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1 – 10 of 123
Article
Publication date: 5 March 2018

Sofia Bogdan, Cecilia Deya, Oscar Micheloni, Natalia Bellotti and Roberto Romagnoli

This paper aims to study five vegetables extracts as possible additives to control bacterial growth on indoor waterborne paints. The extracts were obtained from the weeds Raphanus…

Abstract

Purpose

This paper aims to study five vegetables extracts as possible additives to control bacterial growth on indoor waterborne paints. The extracts were obtained from the weeds Raphanus sativus, Rapistrum rugosum, Sinapis arvensis, Nicotiana longiflora and Dipsacus fullonum, used in traditional medicine as antimicrobial compounds.

Design/methodology/approach

Weeds extracts were characterized by Fourier transform infrared spectroscopy and UV–Vis spectrophotometry. Their antibacterial activity against Escherichia coli and Staphylococcus aureus was also determined. Afterward, selected extracts were incorporated in waterborne paint formulations. The paintsantimicrobial activity was assessed against S. aureus, monitoring biofilm formation by environmental scanning electron microscopy.

Findings

As a general rule, results showed that tested paints were efficient in inhibiting biofilm formation, especially that formulated with Nicotiana longiflora.

Practical implications

The tested paints can be used to protect walls from microbial colonization, which shortened coatings’ useful life by discoloration and/or degradation. Concomitantly, indoor microbial colonization by aerosols could be also diminished. This is especially important in places that should have high standards of environmental hygiene, as in the food industry, health-care and sanitary centers.

Originality/value

The main value of this research was to study the antimicrobial activity of weeds extracts and to incorporate them in waterborne paints to diminish bacterial biofilm formation. This biofilm discolors and degrades the paint, and causes health problems. The use of natural compounds in coatings is increasing because of the convenience of using renewable sources, such as natural antimicrobials, in paint formulations.

Details

Pigment & Resin Technology, vol. 47 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 March 2022

Mohamed H. Sharaf, Adham M. Nagiub, Salem S. Salem, Mohamed H. Kalaba, Esmail M. El Fakharany and Hamada Abd El-Wahab

This study aims to focus on the preparation and characterization of the silver nanowire (AgNWs), as well as their application as antimicrobial and antivirus activities either with…

Abstract

Purpose

This study aims to focus on the preparation and characterization of the silver nanowire (AgNWs), as well as their application as antimicrobial and antivirus activities either with incorporation on the waterborne coating formulation or on their own.

Design/methodology/approach

Prepared AgNWs are characterized by different analytical instruments, such as ultraviolet-visible spectroscope, scanning electron microscope and X-ray diffraction spectrometer. All the paint formulation's physical and mechanical qualities were tested using American Society for Testing and Materials, a worldwide standard test procedure. The biological activities of the prepared AgNWs and the waterborne coating based on AgNWs were investigated. And, their effects on pathogenic bacteria, antioxidants, antiviral activity and cytotoxicity were also investigated.

Findings

The obtained results of the physical and mechanical characteristics of the paint formulation demonstrated the formulations' greatest performance, as well as giving good scrub resistance and film durability. In the antimicrobial activity, the paint did not have any activity against bacterial pathogen, whereas the AgNWs and AgNWs with paint have similar activity against bacterial pathogen with inhibition zone range from 10 to 14 mm. The development of antioxidant and cytotoxicity activity of the paint incorporated with AgNWs were also observed. The cytopathic effects of herpes simplex virus type 1 (HSV-1) were reduced in all three investigated modes of action when compared to the positive control group (HSV-1-infected cells), suggesting that these compounds have promising antiviral activity against a wide range of viruses, including DNA and RNA viruses.

Originality/value

The new waterborne coating based on nanoparticles has the potential to be promising in the manufacturing and development of paints, allowing them to function to prevent the spread of microbial infection, which is exactly what the world requires at this time.

Details

Pigment & Resin Technology, vol. 52 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 19 May 2022

H. Abd El-Wahab and Raafat A. El-Eisawy

This paper aims to prepare new modified alkyd resins and use it as an antimicrobial binder for surface coating applications.

Abstract

Purpose

This paper aims to prepare new modified alkyd resins and use it as an antimicrobial binder for surface coating applications.

Design/methodology/approach

Various modified alkyd resins were prepared by partial replacement of 3,6-dichloro benzo[b]thiophene-2-carbonyl bis-(2-hydroxy ethyl)-amide as a source of polyol with glycerol and confirmed by acid value, FT-IR, 1H-NMR. The modified alkyd resins were covering a wide range of oil lengths and hydroxyl content (0%, 10%, 20% and 30% excess-OH). The antimicrobial activity of the prepared alkyds was also investigated. The coatings of 60 ± 5 µm thickness were applied to the surface of glass panels and mild steel strips by means of a brush. Physico-mechanical tests, chemical resistance and antimicrobial activities were investigated.

Findings

The obtained results illustrate that the introduction of benzo[b]thiophene derivative as a modifier polyol within the resin structure improved the film performance and enhanced the physico-mechanical characteristics, chemical resistance and the antimicrobial activities.

Practical implications

The modified alkyd resins can be employed as antimicrobial binders in paint compositions for a variety of surfaces, particularly those that are susceptible to a high number of bacteria.

Originality/value

Modified alkyd resins based on antimicrobial heterocyclic compounds have the potential to be promising in the manufacturing of antimicrobial coatings and development of paints, allowing them to function to prevent the spread of microbial infection, which is exactly what the world requires at this time. Also, they can be applied in different substrates for industrial applications.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 27 October 2020

Ahmed Mohamed, Abdelhalim Mustafa, M.S.A. Elgaby, H. Abd El-Wahab, Said Ahmed Abed and A. Kazlauciunas

This paper aims to prepare a new modified poly(ester amide) (PEA) resins and use it as a binder for anticorrosive and antimicrobial coatings.

Abstract

Purpose

This paper aims to prepare a new modified poly(ester amide) (PEA) resins and use it as a binder for anticorrosive and antimicrobial coatings.

Design/methodology/approach

New modified PEA compositions were prepared based on 4-amino-N, N-bis(2-hydroxyethyl) benzamide (AHEB) as the ingredient source of the polyol used and evaluated as vehicles for surface coating. The structure of the modifier and PEA resin was confirmed by FT-IR, H¹-NMR, MW, thermogravimetric analysis and scanning electron microscope studies. Coatings of 50±5 µm thickness were applied to the surface of glass panels and mild steel strips by means of a brush. The coating performance of the resins was evaluated using international standard test methods and involved the measurement of phyisco-mechanical properties and chemical resistance.

Findings

The tests carried out revealed that the modified PEA based on AHEB enhanced both phyisco-mechanical and chemical properties. Also, the resins were incorporated within primer formulations and evaluated as anti-corrosive and antimicrobial single coatings. The results illustrate that the introduction of AHEB, within the resin structure, improved the film performance and enhances the corrosion resistance and antimicrobial activity performance of PEA resins.

Practical implications

The modified PEA compounds can be used as binders in paint formulations to improve the chemical, physical, corrosion resistance and antimicrobial activity properties.

Originality/value

Modified PEA resins are cheaper and can be used to replace other more expensive binders. These modified PEA resins can compensate successfully for the presence of many the anticorrosive and antimicrobial paint formulations, and thus, lower the costs. The main advantage of these binders is that they combine the properties of both polyester and polyamide resins based on nitrogenous compound, are of lower cost and they also overcome the disadvantages of both its counterparts. Also, they can be applied in other industrial applications.

Article
Publication date: 14 October 2021

Nashwa Mostafa Saleh, Maha Mohammed Elsawy, Hamada Abd El-Wahab, Salem Salah Salem and Nour El-Din Abd El-Sattar

The purpose of this study is to develop a new protective coating formulation for industrial use, using benzodiazepine derivatives as double function additives.

Abstract

Purpose

The purpose of this study is to develop a new protective coating formulation for industrial use, using benzodiazepine derivatives as double function additives.

Design/methodology/approach

Benzodiazepine’s derivatives of types (3–5) were prepared and confirmed by infrared, Mass, 1H-Proton nuclear magnetic resonance (NMR) and 13C NMR spectra. The synthesized compound was physically incorporated in the alkyd paint formulation by pebble mill grinding until all particulates are smaller than 20 ums. The prepared coatings were applied by air spray on steel panels. The physical, mechanical characteristics, corrosion resistance and antimicrobial test of the prepared coatings were studied to evaluate the prepared compounds drawbacks.

Findings

The results of the mechanical and physical properties of the paint formulation revealed that the paint formulation incorporating benzodiazepines derivatives 3–5 performed best and improved corrosion-resistance and antibacterial activity tests.

Research limitations/implications

In alkyd paint, heterocyclic compounds are the most used antibacterial additives. Other functionalities of these compounds, such as corrosion inhibitors, might be studied to see if they are suited for these applications.

Practical implications

Because of the activity of various benzodiazepine derivatives, which may be attributable to the presence of some function groups such as sulfonamide aromatic amino NH2 group, and elements such as Sulphur, Nitrogen, Chlorine, in its chemical structure. As a result, paint compositions including these compounds as additives can be used as dual-purpose paint and for a variety of industrial applications.

Originality/value

The research demonstrates how a low-cost paint composition based on synthesized benzodiazepine derivatives 3–5 may be used as a dual-function paint for industrial use.

Details

Pigment & Resin Technology, vol. 51 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 June 2023

Roma G. Elfadel, Hala M. Refat, H. Abdelwahab, Salem S. Salem, Mohamed A. Awad and M.A.M. Abdel Reheim

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

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Abstract

Purpose

This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications.

Design/methodology/approach

Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated.

Findings

The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins.

Research limitations/implications

The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms.

Originality/value

Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Content available

Abstract

Details

Pigment & Resin Technology, vol. 37 no. 3
Type: Research Article
ISSN: 0369-9420

Content available
Article
Publication date: 27 June 2008

128

Abstract

Details

Anti-Corrosion Methods and Materials, vol. 55 no. 4
Type: Research Article
ISSN: 0003-5599

Article
Publication date: 17 May 2022

Sampson Kofi Kyei, William Iheanyi Eke, Godfred Darko and Onyewuchi Akaranta

This study aims to synthesize pigment and resin from agro-wastes and use them in the formulation of eco-friendly surface coatings.

Abstract

Purpose

This study aims to synthesize pigment and resin from agro-wastes and use them in the formulation of eco-friendly surface coatings.

Design/methodology/approach

The pigments and resin were synthesized through a chemical modification of agro-wastes. The pigments were characterized by infrared spectroscopy (FTIR) and were screened for their antimicrobial activities. The physicochemical characteristics of the cashew nutshell liquid (CNSL)-modified resin were evaluated. These precursors and other natural additives were used to formulate surface coatings, and their drying and adhesive properties were evaluated using international testing methods.

Findings

It was observed that the curing of the CNSL-modified resin depended on time and temperature. The pigments exhibited antimicrobial activity against E. coli and S. aureus and had high melting points, affirming their stability. The chemically modified precursors successfully yielded surface coatings with acceptable drying times and adhesion to the base substrate.

Practical implications

The use of agro-wastes as the main components of the surface coatings implies waste valorization, a reduction in production costs and the creation of job opportunities for sustainable development. To increase the chemical, physical, corrosion resistance and antimicrobial qualities of paint compositions, chemically modified peanut skin extracts and CNSL can be used as pigments and resins, respectively. This could be a green approach to achieving the targets of Sustainable development goals 11 and 12.

Originality/value

The paper outlines a prospective approach to use unwanted waste (peanut skin, cashew nutshells) and other natural additives as industrial raw materials. These novel surface coating precursors are cost-effective, readily available, eco-friendly and could replace conventional precursors.

Details

Pigment & Resin Technology, vol. 52 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 20 October 2021

Ali A. Ali, Maha Mohammed Elsawy, Salem S. Salem, Ahmed A. El-Henawy and Hamada Abd El-Wahab

Paper aims to preparation of new acid disperse dyes based on thiadiazol derivatives and evaluation of their use as antimicrobial colorants in digital transfer-printing ink…

Abstract

Purpose

Paper aims to preparation of new acid disperse dyes based on thiadiazol derivatives and evaluation of their use as antimicrobial colorants in digital transfer-printing ink formulations for printing onto polyester fabric substrates.

Design/methodology/approach

New disperse dyes based on 1,3,4 - thiadiazol derivative (dyes 1–3) were prepared and evaluated by different analysis then formulated as colored materials in the ink formulations. The viscosity, dynamic surface tension and particle size distribution of the prepared inks were measured. The printed polyester fabric substrates were tested using a variety of tests, including light fastness, washing, alkali perspiration and Crock fastness, as well as depth of penetration. Density-functional theory (DFT) calculations were carried out at the Becke3-Lee-Yang-parr (B3LYP) level using the 6–311** basis set, and the biological activity of the prepared disperse dyes was investigated.

Findings

The obtained results of the physical of the prepared ink revealed that thiadiazol disperse ink is a promising ink formulation for polyester printing and agrees with the quality of the printed polyester fabric. The optimization geometry for molecular structures agreed with the analysis of these compounds. The HOMO/LUMO and energy gap of the studied system were discussed. The molecular docking analysis showed strong interaction with DNA Gyrase and demonstrated to us the high ability of these inks to act as antimicrobial agents.

Practical implications

The prepared inks containing the prepared thiadiazol disperse dye were high-performance and suitable for this type of printing technique, according to the results. The prepared inks resist the growth of microorganisms and thus increase the ink's storage stability.

Originality/value

The prepared disperse dyes based on 1,3,4 - thiadiazol derivative (dyes 1–3) can be a promising colorant in different applications, like some types of paint formulations and as a colorant in printing of different fabric substrates.

Details

Pigment & Resin Technology, vol. 52 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

1 – 10 of 123