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1 – 10 of 26Manal El-Zawahry and Hager Gamal
This paper aims to focus on the aqueous extraction of natural dye from haematoxylum campechianum L. bark for finishing the bio-mordant cotton fabrics producing value-added…
Abstract
Purpose
This paper aims to focus on the aqueous extraction of natural dye from haematoxylum campechianum L. bark for finishing the bio-mordant cotton fabrics producing value-added, environment-friendly textile products, for biomedical applications.
Design/methodology/approach
The study focuses on the creation of eco-friendly bio-mordant cotton fabric using gallic acid and gelatin, Al3+ and Fe2+ salts and metal mordant. The optimal pH for extraction, structural characterization and phytochemical analysis of the extracted dye were estimated using UV-visible spectrophotometer, FTIR and qualitative analysis. Variations in electrolyte concentration and pH medium were also considered. The study also examines build-up properties, colorimetric values and fastness characteristics of the colored fabrics.
Findings
All the dyed fabrics exhibit very good to excellent in terms of antimicrobial resistance against S. aureus and C. allbicans.
Practical implications
Pre-mordant cotton fabrics with Fe2+ and a combination of metal and bio-mordant show higher antibacterial resistance against P. aerugionsa. Further, bio-mordant and a combination of both mordant exhibit excellent UV protection and antioxidant activity performance compared to that of undyed fabrics.
Originality/value
This work opens up a huge potential for producing healthy bioactive-colored fabrics used in medical textiles and other usages.
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Ali A. Ali, H. Abd El-Wahab, Moustafa S. Abusaif, Ahmed Ragab, Omar A. Abdel-Jaid, E.A. Eldeeb and Yousry A. Ammar
The paper aims to the preparation of novel disperse dye based on azo salicylaldehyde derivatives TF-A [2-hydroxy-5-((3-(trifluoromethyl)phenyl)diazenyl)benzaldehyde] and full…
Abstract
Purpose
The paper aims to the preparation of novel disperse dye based on azo salicylaldehyde derivatives TF-A [2-hydroxy-5-((3-(trifluoromethyl)phenyl)diazenyl)benzaldehyde] and full evaluation of their use as disperse dye TF-ASC [bis 2-hydroxy-5-((3-(trifluoromethyl)phenyl)diazenyl)benzaldehyde Schiff base with 4,4'-methylenedianiline] for dyeing polyester fabric at various conditions.
Design/methodology/approach
The dispersed dye was synthesized via Schiff base condensation in the presence of ceric ammonium nitrate cerium ammonium nitrate 10 mmole% as an eco-friendly catalyst at room temperature. The chemical structure of the prepared dye was characterized via elemental analysis, Fourier-transform infrared spectroscopy, 1H- and 13 C-NMR spectroscopic analysis tools. This study thoroughly examined the dyeing of disperse dye TF-ASC on polyester at various conditions. The characteristics of dyed polyester fabric were measured by colour measurements, as well as light, washing, crock fastness and finally, colour strength. The discrete fourier transform (DFT) theoretical studies, including EHOMO, ELUMO and optimized geometrical structure, were assumed and discussed in detail.
Findings
The results showed that the synthesized organic dye TF-ASC was highly functional and appropriate for this kind of dyeing method. The dyeing fabrics obtained from disperse dye TF-ASC, properties possess high colour strength as well as good overall fastness properties. These dyes had a high affinity for polyester fabric, with just a tiny change in dye affinity when the pH was changed, even under alkaline circumstances. The dye levelness and shade depth of the colour results were good, and there were a variety of hues from light brownish yellow to deep brownish yellow. The results obtained from DFT computational studies such as EHOMO, ELUMO, optimized structure, diploe moment µ and electrophilicity index deduced that prepared organic dye TF-ASC is more applicable as a dispersed dye.
Originality/value
This research is significant because it provides a new dye for dyeing polyethylene terephthalate fibres with exceptional brightness and levelness; the method of preparation is a useful pathway due to its being known as a green chemistry method.
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Ali A. Ali, Malek Alshukur, Ashraf M. Ashmawy, Ammar M. Mahmoud, Ahmed Saleh, Hesham S. Nassar and Bo Yao
This study aims to show the dyeing behaviour of polyester fabrics using four novel heterocyclic disperse dyes.
Abstract
Purpose
This study aims to show the dyeing behaviour of polyester fabrics using four novel heterocyclic disperse dyes.
Design/methodology/approach
The four dyes were synthesized based on 5, 5'-(1, 4-phenylene) bis (1, 3, 4-thiadiazol-2-amine) as a diazonium compound. The UV/Vis absorption spectroscopic data of these disperse dyes while dyeing polyester fabrics were investigated. Following this, the dyeing properties of these dyes on polyester fabrics were investigated under acid condition.
Findings
The results showed that increasing the dyeing temperature from 80°C to 100°C led to an increase in dye uptake for all dyes, but further increases of the temperature to 130°C led to higher dye uptake for dye 3 as the dye exhaustion increased by about 50% from 55.9% to 91.4%.
Originality/value
This study is important as it introduces new dyes for the dyeing of polyethylene terephthalate (PET) fibres with colours that range from yellowish orange to bluish yellow and scarlet red and all with excellent brightness, levelness and depth of shade.
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Shahin Hossain, M. Abdul Jalil, Rois Uddin Mahmud and Abdul Kader
In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic…
Abstract
Purpose
In recent years, natural dyes have attracted significant attention globally because of growing public awareness of the environment and health hazards associated with synthetic dyes. Natural dyes can provide special aesthetic qualities as well as the ethical significance of a product which is environmentally friendly. By keeping this burning issue in mind, this study aims to explore the dyeing properties of various unexplored environmentally friendly natural dyes.
Design/methodology/approach
In this study, the aqueous extract of coconut leaves is used for dyeing purpose. The silk and jute fabrics were dyed with the extract alone as well as in combination with metal salts as mordants by employing pre-, meta- and postmordanting techniques. The dyeing properties of the colored samples were evaluated by measuring their color strength; CIEL*a*b* values; and color fastness to washing, light and rubbing.
Findings
A yellow shade was achieved when the fabric samples were dyed solely with the extract. However, shade variations were observed when different mordants and mordanting techniques were applied. In all the cases, metallic salts improved the color fastness properties of dyed samples to washing, light and rubbing especially for the silk fabric.
Originality/value
To the best of the authors’ knowledge, this is the first report on a natural dye extracted from the leaves of coconut. Leaf as the source of dye has added an extra advantage, as it is reproducible and can be collected easily without harming the plants. The reported dye could be an attractive choice for sustainable and eco-friendly dyeing.
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María Higueras, Ana Carrasco-Huertas, Ana Isabel Calero-Castillo, Manuel Moreno Alcaide and Francisco José Collado Montero
This paper aims to study the suitability of a selection of 3D printing liquid photopolymer resins for their application in the cultural heritage context.
Abstract
Purpose
This paper aims to study the suitability of a selection of 3D printing liquid photopolymer resins for their application in the cultural heritage context.
Design/methodology/approach
The main concerns regarding the conservation and restoration of cultural assets are the chemical composition and long-term behavior of the new materials that will be in contact with the original object. Because of this, four different LED curing resins were exposed to an accelerated aging procedure and tested to identify the materials which demonstrated a better result. Some specific properties of the material (color, glossiness, pH and volatile organic compound emissions) were measured before and after the exposure.
Findings
Some of the properties measured reported good results demonstrating a decent stability against the selected aging conditions. The main changes were produced in the colorimetric aspect, probably indicating other chemical reactions in the material. Likewise, a case study could be also executed to demonstrate the usefulness of these materials in the cultural field.
Research limitations/implications
It is necessary to study in more detail the long-lasting behavior of the materials employed with these technologies. Further analysis should be carried out highlighting the chemical composition and degradation process of the materials proposed.
Originality/value
This paper contributes to the introduction of curing 3D printing resins in the restoration methodologies of cultural assets. For this, the study of a selection of properties represents the first stage to suggest or reject their use.
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Souty Adel Nassef Beskhyroun and Mohamed Abdel-Aziz
This paper aims to assess the efficiency of emulsified essential oils in glycerol as eco-friendly antimicrobial and plasticized agents added to the biopolymer of gelatin for…
Abstract
Purpose
This paper aims to assess the efficiency of emulsified essential oils in glycerol as eco-friendly antimicrobial and plasticized agents added to the biopolymer of gelatin for lining historical oil paintings on canvases.
Design/methodology/approach
Cedar oil, cinnamon oil and their mixtures were emulsified in glycerol and incorporated into gelatin adhesive as green biocides and plasticizers. Physical, biological, chemical and mechanical tests were conducted on experimental mock-ups to assess the gelatin-based adhesive formulations for the reinforcement of canvas supports. Scanning electron microscope, colorimetric measurements, antimicrobial activity test, attenuated total reflection-Fourier transform infrared spectroscopy, tensile strength and elongation tests were carried out on the mock-ups before and after the artificial aging.
Findings
The formulations of gelatin-based adhesive with cinnamon and cinnamon-cedar mixture emulsified in glycerol proved their efficiency on the antimicrobial activity test, chemically delaying the decomposition of gelatin and accordingly providing compatible mechanical properties. Gelatin-based adhesive with emulsified cinnamon oil showed a slight yellowing that was quite improved with the mixture of the cinnamon-cedar-based adhesive formulation.
Originality/value
This study promotes a green approach to lining historical oil paintings by developing green formulations from bio-based origins that minimize the shrinkage and microbial infection of gelatin for lining paintings.
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Fatma Burcu Karakoç, Nilgün Ertaş and Mine Aslan
The utilization of oilseeds in food formulations is prevalent due to their health benefits and nutritional value. These protein-rich oilseeds serve as an affordable and essential…
Abstract
Purpose
The utilization of oilseeds in food formulations is prevalent due to their health benefits and nutritional value. These protein-rich oilseeds serve as an affordable and essential source of nutrients and bioactive compounds, fulfilling human protein requirements. As such, this study sought to investigate the impact of partially replacing wheat flour with oilseeds in different proportions on the nutritional and quality characteristics of biscuits.
Design/methodology/approach
Oilseeds, including terebinth, sesame and flaxseed, were partially substituted with wheat flour in amounts of 0, 5, 10, 15, 20 and 25%. The effects of this substitution on the storage stability, nutritional content and physical properties of the resulting biscuits were examined.
Findings
The L* (from 69.75 to 54.06) and b* (from 28.59 to 21.60) color values of biscuits decreased with the supplement of oilseeds. The oilseeds addition increased the protein, fat, energy, and ash values of biscuits. At the highest level of added terebinth, sesame and flaxseed, respectively, the amounts measured were 5984.62 mgGAE/kg, 1553.85 mgGAE/kg and 2169.23 mgGAE/kg, which were higher than the control biscuits (715.39 mgGAE/kg). The incorporation of oilseeds resulted in a substantial decrease in pH and peroxide values, while the moisture content was increased throughout the 6-month storage period. The use of terebinth in biscuits led to better oxidative stability than sesame and flaxseed-containing samples. The biscuit samples with terebinth had a longer induction time. The lowest induction time of biscuits with 25% flaxseed was chosen, approximately 3.5 h.
Research limitations/implications
Oilseed flours, which are rich in lipids, have been shown to enhance the quality of biscuits. However, further studies could aim to reduce the amount of shortening used to improve their quality even further. Reducing the shortening could keep the lipid content at an acceptable amount, especially considering consumers' current expectations for low-fat foods.
Practical implications
Plant-based bioactive are generally known as secondary metabolites and have promising therapeutic attributes, especially antioxidative properties.
Social implications
Thanks to this composition, some of these seeds have proven effective in controlling and preventing metabolic diseases (hypertension, hypercholesterolemia, diabetes, coronary heart disease and several types of cancer) as well as providing interesting properties to foods.
Originality/value
As result, oilseeds can be successfully used as functional and sustainable food ingredients to improve the functional, nutritional and storage stability of biscuits.
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Nandalal Acharjee, Subhas Ganguly, Prasenjit Biswas and Bidyapati Sarangi
The purpose of this study is to develop black pigmented ceramic stoneware bodies that integrate various aspects of material composition and color potential. Recent research has…
Abstract
Purpose
The purpose of this study is to develop black pigmented ceramic stoneware bodies that integrate various aspects of material composition and color potential. Recent research has explored black pigmented calcium aluminosilicate glass (BPCG), a specialized material known for its unique properties, which holds promise for transforming the color capabilities of traditional ceramics.
Design/methodology/approach
In this investigation, initially composite ceramic sample (B-1) was prepared by milling process prior to sieve analysis to attain the particle size within 44 microns. Microanalysis and morphology and thermography were studied by energy-dispersive X-ray spectroscopy, scanning electron microscope and thermogravimetric analysis and found Sample-B-1 received attractive properties like firing shrinkage, porosity, bulk density and firing strength along with good pyro-plastic properties at various temperatures like 950°C, 1050°C, 1000°C and 1180°C. Furthermore, BPCG-assisted pigmented ceramic composites were synthesized with B-1 matrix. CIE lab investigation of the attributed composites (C-series) within selective soaking range of 5–20 min was performed, and the investigation found that prominent black hue appeared (L: 24.09, a*: −0.17, b*: −0.49) for C-10 containing appeared phases of Di-Co-Silicide (26%), Ni-Chromite, Stilpnomelane (rich in iron) as obtained by X-ray diffraction studies.
Findings
Ceramic material played a significant role in the realms of art and craft, as well as in technology. The artistic facet reveals concepts or ornamentation, while the craft echoes both traditional and functional appeal. Technology, on the other hand, involves the logical implementation behind the creation.
Originality/value
This C-10 Sample comprised the lower percentage of mullite which attributed that the BPCG homogeneously mixed in the matrix of base (B-1) and appeared as spinal staff. Therefore, BPCG was a potential candidate for ceramic metallization, and this traditional metallization processes often faced some challenges like uniformity and mixing in the ceramic composite domain practices. This study aimed to open up new avenues for artistic decoration and bridging the gap between traditional craftsmanship and modern technology. Furthermore, BPCG’s role in color assessment through shocking techniques added an exciting concept for the ceramic practitioners, designers or ceramic educators.
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This study aims to explore the enhancement of mechanical properties in epoxy resin composites through the incorporation of graphene nanoparticles, focusing on their impact and…
Abstract
Purpose
This study aims to explore the enhancement of mechanical properties in epoxy resin composites through the incorporation of graphene nanoparticles, focusing on their impact and wear resistance. It investigates the role of graphene, both treated and untreated, as a reinforcing agent in composites, highlighting the significance of nanoparticle dispersion and surfactant treatment in optimizing mechanical performance.
Design/methodology/approach
Employing a novel dispersion technique using a drawing brush, this research contrasts with traditional methods by examining the effects of graphene nanoparticle concentrations treated with surfactants – Polyvinylpyrrolidone (PVP) and Sulphonated Naphthalene Formaldehyde (SNF) – on the mechanical properties of epoxy resin composites. The methodology includes conducting a series of impact and wear tests to assess the influence of graphene reinforcement on the composites' performance.
Findings
The findings reveal a marked enhancement in the composites impact resistance and energy absorption capabilities, which escalate with an increase in graphene content. Additionally, the study demonstrates a significant improvement in wear resistance, attributed to the superior mechanical properties, robust interface adhesion and effective dispersion of graphene. The use of surfactants for graphene treatment is identified as a crucial factor in these advancements, offering profound insights into the development of advanced composite materials for diverse industrial uses.
Originality/value
This study introduces a unique dispersion technique for graphene in epoxy composites, setting it apart from conventional methods. By focusing on the critical role of surfactant treatment in enhancing the mechanical properties of graphene-reinforced composites, it provides a novel insight into the optimization of impact and wear resistance.
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Heba Raslan, Khaled El-Nemr, Magdy Ali and Medhat Hassan
This study aims to investigate the influences of polyester fabric layers on the mechanical properties of SBR and devulcanized waste rubber composite materials, as well as the…
Abstract
Purpose
This study aims to investigate the influences of polyester fabric layers on the mechanical properties of SBR and devulcanized waste rubber composite materials, as well as the effect of gamma irradiation dose.
Design/methodology/approach
The devulcanized waste rubbers (DWR) were carried out by different methods. First, chemically, by two different reclaiming agents such as tetramethylthiuram disulfide (TMTD) and 2-mercapto benzothiazole disulfide (MBTS). Secondary by a physical method like microwave (MW). The devulcanized rubbers were mixed with virgin styrene butadiene rubber (SBR) in different ratios, as follows: SBR-DWR (TMTD) 50 / 50, SBR-DWR (MBTS) 80 / 20 and SBR-DWR (MW) 80 / 20. A series of sandwich polyester tire cord fabrics were used as reinforcement for making SBR and devulcanized waste rubber composite materials and molded on a hot press into rubber sheet films, then subjected to gamma radiation at different doses ranging from 100 up to 200 kGy.
Findings
The experimental results indicate that increasing the layer number improves the mechanical properties of composites. The tensile strength, tearing, hardness and elastic modulus of the rubber composites increased with the rise of the fiber layers and by increasing the irradiation dose up to 200 kGy. The reclaiming agent TMTD gave the best results for mechanical properties, followed by MW and then MBTS.
Originality/value
This phenomenon can be detailed based on the fact that when the fiber-reinforced composites are subjected to loading, the fibers act as load carriers, depending on the population and orientation of the fibers. Also, scanning electron microscopy (SEM) reveals that adhesion was caused by tire cord fabrics and rubber blend matrix.
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