Search results

The present work aims to deal with ultrasound-assisted organic pigment (phthalocyanine blue and green) dispersion and its comparison with the conventional approach.

Ultrasound is expected to give beneficial results based on the strong shear forces generated by cavitational effects. The dispersion quality for preparation using an ultrasound-based method has been compared with dispersion obtained using high-speed dispersion mill. Effects of different operating parameters such as probe diameter and use of surfactants on the physical properties of dispersion and the colour strength have been investigated. Calculations for the energy requirement for two approaches have also been presented.

The use of sodium dodecyl sulphate and Tween 80 surfactants shows better performance in terms of the colour properties of dispersion prepared in water and organic solvent, respectively. Ultrasound gives better dispersion quality as compared to the conventional approach.

The present work presents a new approach of ultrasound-assisted dispersion of phthalocyanine blue and green pigments. Understanding into the effect of surfactants and type of solvent also presents new important design-related information.

Painting of buildings predates civilization. The primary purpose was to add beauty or aesthetics to the built environment. It was also to showcase the level of civilization, taste and fashion drive of the people. However, modern findings have proved that paint (when applied as a finishing coat on buildings) can elongate the service life of such buildings due to some characteristic properties it contains and modern additives that are included at production stage. This paper aims to examine some of the properties inherent in paint through which resistance to failure and better performance is enhanced, aesthetics is maintained and maintenance is reduced. It also examines whether these qualities subsist in all environments. Particular attention is given to its resistance to the impact of saline air when used around the Atlantic Ocean.

The research adopted a qualitative and quantitative approach with empirical analysis in examining the performance of paint used in salt laden environment.

It shows that paint used in an environment where saline air and salt is prevalent begins to deteriorate after two years and requires repainting as against the established norm of five to seven years (5‐7) in areas that are not exposed to saline air. The impact of saline air is significant at p<0.01.

Maximum life span of current paint products in the area is determined to provide adequate information for the preparation of maintenance schedule for painted exterior. Paint with higher resistance to salt attack is required to enhance the longevity of painted exterior in areas at close proximity to sources of salt. Specifying current available paint for exterior finish will be uneconomical and non‐compatible with the principle of sustainability.

The authors made a fresh attempt at investigating the life's span of paint used as exterior finish in salt laden area around the Atlantic Ocean due to the peculiarity of the stresses of the tropical region on external finishes. It also compared the result with existing researches. Differences in paint performance are established.

In recent years, increased use of all-aspect infrared (IR)-guided missiles based on the long-wave infrared (LWIR; 8–12 µm) band has lowered the probability of aircraft survival in warfare. The lock-on of these highly sensitive missiles is difficult to break, especially from the front. Aerodynamically heated swept-back leading edges (SBLE), because of their high temperature and large area, serve as a prominent LWIR source for aircraft detection from the front. This study aims to report the influence of sweep-back angle (Λ, based on the Mach number [M_∞]) on aerodynamic heating and the LWIR signature of SBLE.

The temperature along SBLE is obtained numerically as radiation equilibrium temperature (T_w) by discretizing the SBLE length into “n” number of segments, and for each segment, emission based on T_w is evaluated. IR radiance due to reflected external sources (sky-shine and Earthshine) and radiance due to T_w are collectively used to determine the IR contrast between SBLE and its replaced background in the LWIR band (i_{cont-SBLE,LWIR}).

The results are obtained for low subsonic turboprop aircraft (Λ = 3°, M_∞ = 0.44); high subsonic strategic bombers (Λ = 35°, M_∞ = 0.8); fifth-generation stealth aircraft (Λ = 40°, M_∞ = 1.6); and aircraft with supercruise/supersonic capability (Λ = 50°, M_∞ = 2.5). The aircraft with supersonic capability (Λ = 50°, M_∞ = 2.5) reports the maximum LWIR signatures and hence the highest visibility from the front. The results obtained are compared with values at Λ = 0° for all cases, which shows that increasing Λ significantly reduces aerodynamic heating and LWIR signatures.

The novelty of this study comes from its report on the influence of Λ on the LWIR signatures of aircraft SBLE in the frontal aspect for the first time.

This paper aims to propose a reference model based simple strategy for the design of proportional-integral-derivative (PID) controller using frequency response matching for high-order stable, integrating and unstable processes that may have time-delay and non-minimum phase zero.

The reference sensitivity model is designed fulfilling stability conditions of the control system responses such as set-point response, load-disturbance response and noise response along with transient response criteria. The analytical controller thus designed is approximated to a PID controller using a simple formula based on a model-matching technique at low frequency.

PID controllers are designed for examples with varied dynamics taken from the literature, and the performances of the designed control systems are compared with some methods prevalent in the literature to show the efficacy of the proposed work. Overall, the method gives satisfactory set-point, as well as load-disturbance responses and controller-outputs in all the cases considered.

The method is applicable to high-order processes of various monotonic or oscillating dynamics without requiring process reduction. The PID controller designed considering a reference model with suitable criteria ensuring stability and a modified model matching technique, which provides a stable control system for all these high-order processes.

Silane cross-linkers have been used to strengthen the mechanical stabilities and friction resistance of plastic products. Therefore, the effect of silane cross-linkers on latex has been studied through preparing modified self-cross-linking long fluorocarbon polyacrylate latex. In this paper, nonionic surfactant alcohol ether glycoside (AEG1000) and anionic polymerizable surfactant 1-allyloxy-3-(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) acted as mixed emulsifier and 3-(methacryloyloxy) propyltrimethoxysilane (KH-570) and bis (2-ethylhexyl) maleate (DOM) were used as functional monomers.

The modified acrylate polymer latex was synthesized through the semi-continuous seeded emulsion polymerization with methyl methacrylate (MMA), butyl acrylate (BA), dodecafluoroheptyl methacrylate (DFMA) and hydroxypropyl methacrylate (HPMA) as main monomers. Potassium persulfate (KPS) was applied to initiate polymerization reaction, nonionic surfactant AEG1000 and DNS-86 acted as emulsifier, KH-570 and DOM were used as functional monomers, respectively.

The optimum conditions of synthesizing the modified latex were the following. The mass ratio of monomers containing MMA, BA, DFMA, HPMA, KH-570 and DOM was 13.58:13.58:0.90:1.20:0.15:0.60, the usage of initiator KPS was 0.5% of the total weight of monomers and the amount of emulsifier was 7% of all monomers with AEG1000:DNS-86 = 1:1. The results indicated that the conversion of monomer was 99% and the coagulation was about 2.0%.

The resultant latex was modified silane cross-linker KH-570 and DOM, which positively affected the comprehensive properties of latex and its film. Apart from this, the novel mixed emulsifier was used to improve the size and distribution of latex particles and reduce environmental problems caused by the use of emulsifiers.

The purpose of this work was to develop a new trispiperazido phosphate-based reactive diluent (diphosphate-piperazine hydroxyl acrylate [DPHA]) and used as a flame retardant with an epoxy acrylate (EA) in ultraviolet (UV)-curable wood coating.

The concentration of reactive diluent was varied from 0% to 20% in the UV-curable formulation with constant photoinitiator concentration. The effect of DPHA concentration on film properties was studied by differential scanning calorimetry and thermogravimetric analysis, gel content, water absorption and limiting oxygen index.

The results showed that the viscosity of the prepared formulation decreased by increasing reactive diluent (DPHA) concentration which leads to improving the coating efficiency. A high concentration of reactive diluent (DPHA) of the cured films shows good resistance against stain, mechanical and thermal properties, which results in an increased glass transition temperature (T_g) and cross-linking density of the films.

The new trispiperazido phosphate-based reactive diluent was used in wood coating formulation, which resulted in excellent flame-retardant properties with higher cross-linked density with good stain resistance. This material can provide a wide range of application for coating industries to produce a glossy finish.

The purpose of this paper is to handle the anaphors through anaphora resolution in aspect-oriented sentiment analysis. Sentiment analysis is one of the predictive analytics of social media. In particular, the social media platform Twitter is an open platform to post the opinion by subscribers on contextual issues, events, products, individuals and organizations.

The sentiment polarity assessment is not deterministic to conclude the opinion of the target audience unless the polarity is assessed under diversified aspects. Hence, the aspect-oriented sentiment polarity assessment is a crucial objective of the opinion assessment over social media. However, the aspect-oriented sentiment polarity assessment often influences by the curse of anaphora resolution.

Focusing on these limitations, a scale to estimate the aspects oriented sentiment polarity under anaphors influence has been portrayed in this article. To assess the aspect-based sentiment polarity of the tweets, the anaphors of the tweets have been considered to assess the weightage of the tweets toward the sentiment polarity.

The experimental study presents the performance of the proposed model by comparing it with the contemporary models, which are estimating the sentiment polarity tweets under anaphors impact.

The purpose of this paper is to simulate flow inside differentially heated rotating cavity using two different formulations; one using Navier‐Stokes (NS) equations derived in non‐inertial (rotating) frame of reference and the other using NS equations in inertial frame of reference. Then to compare the results obtained from these formulations to find their merits and demerits.

The NS equations for both non‐inertial and inertial formulations are written in artificial compressibility form before discretizing them by a high resolution finite volume method. The dual time steeping approach of Jameson is used for time accuracy in both the formulations. Arbitrary Lagrangian Eulerian (ALE) approach is used for taking care of moving boundary problem arising in the inertial formulation. A newly developed HLLC‐AC Riemann solver for discretizing convective fluxes and central differencing for discretizing viscous fluxes are used in the finite volume approach. Results for both the formulations are first validated with test cases reported in literature. Then the results of the two formulations are compared among themselves.

Results of the non‐inertial formulation obtained by the proposed method are found to match well with those reported in literature. The results of both the formulations match well for low rotational speeds of the cavity. The discrepancies between the results of the two formulations progressively increase with the increase in rotational speed. Implicit treatment of the source term is found to reduce the discrepancies.

The present approach is useful for accurate prediction of flow feature and heat transfer characteristic in case of applications such as manufacturing of single wafer crystal for semiconductor and in numerous metallurgical processes.

The ALE formulation is used for the first time to simulate a differentially heated rotating cavity problem. The attempt to compare non‐inertial and inertial formulations is also reported for the first time. Implicit treatment of the source term leading to change in solution accuracy is one of the important findings of the present investigation.

Heat exchangers (HEXs) are extensively used in many applications such as heating and cooling systems. To increase the thermal performance of HEXs, nano-sized particles could be added to the base working fluid which can improve the thermophysical properties of the fluid. In addition, further improvement in the thermal performance of nanofluids can be obtained by using two or more different nanoparticles which are known as hybrid nanofluids. This paper aims to improve the thermal efficiency of U-type tubular HEX (THEX) by using CuO-Al₂O₃/water hybrid nanofluid.

Numerical simulation has been used to model THEX with various configurations. Also, CuO-Al₂O₃/water hybrid nanofluid has been experimented in THEX in two various modes including parallel (PTHEX) and counter flow (CTHEX) regarding to the numerical findings. Hybrid nanofluids have been prepared in two particle concentrations and compared with CuO/water nanofluid at the same concentrations and also with water.

The numerical simulation results showed that adding fins and also using hybrid nanofluid can increase heat transfer rate in HEX. However, adding fins cannot be a good option in U-type THEX with lower diameter because it increases pressure drop notably. Experimental results of this work illustrated that using Al₂O₃-CuO/water hybrid nanofluid in the THEX improved thermal performance significantly. Maximum enhancement in overall heat transfer coefficient of THEX by using CuO-Al₂O₃/water nanofluid in 0.5% and 1% concentrations achieved as 9.5% and 12%, respectively.

The obtained findings of the study showed the positive effects of using hybrid type nanofluid in comparison with single type nanofluid. In this study, numerical and experimental analysis have been conducted to investigate the effect of using hybrid type nanofluid in U-type HEX. The obtained results exhibited successful utilization of CuO-Al₂O₃/water hybrid type nanofluid in HEX. Moreover, it was observed that thermal performance analysis of the nanofluids without any experiment can be done by using numerical method.

Nanofluid exhibits higher density, higher viscosity, higher thermal conductivity and reduced specific heat capacity along with improved heat transfer characteristics. It is comparatively better than conventional fluids in terms of thermo-physical properties. This paper aims to investigate experimentally the overall performance of the shell and tube heat exchanger operated under two different configurations – without baffles (STHX_1) and with baffles (STHX_2) using 0.01 Vol.% and 0.02 Vol.% of CuO-W nanofluid.

Two different configurations, one without baffles (STHX_1) and other with single segmental baffles (STHX_2), are chosen with all other dimensional details of shell and tube remaining same. Water is used as base fluid. CuO nanoparticle is chosen, as its thermal conductivity is higher compared to other metal oxides. A comparative study on the thermal performance of these shell and tube heat exchangers are performed by considering different Vol.% concentrations of CuO-W nanofluid and the outcome are compared with the base fluid (i.e., water). The influence of varying the mass flow rate of the tube side fluid by keeping shell side fluid mass flow rate as constant and vice versa on the thermal performance of shell and tube heat exchanger are studied.

The modified shell and tube heat exchanger with baffles (STHX_2) give an improved performance. The heat transfer coefficient improved by about 11.28 and 7.54 per cent for 0.02 and 0.01 Vol.% of CuO-W nanofluid compared to water. Overall heat transfer coefficient for STHX_2 enhanced between 118.26% to 123.06% in comparison with base fluid for 0.02 Vol.% of CuO-W nanofluid whereas, it improved between 79.20% to 87.51% for 0.01 Vol.% of CuO-W nanofluid. Similarly, the actual heat transfer enhanced between 71.79% to 77.77% and between 48.71% to 55.55% for 0.02 and 0.01 Vol.% of CuO-W nanofluid, respectively. Moreover, mass flow rates of the working fluids significantly influence the performance of the shell and tube heat exchanger.

Two cases are considered here. first, by varying the shell side fluid mass flow rate and keeping the tube side fluid mass flow rate as constant. Later, tube side fluid mass flow rates are varied and shell side fluid mass flow rate is kept constant. It is found that in Case 2, for both 0.01 and 0.02 Vol.% of CuO-W nanofluid, highest performance is obtained for 150 kg/h of shell side and tube side fluid flows involving STHX_2. Finally, the modified shell and tube heat exchanger with baffle arrangement gives the best performance by using 0.02 Vol.% of CuO-W nanofluid.