Search results

To develop a method for the preparation of multi‐walled carbon nanotube reinforced low density polyethylene (LDPE) composites (MWNTs/LDPE), based on ultrasonic vibration, solution casting and melt mixing.

The preparation for MWNTs/LDPE composites was carried out by vibration of carbon nanotubes (CNT), solution casting and melt mixing for MWNTs and LDPE. The physical chemical properties of the composites were characterised using a variety of techniques including scanning electron microscopy, resistance and tensile measurement.

It was found that the preparation method reported had significantly improved the dispersion of multi‐walled carbon nanotubes (MWNTs) in LDPE matrix, resulting in the improvement of tensile strength of the composite. The percolation of MWNTs in LDPE matrix was between 10 and 15 wt% (10¹⁶‐10⁸ Ω cm).

The preparation method reported addressed a problem concerning the dispersion of CNT in polymer matrix. The method developed provided a practical and effective solution to such a problem.

The preparation method for MWNTs/LDPE composites involving vibration of CNT, solution casting and melt mixing for MWNTs and LDPE was novel. The method could be adapted for use in industrial scale.

Nowadays, nano-antennas or nanoscale absorbers made by innovative materials such as carbon nanotubes are gaining more and more interest, because of their outstanding features. The purpose of this paper is to investigate the scattering properties of carbon nanotubes, either isolated or arranged in arrays. The peculiar behaviour of such innovative materials is studied, taking also into account the finite length of the structure and the dependence of the scattering field from the operating temperature.

First a model is presented for the electrical transport along the carbon nanotubes, based on Boltzmann quasi-classical transport theory. The model includes quantistic and inertial phenomena observed in the carbon nanotube electrodynamics. The model also includes the effects of temperature. Using this electrodynamical model, the electromagnetic formulation of the scattering problem is cast in terms of a Pocklington-like equation. The numerical solution is obtained by means of the Galerkin method, with special care in handling the logarithmic singularity of the kernel. Case studies are carried out, either referred to isolated single-wall carbon nanotubes (SWCNTs) and array of SWCNTs.

The scattering properties of SWCNT are strongly influenced by the temperature and by the distance between the tubes. As temperature increases, the amplitude of the resonance peaks decreases, at a rate which is double the rate of changes of temperature. The resonance frequencies are insensitive to temperature. As for the distance between the tubes in an array, it influence the scattering resonance introducing a shift in the resonance frequencies which is appreciable for distances lower than the semi-length of the CNT. For higher distances the CNT scattered field may be regarded as the sum of the fields emitted by each CNT, as if they were isolated.

As far as now only SWCNTs have been studied. The multi-wall carbon nanotubes would show a richer behaviour with temperature, due to the joint effect of reduction of the mean free path and increase of the number of conducting channels, as temperature increases.

Possible use of carbon nanotubes as absorbing material or scatterers.

The model presented here is based on a self-consistent and physically meaningful description of the CNT electrodynamics, which takes rigorously into account the effect of temperature, size and chirality of each CNT.

The purpose of this paper is to analyze the effect of driver size and number of shells on propagation delay and power for multi‐walled carbon nanotubes (MWCNT) interconnects at 22 nm technology node.

An equivalent circuit model of MWCNT is used for estimation and analysis of propagation delay and power. The delay and power through MWCNT and Cu interconnects are compared for various driver sizes and number of MWCNT shells.

The SPICE simulation results show that the MWCNT interconnect has lower propagation delay than Cu interconnects. The delay ratio of MWCNT to Cu decreases with increase in length for different driver size and number of MWCNT shells. However, the delay ratio increases with reduction in number of MWCNT shells. The ratio of average power consumption (MWCNT/Cu) also decreases with the variation in driver size and numbers of shells with respect to the length of interconnect. The theoretical study proves CNTs to be better alternatives against copper on the ground of performance parameters.

Several challenges remain to be overcome in the areas of fabrication and process integration for CNTs. Lowering of metal nanotube contact resistance would be vital, especially for local interconnect and via applications. Moreover, rigorous characterization and modeling of electromagnetic interactions in CNT bundles; 3‐D (metal) to 1‐D (CNT) contact resistance; impact of defects on electrical and thermal properties; and high‐frequency effects are being seen as additional challenges.

This paper investigates, assesses and compares the performance of carbon nanotubes (CNT) based interconnects as prospective alternatives to copper wire interconnects in future VLSI chips. Multi walled CNTs assure for long/global interconnect applications.

The synergistic effect of functionalization of multi-walled carbon nanotubes (CNT) using KMnO4 oxidation and initial tensile deformation on the electrical resistance of nanotube network/polyurethane composite subjected to elongation was studied.

Though the initial deformation irreversibly changed the arrangement of carbon nanotube network, subsequent cyclic elongation confirmed stable resistance values. The increased strain-dependent resistance of stimulated nanotube network/polyurethane composite was demonstrated by monitoring vibration of tambour leather after a bead impact and finger flexion.

The results showed a tenfold composite resistance increase for the composite prepared from KMnO₄ oxidized nanotubes, quantified by a so-called gauge factor, from a value of about 20 in comparison to the network prepared from pristine nanotubes. This is a substantial increase, which ranks the stimulated composite among materials with the highest electromechanical response.

The results in this paper are new and have not been published yet. The paper combines different ideas which are developed together. It presents a new concept of synergistic effect of CNT oxidation and application of pre-strain simulation. Oxidation and pre-strain increases by several times the sensitivity of the tested composites which are predetermined for use as strain sensors of various sizes and shapes.

A computational structural mechanics approach, based on the exclusive use of standard bar elements is utilized in order to investigate the elastic stability of single-walled carbon nanotubes (SWCNTs) with atom vacancy defects under axial compressive loads. The paper aims to discuss this issue.

The proposed model uses three dimensional, two nodded, linear truss finite elements of three degrees of freedom per node to represent the force field appearing between carbon atoms due to the basic interatomic interactions.

Numerical results concerning the critical forces which cause instability of pristine nanotubes are compared with corresponding data given in the open literature in the effort to demonstrate the good accuracy of the method. Then, it is assumed that SWCNTs present-specific structural defects defined by their length, width, orientation and longitudinal position. The influence of these four geometric parameters of the imperfections considered on the stability of SWCNTs is investigated in detail and essential conclusions are revealed.

To the authors’ best knowledge, is the first time that the specific method is introduced for the prediction of buckling behavior of defective SWCNTs. The structural defect here is considered as atoms vacancy that forms a like-crack defect having a specific length, width, orientation and position along the nanotube length.

The purpose of this paper is to investigate nonlinear vibrations of triple-walled carbon nanotubes buried within Pasternak foundation carrying viscous fluids.

Considering the geometry of nanotubes, the governing equations were initially derived using Timoshenko and modified couple stress theories and by taking into account Von-Karman expressions. Then, by determining boundary conditions, type of fluid motion, Knudsen number and, ultimately, fluid viscosity, the principal equation was solved using differential quadrature method, and linear and nonlinear nanotube frequencies were calculated.

The results indicated that natural frequency is decreased as the fluid velocity and aspect ratio increase. Moreover, as the aspect ratio is increased, the results converge for simple and fixed support boundary conditions, and the ratio of nonlinear to linear frequencies approaches. Natural frequency of vibrations and critical velocity increase as Pasternak coefficient and characteristic length increase. As indicated by the results, by assuming a non-uniform velocity for the fluid and a slip boundary condition at Kn = 0.05, reductions of 10.714 and 28.714% were observed in the critical velocity, respectively. Moreover, the ratio of nonlinear to linear base frequencies decreases as the Winkler and Pasternak coefficients, maximum deflection of the first wall and characteristic length are increased in couple stress theory.

This paper is a numerical investigation of nonlinear vibration analysis for triple-walled carbon nanotubes conveying viscous fluid.

Strain sensing characteristic of carbon nanotubes has been established in the past at nanoscale. In this study, it is shown that the carbon nanotube film sensors, made up of randomly oriented carbon nanotubes, can be used as strain sensors at macro level. A nearly linear trend between the change in voltage, measured using a movable four point probe, and strains, measured using conventional electrical strain gage, indicates the potential of such carbon nanotube films for measuring flexural strains at macro level. Isotropic strain sensing capability of the carbon nanotube film sensors, due to randomly oriented carbon nanotubes, allows multidirectional and multi‐location measurements.

The purpose of this paper is concerned with the study of nonlinear ultrasonic waves in a magneto-flexo-thermo (MFT) elastic armchair single-walled carbon nanotube (ASWCNT) resting on polymer matrix.

A mathematical model is developed for the analytical study of nonlinear ultrasonic waves in a MFT elastic armchair single walled carbon nanotube rested on polymer matrix using Euler beam theory. The analytical formulation is developed based on Eringen’s nonlocal elasticity theory to account small scale effect. After developing the formal solution of the mathematical model consisting of partial differential equations, the frequency equations have been analysed numerically by using the nonlinear foundations supported by Winkler-Pasternak model. The solution is obtained by ultrasonic wave dispersion relations.

From the literature survey, it is evident that the analytical formulation of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix is not discussed by any researchers. So, in this paper the analytical solutions of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix are studied. Parametric studies is carried out to scrutinize the influence of the nonlocal scaling, magneto-electro-mechanical loadings, foundation parameters, various boundary condition and length on the dimensionless frequency of nanotube. It is noticed that the boundary conditions, nonlocal parameter and tube geometrical parameters have significant effects on dimensionless frequency of nanotubes.

This paper contributes the analytical model to find the solution of nonlinear ultrasonic waves in an MFT elastic ASWCNT embedded on polymer matrix. It is observed that the increase in the foundation constants raises the stiffness of the medium and the structure is able to attain higher frequency once the edge condition is C-C followed by S-S. Further, it is noticed that the natural frequency is arrived below 1% in both local and nonlocal boundary conditions in the presence of temperature coefficients. Also, it is found that the density and Poisson ratio variation affects the natural frequency with below 2%. The results presented in this study can provide mechanism for the study and design of the nano devices such as component of nano oscillators, micro wave absorbing, nano-electron technology and nano-electro--magneto-mechanical systems that make use of the wave propagation properties of ASWCNTs embedded on polymer matrix.

The purpose of this paper is to investigate in detail the effects of acid treatment on multi‐walled carbon nanotubes (MWNTs), which could find a variety of applications in coatings and composites.

A number of analytical techniques, including Fourier transform infrared spectroscopy (FT‐IR), X‐ray photoelectron spectroscopy (XPS), Raman spectroscopy (Raman), and scanning electron microscopy (SEM), were employed to assess the effects of acid treatment on MWNTs.

It was found that desirable modifications to MWNTs occurred after acid treatment. Thus, carboxylic acid groups were introducing on to the surface of MWNTs. It was also found that both chemical and physical properties of MWNTs could be modified/altered.

The investigation established a method to modify MWNTs via acid treatment and the effects of such a treatment on MWNTs in detail. The modified MWNTs can be used for various applications and further modifications. The acid treated and the further modified MWNTs can be dispersed into polymers to prepare polymer/MWNTs composite materials and composite surface coatings. Some properties of the resulting composites were improved by the dispersed MWNTs, giving excellent mechanical, electrical, thermal and magnetic properties.

The finding on the effects of acid treatment on MWNTs, supported by detailed FT‐IR, XPS, Raman and SEM data, would be of interest to the field. The modification technique provided a route to further modification of carbon nanotubes. The acid treated and the further modified MWNTs are useful for preparation of polymer/MWNTs composite materials and composites surface coatings with improved mechanical, electrical, thermal and magnetic properties.

The novel mechanical, chemical and thermodynamics characteristics of both single- and multi-wall carbon nanotubes (CNTs) make them a subject of much attention for the scientists and engineers from all domains. Fluid flows subject to CNTs are significant in biomedical engineering, energy storage systems, domestic and industrial cooling, automobile industries and solar energy collectors, etc. Keeping such effectiveness of CNTs in mind, this paper aims to examine peristaltic flow subject to CNTs in an asymmetric tapered channel. Both single and multiple walls CNTs are considered. The viscosity of nanomaterial depends on nanoparticles volume fraction and temperature. Total entropy rate through second law of thermodynamics is calculated. Heat source/sink and nonlinear heat flux are accounted.

The complicated flow expressions are simplified through lubrication approach. The velocity, temperature and entropy expressions are numerically solved by the built-in-shooting method.

The solutions for entropy generation, temperature and velocity are plotted, and the influences of pertinent variables are examined. The authors noticed that entropy generation is an increasing function of the Brinkman number.

The originality of this work is to communicate peristaltic CNTs-based nanomaterial peristaltic flow of viscous fluid in an asymmetric channel. No such consideration is yet published in the literature.