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1 – 10 of over 1000The Huyen Nguyen, Tuan Anh Nguyen, Van Khu Le, Thi Mai Thanh Dinh, Hoang Thai, Xianming Shi and The Huu Nguyen
This work aims to demonstrate the use of electrochemical chloride extraction (ECE) to remove chloride ions away from the steel rebar in chloride-contaminated mortar and to…
Abstract
Purpose
This work aims to demonstrate the use of electrochemical chloride extraction (ECE) to remove chloride ions away from the steel rebar in chloride-contaminated mortar and to mitigate the corrosion of the embedded steel.
Design/methodology/approach
To simulate salt contamination in concrete, sodium chloride was added at 0.5 per cent by weight of cement in the fresh mortar featuring a water-to-cement ratio of 0.45. The ECE treatments were varied at two electrical current densities (1 and 5 A/m2), using two electrolytes (0.1M NaOH and 0.1M Na3BO3 solutions) and for two periods (2 and 4 weeks). The average free chloride concentration in cement mortars before and after ECE treatment was quantified using a customized chloride sensor, whereas the spatial distribution of relevant elements was obtained using energy-dispersive X-ray spectroscopy. The effect of ECE treatment on the electric resistivity of mortar and the corrosion resistance of steel rebar was investigated by electrochemical impedance spectroscopy and potentiodynamic polarization measurements, respectively.
Findings
The experimental results reveal that the ECE treatment was effective in removing chlorides and in improving electric resistivity and compressive strength of the mortar, when using the sodium borate solution as the electrolyte. In this case, a 4-week ECE treatment at 1 A/m2 decreased the free chloride content in the mortar by 70 per cent, significantly increased the Ca/Si ratio in the mortar near rebar, led to a more refined and less permeable microstructure of the mortar and significantly improved its compressive strength. The ECE treatment was able to halt the chloride-induced corrosion of steel rebar by passivation. A 4-week ECE treatment at 1 A/m2 using sodium hydroxide and sodium borate solutions decreased the corrosion rate of rebar by 36 and 34 per cent, respectively.
Originality/value
This electrochemical rehabilitation of steel-reinforced concrete under chloride-contaminated condition is very effective in prolonging its service life.
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Wei Zhang, Weiwei Lv, Xiaoyan Li and Jiming Yao
In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical…
Abstract
Purpose
In this study, the oxidative degradation performance of indigo wastewater based on electrochemical systems was explored. The decolourization degrees, removal rate of chemical oxygen demand and biochemical oxygen demand of the indigo wastewater after degradation were evaluated and optimized treatment conditions being obtained.
Design/methodology/approach
The single factor method was first used to select the electrolyte system and electrode materials. Then the response surface analysis based on Box–Behnken Design was chosen to determine the influence of four independent variables such as FeCl3 concentration, NaCl concentration, decolourization time and voltage on the degradation efficiency.
Findings
On the basis of single factor experiment, the electrode material of stainless steel was selected in the double cell, and the indigo wastewater was electrolyzed with FeCl3 and NaCl electrolytes. The process conditions of electrochemical degradation of indigo wastewater were optimized by response surface analysis: the concentration of FeCl3 and NaCl was of 16 and 9 g/L, respectively, with a decolourization time of 50 min, voltage of 10 V and decolourization percentage of 98.94. The maximum removal rate of chemical oxygen demand reached 75.46 per cent. The highest ratio of B/C was 3.77, which was considered to be more biodegradable.
Research limitations/implications
Dyeing wastewater is bringing out more and more pollution problems to the environment. However, there are some shortcomings in traditional technologies such as adsorption and filtration. As a kind of efficient and clean water treatment technology, electrochemical oxidation has been applied to the treatments of various types of wastewater. The decolourization and degradation of indigo wastewater is taken as an example to provide reference for the treatment of wastewater in actual plants.
Practical implications
The developed method provided a simple and practical solution for efficiently degrading indigo wastewater.
Originality/value
The method for the electrochemical oxidation technology was novel and could find numerous applications in the degradation of printing and dyeing wastewater.
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Maryam Khashij, Mohammad Hossein Salmani, Arash Dalvand, Hossien Fallahzadeh, Fatemeh Haghirosadat and Mehdi Mokhtari
This paper aims to investigation of processes for Pb2+ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb2+ ions by…
Abstract
Purpose
This paper aims to investigation of processes for Pb2+ elimination from water/wastewater as a significant public health issue in many parts of world. The removal of Pb2+ ions by various nanocomposites has been explained from water/wastewaters. ZnO-based nanocomposites, as eco-friendly nanoparticles with unique physicochemical properties, have received increased attention to remove Pb2+ ions from water/wastewaters.
Design/methodology/approach
In this review, different ZnO-based nanocomposites were reviewed for their application in the removal of Pb2+ ions from the aqueous solution, typically for wastewater treatment using methodology, such as adsorption. This review focused on the ZnO-based nanocomposites for removing Pb2+ ions from water and wastewaters systems.
Findings
The ZnO-based nanocomposite was prepared by different methods, such as electrospinning, hydrothermal/alkali hydrothermal, direct precipitation and polymerization. Depending on the preparation method, various types of ZnO-based nanocomposites like ZnO-metal (Cu/ZnO, ZnO/ZnS, ZnO/Fe), ZnO-nonmetal (PVA/ZnO, Talc/ZnO) and ZnO-metal/nonmetal (ZnO/Na-Y zeolite) were obtained with different morphologies. The effects of operational parameters and adsorption mechanisms were discussed in the review.
Research limitations/implications
The findings may be greatly useful in the application of the ZnO-based nanocomposite in the fields of organic and inorganic pollutants adsorption.
Practical implications
The present study is novel, because it investigated the morphological and structural properties of the synthesized ZnO-based nanocomposite using different methods and studied the capability of green-synthesized ZnO-based nanocomposite to remove Pb2+ ions as water contaminants.
Social implications
The current review can be used for the development of environmental pollution control measures.
Originality/value
This paper reviews the rapidly developing field of nanocomposite technology.
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Wei Zhang, Mengdi Zhang, Zhijie Huangfu, Jiming Yao and Yuan Xie
This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.
Abstract
Purpose
This study aims to explore suitable anode materials used in the electrochemical system for indigo dyeing wastewater, to achieve optimal treatment performances.
Design/methodology/approach
The single factor experiment was used to explore the optimum process parameters for electrochemical decolorization of indigo dyeing wastewater by changing the applied voltage, electrolysis time and electrolyte concentration. At the voltage of 9 V, the morphology of flocs with different electrolytic times was observed and the effect of electrolyte concentration on decolorization rate in two electrolyte systems was also investigated. Further analysis of chemical oxygen demand (COD) removal rate, anode weight loss and sediment quantity after electrochemical treatment of indigo dyeing wastewater were carried out.
Findings
Comprehensive considering the decolorization degree and COD removal rate of the wastewater, the aluminum electrode showed the best treatment effect among several common anode materials. With aluminum electrode as an anode, under conditions of applied voltage of 9 V, electrolysis time of 40 min and sodium sulfate concentration of 6 g/L, the decolorization percentage obtained was of 94.59% and the COD removal rate reached at 84.53%.
Research limitations/implications
In the electrochemical treatment of indigo dyeing wastewater, the aluminum electrode was found as an ideal anode material, which provided a reference for the choice of anodes. The electrodes used in this study were homogenous material and the composite material anode needed to be further researched.
Practical implications
It provided an effective and practical anode material choice for electrochemical degradation of indigo dyeing wastewater.
Originality/value
Combined with the influence of applied voltage, electrolysis time and electrolyte concentration and anode materials on decolorization degree and COD removal rate of indigo dyeing wastewater, providing a better electrochemical treatment system for dyehouse effluent.
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M.A. Kewther, B.S. Yilbas and M.S.J. Hashmi
Inconel 617 alloy is widely used in industry due to its superior high temperature properties. After long periods of operation, the alloy microstructure changes. One of the methods…
Abstract
Inconel 617 alloy is widely used in industry due to its superior high temperature properties. After long periods of operation, the alloy microstructure changes. One of the methods to regain the alloy microstructure is heat treatment at elevated temperatures. In the present study, electrochemical and mechanical responses of Inconel 617 alloy over 30,000 hours of operation as a transition‐piece in agas turbine engine are examined. The heat treatment process at two different temperature levels is applied when refurbishing the alloy microstructure. The electrochemical tests are conducted to investigate the corrosion response of the alloy before and after the heat treatment process. Fatigue and tensile tests are carried out for the workpieces subjected to the electrochemical tests. SEM is introduced to examine the fractured surfaces.
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Qi Gongtai and Qiu Yubin
The purpose of this paper is to consider the effect of heat treatment on alloying element distribution and the electrochemical properties of Al‐5Zn‐0.03In anodes.
Abstract
Purpose
The purpose of this paper is to consider the effect of heat treatment on alloying element distribution and the electrochemical properties of Al‐5Zn‐0.03In anodes.
Design/methodology/approach
The Al‐5Zn‐0.03In alloy anodes are treated at 510°C for 10 h, then cooled in water. Electron probe microanalysis of JXA‐8800 and EDAX quantitative energy dispersive X‐ray analysis is used to examine the microstructure of the anodes before and after heat treatment, and the electrochemical properties of the anodes are tested.
Findings
By heat treatment, the solubility of Zn in aluminum is increased while the solubilities of Fe and Si are changed only slightly. The quantity of the Al‐Zn intermetallic compounds is evidently decreased and the Al‐Fe‐Si intermetallic compound is preserved. Strip segregation along grain boundaries is changed to spherical particulates. The attack of aluminum anodes initiates and propagates in grain boundaries and interdendritic zones, which are enriched in In and Zn, so the current efficiency of the aluminum anodes is related to the degree of corrosion taking place at grain boundaries and the extent of exfoliation of grains. The greater the extent of Al‐Zn metallic compounds that are present at grain boundaries, the more sensitive to grain boundary corrosion is the alloy and the greater the degree of desquamation of grains, the lower is the current efficiency of the aluminum anode.
Originality/value
The results of this paper clarify the role of water‐quenching affect on the microstructure and electrochemical properties of Al‐Zn‐In anodes.
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Lutfiye Canan Pekel, Suna Ertunc, Zehra Zeybek and Mustafa Alpbaz
The purpose of this paper is to investigate the electrochemical treatment of textile dye wastewater in the presence of NaCl electrolyte by using aluminium electrodes.
Abstract
Purpose
The purpose of this paper is to investigate the electrochemical treatment of textile dye wastewater in the presence of NaCl electrolyte by using aluminium electrodes.
Design/methodology/approach
The electrochemical treatment of textile dye wastewater was optimized using response surface methodology (RSM). RSM‐based D‐optimal design was employed to construct statistical models relating turbidity and designed effective parameters known as current density, electrolyte concentration and electrolysis time. The experimental plan consists of a three‐factor (three numerical) matrix.
Findings
The results show that the current density has significant effect on the reduction of turbidity. Besides, electrolysis time is the most influential factor on the turbidity. In order to enhance the electrochemical treatment performance, no coagulant addition or further physicochemical processes were employed.
Originality/value
Industrial certain textile dye wastewater in Turkey is used to determine optimal values.
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Keywords
Zhijie Huangfu, Wei Zhang, Shang Hao, Mengdi Zhang and Jiming Yao
This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to…
Abstract
Purpose
This study aims to evaluate the efficiency of metal electrode and electrolytes on the electroflocculation of indigo wastewater, produced by printing and dyeing factory, and to optimize the treatment system.
Design/methodology/approach
For effective purging, various types of metal electrodes (graphite, pure aluminum and stainless steel) and supporting electrolytes (sodium chloride and sodium sulfate) were selected for electroflocculation experiments. The decolorization rate and chemical oxygen demand (COD) removal rate were characterized.
Findings
The treatment effects of stainless steel and aluminum were similar, but the dissolution loss of aluminum and the production of flocs greatly limit its application. Electrolytes gave obvious effects to these systems. Sodium sulfate was better than sodium chloride, the decolorization rate was increased by 3.31%, the removal rate of COD in the solution was increased by 28.65% and the weight of flocculation precipitation was reduced by 0.214 g.
Research limitations/implications
The electrochemical treatment system was constructed to compare and analyze the influence of experimental parameters and to provide a reference for the actual treatment of indigo wastewater.
Practical implications
Electrochemical flocculation can remove the insoluble indigo solids and it plays a key role in wastewater treatment.
Originality/value
It is novel to optimize the combination of electrode and electrolyte to improve the efficiency of electroflocculation, which can be widely used in the actual wastewater treatment process.
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Wilian da Silva Labiapari, Henara Lillian Costa and José Daniel Biasoli De Mello
The progressive wear of cutting tools used in industrial cutlery production results in excessive burr formation and reduces tool service life. This paper aims to investigate the…
Abstract
Purpose
The progressive wear of cutting tools used in industrial cutlery production results in excessive burr formation and reduces tool service life. This paper aims to investigate the effects of the sheet surface finish on tool wear and service life during blanking.
Design/methodology/approach
Two alternative surface finish techniques were proposed and initially implemented under laboratorial conditions and compared with conventional acid pickling. Those surface finish techniques were then implemented on an industrial scale to improve the service life of cutting tools. Industrial blanking tests characterized the effect of sheet surface finish on tool life.
Findings
In the first technique, called skin pass, an additional mechanical pass under controlled conditions reduced the height of the surface peaks and resulted in partial embedding of the carbides into the surface. The second technique, called electrochemical pickling, removed solely the surface carbides, leaving behind a smoother surface without carbides. Real industrial blanking tests identified that the use of skin pass reduced burr formation and increased tool life by around 300 per cent when compared with conventional acid pickling. With electrochemical pickling, burr formation was further reduced and tool life increased further by 300 per cent when compared with skin pass.
Research limitations/implications
First, this work proposes an alternative surface finishing technique (electrochemical pickling) to be used after annealing of stainless steel. Second, the work clearly shows the presence of protruding surface carbides when conventional surface finishing techniques are used, which do not exist after acid pickling.
Practical implications
When electrochemical pickling is implemented on an industrial scale, the life of blanking tools is substantially improved.
Originality/value
Although the sheet surface finish is widely recognized to affect metalforming processes, the literature lacks studies on the effect of sheet surface finish on tool wear during blanking. First, this work proposes an alternative surface finishing technique (electrochemical pickling) to be used after annealing of stainless steel. Second, the work clearly shows the presence of protruding surface carbides when conventional surface finishing techniques are used, which do not exist after acid pickling. Third, when electrochemical pickling is implemented on an industrial scale, the life of blanking tools is substantially improved.
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Weiwei Lv, Zhijie Huangfu, Kangkang Wang, Wei Zhang and Jiming Yao
Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.
Abstract
Purpose
Indirect electrochemical oxidation and electro-flocculation were combined to degrade indigo wastewater.
Design/methodology/approach
The degradation efficiency of indigo wastewater in single-cell and double-cell were investigated. Based on the previous single factor experiments, the oxidative degradation conditions of indigo wastewater in single cell were optimized by response surface methodology (RSM). The decolorization rate, chemical oxygen demand (COD) removal rate, the contents of flocculation precipitation and indigo were measured and analyzed.
Findings
The degradation efficiency in single cell was higher than in double cell. The electrolysis conditions were optimized by RSM and the decolorization rate was 99.01% with COD removal rate of 60.34% and conductivity of 89.75 mS/cm. The amount of flocculated precipitation decreased by 53.33% and the indigo increased by 86.34%. The content of Na and S decreased by 12.13 and 6.49%, respectively. The ratio of Fe3+ to Fe2+ in the solution was 4.62:1, indicating that most of the iron dropped on the electrode sheet was converted to Fe3+.
Research limitations/implications
The one-step electrochemical oxidation and flocculation method with the advantages of simple operation and environmental protection, provided a reference for the actual treatment of dyeing wastewater.
Practical implications
Combining the electrochemical flocculation and oxidation provided an efficient and practical solution for degradation of indigo wastewater.
Originality/value
Combining the advantages of electrochemical oxidation and electroflocculation, the application of electrochemistry in printing and dyeing wastewater treatment technology has been expanded.
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