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This paper aims to investigate the effects of different electrolyte systems on the properties of micro-arc oxidation coating on 7050 high strength aluminum alloy.

The coatings were prepared in silicate system with Na₂SiO₃ as main component, borate system with Na2B4O7 as main component and aluminate solution with Na₂AlO₂ as main salt, respectively.

The results show that the 7050 high strength aluminum alloy shows the best properties in silicate system.

This manuscript studied the crucial influence of different electrolyte systems on the microstructure and properties of the aluminum alloy micro-arc oxidation layer.

The purpose of this paper is a theoretical modeling use of electrochemical impedance spectroscopy (EIS) technique for different cases that could describe the possible electrochemical behaviour on steel coated with metallic and oxide thin films (of nickel) deposited by magnetron sputtering, and compare them to know if the theoretical analysis resembles the real case. It is extremely important to clarify that such simulations do not consider the use of the constant phase element (CPE) for the analysis. Therefore, the goal for the theoretical models should be to gain acceptance in electrochemical research.

In order to obtain the equivalent circuits to explain the different possible behaviours of the films and their protective properties in sour media, EIS experimental data were correlated with data from the simulation software. The different nickel and nickel oxide thin films were tested after their deposition by magnetron sputtering on low‐carbon steel and after they had then been exposed to the sour media electrolyte of NaCl 3 wt% + H₂S (saturated).

The EIS simulation starts from the laboratory evaluation of nickel and nickel oxide thin films as anticorrosive protection for low‐carbon steel exposed to sour media. From these results, it is found that the nickel and nickel oxide films could adopt seven different behaviours, and all are possible to occur.

The equivalent circuits proposed will give an insight into the corrosion phenomena for different metals coated with thin films and exposed to sour media, because all of the simulations are made on the basis of real EIS results.

The electrical analysis in the simulation diagram did not consider the use of the CPE to adjust the plots. In consequence, the values of all parameters for the seven different adjustments obtained through the simulations establish a reference for the explanation of the corrosion phenomena. They are also a tool with which to predict the possible behaviour of a thin film deposited on metal and exposed to electrolytes that are as aggressive as sour media.

This paper aims at analyzing the potential of new materials in magnesium-ion batteries (MIBs) with a particular focus on options for electrodes and electrolyte solutions while also carefully considering the barriers to their entry in this application for MIBs, with a particular focus on the material options for electrodes and electrolyte solutions.

Potential materials for MIBs were examined for sustainability, safety and efficiency to develop the sustainable and well-working MIBs.

For anode materials, the use of Mg-bismuth alloys has shown promise, whereas Chevrel phases or layered molybdenum disulfide have potential as cathode materials. Potential electrolytes range from traditional materials to the development of tailored solid-state and liquid-based options.

This study considers the growing need for Mg-based ion batteries, as well as the need for suitable electrode and electrolyte materials and analyzes suitable options.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-03-2023-0081/

IT is well known that gas mains which carry petroleum gases containing hydrogen sulphide are subject to strong corrosion by the latter; their normal life is of the order of a few years but, in places where condensate collects, the main may show penetration within a few months.

The aim of this paper is to study and analyse the advantages and limitations of the scanning reference electrode technique (SRET) to detect and assess localised electrochemical activity based on an evaluation of the influence of the principal test parameters on the sensitivity and resolution of the technique.

Measurements of Ohmic potential gradients induced by ionic flux close to a point current source (PCS) were carried out using a scanning reference electrode technique (SRET) instrument, which comprised a vertical rotating working electrode and a scanning probe formed by a pair of platinum electrodes of approximately 200 μm of diameter. Ionic flux was induced by anodic polarisation applied to a gold micro‐disc electrode, which acted as the PCS. Measurements were conducted in electrolytes of ten different conductivities, using different scanning probe tips to sample surface distance and different working electrode rotation rates. The range of conductivities used included most of the possible electrolytes to which metallic materials can be in contact under real service conditions.

The SRET signal sensed from a polarised PCS showed a strong dependence on the rotation rate of the working electrode for electrolytes of low conductivity but a minimal effect on electrolytes with conductivities higher than 50 mS/cm.

This work presents the effect of wide variations on the electrochemical and operational conditions on the sensitivity and resolution of SRET signal response and discusses the limitations of the technique to assess localised electrochemical activity due to the effect of high conductivity electrolytes, large separation distance between the SRET scanning probe and developing dissolution and scanning rate of a the localised site.

This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.

The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.

Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.

In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.

It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.

Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.

This study aims to apply an electrochemical grinding (ECG) technology to improve the material removal rate (MRR) under the premise of certain surface roughness in machining U71Mn alloy.

The effects of machining parameters (electrolyte type, grinding wheel granularity, applied voltage, grinding wheel speed and machining time) on the MRR and surface roughness are investigated with experiments.

The experiment results show that an electroplated diamond grinding wheel of 46# and 15 Wt.% NaNO₃ + 10 Wt.% NaCl electrolyte is more suitable to be applied in U71Mn ECG. And the MRR and surface roughness are affected by machining parameters such as applied voltage, grinding wheel speed and machining time. In addition, the maximum MRR of 0.194 g/min is obtained with the 15 Wt.% NaCl electrolyte, 17 V applied voltage, 1,500 rpm grinding wheel speed and 60 s machining time. The minimum surface roughness of Ra 0.312 µm is obtained by the 15 Wt.% NaNO₃ + 10 Wt.% NaCl electrolyte, 13 V applied voltage, 2,000 rpm grinding wheel speed and 60 s machining time.

Under the electrolyte scouring effect, the products and the heat generated in the machining can be better discharged. ECG has the potential to improve MRR and reduce surface roughness in machining U71Mn.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-10-2023-0341/

The purpose of this paper is to present a summary of development work made in technical centres and on the subsequent customer qualification of copper filled through holes and blind microvias.

Various copper deposition parameters were investigated in a small‐scale production line which was then extended to full‐scale production qualification in a horizontal conveyorised system. Samples of substrates with copper filled through holes were qualified at end‐user facilities.

The copper plating process may be used to replace an existing production process for printed circuit boards. The proposed system can give a more reliable result in terms of filling and technical capability for the produced substrate. Overall production cost savings are possible.

The technology is based on a copper plating electrolyte using a redox pair for copper replenishment. The results achieved depend on use of this system and on production equipment which can control the redox system and copper concentration within a tight range.

The paper shows how the use of a horizontal production system with redox copper replenishment can achieve filling of though holes and blind microvias with reduced surface plated copper thickness. Reduction in the use of copper saves both resources and also reduces production costs. The process is proposed as an alternative to existing paste plugging processes, which are both cost and labour intensive.

The purpose of this study is analysis of deformation and vibrations of turbine blades produced by high electrolyte pressure during electrochemical machining.

An experimental setup was designed, experiments were conducted and the obtained results were compared with the finite element results. The deformations were measured according to various flow rates of electrolyte. In finite element calculations, the pressure distribution created by the electrolyte on the blade surface was obtained in the ANSYS® (A finite element analysis software) Fluent software and transferred to the static structural where the deformation analysis was carried out. Three different parameters were examined, namely blade thickness, blade material and electrolyte pressure on blade disk caused by mass flow rate. The deformation results were compared with the gap distances between cathode and anode.

Large deformations were obtained at the free end of the blade and the most curved part of it. The appropriate pressure values for the electrolyte to be used in the production of blisk blades were proposed numerically. It has been determined that high pressure applications are not suitable for gap distance lower than 0.5 mm.

When the literature is examined, it is required that the high speed flow of the electrolyte is desired in order to remove the parts that are separated from the anode from the machining area during electrochemical machining. However, the electrolyte flowing at high speeds causes high pressure in the blisk blades, excessive deformation and vibration of the machined part, and as a result, contact of the anode with the cathode. This study provides important findings for smooth electro chemical machining at high electrolyte flows.

The purpose of this paper is to show the main features of the redox flow battery technology, present the current state-of-the-art of both industrial and research systems and to highlight the main research challenges.

The study is based on an extensive survey of recent literature as well as on the authors' own experience in the modelling of RFB systems.

RFBs present unique features which make them suitable for distributed storage and thus particularly interesting in the context of smart grids. Current research aims at resolving some outstanding issues which still limit the widespread use of RFBs.

A more widespread use of energy storage technologies, and RFBs in particular, will allow a much higher penetration of renewable energy sources.

The paper presents one of the few comprehensive studies on RFBs including both technological and modelling aspects.