetric analysis, minimum film forming temperature and particle size analyzer methods.

The synthesized emulsion terpolymers have shown small particle sizes averaged of 70 nm and a narrow distribution range, along with good mechanical, thermal and chemical stabilities. The surface coating layers of the terpolymers also have some important in terms of smoothness, clarity and binding ability in water-based coating for up to 4425 scrub cycles at 30 GU. Further, a high potential application textile printing was achieved at high solid content of 47–50%.

The effects of different isocyanates and vinyl monomers on the properties of obtained emulsion coatings have been studied. The improvement consequences of the coating evaluation of the waterborne binders for emulsion paints have been described. The properties of polyester/cotton fabric print pigment printing of textiles appear to be most promising enhancements by using the prepared nanocomposites of PU-co-vinyl acetate-co-vinyl ester as waterborne binders. So that the prepared emulsions have the potential to replace solvent-based coatings as waterborne binders for both emulsion coating and textile printing applications.

Previous articles in this series were concerned with the lubricant handling consultant's survey (September and November issues) and in this, the last part, the actual figures showing savings to be effected are given. We have taken up with Mr. Hunt the practicability of the suggestions made in this series—workmen spending most of their time humping oil barrels or buckets of oil, hundreds of hours spent in walking between machine and stores. We have received the most reliable evidence that the figures given in this article are the average of a number of real surveys that Mr. Hunt's staff have carried out. And what is more, this state of affairs exists all too often at large companies who should know better and whose production methods are otherwise very efficient.

Lawrence Industries have announced their new distributorship for Fortrex micaceous extender for use in paint systems. This high brightness, plate‐like and fine particle size extender can be used in the production of a wide variety of paint systems giving improved mechanical strength, chemical resistance, better substrate adhesion, wash resistance, light fastness and resistance to chalking.

The purpose of this study was to explore the potential of Aloe vera as a novel source of natural antioxidant and preservative in the muscle foods and to evaluate the effect of Aloe vera on the storage quality of aerobically packaged chicken nuggets.

The Aloe vera pulp was incorporated at various levels, namely, 0, 5, 10 and 15 per cent, replacing lean meat in the formulation. The products were analyzed for proximate composition, physicochemical and sensory parameters. Chicken nuggets incorporated with optimum level of Aloe vera (10 per cent) along with control nuggets (0 per cent Aloe vera) were aerobically packaged and assessed for lipid oxidation, physicochemical and microbiological characteristics under refrigerated (4°C) conditions.

pH, crude protein, ether extract and ash content of the nuggets showed significant (p < 0.05) decreasing trend with increasing levels of Aloe vera; however, there was a significant (p < 0.05) increase in the moisture content, emulsion stability and cooking yield. Aloe vera-enriched nuggets showed significantly (p < 0.05) lower values than control nuggets for almost all the lipid oxidation and microbiological parameters, i.e. free fatty acid, thiobarbituric acid-reactive substances value, total plate count, psychrophillic count and yeast and mould count. No significant (p > 0.05) difference was observed in the sensory parameters of the Aloe vera-enriched nuggets and the control samples throughout the period of storage.

The paper has demonstrated the use of Aloe vera as a potential natural antioxidant without any marginal decline in the sensorial characteristics and nutritive value of the muscle foods.

Some ten years ago, industry world‐wide entered a period of economic shortages and rising prices of petroleum, a situation making it essential for economy to be exercised in the use of organic solvents. This led to an upsurge of interest in water‐based products for use in printing and packaging. Interest was further stimulated by the increasing pressures from health and safety legislation and growing concern about environmental pollution problems. There were possibilities to develop alternative water‐based products to many solvent based inks, varnishes, lacquers and adhesives and quite a number of commercial successes were achieved and sustained. The following recession of the mid 1970's and depressed economic climate of recent years has done little to advance progress in water‐based inks. There were subsequently no major problems in availability of organic solvents and from this aspect no urgent needs to evaluate alternative water‐based products, unless real economic or technical advantages could be demonstrated.

Polyoxyethylated hydroxy benzyl oleamide has found use in lubricants to prevent adhesion in moulds during the production of vulcanizates of natural and of synthetic rubbers. Polyoxyethylated oleamide acts as a mould lubricant for synthetic rubbers, whilst polyglycol 400 dilaurate can be used to reduce the time and temperature necessary for the recovery of old vulcanizates using paraffin oil and bitumen. Anti‐fogging properties can be sustained in rubber hydrochloride films by the use of polyglycol 1500 dilaurate, and improved percentage elongation can be promoted in intimate blends of polystyrene and SBR rubbers by the inclusion of polyglycol 4000 monostearate. Polyoxyethylated sorbitan monostearate acts as an emulsifer in the emulsion polymerisation of styrene, butadiene and styrene/ butadiene copolymer rubbers, and it can perform as an anti‐static for the latter. Polyoxyethylated stearylamine can be incorporated into lubricants designed to prevent adhesion in moulds during production of vulcanizates of synthetic and of natural rubber, and rubber latexes and other aqueous dispersions of rubber can be rendered more stable by the employment of polyoxyethylated stearyl alcohol, and thus allow storage in untreated containers for long periods of time. Polyoxypropylated sorbitan monopalmitate will serve as a parting agent, releasing aid, for unvulcanized rubber and vulcanized rubber, without interfering with further bonding and coating of rubber.