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Article
Publication date: 21 July 2022

Rehab El-Gamal, Khaled El-Nagar, Nagwa A. Tharwat and Gomaa Abdel-Maksoud

This study aims to use whiteness (WI) and yellowness indices (YI) that were calculated from the International Commission on Illumination (CIE) color parameter to evaluate the…

Abstract

Purpose

This study aims to use whiteness (WI) and yellowness indices (YI) that were calculated from the International Commission on Illumination (CIE) color parameter to evaluate the efficiency of some triazole fungicides [propiconazole (C15H17Cl2N3O2) and tebuconazole (C16H22ClN3O)] to protect wooden artifacts from fungal deterioration.

Design/methodology/approach

Archeological wooden samples were collected from some historical Islamic buildings in Cairo, Egypt. Three species of fungi were identified in previous work. Propiconazole and tebuconazole with different concentrations treated the infected wooden samples aged for different periods. WI and YI of studied samples were measured using UV spectrophotometer. Calibration and uncertainty estimation accompanied by color measurement were studied.

Findings

Studying the uncertainty sources of diffuse reflection of the standard white tiles revealed that the uncertainty of calibration for both the spectrophotometer and white tiles had the highest contribution. The treated samples with tebuconazole and propiconazole fungicides gave good resistance against fungal deterioration at 0.50% for WI and YI.

Originality/value

This study presents the importance of colorimetry in the conservation field because they are considered one of the most important criteria to evaluate conservation materials. From color measurements and their uncertainties, it became clear that triazole fungicides have good efficiency in the protection of wooden artifacts from fungal deterioration. The value of this study is that propiconazole and tebuconazole fungicides at 0.50% can be applied to archaeological wood that is endangered to improper conditions, especially in the case of high levels of relative humidity.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 June 1978

Standard laboratory equipment used by numerous UK and overseas companies in the inks, resins, plastics and paints industries for colour quality control and experimental work, is…

Abstract

Standard laboratory equipment used by numerous UK and overseas companies in the inks, resins, plastics and paints industries for colour quality control and experimental work, is the Lovibond Universal Tintometer (model AF 702), a visual colorimeter made by the Salisbury‐based Tintometer.

Details

Pigment & Resin Technology, vol. 7 no. 6
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 5 January 2015

Sara Ahmadi, Alireza Aghaei and Bijan Eftekhari Yekta

The purpose of this article is to evaluate the role of mineralisers on the formation of perovskite structure, optimise the amounts of chromium content, soaking time and finally…

Abstract

Purpose

The purpose of this article is to evaluate the role of mineralisers on the formation of perovskite structure, optimise the amounts of chromium content, soaking time and finally the ratio of fuel (citric acid) to oxidiser (metal nitrate) and investigation of the physical properties of resulted pigments.

Design/methodology/approach

A red pigment based on perovskite structure (YAl1-yCryO3, y = (0.01-0.1) was synthesised by solution combustion method with various mineralisers, like NaF, MgF2 and Li2CO3. Thermal decomposition of the resulting nitrate-citrate gels and the phase evolution of calcined powders were investigated and the microstructure and colorimetry of the emerging products were characterised.

Findings

The most effective mineraliser system for the formation of YAlO3 perovskite was NaF:MgF2:Li2CO3 (3:2:1 by weight). Furthermore, desirable pigments were obtained by firing the samples at 1,400°C for 4 hours. The highest redness parameter (a*) and reflectance value were obtained when y was 0.03 and 0.01, respectively. Increasing the fuel: oxidiser ratio led to an increase in the a* parameter. Use of the optimum prepared red pigment in the low and high firing temperature glazes gave a high chemical and thermal stability.

Research limitations/implication

Only citric acid was used as fuel. Other fuels and different ratios of fuel to oxidiser could also be studied.

Practical implications

The method developed provided a new approach for preparation to nontoxic, high-temperature, ceramic red pigment compared to the solid-state method.

Originality/value

The methods for synthesis of pigment based on perovskite structure with different chromium contents and for evaluation of thermal stability of pigment in glaze were novel.

Details

Pigment & Resin Technology, vol. 44 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 March 2013

S.V. Lee, N.A. Halim, A.K. Arof and Z.H.Z. Abidin

The purpose of this paper is to develop a new water‐based coating system composed of poly(vinyl alcohol) and anthocyanin colourant extracted from Hibiscus sabdariffa L. and to…

Abstract

Purpose

The purpose of this paper is to develop a new water‐based coating system composed of poly(vinyl alcohol) and anthocyanin colourant extracted from Hibiscus sabdariffa L. and to characterise the system.

Design/methodology/approach

Anthocyanin from Hibiscus sabdariffa L. (roselle) calyxes was extracted by using distilled water and filtered to remove insoluble particle. Salts introduced into the extract were 5wt percent calcium nitrate, 5wt percent magnesium nitrate, and 5wt percent zinc nitrate. The solution was mixed with poly(vinyl alcohol) in ratio of 3:1. The mixtures were coated on glass substrate and allowed to cure for approximately one day. Colour of the extract systems was determined by CIELab colourimetry. FTIR spectroscopy was conducted on the samples to identify their functional groups and changes upon addition of salt. Thermal stability was assessed by thermogravimetric analysis (TGA). Differential scanning calorimetry (DSC) was employed to measure the glass transition temperature Tg of the samples. XRD was employed to determine the amorphous properties of the coating samples.

Findings

From FTIR spectroscopy, shifting in the OH stretching and CH2 bending bands was attributed to hydrogen bonds formation between PVA and nitrate salt. Shifting in the main decomposition step in samples with addition of nitrate salts in TGA was due to interaction of PVA and nitrate. Increase in glass transition temperature of samples with salts was attributed to the formation of hydrogen bonding. From XRD study, increase in the amorphous properties was due to the incorporation of nitrate salts into PVA coating.

Research limitations/implications

Limitation of implementating poly(vinyl alcohol) as coating is caused by its weak water resistance and hydrophilic properties. This study could bring about research towards incorporation of different natural colourant with different binder materials to form coatings which are environmental‐friendly and low cost.

Practical implications

Mixture of PVA and anthocyanin colourant from roselle for use as coating has been developed. The coating can find usage in various applications such as coloured coating for furniture and wooden materials for decorative purposes, biodegradable design materials for interior purposes. It can be practically applied on a variety of substrates such as glass and wood.

Originality/value

Development of water‐based coating from PVA binder with anthocyanin colourant is introduced in this study.

Details

Pigment & Resin Technology, vol. 42 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 January 1988

Tristimulus colorimetry started in the nineteenth century. Young discovered the fact that the eyes were susceptible to three colours, red, green and blue and Clark Maxwell did…

Abstract

Tristimulus colorimetry started in the nineteenth century. Young discovered the fact that the eyes were susceptible to three colours, red, green and blue and Clark Maxwell did experiments based on the mixing of red, green and blue colours to try and simulate the effects on the eye of any other colour. The result, in tristimulus values, where X represents red, Y represents green and Z represents the proportion of blue with regard to their respective saturations, provided a series of numbers which were additive only. These values, although they are used currently, are very difficult to establish meaningful colour difference work. The addition of two colours results in modifications to the X, Y and Z values of both of the colours, i.e. they progressively increase and do not decrease.

Details

Pigment & Resin Technology, vol. 17 no. 1
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 February 2008

Kavita Mathur, Abdel-Fattah M. Seyam, David Hinks and R. Alan Donaldson

Today, Jacquard woven fabric producers are able to digitally control each warp yarn individually, pre-program the variable pick density and speed for each filling yarn, and…

Abstract

Today, Jacquard woven fabric producers are able to digitally control each warp yarn individually, pre-program the variable pick density and speed for each filling yarn, and automatically change a pattern without stopping the weaving process. Jacquard CAD systems dramatically reduce the time to produce fabric from the artwork or target design The process of weave/color selection for each area of the pattern is, however, still highly dependent on the CAD system operator who works from a particular color gamut. Multiple weaving trials are required to get a sample that matches the original artwork since the process requires the designer‘s subjective evaluation. The lack of automatic selection of weaves/color matching prompts this research.

This paper addresses the development of a geometric model for predicting the color contribution of each warp and filling yarn on the fabric surface in terms of construction parameters. The combination of geometric modeling and existing color mixing equations enables the prediction of the final color of different areas of a Jacquard pattern. The model was verified experimentally and a close agreement was found between a color mixing equation and the experimental measurements.

Details

Research Journal of Textile and Apparel, vol. 12 no. 1
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 16 July 2021

Hussein Marey Mahmoud

This contribution aims to introduce an effective low cost polymer-nanocomposite for possible application to achieve a super protection for highly damaged ancient Egyptian wall…

Abstract

Purpose

This contribution aims to introduce an effective low cost polymer-nanocomposite for possible application to achieve a super protection for highly damaged ancient Egyptian wall paintings.

Design/methodology/approach

SiO2 and Al2O3 nanoparticles were synthesized by the sol-gel method. Then, the polymer-nanocomposite was prepared by simple mixing and dispersing the nanoparticles into the tetraethoxysilane polymer solution, with the aid of an ultrasonic dismembrator. The application of the polymer-nanocomposite and other polymeric nanodispersions, on laboratory models, was performed by the brushing technique. Next, the materials stability was evaluated by means of digital optical microscope, colorimetry, FE-scanning electron microscope, measuring the static contact angle and water absorption rates.

Findings

The results were promising in creating a superhydrophobicity and the static contact angle (?S) measured for the polymer-nanocomposite reached 135o. An average of three measurements of the water absorption rate after polymer-nanocomposite treatment was 0.66 g/m2 s, compared to 2.60 g/m2 s for the control model (untreated). Further, an average of color difference (?E*) for the treated surface was 2.78, and after the accelerated thermal aging was 3.6. Observing the surface morphology, the polymer-nanocomposite enhanced the roughness of the treated surface and showed a high resistance to laboratory salt weathering.

Practical implications

Preparation of a polymer-nanocomposite by adding SiO2 and Al2O3 NPs to tetraethoxysilane polymer has been proposed. As a promising conservation material, the produced polymer-nanocomposite helped to form an efficient protective film.

Originality/value

This paper attains to develop an economic polymer-nanocomposite to maintain a high protection to damaged ancient Egyptian wall paintings and similar objects.

Details

Pigment & Resin Technology, vol. 51 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 June 2013

Emmanuel Annerel and Luc Taerwe

As concrete structures exposed to fire behave in most cases very well, it could be of economic interest to repair the fire damaged structure. For this purpose a damage assessment…

Abstract

As concrete structures exposed to fire behave in most cases very well, it could be of economic interest to repair the fire damaged structure. For this purpose a damage assessment based on scientific research is required as first step. In this paper, the Schmidt Rebound Hammer and colorimetry are addressed as tools for this assessment. Firstly, the effect of both methods is studied on heated siliceous concrete specimens under laboratory conditions. Secondly, the practical applicability of both methods is examined by evaluating the fire damage of a concrete girder exposed to a real fire. Both techniques show to be very useful in evaluating the fire damage of the girder.

Details

Journal of Structural Fire Engineering, vol. 4 no. 2
Type: Research Article
ISSN: 2040-2317

Article
Publication date: 1 May 2011

Eman Osman and Nabawia Abd El-Zaher

Natural dye (Sambucus nigra, whose common name is elder) is used to dye silk fabric. The dyed fabric samples have been post mordanted with three different mordants, including…

Abstract

Natural dye (Sambucus nigra, whose common name is elder) is used to dye silk fabric. The dyed fabric samples have been post mordanted with three different mordants, including alum; ferrous and chrome. A thermo-gravimetric analysis (TGA) and differential scanning colorimetry (DSC) of all the samples are used to investigate the thermal stability of the dyed mordanted silk fabrics. The TGA provides the changes in the sample weight loss as a function of time and temperature. The DSC gives information about the possible changes in the fiber structure. In addition, the DSC is a method commonly used to determine crystallinity in polymers and involves measuring the melting enthalpy. The TGA tested results for silk samples mordanted with ferrous has the highest thermal stability. The endothermic peak at 318°C shifts to a lower or higher temperature than in the case of blank samples according to the type of mordant used. Fastness to light, washing and perspiration of the examined silk fabrics have also been examined and the results are reported.

Details

Research Journal of Textile and Apparel, vol. 15 no. 2
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 1 March 2000

J.H. Nobbs and C. Connolly

Camera‐based colour measurement systems have application where it is difficult to apply a contact instrument, or where the contact instrument, because of its fixed lighting…

Abstract

Camera‐based colour measurement systems have application where it is difficult to apply a contact instrument, or where the contact instrument, because of its fixed lighting geometry, does not provide the necessary data. The paper describes the principles, procedures and precautions necessary for camera based colorimetry. Equations are presented to convert digitised R G and B values, which are system specific, into CIE X Y Z colour values, an international standard method of colour specification. It is reported that colours spaced equally in RGB values appear to have visual colour difference steps varying in size by as much as 30:1 through the different regions. The poorest colour resolution occurs for RGB values that represent dark or strongly coloured shades. At least ten bits per channel digitisation of RGB values is required to achieve a colour resolution similar to the human visual system for dark, intense shades.

Details

Sensor Review, vol. 20 no. 1
Type: Research Article
ISSN: 0260-2288

Keywords

1 – 10 of 163