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Effect of chloride concentration on the properties of passive film formed on Q235 steel in simulated concrete pore solutions

Lupeng Liu (Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, China)
Senlin Li (Nanjing Hydraulic Research Institute, Nanjing, China)
Zhiming Gao (Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, China)
Hang Jia (Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, China)
Wenbin Hu (Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, China)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 7 November 2022

Issue publication date: 2 January 2023

126

Abstract

Purpose

This paper aims to study the effect of chloride concentration on the properties of passive film formed on Q235 steel in simulated concrete pore solutions.

Design/methodology/approach

Mott–Schottky analysis and electrochemical impedance spectroscopy were used to study the passive film of Q235 steel in simulated concrete pore solution. X-ray photoelectron spectroscopy was used to analyze the composition of passive film on Q235 steel.

Findings

When the chloride concentration is below the chloride threshold value, open circuit potential (OCP) and Rct gradually increases and donor concentration (ND) remains unchanged with the increasing immersion time. When the chloride concentration exceeds chloride threshold value, OCP and Rct decreases after a temporary increase and ND increases. The linear region of the Mott–Schottky curve lost its linearity. The electrochemical process control step is changed from charge transfer control to oxygen diffusion control. As the chloride concentration increases, the FeO content in the passive film increases and the Fe2O3 content decreases. Chloride can destroy the outer layer of passive film and introduce impurities.

Originality/value

The effects of chloride and immersion time on the change process of passive films on Q235 steel in simulated concrete pore solution were studied using electrochemical methods. The mechanism of chloride destroying passive film was analyzed.

Keywords

Acknowledgements

This work was supported by National Natural Science Foundation of China (No. 51871164) and National key R&D Program (2018YFC0407102).

Citation

Liu, L., Li, S., Gao, Z., Jia, H. and Hu, W. (2023), "Effect of chloride concentration on the properties of passive film formed on Q235 steel in simulated concrete pore solutions", Anti-Corrosion Methods and Materials, Vol. 70 No. 1, pp. 9-17. https://doi.org/10.1108/ACMM-04-2022-2646

Publisher

:

Emerald Publishing Limited

Copyright © 2022, Emerald Publishing Limited

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