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The objective of this work was to examine the anticorrosive behaviour of four different epoxy coatings, which were formulated with zinc pigments and were applied on pretreated steel panels exposed to deionised/deaerated water taken from the installations of the Greek Public Electricity Company, as well as to compare the results of this study with those of a relevant, previous work. The coating's performance was assessed by the measurement of the potentiodynamic polarisation resistance, by electrochemical impedance spectroscopy and the measurement of dielectric permittivity, during the deionised/deaerated water immersion tests. Additionally, accelerated salt spray tests were performed. All types of coatings tested exhibited a high protective performance. It was concluded that the epoxy system containing zinc dust was the most effective anticorrosion coating under the conditions relevant to this study.

The severe friction and wear of the spindle in a cotton picker often occur in a picking cotton, which affects the spindle lifetime and its efficiency of picking cottons. This paper aims to investigate the effect of an electroless nick coating on the spindle performances to avoid its abnormal phenomena.

First, it is coated on the surface of the test specimen with the material same as that of the spindle. Then, the friction coefficient and wear for the coating are measured under oil lubrication to evaluate its effect in improving the tribological performances for the spindle.

The stabilized friction coefficient of the electroless nick coating decreases with increasing reciprocating frequency of specimen and increasing applied load. There exists a critical coating thickness yielding the smallest friction coefficient. Moreover, this coating has a property of the smaller friction coefficient in comparison with a hard chromium coating.

The research about the electroless nick effect on the spindle’s tribological performances is not found yet to date. To avoid severe friction and wear of the spindle, this paper investigated how the reciprocating frequency of specimen, applied load and coating thickness affect the spindle’s tribological performances. The associated conclusions can provide a reference to enhance the spindle lifetime and its transmission efficiency.

During offshore pipe-lay, pipe lengths with anticorrosion coating are welded together, and, to facilitate the welding process, the ends of the pipe remain uncoated. A wide range of field joint coating (FJC) types is available for coating this bare section, functioning in conjunction with the pipeline cathodic protection system to provide an anti-corrosion system or package. This paper aims to relate to two-layer type heat shrink sleeves (2LHSS), which commonly are used for FJC of concrete-weighted offshore pipelines where the sleeve typically is over-coated with a solid or foam type polyurethane “infill”. Similar sleeves also are used sometimes in exposed conditions on lines without concrete over-coating. The maximum allowable soluble salt contamination prior to application of high-performance coating systems can vary, depending upon the coating type, but typically has been set at 20 mg/m2 (de la Fuente et al., 2006). The first layer of three-layer heat shrink sleeve (3LHSS) systems for pipeline FJC, liquid epoxy, falls into this category (ISO_21809-3:2008, 2008). In contrast, the 2LHSS system does not use a liquid epoxy first layer but relies instead on the bonding of a “mastic” layer directly to the pipe metal surface. The maximum acceptable concentration of salt contamination on prepared metal surfaces prior to the application of 2LHSS has been a subject of debate and was the focus of this study. International standards for FJC do not provide a maximum salt level. However, some companies have continued to specify low thresholds for the maximum allowable salt level for 2LHSS, which can result in expensive delays in production during offshore pipe-lay. In this study, salt contamination levels of up to 120 mg/m2 were found to have no effect on peeling performance after accelerated aging by hot water immersion. Furthermore, preparation for welding and the use of potable water during ultrasonic testing procedures prior to FJC, typically reduces the salt contamination level to below 50 mg/m2 providing a strong case for the deletion of salt contamination testing for 2LHSS.

The potential risk of failure of the coating due to poor surface cleanliness/contamination was assessed by testing the adhesion between the coating and the steel substrate to which the coating is adhering, following a period of hot water immersion. Compliance with ISO 21809-3 “Annex I” requires 28 days’ immersion at maximum operating temperature. For this study, to create a severe situation, the test rings were subjected to accelerated aging by water immersion at the HSS upper specified temperature of 65°C for more than twice the specified period (ISO_21809-3:2008, 2008). Two HSS were tested; one was widely used in applications where exposure to moderate mechanical stress is required, having a high shear strength type mastic “hybrid” adhesive containing a significant proportion of amorphous polypropylene blended with tackifiers and ethylene vinyl acetate (EVA), Andrenacci et al. (2009) referred to as “Type A”. The second, referred to as “Type B”, is widely used in applications where it is covered by a layer of “infill”, typically consisting of polyurethane foam or solid polyurethane elastomer, i.e. typical design methodology for concrete coated pipelines. “Type B” HSS had a more moderate strength traditional type mastic than “Type A” containing a significant percentage of butyl rubber with asphalt, activation agents and tackifying resins. To determine how to apply the salt contamination without causing flash rust, a mini-study was completed on the steel substrate. After numerous trials, it was found impossible to not to form visible rust on the pipe surface. The extent of rusting was minimised by heating the pipe immediately after the application of the salt solution.

High levels of sea salt on power tool prepared pipe surfaces were investigated by peel testing of 2LHSS after hot water immersion and compared against peel tests undertaken prior to hot water immersion. The test conditions were considered severe: salt contamination levels of up to 120 mg/m2 applied on power tool cleaned pipe surfaces that had been aged for one year without prior grit blasting. The accelerated ageing procedure had twice the specified (ISO_21809-3:2008, 2008) water immersion duration, and the test samples had exposed edges providing the possibility for moisture to creep under the coating. The test results showed that there were no noticeable deleterious effects on the performance of the two most commonly used FJCs, 2LHSS. Therefore, it was concluded that, as the level of salt contamination on prepared pipe surfaces after wet non-destructive testing typically is much lower than the levels tested in this study, pipe surfaces prepared for the application of 2LHSS type do not require specific additional measures to further reduce salt contamination, provided that care is taken to ensure that these conditions are maintained consistently during pipe laying operations.

The frequency of salt contamination testing of power tool cleaned surfaces prior to mastic type heat shrink sleeves can be minimised, and perhaps omitted entirely, provided the above criteria are satisfied.

A literature review revealed there was little published information on the testing of 2LHSS and nothing related to hot water immersion testing. Hence, the results of this investigation have provided useful industrial data regarding the effect of hot water ageing and the influence of surface salt contamination on field joint corrosion prevention capabilities.

The anticorrosion coatings used in marine and atmospheric environment are subjected to many environmental factors. And the aging failure has been puzzling researchers. The purpose of this study is to find the correlation between the initial aging of epoxy coatings and the typical marine atmospheric environmental factors.

The epoxy coatings were subjected to a one-year exposure in three typical marine atmospheres. Meanwhile, principal component analysis, linear regression and Spearman and gray correlation analysis were applied to quantify the environmental characteristics and establish correlations with the coating aging.

The results indicate that the coating will undergo macroscopic fading and chalking upon exposure to the marine atmosphere, while microscopic examination reveals holes, cracks and partial peeling. The adhesion performance and electrochemical properties of the coating deteriorated with prolonged exposure, coating aging mainly occurs with the generation of O-H bonds and the breakage of molecular chains such as C-N and C-O-C. The coating was most deeply aged after exposure to the Xisha, followed by Zhoushan and finally Qingdao. Environmental factors affect the photooxidative aging and hydrolytic degradation processes of coatings and thus coating aging. To further demonstrate the correlation between environmental factors and coating aging, principal component analysis was used. The correlation model between environmental factors and coating aging was subsequently obtained. The correlation model between the rate of coating adhesion loss (E) and the comprehensive evaluation parameter of environmental factors (Z) is expressed as E = 0.142 + 0.028Z. Meanwhile, the Spearman correlation analysis and gray correlation method were used to investigate the impact of each environmental factor on coating aging. Solar irradiation, relative humidity and wetting time have the highest correlation with coating aging, which are all above 0.8 and have the greatest influence on coating aging; wind speed and temperature have the smallest correlation with coating aging, which are about 0.6 and have the least influence on coating aging.

This paper establishes a correlation between typical marine environmental factors and coating aging performance, which is crucial for predicting the service life of other coatings in diverse environments.

The effect of using microcrystalline cellulose (MCC) as an additive in coating paint films for non-stick coatings was studied in this work. This paper aims to discuss the benefits of MCC blended in the coating paint film that consists of poly(methyl methacrylate) (PMMA) and dammar.

PMMA and dammar mixed at a specific Wt.% ratio with xylene as its solvent. Two sets of mixtures were prepared, where one mixture contained MCC and another, without. The mixtures were applied to metal substrates as coating paint films. The performance of the non-stick coating paint film was observed through the adhesive test between adhesion layers on the coating paint film and also through the cross-hatch test for the adhesion of the non-stick coating paint film to the metal substrate. The results correlate with the surface roughness and glossiness tests.

The results showed that for the coating paint films, Sample B consisted of 80:20 Wt.% ratio of PMMA-dammar with an addition of 5 Wt.% MCC had an excellent performance as non-stick coating paint films. The MCC formed microparticles on the surface of the coating paint film sample and this causes the coating paint film samples with MCC to develop a rougher surface compared to the coating paint film without MCC. Sample B coating paint film had the highest average surface roughness (Ra) of 383 µm. The cross-hatch test showed the coating paint film with the addition of MCC had stronger adhesiveness on the substrate’s surface thus prevents the coating from peeling off from the surface.

The developed coating paint film in this study would be suitable for outdoor applications to prevent illegal advertisements and stickers.

MCC added to the coating paint film improves the surface performance as a non-stick coating.

This paper aims to analyse the coating behaviour in corrosion environment as well as to evaluate the best percentage amount of copper oxide and copper needed for organic coating in order to prevent the corrosion degradation. Electrochemical impedance spectroscopy (EIS) studies have been conducted in order to evaluate the corrosion performance of polyester-epoxy-copper oxide and polyester-epoxy-copper coating systems.

The availability of this modem instruments is used to obtain impedance data as well as computer programs to interpret the results that made the technique popular. In addition, EIS is well suited to the study of polymer-coated metals.

The results showed that samples containing 25 weight per cent of copper oxide and copper (90P25CuO and 90P25Cu) obtained the excellent corrosion properties from the first day up to 30 days of NaCl immersion. The highest corrosion resistance values obtained by 90P25CuO and 90P25Cu on the 30th day were 7.107 × 108 O and 5.701 × 108 O, respectively, with lower double layer capacitance of 1.407 × 10⁻⁹ Farad and 3.935 × 10⁻⁹ Farad, respectively. Moreover, the water uptake gained by these two coating samples was the lowest at the end of immersion, which was 0.0084 for 90P25CuO and 0.1592 for 90P25Cu, showing that the sample has good corrosion performance.

This paper discussed on the highest corrosion resistance, double layer capacitance and the water uptake of the copper (Cu) and copper oxide (CuO) coating system obtained from the EIS measurements.

The performance of epoxy coating on metal substrate at low temperature and high humidity application has adverse effect on cure rate, film properties and adhesion. In recent years, several advanced amine cross-linking agents having superior curing ability at low temperature application environment have been introduced. The aim of this paper is to study the properties of epoxy-based coating cured with different cross-linking agents designed for low temperature application at different environmental conditions.

Series of cross linking agents such as modified cycloaliphatic amine (H1), polyamine adduct (H2), modified aliphatic ketamine (H3), phenalkamine (H4) and phenalkamide (H5) have been studied to evaluate their performance in epoxy compositions when cured at four environmental conditions, i.e. at ambient and sub-ambient temperatures with 60 and 90 per cent relative humidity, respectively. The effect of curing conditions was investigated by evaluating different physico-mechanical properties. Dynamic mechanical analyser technique was used to determine glass transition temperature (T_g) and cross-link density (ρ) of coatings. Anticorrosive properties of coatings also have been studied by electrochemical impedance spectroscopy.

The outcome of this study is expected to generate new insight into the curing behaviour of epoxy coating using different cross-linking agents which are recommended for low temperature application. Optimum physico-mechanical and corrosion resistance properties have been obtained by phenalkamine curing agent at low temperature and high humidity condition.

This study is an experimental approach to select the better cross-linking agent for low temperature application. Different test conditions were measured for understanding the performance of epoxy coating cured at different environmental condition.

The understanding reaction mechanism of the epoxy resin with cross-linking agent at different environmental condition is the great challenge and is hardly investigated in the literature. Therefore, in this research, the influence of climatic conditions and type of cross-linking agents on curing behaviour of epoxy-based coating was investigated.

The deposition of particles onto a substrate during the cold spraying (CS) process relies on severe plastic deformation, so there are various micro-defects induced by insufficient deformation and severe crushing. To solve the problems, many post-treat techniques have been used to improving the quality by eliminating the micro-defects. This paper aims to help scholars and engineers in this field a better and systematic understand of CS technology by summarizing the post-treatment technologies that have been investigated recently years.

This review summarizes the types of micro-defects and introduces the effect of micro-defects on the properties of CS coating/additive manufactured, illustrates the post-treatment technologies and its effect on the microstructure and performances, and finally outlooks the future development trends of post-treatments for CS.

There are significant discoveries in post-treatment technology to change the performance of cold spray deposits. There are also many limitations for post-treatment methods, including improved performance and limitations of use. Thus, there is still a strong requirement for further improvement. Hybrid post-treatment may be a more ideal method, as it can eliminate more defects than a single method. The proposed ultrasonic impact treatment could be an alternative method, as it can densify and flatten the CS deposits.

It is the first time to reveal the influence factors on the performances of CS deposits from the perspective of microdefects, and proposed corresponding well targeted post-treatment methods, which is more instructive for improving the performances of CS deposits.

This paper aims to analyze the effect of Y₂O₃ mass fraction on the tribological performance of CrNi coating, which solved the problem of wear resistance on AISI H13 steel.

Y₂O₃ reinforced CrNi coatings were fabricated on AISI H13 steel. The microstructure and phases of obtained coatings were analyzed using a super-depth of field microscope and X-ray diffraction, respectively, and the effects of Y₂O₃ mass fraction on the microstructure and wear resistance were methodically investigated using a wear tester.

The average coefficients of friction and wear rates of Y₂O₃ reinforced CrNi coatings decrease with the increase of Y₂O₃ mass fraction, in which the Y₂O₃ plays a role of friction reduction and wear resistance. The wear mechanism of Y₂O₃ reinforced CrNi coating is primary abrasive wear, accompanied by adhesive wear, which is contributed to the grain refinement and dense structure by the Y₂O₃ addition.

The Y₂O₃ was added to the CrNi coating by laser cladding, and the effect mechanism of Y₂O₃ mass fraction on the tribological performance of CrNi coating was established by the wear model.

This paper aims to evaluate the efficacy of a zeolite-filled silane sol–gel coating as protective layer on pretreated AZ31 magnesium alloy substrates.

Anti-corrosion properties of a silane–zeolite composite coating, at various zeolite content, have been investigated on AZ31 magnesium substrates subjected to different surface pretreatment procedures before coating deposition. A short time etching by hydrofluoric acid (HF) and an anodic polarization in NaOH solution were used as surface pretreatments.

High hydrophobicity and good adhesion performances of coatings have been observed. Corrosion protection performance, during immersion in 3.5 per cent NaCl solution, was evaluated by means of electrochemical impedance spectroscopy tests. All coating formulations evidenced good barrier properties. Better durability properties have been shown by coating obtained on HF pretreated magnesium substrate and with a 60 per cent of zeolite content.

High electrochemical reactivity of magnesium alloys represents the mayor limit of its application in many different fields. In this concern, zeolite-based coatings are emerging as potentially effective environmentally friendly coating for metallic substrates. Despite aluminum and stainless steel substrates, in the literature, only expensive direct synthesis zeolite coating was investigated for its application on magnesium alloys protection. For this reason, this paper fulfills the need to assess the adhesion and anti-corrosion behavior of sol–gel silane–zeolite coating in magnesium alloy substrates.