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Article
Publication date: 2 October 2018

Qi Jie Kwong, Jamalunlaili Abdullah, Sheng Chuan Tan, Tzer Hwai Gilbert Thio and Win Shyang Yeaw

Maintaining good indoor air quality (IAQ) in the built environment is essential to assure health, safety and productivity of occupants. The purpose of this paper is to report on…

Abstract

Purpose

Maintaining good indoor air quality (IAQ) in the built environment is essential to assure health, safety and productivity of occupants. The purpose of this paper is to report on the preliminary IAQ assessment of selected air-conditioned laboratories and naturally ventilated workshops in a tropical education institution.

Design/methodology/approach

The concentration levels of five major indoor air pollutants (IAPs) – carbon dioxide, carbon monoxide, respirable particulates, formaldehyde (HCHO) and total volatile organic compounds (TVOC) in each sampling area were measured using calibrated air sampling sensors and the tracer-gas analysis was used to determine the ventilation effectiveness. A questionnaire survey was carried out concurrently to study the prevalence of sick building syndrome (SBS) among users of laboratories and workshops and the data collected were statistically analysed using χ2 test.

Findings

The air pollutant levels were found to be below the threshold limit values set in the local code of practice on IAQ, except for two of the air-conditioned laboratories. This is possibly due to insufficient ventilation, smaller floor area per occupant ratio, long-term exposure to chemical substances, and improper disposal of the used chemical substances. The total particulate levels were higher in naturally ventilated workshops because such spaces were assigned for mechanical works which involved grinding, welding and fabrication. Besides, it was identified that most of the air contaminant levels were not normally distributed (p<0.05) within the sampling areas and SBS like dry eyes, watery eyes, tiredness and dry throat were reported in both laboratories and workshops. The outcomes of this work suggest that an increase of ventilation rate was necessary to reduce the concentration of the IAPs in air-conditioned laboratories and improved housekeeping would help mitigate the prevalence of SBS symptoms.

Research limitations/implications

This research was carried out in selected laboratories and workshops in a Malaysian educational institution and only five major IAPs stipulated in the Department of Occupational Safety and Health (DOSH) code of practice were measured.

Practical implications

The results of this study will enable facility engineers and managers to understand the IAPs concentration levels and potential SBS problems in academic laboratories and workshops. The recommended strategies can be considered to improve IAQ conditions in such spaces.

Originality/value

Most of the previously conducted IAQ studies focused only on commonly occupied building spaces such as offices, classrooms and houses. Information of the quality of air and SBS conditions in experimental facilities in developing nations that is available is currently very limited. This case study provides detailed information on IAQ in laboratories and workshops in Malaysia with focuses on the concentration levels of particular harmful gases, the prevalence of SBS among users of these facilities and the appropriate mitigation strategies. The results presented are of value to both academic and industry communities.

Details

Management of Environmental Quality: An International Journal, vol. 30 no. 2
Type: Research Article
ISSN: 1477-7835

Keywords

Article
Publication date: 3 May 2016

Altaf H. Basta, Houssni El-Saied and Emad M. Deffallah

The purpose of this paper is to examine the effects of denaturised rice bran (RB) and route of its incorporation during synthesis of urea-formaldehyde adhesive, on the performance…

Abstract

Purpose

The purpose of this paper is to examine the effects of denaturised rice bran (RB) and route of its incorporation during synthesis of urea-formaldehyde adhesive, on the performance of the resulting adhesive, especially viscosity, free-formaldehyde (HCHO) and quality of the produced bagasse-based composites, in comparison with those produced from commercial urea formaldehyde (UF) and RB-added UF.

Design/methodology/approach

The experiments were carried out using different denaturised RB at different percentages (1-5 per cent) and pH’s (9-11 per cent). These denaturised RB were incorporated at the last synthesis stage of UF synthesis process. The assessment was carried out on both the viscosity and environmental safety of the adhesive system, as well as the quality of the manufactured bagasse-based composites, of the particleboards (static bending, internal bond (IB) strength and water resistance properties), in comparison to commercial UF and RB added to UF. The performance of the adhesive system was evidenced by the thermogravimetric analysis and differential scanning calorimetry analyses.

Findings

The results showed that maximum static bending [modulus of rupture (MOR) and modulus of elasticity (MOE)], IB strength and water resistance properties of the resulted wood product accompanied the incorporating 5 per cent of the denaturised RB (pH = 9.0), at the last synthesised stage of UF synthesis process. Where, this synthesis process provided adhesive with viscosity nearly approaching to commercial UF adhesive, and reduced the free-HCHO of adhesive and board by approximately 56 and 49 per cent, respectively. For mechanical and water resistance properties, it provided board with 24.5 MPa MOR, 3,029 MPa MOE, 0.64 MPa IB, 11 per cent swelling (SW) and 20.5 per cent absorption. These properties fulfil the requirements of high grade particleboards American National Standard Institute (ANSI) A208.1, especially with respect to static bending values and water swelling property.

Research limitations/implications

Incorporating 5 per cent of pre-denaturised RB, at pH 9.0, in wet form, and in the last stage of synthesis UF, provided adhesive system with convenient viscosity together with lower free-HCHO and acceptable board properties, compared with that produced from commercial UF, or adding denaturised RB to already synthesised UF. For the mechanical (MOR, MOE and IB) and water resistance properties (SW per cent and absorption per cent) of the produced composite are complied the standard values of H-3 grade of particleboard.

Practical implications

Promising adhesive system is resulted from incorporating 5 per cent of pre-denaturised RB at pH 9.0, in wet form, during last stage of UF synthesis process.

Social implications

Incorporating the RB by-product of oil production to commercial UF or during synthesis of UF will be benefit for saving the healthy of wood co-workers, and motivating the wood mill to export its wood products.

Originality/value

The article provides a potential simple way to solve the drawback of increasing the viscosity of UF, as a result of adding RB, via incorporating the RB during synthesis process. The viscosity of the synthesised RB-modified UF approaches RB-free UF, and consequently the adhesive system easily penetrates through agro-fibres, and provides good bonding behaviour and high performance wood product (both quality and environmental by minimising formaldehyde emission or toxic gasses during board formation).

Article
Publication date: 1 February 2005

A.H. Basta, H. El‐Saied, R.H. Gobran and M.Z. Sultan

To investigate a new approach for the prevention of lignocellulosic composites based on agro‐fibres (e.g. sugar‐cane bagasse) from the emission of toxic formaldehyde.

Abstract

Purpose

To investigate a new approach for the prevention of lignocellulosic composites based on agro‐fibres (e.g. sugar‐cane bagasse) from the emission of toxic formaldehyde.

Design/methodology/approach

Five organic polymer containing nitrogen‐urea formaldehyde (UF) adhesive systems were used as bonding agents for bagasse fibres. The environmental performance of the lignocellulosic composites prepared were evaluated in terms of the effect of the organic polymers on the percentage of free formaldehyde in the adhesive system and the adhesion properties (static bending and water resistance properties) of the composite produced, in comparison with that prepared from un‐modified UF. The nitrogen content of the polymer and the amount of organic polymers incorporated in the adhesive system were optimised using the 3D response surface methodology and the multi‐linear regression technique.

Findings

All investigated organic polymers (crude PAM‐g‐starch, PAM‐g‐starch, PAM, CE‐starch and Cm‐starch) were found to enhance the performance of the UF‐adhesive for producing environmentally friendly bagasse‐composite, whereas the reduction of free‐HCHO in UF‐adhesive systems ranges from 26 to 100 percent. The performance of the composite produced exceeded the ANSI requirements for Grade H‐3 particle‐board.

Research limitations/implications

Despite the success in improving the performance (mechanical properties and reduction of free‐formaldehyde) of the UF‐adhesive and agro‐composites, the polymers needed to be incorporated at a high percentage (12‐20 percent) resulting in reduced water resistance of the product. Further investigation is needed to resolve this problem.

Practical implications

The approach developed provided a simple and practical solution to enhancing the performance of waste agro‐fibres and commercial amino adhesive in the production of high performance lignocellulosic composite.

Originality/value

The organic polymers UF adhesive systems are novel bonding agents for agro‐fibres and could be used in timber mills for production of particle‐board and medium density fibre‐board.

Details

Pigment & Resin Technology, vol. 34 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 6 March 2017

Altaf Halim Basta, Houssni El-Saied, Amin Mahmoud Baraka and Vivian Fayez Lotfy

The purpose of this research paper focused on studying the role of activated carbons (ACs), which were synthesized from long-chain aldehyde-based xerogels (Xs-AC), as benefit…

Abstract

Purpose

The purpose of this research paper focused on studying the role of activated carbons (ACs), which were synthesized from long-chain aldehyde-based xerogels (Xs-AC), as benefit additives to enhance the application of a low-cost urea formaldehyde (UF) adhesive for production of rice straw (RS) composites complying with both the standard specifications of particle-board type and the board produced from using conventional adhesive of RS fibers (methylene diphenyl diisocyanate, MDI). The results are supported by differential scanning calorimetry (DSC) analysis, which indicated the curing and interaction of RS fibers with the adhesive systems.

Design/methodology/approach

RS-based composites of particle-board type were prepared from applying new Xs-AC–UF adhesive systems to RS particles. For comparison, particle boards by using commercial UF and 4 per cent MDI were also prepared. To clear the beneficial effect of X-ACs as new HCHO (formaldehyde)-scavengers, the properties of the resulted boards were compared with those produced from the previous investigated scavenger: amide-containing starch-UF (AM/St–UF), and treated RS. DSC analysis was performed on the RS adhesive system, to follow the curing and the interaction behavior of UF with fibers in the presence of Xs-ACs.

Findings

The promising results obtained of RS particle boards from using the investigated new HCHO-scavenger are modulus of rupture (MOR) = 17.2 MPa, modulus of elasticity (MOE) = 4,689 MPa and internal bond (IB) strength = 0.49 MPa. While, the thickness swelling (TS) and maximum reduction in free-HCHO are 48.5 and 44.6 per cent, respectively; this reduction value specified the particle-board of E1-E2 type.

Research limitations/implications

The X-AC-UF adhesive systems and treated RS provided particle boards with mechanical properties (MOR, MOE and IB) that met the standard specification values (class M-2 according to ANSI standard and P-2 according to EN standard requirements), together with maximum reduction in toxicity of UF. However, the resistance in water swelling property is weak and needs further study to be solved.

Practical implications

The incorporation of small percentage of new HCHO-scavenger (X-AC) to UF is an effective way to improve its thermal behavior. Moreover, the mechanical properties of agro-based composites based on the treated RS waste together with the X-AC-UF system exceeded those values of panels produced from (AM/St-UF) and also from (4 per cent MDI).

Social implications

Incorporating the Xs-AC to commercial UF will be of benefit for saving the health of wood co-workers and motivating the wood mill to export its wood products, as well as minimizing the export of MDI.

Originality/value

This paper was based on enhancing the potential utilization of both undesirable RS agro wastes and environmentally unacceptable low-cost UF adhesive in the production of agro-composites that comply with the International Standard Specifications of particle board type. In this respect, a new HCHO-scavenger was synthesized and applied, based on AC from non-conventional xerogels. This study presents a solution to protect the environment from pollution, as a result of burning the undesirable RS, as well as to protect the workers and users of wood panels from exposure to the toxic and carcinogenic gas (formaldehyde). It also benefits in replacing the high cost of the RS adhesive (MDI) by using low-cost modified UF.

Article
Publication date: 1 July 2014

Altaf H. Basta, Houssni El-Saied and Emad M. Deffallah

The purpose of this paper is to prepare high-performance agro-based composites from the non-toxic rice bran-urea-formaldehyde (RB-UF) adhesive system. Investigations have…

Abstract

Purpose

The purpose of this paper is to prepare high-performance agro-based composites from the non-toxic rice bran-urea-formaldehyde (RB-UF) adhesive system. Investigations have continued for production high performance agro-based composites using environmentally acceptable approaches. The utilisation of such system with the available used local agro-based wood products (sugar-cane bagasse, SCB) adds economic value and helps reducing the environmental impact of commercial urea-formaldehyde (UF) adhesive, and most importantly, provides a potentially inexpensive alternative to the existing commercial artificial wood-panel mills.

Design/methodology/approach

Optimising the process for incorporating the RB in UF, as wood adhesive for binding the bagasse fibres, was carried out, by partially replacing commercial UF by denaturalised RB in slurry (wet) and dry form or through synthesis of UF. The denaturalisation of RB was carried out at different pHs (10-11) and at temperature 60°C for two hours. While incorporating the RB during synthesis of UF, it was carried out according to the method reported elsewhere. The formulation of adhesive components, pH value of the denaturalisation stage and the process of incorporating the RB were optimised. Assessment of the role of RB adhesive was specified from its free-formaldehyde (HCHO) content, as well as the properties (mechanical and physical properties) of the produced composites of bagasse particle board type, in comparison with the environmental impact of commercial thermosetting resin (UF).

Findings

The promising adhesive system exhibits improvement in the environmental performance (as E1 type) over a commercially UF adhesive (as E2 type), besides providing boards fulfill the requirements of grade H-3 (according to ANSI A208.1 (NPA1993). This adhesive system was resulted from replacing 30 per cent of UF by denalturalised RB (at pH 10) in slurry form. Where, its reduction in free-HCHO reached 53 per cent, as well as modulus of rupture (MOR), modulus of elasticity (MOE), internal bond (IB) and TS of the produced boards were approximately 24.2 N/mm2, approximately 3753 N/mm2, approximately 0.84 N/mm2 and approximately 11.4 per cent, respectively.

Research limitations/implications

The eco-adhesive with relatively high percentage of low-cost commercial UF (70 per cent) and 30 per cent RB, as oil production by-product, in slurry form provides good board strength and is environmentally friendly compared to SCB-based composite properties, with that produced from commercial UF. The mechanical (MOR, MOE and IB) and water-resistance properties of the produced composite comply with the standard values.

Practical implications

The approach provided low HCHO-free UF adhesive with good comparative board strength and water resistance and reasonable working life. Replacing 30 per cent of UF by RB in slurry form and denaturalised at pH 10 is considered a promising inexpensive alternate adhesive (as E1) in the wood industry based on SCB wastes.

Social implications

Incorporating the RB by-product of oil production to commercial UF will be beneficial for saving the health of wood co-workers and motivating the wood mill to export its wood products.

Originality/value

It provided a potentially simple way to improve both the utilisation of commercial UF and SCB as industrial substrates for particle-board production. This will benefit farmers, local wood mills in Upper Egypt, significantly. Meanwhile, incorporating low percentage of RB, as oil-mill by-products, is promising to partly replace UF resin in the wood industry, minimising formaldehyde emission or toxic gasses during board formation.

Details

Pigment & Resin Technology, vol. 43 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 April 1990

J.D. Holly

The spent electroless copper bath is deactivated at the overflow by the automatic addition of hydrogen peroxide (H2O2) to prevent copper from plating out in the drain lines…

Abstract

The spent electroless copper bath is deactivated at the overflow by the automatic addition of hydrogen peroxide (H2O2) to prevent copper from plating out in the drain lines, causing the lines to become blocked. Caustic (NaOH) and formaldehyde (HCHO) are then added to the deactivated electroless copper solution in a batch treatment process. Powdered aluminium or aluminium fines are added to precipitate out the copper as metallic copper. The copper concentration (<1 ppm) can be made stable for several days if necessary. The metallic copper is filtered out and salvaged. The mother liquor is neutralised (pH 6·5–9·0) and discharged. United States patent applied for, 07–345865.

Details

Circuit World, vol. 17 no. 1
Type: Research Article
ISSN: 0305-6120

Open Access
Article
Publication date: 6 March 2024

Chuloh Jung, Muhammad Azzam Ismail, Mohammad Arar and Nahla AlQassimi

This study aims to evaluate the efficiency of various techniques for enhancing indoor air quality (IAQ) in construction. It analyzed the alterations in the concentration of indoor…

Abstract

Purpose

This study aims to evaluate the efficiency of various techniques for enhancing indoor air quality (IAQ) in construction. It analyzed the alterations in the concentration of indoor air pollutants over time for each product employed in controlling pollution sources and removing it, which included eco-friendly substances and adsorbents. The study will provide more precise and dependable data on the effectiveness of these control methods, ultimately supporting the creation of more efficient and sustainable approaches for managing indoor air pollution in buildings.

Design/methodology/approach

The research investigates the impact of eco-friendly materials and adsorbents on improving indoor air quality (IAQ) in Dubai's tall apartment buildings. Field experiments were conducted in six units of The Gate Tower, comparing the IAQ of three units built with “excellent” grade eco-friendly materials with three built with “good” grade materials. Another experiment evaluated two adsorbent products (H and Z) in the Majestic Tower over six months. Results indicate that “excellent” grade materials significantly reduced toluene emissions. Adsorbent product Z showed promising results in pollutant reduction, but there is concern about the long-term behavior of adsorbed chemicals. The study emphasizes further research on household pollutant management.

Findings

The research studied the effects of eco-friendly materials and adsorbents on indoor air quality in Dubai's new apartments. It found that apartments using “excellent” eco-friendly materials had significantly better air quality, particularly reduced toluene concentrations, compared to those using “good” materials. However, high formaldehyde (HCHO) emissions were observed from wood products. While certain construction materials led to increased ethylbenzene and xylene levels, adsorbent product Z showed promise in reducing pollutants. Yet, there is a potential concern about the long-term rerelease of these trapped chemicals. The study emphasizes the need for ongoing research in indoor pollutant management.

Research limitations/implications

The research, while extensive, faced limitations in assessing the long-term behavior of adsorbed chemicals, particularly the potential for rereleasing trapped pollutants over time. Despite the study spanning a considerable period, indoor air pollutant concentrations in target households did not stabilize, making it challenging to determine definitive improvement effects and reduction rates among products. Comparisons were primarily relative between target units, and the rapid rise in pollutants during furniture introduction warrants further examination. Consequently, while the research provides essential insights, it underscores the need for more prolonged and comprehensive evaluations to fully understand the materials' and adsorbents' impacts on indoor air quality.

Practical implications

The research underscores the importance of choosing eco-friendly materials in new apartment constructions for better IAQ. Specifically, using “excellent” graded materials can significantly reduce harmful pollutants like toluene. However, the study also highlights that certain construction activities, such as introducing furniture, can rapidly elevate pollutant levels. Moreover, while adsorbents like product Z showed promise in reducing pollutants, there is potential for adsorbed chemicals to be rereleased over time. For practical implementation, prioritizing higher-grade eco-friendly materials and further investigation into furniture emissions and long-term behavior of adsorbents can lead to healthier indoor environments in newly built apartments.

Originality/value

The research offers a unique empirical assessment of eco-friendly materials' impact on indoor air quality within Dubai's rapidly constructed apartment buildings. Through field experiments, it directly compares different material grades, providing concrete data on pollutant levels in newly built environments. Additionally, it explores the efficacy of specific adsorbents, which is of high value to the construction and public health sectors. The findings shed light on how construction choices can influence indoor air pollution, offering valuable insights to builders, policymakers and residents aiming to promote public health and safety in urban living spaces.

Details

Smart and Sustainable Built Environment, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2046-6099

Keywords

Article
Publication date: 1 October 1996

Natasa Kalinic and Kresimir Sega

Presents the results of formaldehyde (HCHO) concentration measurements undertaken in ten kindergartens and ten primary schools (one room in each) during the summer and the winter…

210

Abstract

Presents the results of formaldehyde (HCHO) concentration measurements undertaken in ten kindergartens and ten primary schools (one room in each) during the summer and the winter periods. The buildings were of differing age (1‐100 years) and structure (from conventional to prefabricated type), and particle‐board furniture was used in all premises. Results show that the proposed limit value of 120 μg/m3, recommended by WHO for living accommodation, was frequently exceeded. The seasonal differences of concentrations were statistically significant for nine kindergartens and seven schools.

Details

Environmental Management and Health, vol. 7 no. 4
Type: Research Article
ISSN: 0956-6163

Keywords

Article
Publication date: 18 July 2022

Laina Hilma Sari, Brit Anak Kayan and Zahriah Zahriah

During the COVID-19 pandemic in 2020–2021 in Indonesia, the indoor environmental quality (IEQ) of local houses occupied by infected occupants was adversely affected. This paper…

Abstract

Purpose

During the COVID-19 pandemic in 2020–2021 in Indonesia, the indoor environmental quality (IEQ) of local houses occupied by infected occupants was adversely affected. This paper aims to appraise the IEQ of the affected Banda Aceh houses with insights into enabling them to be resilient against the negative impacts of the pandemic.

Design/methodology/approach

Quantitative field measurement in the case study of five concrete houses located in urban areas which are affected by IEQ factors: (1) indoor air quality (IAQ), (2) thermal comfort and (3) visual comfort, compared against the Indonesian National standard (SNI). The case study involved measurement of the first two factors over 24 h, while the third factor was measured during sun hours. Considering the limitations of the measuring tools for logging available data in this research, air quality is measured from 8 am to 10 pm.

Findings

Thermal comfort in the affected houses is generally regarded as warm, optimal and cool comfort, indicated by the effective temperatures of between 20.5 and 27.1°C. Frequently closed windows, limited land area and access had caused a lack of air circulation, with air velocity of dominantly 0 m/s in the houses. The illuminance of natural light received in three houses was insufficient – less than 120 lux as compared with the other two. This study found an uptrend of higher air temperature and relative humidity in the affected houses resulting in poorer IAQ; conversely, the higher the air velocity in the houses, the fewer the indoor air pollutants such as formaldehyde (HCHO), total volatile organic compounds (TVOC) and carbon dioxide (CO2).

Originality/value

This study is a pioneer in evaluating IEQ in houses occupied by COVID-19 patients in Indonesia, especially in dwelling cases in Aceh Province. It also encompasses environmental and societal challenges to sustaining resilient buildings in pandemic hit regions.

Details

International Journal of Building Pathology and Adaptation, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2398-4708

Keywords

Article
Publication date: 8 July 2022

Syafiqah Ishak, Shazlina Johari, Muhammad Mahyiddin Ramli and Darminto Darminto

This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film…

Abstract

Purpose

This review aims to give an overview about zinc oxide (ZnO) based gas sensors and the role of doping in enhancing the gas sensing properties. Gas sensors based on ZnO thin film are preferred for sensing applications because of their modifiable surface morphology, very large surface-to-volume ratio and superior stability due to better crystallinity. The gas detection mechanism involves surface reaction, in which the adsorption of gas molecules on the ZnO thin film affects its conductivity and reduces its electrical properties. One way to enhance the gas sensing properties is by doping ZnO with other elements. A few of the common and previously used dopants include tin (Sn), nickel (Ni) and gallium (Ga).

Design/methodology/approach

In this brief review, previous works on doped-ZnO formaldehyde sensing devices are presented and discussed.

Findings

Most devices provided good sensing performance with low detection limits. The reported operating temperatures were within the range of 200̊C –400̊C. The performance of the gas sensors can be improved by modifying their nanostructures and/or adding dopants.

Originality/value

As of yet, a specific review on formaldehyde gas sensors based on ZnO metal semiconductors has not been done.

Details

Sensor Review, vol. 42 no. 5
Type: Research Article
ISSN: 0260-2288

Keywords

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