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The electronics assembly industry has fortunately rediscovered conductive adhesives as the search for lead‐free joining materials and improved performance intensifies. Although these intrinsically clean bonding agents are often first sought for their favourable environmental attributes, many are surprised to find that conductive adhesives can solve old and new problems. Today, new polymer solders for SMT allow low temperature processing, finer pitch assembly and wider processing latitude while providing compatibility with a very much larger range of materials than solder. State‐of‐the‐art adhesives are oxide‐tolerant and absolutely no fluxing or cleaning is required. Adhesives work where solder cannot be used. What's more, polymer‐based solder alternatives can run on existing SMT lines — no new equipment is needed. Z‐axis, or anisotropic, bonding agents are uni‐directional conductive materials that solve fine pitch interconnect problems in several areas. The anisotropics now dominate the flat panel interconnect field. Nearly every LCD and other flat panel display is connected with a polymer adhesive. The Z‐axis adhesives are also beginning to enable high density multilayer circuits and MCMs to be built more effectively. Finally, Z‐axis appears to offer the simplest and most cost‐effective means for flip chip bonding. However, special equipment is required. The paper compares the metallurgical solder joint, the present de facto standard, with the polymer composite bond to highlight similarities and important differences. All types of conductive adhesives are discussed including the latest — Area Array Z‐axis types. Bonding materials, assembly processes and performance are also covered.

Polymer thick film (PTF) technology provides the lowest cost, cleanest and most efficient manufacturing method for producing flexible circuits. Non‐contact radio frequency (RF) smart cards and related information transaction devices, such as RFID tags, appear to be a good fit for PTF‐flex. Flip chip also seems well suited for these “contactless” RF transceiver products. Flip chip and PTF adhesive technologies are highly compatible and synergistic. All PTF SMT adhesives assembly methods are viable for flip chip. However, the merging of flip chip with PTF‐flex presents major challenges in design, materials and processing. This paper will compare assembly methods and discuss obstacles and solutions for state‐of‐the‐art flip chip on flex within the RFID product environment.

The purpose of this paper is to examine electrical and mechanical properties of radio frequency identification (RFID) chip joints assembled on a flexible substrate and made from isotropic conductive adhesives (ICAs) reinforced with graphene nanoplatelets (GPNs) or graphite nanofibers (GFNs).

The ICAs reinforced with GPNs or GFNs were prepared and screen printed on a test pattern to investigate resistance and thickness of these adhesive layers. Differential Scanning Calorimetry (DSC) was performed to assess a curing behaviour of the prepared ICAs. Then, RFID chips were mounted with the prepared ICAs to the pattern of silver tracks prepared on foil. Shear test was carried out to evaluate mechanical durability of the created chip joints, and resistance measurements were carried out to evaluate electrical properties of the tested ICAs.

The 0.5 per cent (by weight) addition of GFNs or GPNs to the ICA improved shear force values of the assembled RFID chip joints, whereas resistance of these modified adhesives increased. The DSC analysis showed that a processing temperature of the tested adhesives may range from 80 to 170°C with different curing times. It revealed a crucial influence of curing time and temperature on electrical and mechanical properties of the tested chip joints. When the chip pads were cured for too long (i.e. 60 minutes), it resulted in a resistance increase and shear force decrease of the chip joints. In turn, the increase of curing temperature from 80 to 120°C entailed improvement of electrical and mechanical properties of the assembled chips. It was also found that a failure location changed from the chip – adhesive interface towards the adhesive – substrate one when the curing temperature and time were increased.

Further investigations are required to examine changes thoroughly in the adhesive reinforced with GFNs after a growth of curing time. It could also be worth studying electrical and mechanical properties of the conductive adhesive with a different amount of GFNs or GPNs.

The tested conductive adhesive reinforced with GFNs or GPNs can be applied in the production of RFID tags because it may enhance the mechanical properties of tags fabricated on flexible substrates.

Influence of GFNs and GPNs on the electrical and mechanical properties of commercial ICAs was investigated. These properties were also examined depending on a curing time and temperature. New conductive materials were proposed and tested for a chip assembly process in fabrication of RFID tags on flexible substrates.

The purpose of this paper is to characterise the electrical and mechanical properties of multiwall carbon nanotubes (MWCNTs)-based isotropic conductive adhesives (ICAs). The paper also compares the electrical and mechanical performance of MWCNTs-based ICAs with silver flakes and silver nanoparticles-based ICAs.

The ICAs were formulated with dyglycidyl ether bisphenol A epoxy resin and conductive fillers such as silver flakes, silver nanoparticles and MWCNTs. The four-point probe is used to measure the bulk resistivity of the ICAs.

The results from the study showed that the percolation threshold of the MWCNTs-based ICAs is 1.5 Wt.%. At 3 Wt.%, the drop in bulk resistivity is lower than the conventional ICAs. The addition of silver nanoparticles increased the overall bulk resistivity of the system. The mechanical properties improved with the introduction of carbon nanotubes into the silver flakes–epoxy system.

The results from bulk resistivity and mechanical properties of the MWCNTs could help to formulate MWCNTs-based ICAs with optimum weight fraction.

The paper demonstrates that the addition of MWCNTs to the silver-based ICAs will enhance their mechanical and electrical conductivity. In addition, the optimum weight percentage is also determined, which shows a bulk resistivity value lower along with improved mechanical property with the conventional ICA system.

This paper investigates the variations in electrical properties of a typical isotropic conductive adhesive (ICA) made with an epoxy‐based binder that are caused by differences in the curing conditions.

In‐situ monitoring of the various processes that were used to cure the ICA revealed that electrical conduction in the ICA specimens depends on both the high‐temperature curing conditions and the conditions during cooling to temperatures below the glass transition temperature (T_g).

The electrical resistivity of the cured ICA specimens after cooling to ambient temperature decreased with increasing degree of conversion, tending towards a convergence value that decreased with increasing curing temperature. The electrical resistivity of the specimens also varied significantly depending on the subsequent annealing process. However, the electrical resistivity achieved after annealing at temperatures above the curing temperatures clearly depended on the particular curing temperature that was used. The characteristics of the polymer structure in the adhesive binder are considered to be different, depending on the curing temperature, and this affects the electrical properties of the ICA;, i.e. the characteristics of the polymer structure obtained during the curing process affect the electrical resistance of the ICA, even after subsequent annealing processes.

This paper discusses generalities of variation in the electrical properties of ICAs during heating and cooling processes. The variation in behaviour in practice will differ depending on the type of adhesive binder in the ICA.

This paper clarifies how the electrical properties of ICAs evolve during the curing, annealing and cooling processes.

As the transition away from lead‐containing solders gathers momentum, isotropic conducting adhesives (ICAs) are being considered as possible replacements for conventional SnPb solder in a range of applications. Consequently, the reliability of ICA joints is under scrutiny. The purpose of this paper is to report the effect of printed circuit board (PCB) and component finishes on the reliability of ICA joints.

Previous work by the authors identified a suitable test regime to generate relevant reliability data. In the present work, those tests are employed to investigate whether the finishes on the components and/or PCBs have any effect on the reliability of the ICA joints after exposure to damp heat conditions.

The effect of different finishes is found to be very adhesive material dependent. Two adhesives are studied, and for one material the joint reliability is relatively unaffected by changes in component or PCB surface finish. However, for the second material, and components with a high‐tin content‐plated finish, the joints display a less stable resistance. The surface finish on the PCB is found to have a smaller effect on joint reliability than the component finish, with results dependent on adhesive material type. Performance with one material exhibited little difference in reliability irrespective of the PCB surface finish. For the second material, the joint reliability performance with components having the electroless nickel/immersion gold finish, is not as good as that with components having the immersion tin or silver finishes.

The paper shows that surface finish is an important factor in determining the conductivity of ICA joints during exposure to the 85°C/85%RH environment. Systems containing tin are more prone to lose conductivity and, conversely, noble metal systems are more immune to degradation. This is a major concern as the industry is showing many signs that the component termination of choice will be pure tin.

Electrically conductive adhesives are considered to be strong candidates for replacing toxic lead‐based solders. The present work has focused on thermal fatigue cracking of isotropic conductive adhesive (ICA) joints. The initiation and propagation of cracks in the ICA joints were investigated with scanning electron microscopy. A linear elastic finite element analysis has been performed to analyse the stress distribution in the ICA joint and correlate the critical stress concentrations with the observed crack initiation sites. The effect of joint configurations on thermal stresses was also evaluated with numerical calculations.

The purpose of this paper is to discuss the use of epoxy‐based conducting adhesives in z‐axis interconnections.

A variety of conductive adhesives with particle sizes ranging from 80 nm to 15 μm were laminated into printed wiring board substrates. SEM and optical microscopy were used to investigate the micro‐structures, conducting mechanism and path. The mechanical strength of the various adhesives was characterized by 90° peel test and measurement of tensile strength. Reliability of the adhesives was ascertained by IR‐reflow, thermal cycling, pressure cooker test (PCT), and solder shock. Change in tensile strength of adhesives was within 10 percent after 1,000 cycles of deep thermal cycling (DTC) between −55 and 125°C.

The volume resistivity of copper, silver and low‐melting point (LMP) alloy based paste were 5 × 10⁻⁴, 5 × 10⁻⁵ and 2 × 10⁻⁵ Ω cm, respectively. Volume resistivity decreased with increasing curing temperature. Adhesives exhibited peel strength with Gould's JTC‐treated Cu as high as 2.75 lbs/in. for silver, and as low as 1.00 lb/in. for LMP alloy. Similarly, tensile strength for silver, copper and LMP alloy were 3,370, 2,056 and 600 ψ, respectively. There was no delamination for silver, copper and LMP alloy samples after 3X IR‐reflow, PCT, and solder shock. Among all, silver‐based adhesives showed the lowest volume resistivity and highest mechanical strength. It was found that with increasing curing temperature, the volume resistivity of the silver‐filled paste decreased due to sintering of metal particles.

As a case study, an example of silver‐filled conductive adhesives as a z‐axis interconnect construction for a flip‐chip plastic ball grid array package with a 150 μm die pad pitch is given.

A high‐performance Z‐interconnect package can be provided which meets or exceeds JEDEC level requirements if specific materials, design, and manufacturing process requirements are met, resulting in an excellent package that can be used in single and multi‐chip applications. The processes and materials used to achieve smaller feature dimensions, satisfy stringent registration requirements, and achieve robust electrical interconnections are discussed.

This review paper aims to provide a better understanding of formulation and processing of anisotropic conductive adhesive film (ACF) material and to summarize the significant research and development work for the mechanical properties of ACF material and joints, which helps to the development and application of ACF joints with better reliability in microelectronic packaging systems.

The ACF material was cured at high temperature of 190°C, and the cured ACF was tested by conducting the tensile experiments with uniaxial and cyclic loads. The ACF joint was obtained with process of pre-bonding and final bonding. The impact tests and shear tests of ACF joints were completed with different aging conditions such as high temperature, thermal cycling and hygrothermal aging.

The cured ACF exhibited unique time-, temperature- and loading rate-dependent behaviors and a strong memory of loading history. Prior stress cycling with higher mean stress or stress amplitude restrained the ratcheting strain in subsequent cycling with lower mean stress or stress amplitude. The impact strength and adhesive strength of ACF joints increased with increase of bonding temperature, but they decreased with increase of environment temperature. The adhesive strength and life of ACF joints decreased with hygrothermal aging, whereas increased firstly and then decreased with thermal cycling.

This study is to review the recent investigations on the mechanical properties of ACF material and joints in microelectronic packaging applications.