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The evolution in developed countries has taken a role in global warming and natural disasters such as flash flood, El-Nino, earthquake and groundwater contamination. The underground storage tank leakage problems and spillage of hydrocarbon liquid leading to the contamination of non-aqueous phase liquids (NAPLs) into the groundwater could reduce the quality of groundwater. This chapter is intended to investigate the behaviour and the pattern of NAPL migrations in double-porosity soil under vibration and intact conditions. The experimental model is developed by using kaolin soil type S300 and toluene as NAPLs. The kaolin soil was mixed with 25% of moisture content to produce kaolin granules in the soil column and vibrate under 0.98 Hz of frequency within 60 seconds. As a result, both specimen liquids completely migrated to the bottom of soil column: sample 1 has higher permeability compared to sample 2. This is due to the fracture in double-porosity soil under vibration effect and loosened the soil structure in sample 1 compared to good intact soil sample 2 with stronger and compact soil structure. In conclusion, this study proves that the dangerous hydrocarbon NAPL migration in fractured double-porosity soil has very harmful effect on the environment and groundwater resources.

The objective of this paper is to develop a semi-analytical finite element method for solving chemical dissolution-front instability problems in fluid-saturated porous media.

The porosity, horizontal and vertical components of the pore-fluid velocity and solute concentration are selected as four fundamental unknown variables for describing chemical dissolution-front instability problems in fluid-saturated porous media. To avoid the use of numerical integration, analytical solutions for the property matrices of a rectangular element are precisely derived in a purely mathematical manner. This means that the proposed finite element method is a kind of semi-analytical method. The column pivot element solver is used to solve the resulting finite element equations of the chemical dissolution-front instability problem.

The direct use of horizontal and vertical components of the pore-fluid velocity as fundamental unknown variables can improve the accuracy of the related numerical solution. The column pivot element solver is useful for solving the finite element equations of a chemical dissolution-front instability problem. The proposed semi-analytical finite element method can produce highly accurate numerical solutions for simulating chemical dissolution-front instability problems in fluid-saturated porous media.

Analytical solutions for the property matrices of a rectangular element are precisely derived for solving chemical dissolution-front instability problems in fluid-saturated porous media. The proposed semi-analytical finite element method provides a useful way for understanding the underlying dynamic mechanisms of the washing land method involved in the contaminated land remediation.

The objective of this paper is to establish a solution strategy for obtaining dual solutions, namely trivial (conventional) and nontrivial (unconventional) solutions, of coupled pore-fluid flow and chemical dissolution problems in heterogeneous porous media.

Through applying a perturbation to the pore-fluid velocity, original governing partial differential equations of a coupled pore-fluid flow and chemical dissolution problem in heterogeneous porous media are transformed into perturbed ones, which are then solved by using the semi-analytical finite element method. Through switching off and on the applied perturbation terms in the resulting perturbed governing partial differential equations, both the trivial and nontrivial solutions can be obtained for the original governing partial differential equations of the coupled pore-fluid flow and chemical dissolution problem in fluid-saturated heterogeneous porous media.

When a coupled pore-fluid flow and chemical dissolution system is in a stable state, the trivial and nontrivial solutions of the system are identical. However, if a coupled pore-fluid flow and chemical dissolution system is in an unstable state, then the trivial and nontrivial solutions of the system are totally different. This recognition can be equally used to judge whether a coupled pore-fluid flow and chemical dissolution system involving heterogeneous porous media is in a stable state or in an unstable state. The proposed solution strategy can produce dual solutions for simulating coupled pore-fluid flow and chemical dissolution problems in fluid-saturated heterogeneous porous media.

A solution strategy is proposed to obtain the nontrivial solution, which is often overlooked in the computational simulation of coupled pore-fluid flow and chemical dissolution problems in fluid-saturated heterogeneous porous media. The proposed solution strategy provides a useful way for understanding the underlying dynamic mechanisms of the chemical damage effect associated with the stability of structures that are built on soil foundations.