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The purpose of this study was to investigate the effects of deformation-induced martensite on electrochemical corrosion behaviors of 304 austenitic stainless steel in a simulated primary water environment of a pressurized water reactor nuclear power plant with boric acid and lithium hydroxide contaminated with chloride by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), Mott–Schotty curves and X-ray photoelectron spectroscopy (XPS).

The effects of deformation-induced martensite transformation on electrochemical corrosion behaviors of 304 austenitic stainless steel was investigated in a simulated primary water environment of a pressurized water reactor nuclear power plant with boric acid and lithium hydroxide contaminated with 0.1 M Cl⁻ by potentiodynamic polarization, EIS, Mott–Schotty curves and XPS in this paper.

The results revealed that the martensitic phase contents increased with the level of cold deformation. The general corrosion current density and the corrosion potential increased and decreased, respectively, with the increase of cold deformation degree. However, the pitting potential decreased as the cold deformation increased up to 20 per cent, then a slight increase was observed at 35 per cent cold working. It was found from Mott–Schottky curves and XPS analysis that as the cold deformation degree increased from 0 to 35 per cent, the doping concentrations of the oxide films increased; however, the film thickness decreased, which indicates that both density and integrity of the films are degraded significantly as the deformation degree increases, and this ultimately contributes to the significant increment of the general corrosion rate and reduction of the pitting corrosion resistance.

The effects of deformation-induced martensite transformation on electrochemical corrosion behaviors of 304 austenitic stainless steel was investigated in a simulated primary water environment of a pressurized water reactor nuclear power plant with boric acid and lithium hydroxide contaminated with 0.1 M Cl⁻ by potentiodynamic polarization, EIS, Mott–Schotty curves and XPS in this paper.

This paper aims to study the effect of chloride concentration on the properties of passive film formed on Q235 steel in simulated concrete pore solutions.

Mott–Schottky analysis and electrochemical impedance spectroscopy were used to study the passive film of Q235 steel in simulated concrete pore solution. X-ray photoelectron spectroscopy was used to analyze the composition of passive film on Q235 steel.

When the chloride concentration is below the chloride threshold value, open circuit potential (OCP) and Rct gradually increases and donor concentration (N_D) remains unchanged with the increasing immersion time. When the chloride concentration exceeds chloride threshold value, OCP and Rct decreases after a temporary increase and N_D increases. The linear region of the Mott–Schottky curve lost its linearity. The electrochemical process control step is changed from charge transfer control to oxygen diffusion control. As the chloride concentration increases, the FeO content in the passive film increases and the Fe₂O₃ content decreases. Chloride can destroy the outer layer of passive film and introduce impurities.

The effects of chloride and immersion time on the change process of passive films on Q235 steel in simulated concrete pore solution were studied using electrochemical methods. The mechanism of chloride destroying passive film was analyzed.

This paper aims to clarify the semi-conductive behavior of the passive layer formed in concrete environment without and with presence of chloride ions under different loading conditions. Passivation and depassivation of steel play an essential role in the subsequent stages of the corrosion process. Due to the nature of passive films on metals, they show electrochemical properties of a semi-conductor.

A C-ring model was proposed in this experiment to induce stress on the specimens. Specimens under different levels of compressive and tensile loadings were exposed to chloride-free and chloride-contaminated solutions and their semi-conductive behavior was investigated using Mott–Schottky technique.

Irrespective of the type and magnitude of the applied load, the passive film on rebars in simulated concrete pore solution is a highly disordered n-type semi-conductor. In all specimens, the presence of chloride ions decreases the slope of the Mott-Schottky plots, the donor density and the space charge layer thickness, which leads to a thinner passive film. Results indicate that steel specimens immersed in chloride-free pore solution under tensile loadings passivate more rapidly compared to those under compressive loadings. However, the situation in chloride-contaminated solution is different, and steel under tensile stress exhibits more corrosion than steel under compressive stress or under no load.

Reinforced concrete structures inevitably experience variable mechanical loads, and continuous degradation from aggressive environments. Therefore, it is imperative to study the synergic impact of different types of mechanical loadings and exposure to chloride ions on this process. This paper fulfils this need.

Two corrosion inhibitors for closed cooling water systems, nitrite-based and mixture of nitrite and molybdate corrosion inhibitor, are often compared to each other. This study aims to optimize these two inhibitors in terms of concentration and pH for carbon steel protection, with insights into the double layer structure on surface and its impact on corrosion inhibition.

Electrochemical analysis including electrochemical impedance spectroscopy and potentiodynamic test are carried out for quick assessment of corrosion inhibition efficiency and optimization, which is confirmed by immersion test and microscopic analysis. The electronic properties of the surface film are analyzed through Mott–Schottky method which provides new insights into the inhibition mechanism and the role of each component in mixture inhibitor.

Mixture of nitrite and molybdate is shown to present higher inhibition efficiency, owning to the double layer structure. Nitrite alone can form a protective surface film, whereas molybdate leads to an n-type semiconductive film with lower donor density, hence giving rise to a better inhibition effect.

Surface after inhibitor treatment has been carefully characterized to the microscopic scale, implying the effect of micro-structure, chemical composition and electronic properties on the corrosion resistance. Inorganic corrosion inhibitors can be tuned to provide higher efficiency by careful design of surface film structure and composition.

Almost every study on corrosion inhibitor applies such method for quick assessment of corrosion inhibition effect. Mott–Schottky test is one of electrochemical methods that reveals the electronic properties of the surface film. Previous works have studied the surface layer mainly through X-ray photoelectron spectroscopy. This study provides another insight into the surface film treated by nitrite and molybdate through Mott–Schottky analysis, and relates this structure to the corrosion inhibition effect based on multiple analysis including electrochemistry, microscopic characterization, thermodynamics and interface chemistry.

The purpose of this paper is to develop and optimize anti‐corrosive multi‐layered coatings of zinc‐nickel alloy on carbon steel.

A variety of composition‐modulated multi‐layer alloy (CMMA) coatings of zinc‐nickel were developed on a carbon steel substrate by cyclic changes in cathode current during electrodeposition, coupled with variation of the thicknesses of the individual layers. The corrosion behavior of the coatings was studied in 5 percent NaCl solution by electrochemical methods. Cyclic cathode current densities (CCCDs) and the number of alloy layers were optimized for highest performance of the coatings against corrosion. The factors responsible for improved corrosion resistance were analyzed in terms of change in the intrinsic electrical properties of the capacitance value at the electrical double layer that was associated with micro/nanometric layering. The formation of the semi‐conductive surface film, which was responsible for the improved corrosion resistance, was supported by a Mott‐Schottky plot and the cyclic polarization study. The formation of multi‐layered deposit and the mechanism of corrosion degradation of the coating were analyzed using scanning electron microscopy.

CMMA coatings with an optimal configuration of (Zn‐Ni)_2.0/4.0/300 showed ∼35 times better corrosion resistance compared to a monolithic (Zn‐Ni)_3.0 alloy coating of the same thickness. The peak performance was attributed to the change in intrinsic electrical properties of the coating and this conclusion was supported by dielectric spectroscopy.

The paper describes the optimization of CCCD and the number of deposited layers by development of electrolytic deposition of anti‐corrosive multi‐layered zinc‐nickel coatings from a single plating technique.

Aluminum tripolyphosphate was used as a corrosion inhibitor in a simulated concrete pore solution. For studies of the inhibition mechanism of aluminum tripolyphosphate on the carbon steel, its influence on the pitting initiation on the carbon steel in a Cl⁻ containing pore solution were investigated.

Potentiodynamic polarization curves, Mott–Schottky plots and potentiostatic polarization of the carbon steel in the pore solution with different content of aluminum tripolyphosphate were measured, as well as the optical micrographs of pitting on the carbon steel was observed.

The metastable pitting potential and the stable pitting potential increased, while the donor density and the flat band potential decreased with the concentration of aluminum tripolyphosphate in solution. Furthermore, the initiation of pitting was suppressed, as well as the transition from metastable to stable pitting was hindered by the aluminum tripolyphosphate. The scale parameter (a), in the extreme distribution of the maximum current peak, could be used to predict the transition from metastable to stable pitting.

The inhibition mechanism of aluminum tripolyphosphate on carbon steel in pore solution was revealed. It suppresses the initiation of pitting and hinders the transition from metastable to stable pitting. Furthermore, a parameter defined as the scale parameter (a) in the extreme distribution of the maximum current peak was introduced to predict the transition from metastable to stable pitting.

The purpose of this paper is to study the variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution, is helpful to understand the mechanisms of corrosion resistancethe of plated Pd on 316 L ss.

The variations of composition and properties of the passive film on 316 L stainless steel surface in 80°C, 0.5 mol L-1 H2SO4 + 2 mg L-1 NaF solution after connected to Pd electrode were studied with methods of potential monitor, X-ray photoelectron spectroscopy analysis and electrochemical impedance spectrum (EIS) measurement.

By connecting to a Pd electrode, the potential of the SS sample increased from the active region to the passive region. By connecting to the Pd electrode, the contents of Cr, Cr(OH)3 and Fe3O4 in passive film increased obviously. With increased Pd/SS area ratio, the Cr(OH)3 content in passive film increased but the Fe3O4 content changed little. The results show that after connecting to Pd the corrosion resistance of the passive film on 316 L stainless steel increases obviously, which may be attributed to the more compact passive film because of higher Cr, Cr(OH)3 and Fe3O4 contents and less point defects in the film.

The effects and mechanism of Pd on passivation of SS was studied.

This paper aims to study the influence of the addition of calcium nitrite on the passive films of rebar to reveal what causes calcium nitrite to further prolong the durability service life of the reinforced concrete structures.

A comprehensive experimental study of the passive films, such as components, surface morphologies, electric structure and compactness, was carried out in a saturated calcium hydroxide solution which is normally used to simulate concrete pore solution by using X-ray photoelectron spectroscopy, atomic force microscopy, Mott–Schottky and potentiostatic polarization, respectively.

The results showed that the passivation behavior of rebar has been changed dramatically by the addition of calcium nitrite. That is, the passive film formed in the solution with the addition of 10 g/L Ca(NO₂)₂ had less donor density (Nd), more positive plat potential, smoother surface and lower content of Fe_hydrox than that formed in the solution without Ca(NO₂)₂.

The study focuses on the passive films and provides a more clear cognition of the durability service life extension of the reinforced concrete structures caused by the addition of calcium nitrite.

At present, carbonated drinks such as cola are especially favored by the younger generation. But because of its acid, it often leads to tooth demineralization, resulting in “cola tooth”. However, the influence of cola on the corrosion resistance of passive film of TiA10 alloy restorative materials is rarely reported. The purpose of this study was to analysis the corrosion resistance, composition of the passive film of TA10 alloy in different concentrations of Cola.

The passive behavior of TA10 alloy in artificial saliva (AS) and Cola was studied by means of potentiodynamic polarization, electrochemical impedance spectroscopy, cyclic voltammetry, Mott-Schottky techniques and combined with X-ray photoelectron spectroscopy and Auger electron spectroscopy (AES) surface analysis.

With the increase of cola content, the self-corrosion current density of the alloy increases sharply, and the corrosion resistance of the passive film is the best in AS, while Rp in cola is reduced to half of that in AS. The thickness of the passive film in AS, AS +cola and cola is about 9.5 nm, 7.5 nm and 6 nm, respectively. The passive film in cola has more defects and the carrier density is 1.55 times as high as that in AS. Cola can weaken the formation process of the protected oxide, promote the formation of high valence Ti-oxides and increase the content of Mo-oxides in the passive film.

These results have important guiding significance for the safe use of the alloy in the complex oral environments.

There are obvious differences in corrosion resistance of different 2205 welding joints with different ratios of austenite and ferrite, from the top to the bottom, the austenite content decreased gradually while the ferrite increased. In each region of welded joint, the pitting resistance number of ferrite is higher than that of austenite; pitting corrosion is more likely to occur in austenite phase first on the top region of the weld and in the secondary phase precipitates on the other regions of the weld. The fluctuation of the ratio of austenite and ferrite has a great influence on performance of passive film in 3.5 per cent NaCl solution.

To study the corrosion behavior of welded joint, the samples were obtained by laser hybrid welding. Pitting corrosion was studied in different area of welded joint. The Mott–Schottky curves of welded joints were measured to study the passive film on the different welded joint area.

Due to the difference of heat input and the limit of filler depth of the wire, the microstructure of duplex stainless steel laser welding joint has obvious difference in the thickness direction. In addition, there will be harmful secondary phase (such as chromium nitride and σphase) precipitates in the lower part of the joint. For the welded joint, the corrosion resistance decreases with the increase in the difference of the microstructure. Pitting corrosion usually takes the two phases as the nucleation point and grows up. The surface of 2205 duplex stainless steel laser hybrid welding joint cannot form a complete passive film in 3.5 per cent NaCl solution, and the more the ratios of austenite and ferrite deviate from equilibrium position (50:50), the worse the performance of passive film is.

In this paper, the authors attempt to establish the correlation between the semiconductor electronic properties of passive film and the difference of microstructures and the component in a joint welded by laser hybrid welding. The effect of passive film on the corrosion resistance of the weld was further investigated.