Search results

In recent years, using aberration-corrected transmission electron microscopy, the authors have achieved precisely detecting the structural evolution of passive film as well as its interface zone at atomic scale. The purpose of this paper aims to make a brief review to show the authors’ new understanding and perspective on the issue of critical factors determining stability of passive film of Fe-Cr alloy.

The introduction of single crystal enabled the authors to obtain a distinct metal/passive film interface and better characterize the structure of the interface region. The authors use aberration-corrected TEM to conduct cross-sectional observation and directly capture the details across the entire film at a high spatial and energy resolution.

Apart from the passive film itself, the interface zone, including metal/film (Me/F) interface and the adjacent metal side, is also the site which is attacked. Accordingly, the nature of the interface zone, such as microstructure, composition and atomic configuration, is one of the critical factors determining the stability of passive film.

Deciphering the critical factors determining the stability of passive film is of great significance and has been a fundamental issue in corrosion science. Great attention has been paid to the nature of the passive film itself. In contrast, the possible role of the interface between the passive film and the metal is rarely taken into account. Based on the advanced analytical tool with high spatial resolution, the authors have specified the significant role of interface structures on the macro-scale stability of passive film.

The changes in tensile behavior of polycrystalline nanocopper lattice with changes in temperature, average grain size (AGS) and strain rate, have been explored. The existence of a critical AGS has also been observed which shows that the Hall–Petch relationship behaves inversely.

Nanoscale deformation of polycrystalline nanocopper has been done in this study with the help of an embedded atom method (EAM) potential. Voronoi construction method has been employed for creating four polycrystals of nanocopper with different sizes. Statistical analysis has been used to examine the observations with emphasis on the polycrystal size effect on melting point temperature.

The study has found that the key stress values (i.e. elastic modulus, yield stress and ultimate tensile stress) are significantly influenced by the considered parameters. The increase in strain rate is observed to have an increasing impact on mechanical properties, whereas the increase in temperature degrades the mechanical properties. In-depth analysis of the deformation mechanism has been studied to deliver real-time visualization of grain boundary motion.

This study provides the relationship between required grain size variations for consecutive possible variations in mechanical properties and may help to reduce the trial processes in the synthesis of polycrystalline copper based on different temperatures and strain rates.

In this paper, it can be seen from AFM images of the as-deposited ZnO and CZO films, and the particle size and shape are not clear, while by increasing annealing temperature, they become distinguishable. By increasing temperature to 600°C, ZnO and CZO, CAZO and aluminum-doped zinc oxide (AZO) films particles became almost spherical. Due to high content of Cu in CZO target, and of Al in AZO target which was 5% weight ratio, doping plays a great role in the subject. Therefore, the annealing processing strongly affect the size and the shape of nanoparticles.

In this paper, the authors tried to study, in detail, nobel optical characterizations of ZnO films doped by transition metals in different annealing temperature. The authors found that the values of skin depth, optical density, electron–phonon interaction, steepness parameter, band tail width, direct and indirect carriers transitions and the dissipation factor, free carriers density and roughness of films affect the optical properties, especially the optical absorptions of ZnO films doped by transition metals. Also these properties were affected by annealing temperatures. The authors also found that topography characterizations strongly were affected by these parameters.

The CZO films have maximum value of coordination number ß, with considering N_C = 4, Z_a = 2, N_e = 8. The CZO films annealed at 500 °C have maximum value of optical density. The as-deposited CAZO films have maximum value of steepness parameters in about of 0.13 eV. The as-deposited AZO films have maximum value of dispersion energy Ed in about of 5.75 eV. Optical gap and disordering energy plots of films can be fitted by linear relationships E_g = 0.49 + 0.2 EU and E_g = 0.52 + 0.5 EU, respectively.

With considering N_c = 4, Z_a = 2, N_e = 8 for ZnO films, coordination number ß has maximum value of 0.198. CZO nanocomposites films annealed at 500°C have maximum value of optical density. Different linear fitting of ln (α) for films were obtained as y = A_x + B where 5<A < 17 and 5<B < 12. As-deposited CAZO nanocomposites films have minimum value of electron phonon interaction in about of 4.91 eV. Optical gap and disordering energy plots can be fitted by linear relationships E_g = 0.49 + 0.2 EU and E_g = 0.52 + 0.5 EU for as-deposited films and films annealed at 500°C, respectively. Steepness parameters of as-deposited CAZO nanocomposites films have maximum value of 0.13 eV. Dispersion energy Ed for as-deposited AZO nanocomposites films has maximum value of 5.75 eV.

This paper aims to solve the problems molybdenum disulfide (MoS₂) nanosheets suffer from inadequate dispersion stability and form a weak lubricating film on the friction surface, which severely limits their application as lubricant additives.

MoS₂/C₆₀ nanocomposites were prepared by synthesizing molybdenum disulfide (MoS₂) nanosheets on the surface of hydrochloric acid-activated fullerenes (C₆₀) by in situ hydrothermal method. The composition, structure and morphology of MoS₂/C₆₀ nanocomposites were characterized. Through the high-frequency reciprocating tribology test, its potential as a lubricant additive was evaluated.

MoS₂/C₆₀ nanocomposites that were prepared showed good dispersion in dioctyl sebacate (DOS). When 0.5 Wt.% MoS₂/C₆₀ was added, the friction reduction performance and wear resistance improved by 54.5% and 62.7%, respectively.

MoS₂/C₆₀ composite nanoparticles were prepared by in-situ formation of MoS₂ nanosheets on the surface of C₆₀ activated by HCl through hydrothermal method and were used as potential lubricating oil additives.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-10-2023-0321/

The purpose of this paper is to study the high temperature oxidation behavior of Ti and C-added FeCoCrNiMn high entropy alloys (HEAs).

Cyclic oxidation method was used to obtain the oxidation kinetic profile and oxidation rate. The microstructures of the surface and cross section of the samples after oxidation were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM).

The results show that the microstructure of the alloy mainly consisted of FCC (Face-centered Cubic Structure) main phase and carbides (M₇C₃, M₂₃C₆ and TiC). With the increase of Ti and C content, the microhardness, strength and oxidation resistance of the alloy were effectively improved. After oxidation at a constant temperature of 800 °C for 100 h, the preferential oxidation of chromium in the chromium carbide determined the early formation of dense chromium oxide layers compared to the HEAs substrate, resulting in the optimal oxidation resistance of the TC30 alloy.

More precipitated CrC can preferentially oxidize and rapidly form a dense Cr₂O₃ layer early in the oxidation, which will slow down the further oxidation of the alloy.

The purpose of this study is to investigate the structural, surface roughness and corrosion properties of the zirconium oxide thin films deposited onto SS304 substrates using the direct current (DC) magnetron sputtering technique.

DC sputtering at different powers – 80, 100 and 120 W – was used to deposit ZrO₂ thin films onto different substrates (Si/SS304) without annealing of the substrate. Atomic force microscope (AFM), energy-dispersive X-ray spectroscopy (EDS), Tafel extrapolation and contact angle techniques were applied to investigate the surface roughness, chemical compositions, corrosion behavior and hydrophobicity of these films.

Results showed that the thickness of the deposited film increased with power increase, while the corrosion current decreased with power increase. AFM images indicated that the surface roughness decreased with an increase in DC power. EDS analysis showed that the thin film has a stoichiometric ZrO₂ (Zr:O 1:2) composition with basic uniformity. Water contact angle measurements indicated that the hydrophobicity of the synthesized films decreased with an increase in surface roughness.

DC magnetron sputtering technique is infrequently used to deposition thin films. The obtained thin films showed good hydrophobic and anticorrosion properties. Finally, results are compared with other deposition techniques.

The purpose of this study was carried out to explore the potential use of carrageenan extracted from marine red seaweed (Kappaphycus alvarezii) collected from Munaikadu, Mandapam region, Ramanathapuram district, Tamil Nadu.

Biodegradable film was developed by using carrageenan extracted by using alcohol extraction method. To improve the mechanical properties of the film, rice starch was incorporated. The biodegradable films were made by phase inversion method with varied carrageenan concentration of 1%, 1.5% and 2% (w/v) and rice starch with concentration of 0%, 1%, 1.5% and 2% (w/v). Physical properties, optical properties, mechanical properties and other properties such as biodegradability, solubility and water vapor permeability of the developed biodegradable films were characterized. The results were analyzed in design expert software using Box–Behnken design.

Results show that the biodegradable film’s mechanical and water vapor permeability increases with an increase in carrageenan and rice starch concentration. The optimized film structure was obtained with carrageenan and rice starch composition of 1.5% and 2%, respectively.

The results shown a broad spectrum of commercial applications and future rice starch possibilities incorporated in the carrageenan-based biodegradable film.

The purpose of this paper is to study the effect of chromium content on the microstructure and corrosion resistance of Ni-Cr coating.

Ni-Cr coating was prepared by pulse current electrodeposition with trivalent chromium. On the basis of studying effect of electroplating parameters on composition and morphology, Ni-Cr alloy coatings with various chromium contents were obtained. The microstructure was characterized by scanning electron microscopy, X-ray diffractometer and transmission electron microscopy. Corrosion behavior was studied by potentiodynamic polarization and electrochemical impedance spectroscopy techniques.

Electrodeposited chromium was solidly dissolved in nickel and refined the grain of the coating. With the increase of Cr content, the corrosion resistance of Ni-Cr coating was enhanced, which is due to the formation of continuous nickel hydroxide and compact chromium oxide passive films.

Ni-Cr alloy coating without penetration crack was prepared in trivalent chromium electrolyte, and the mechanism of its excellent corrosion resistance was proposed.

The main purpose of this study was to prepare the cotton fibers and cellulose powder by a layer of nano-crystalline-titanium dioxide (TiO₂) using the sol-gel sono-synthesis method to clean the wastewater containing reactive dye. Moreover, TiO₂ nano-materials are remarkable due to their photoactive properties and valuable applications in wastewater treatment.

In this research, TiO₂ was synthesized and deposited effectively on cotton fibers and cellulose powder using ultrasound-assisted coating. Further, tetra butyl titanate was used as a precursor to the synthesis of TiO₂ nanoparticles. Reactive dye (red 195) was used in this study. X-ray Diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy were performed to prove the aptitude for the formation of crystal TiO2 on the cotton fibers and cellulose powder along with TiO₂ nanoparticles as well as to analyze the chemical structure. Decoloration of the wastewater was investigated through ultraviolet (UV-Visible) light at 30 min.

The experimental results revealed that the decolorization was completed at 2.0 min with the cellulose nano TiO₂ treatment whereas cotton nano TiO₂ treated solution contained reactive dyestuffs even after the treatment of 2 min. This was the fastest method up to now than all reported methods for sustainable decolorization of wastewater by absorption. Furthermore, this study explored that the cellulose TiO₂ nano-composite was more effective than the cotton TiO₂ nano-composite of decoloration wastewater for the eco-friendly remedy.

Cotton fibers and cellulose powder with nano-TiO₂, and only reactive dye (red 195) were tested.

With reactive dye-containing wastewater, it seems to be easier to get rid of the dye than to retain it, especially from dyeing of yarn, fabric, apparel, and as well as other sectors where dyestuffs are used.

This research would help to reduce pollution in the environment as well as save energy and cost.

Decoloration of wastewater treatment is an essential new track with nano-crystalline TiO2 to fast and efficient cleaning of reactive dyes containing wastewater used as a raw material.

The purpose of this paper is to improve the corrosion resistance of stainless-steel bipolar plate by magnetron sputtering.

TiC/amorphous carbon composite film was deposited by magnetron sputter at four different temperature of 25°C, 200°C, 300°C and 400°C. The morphology, composition and structure of the film were characterized by scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. And its corrosion behavior was analyzed through electrochemical impedance spectroscopy, potentiodynamic and potentiostatic polarization tests.

A compact TiC/amorphous carbon film was prepared by magnetron sputtering on 316L stainless steel, and the particles of the film were refined with the increase in sputtering temperature. High temperature promoted the formation of TiC and C–C sp² hybrid carbon, but excessively high temperature caused the oxidation of Ti and a significant decrease in sp² hybrid carbon. The corrosion resistance of the film increased with the temperature, and the corrosion current density polarization at 0.86 V and 1.8 V for TiC/a–C film prepared at 400 °C is only 1.2% and 43.2% of stainless steel, respectively.

The corrosion resistance of amorphous carbon films was improved by the doping of Ti carbide, and the appropriate sputtering temperature was obtained.