Search results

1 – 10 of 543
Article
Publication date: 7 March 2016

Poonam Sharma, Anil Dhawan and S. K. Sharma

The purpose of this paper was to investigate the corrosion behavior of the Zr59Nb3Al10Ni8Cu20 amorphous alloy in aqueous 1M, 6M and 11.5M HNO3 media using potentiodynamic…

Abstract

Purpose

The purpose of this paper was to investigate the corrosion behavior of the Zr59Nb3Al10Ni8Cu20 amorphous alloy in aqueous 1M, 6M and 11.5M HNO3 media using potentiodynamic polarization and weight loss determinations.

Design/methodology/approach

The electrochemical study, weight loss analysis and surface investigation were carried out on amorphous Zr59Nb3Al10Ni8Cu20 alloy that had been immersed in aqueous HNO3 medium at room temperature to understand the corrosion behavior of Zr-based amorphous Zr59Nb3Al10Ni8Cu20 alloy. The amorphous state of the alloy was investigated using X-ray diffraction. Electrochemical studies were carried out in aqueous 1M, 6M and 11.5M HNO3 media by recording open circuit potential/time and potentiodynamic polarization characteristics. Optical microscopy and scanning electron microscopy were used to examine the surface morphology of the alloy after the electrochemical tests and weight loss determinations.

Findings

The electrochemical results revealed that Ecorr values shifted toward more noble values, as the concentration of the nitric acid was increased, and this was attributed to the higher oxidizing power of the nitric acid. The higher value of corrosion current density was obtained for the Zr59Nb3Al10Ni8Cu20 amorphous alloy in aqueous 11.5M HNO3 medium at room temperature. The optical microscopy and scanning electron microscopy examinations revealed that the formation of protective oxide layer on the surface of amorphous Zr59Nb3Al10Ni8Cu20 alloy leads to the improvement in the corrosion behavior in nitric acid medium at room temperature.

Originality/value

The results can be helpful in finding the suitable material for fuel reprocessing applications.

Details

Anti-Corrosion Methods and Materials, vol. 63 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 17 July 2018

Yan Baoxu and Kong Dejun

The amorphous Al-Ni-Fe-Gd coatings were fabricated to improve anti-corrosion performance of offshore platforms.

Abstract

Purpose

The amorphous Al-Ni-Fe-Gd coatings were fabricated to improve anti-corrosion performance of offshore platforms.

Design/methodology/approach

The amorphous Al-Ni-Fe-Gd coatings were first fabricated on S355 steel using the laser thermal spraying.

Findings

The amorphous forming capability and corrosion resistance increases with the laser powers increasing.

Research Limitations/implications

The amorphous Al-Ni-Fe-Gd coatings were applied on S355 steel of offshore platforms to increase its long-term heavy and anti-corrosion protection.

Originality/value

The amorphous Al-Ni-Fe-Gd coatings were first fabricated using a laser thermal spraying, improving its anti-corrosion.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 18 March 2022

Xinlong Wei, Erguang Fu, Aolin Ban, Wy Zhu, Dl Wu, N. Li and C. Zhang

The purpose of this paper is to investigate the effect of nano-alumina sealant sealing treatment on corrosion behavior of the Fe-based amorphous coatings deposited on 304…

Abstract

Purpose

The purpose of this paper is to investigate the effect of nano-alumina sealant sealing treatment on corrosion behavior of the Fe-based amorphous coatings deposited on 304 stainless steel plates by atmospheric plasma spraying (APS) with different hydrogen flow rates.

Design/methodology/approach

The surface morphology and microstructure of the unsealed and sealed coatings were characterized by scanning electron microscopy and X-ray diffraction. The corrosion resistance of the coatings was investigated by potentiodynamic polarization test and electrochemical impedance spectroscopy experiment in 3.5 Wt.% NaCl solution.

Findings

Results show that a few microcracks and pores exist in the as-sprayed Fe-based amorphous coatings. The pores on the surface of the coatings after sealing treatment have been filled with nano-alumina sealant, which can effectively prevent corrosive medium from entering into coatings. Electrochemical tests results show that the corrosion resistance of the coatings before sealing treatment decreases with the increase of hydrogen flow rate and is significantly improved by sealing treatment.

Originality/value

The effect of nano-alumina sealant sealing treatment on corrosion resistance of APS-sprayed Fe-based amorphous coatings is revealed. The corrosion resistance of the as-sprayed Fe-based amorphous coating can be significantly improved by nano-alumina sealant sealing treatment because of the blocking effect of nano-alumina sealant on corrosive medium, which confirms that the application of nano-alumina sealant sealing treatment is of a practical option to improve corrosion resistance of as-sprayed thermal sprayed coatings.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 13 October 2022

Eyyüp Öksüztepe, Ufuk Kaya and Hasan Kurum

More electric aircraft (MEA) is defined as the extensive usage of electric power in aircraft. The demand for electric power in new generation aircraft rises due to environmental…

Abstract

Purpose

More electric aircraft (MEA) is defined as the extensive usage of electric power in aircraft. The demand for electric power in new generation aircraft rises due to environmental and economic considerations. Hence, efficient and reliable starter/generators (SGs) are trending nowadays. The conventional main engine starting system and power generation system can be replaced with an individual SG. The constraints of the SG should be investigated to handle the aviation requirements. Even though the SG is basically an electric machine, it requires a multidisciplinary study consisting of electromagnetic, thermal and mechanical works to cope with aviation demands. This study aims to review conventional and new-generation aircraft SGs from the perspective of electric drive applications.

Design/methodology/approach

First of all, the importance of the MEA concept has been briefly explained. Also, the historical development and the need for higher electrical power in aircraft have been indicated quantitatively. Considering aviation requirements, the candidate electrical machines for aircraft SG have been determined by the method of scoring. Those machines are compared over 14 criteria, and the most predominant of them are specified as efficiency, power density, rotor thermal tolerance, high-speed capability and machine complexity. The features of the most suitable electrical machine are pointed out with data gathered from empirical studies. Finally, the trending technologies related to efficient SG design have been explained with numeric datasets.

Findings

The induction motor, switched reluctance motor and permanent magnet synchronous motor (PMSM) are selected as the candidate machines for SGs. It has been seen that the PMSM is the most preferable machine type due to its efficient operation in a wide range of constant power and speed. It is computationally proven that the using amorphous magnetic alloys in SG cores increases the machine efficiency more. Also, the benefits of high voltage direct current (HVDC) use in aircraft have been explained by a comparison of different aircraft power generation standards. It is concluded that the HVDC use in aircraft decreases total cable weight and increases aircraft operation efficiency. The thermal and mechanical tolerance of the SG is also vital. It has been stated that the liquid cooling techniques are suitable for SGs.

Originality/value

The demand for electrical power in new generation aircraft is increasing. The SG can be used effectively and efficiently instead of conventional systems. To define requirements, constraints and suggestions, this study investigates the SGs from the perspective of electric drive applications.

Details

Aircraft Engineering and Aerospace Technology, vol. 95 no. 3
Type: Research Article
ISSN: 1748-8842

Keywords

Article
Publication date: 15 November 2022

Chao Han, Li Ma, Bo Jiang Ma, Guosheng Huang and Ying Xiang Ma

This paper aims to verify weather atmospheric plasma spray (APS) in situ remelting posttreatment is effective for densifying the porous FeCoCrMoCBY amorphous alloy (FAA) coating…

Abstract

Purpose

This paper aims to verify weather atmospheric plasma spray (APS) in situ remelting posttreatment is effective for densifying the porous FeCoCrMoCBY amorphous alloy (FAA) coating and improving the antiabrasion and anticorrosion performances or not.

Design/methodology/approach

APS was used to deposit and in situ densify FAA coating on the 40Cr substrate. Scanning electron microscope, X-ray diffractometer, energy dispersive spectroscopy, neutral salt spray, hardness and wear behavior test were used to evaluate the densifying effects.

Findings

APS remelting technology can effectively improve the hardness of the coating by reducing the porosity. After remelting at 30 kW power, the hardness of the coating increased by about 260 HV0.2 and the porosity decreased to 2.78%. The amorphous content of the coating is 93.9%, which is about 3.5% lower than original powders. The electrochemical impedance spectrum and neutral salt spray test results show that APS remelting can reduce the corrosion rate by about 62.7%.

Originality/value

APS remelting method is firstly proposed in this work to replace laser remelting or laser cladding methods. APS remelting method can effectively improve the corrosion and abrasion resistance of the FAA coating by increasing the densification with much low recrystallization, which is big progress for application of FAA coatings.

Details

Anti-Corrosion Methods and Materials, vol. 70 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 28 November 2019

Amitava Choudhury, Tanmay Konnur, P.P. Chattopadhyay and Snehanshu Pal

The purpose of this paper, is to predict the various phases and crystal structure from multi-component alloys. Nowadays, the concept and strategies of the development of…

Abstract

Purpose

The purpose of this paper, is to predict the various phases and crystal structure from multi-component alloys. Nowadays, the concept and strategies of the development of multi-principal element alloys (MPEAs) significantly increase the count of the potential candidate of alloy systems, which demand proper screening of large number of alloy systems based on the nature of their phase and structure. Experimentally obtained data linking elemental properties and their resulting phases for MPEAs is profused; hence, there is a strong scope for categorization/classification of MPEAs based on structural features of the resultant phase along with distinctive connections between elemental properties and phases.

Design/methodology/approach

In this paper, several machine-learning algorithms have been used to recognize the underlying data pattern using data sets to design MPEAs and classify them based on structural features of their resultant phase such as single-phase solid solution, amorphous and intermetallic compounds. Further classification of MPEAs having single-phase solid solution is performed based on crystal structure using an ensemble-based machine-learning algorithm known as random-forest algorithm.

Findings

The model developed by implementing random-forest algorithm has resulted in an accuracy of 91 per cent for phase prediction and 93 per cent for crystal structure prediction for single-phase solid solution class of MPEAs. Five input parameters are used in the prediction model namely, valence electron concentration, difference in the pauling negativeness, atomic size difference, mixing enthalpy and mixing entropy. It has been found that the valence electron concentration is the most important feature with respect to prediction of phases. To avoid overfitting problem, fivefold cross-validation has been performed. To understand the comparative performance, different algorithms such as K-nearest Neighbor, support vector machine, logistic regression, naïve-based approach, decision tree and neural network have been used in the data set.

Originality/value

In this paper, the authors described the phase selection and crystal structure prediction mechanism in MPEA data set and have achieved better accuracy using machine learning.

Details

Engineering Computations, vol. 37 no. 3
Type: Research Article
ISSN: 0264-4401

Keywords

Article
Publication date: 13 September 2018

Miao Li, Bi Qing Chen, Min He, Tongtong Xiong and Lixia Gao

This paper aims to obtain rare earth magnesium alloy with good adhesion and corrosion resistance.

Abstract

Purpose

This paper aims to obtain rare earth magnesium alloy with good adhesion and corrosion resistance.

Design/methodology/approach

In 353 K oil bath, cyclic voltammetry was used to study the electrochemical behavior of Pr(III), Mg(II) and Ni(II) in choline chloride-urea ionic liquid. The constant potential method was adopted for electrodeposition of Pr-Mg-Ni ternary alloy films. The content of Pr in the Pr-Mg-Ni alloy films changes with respect to the deposition potential, deposition time and concentration ratio of Pr3+:Mg2+:Ni2+. Response surface methodology was applied to optimize the conditions for obtaining high-quality deposition films.

Findings

The results showed that the reaction of Ni(II) to Ni is irreversible; this result can be verified by Tafel polarization curve and chronocoulometry curve. Its transfer coefficient on the platinum electrode of 0.32 and diffusion coefficient is 1.0510−6 cm2.s−1. Mg(II) and Pr(III) cannot solely be reduced to their elemental form, but they can be induced via codeposition by Ni(II). The result shows that under a voltage of −1.00 V, the alloy coating with even structure is obtained when the concentration ratio of Pr3+:Mg2+:Ni2+ is 1:1:1 and the deposition time is 20 min. Scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy and other analyses revealed that the alloy coating is amorphous. Polarization curves of the cathode are tested, which manifest the lowest corrosion current density, stating which has good corrosion performance in alkaline solution and NaCl solution; this can be attributed to its dense film structure and good combination with the substrate.

Originality/value

It provides some technology for the production of corrosion-resistant materials.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 27 February 2020

Kong Dejun and Chen Haixiang

The purpose of this paper is to investigate the effects of laser power on the electrochemical corrosion performance in 3.5% NaCl, 0.1 M H2SO4 and 0.1 M NaOH solutions, which…

Abstract

Purpose

The purpose of this paper is to investigate the effects of laser power on the electrochemical corrosion performance in 3.5% NaCl, 0.1 M H2SO4 and 0.1 M NaOH solutions, which provided an experimental basis for the application of Al–Ti–Ni amorphous coating in marine environment.

Design/methodology/approach

Amorphous Al–Ti–Ni coatings were fabricated on S355 structural steel by laser thermal spraying (LTS) at different laser powers. The surface and cross-section morphologies, chemical element distribution, phases and crystallization behaviors of obtained coatings were analyzed using a scanning electron microscope, energy-dispersive X-ray spectroscope, X-ray diffraction and differential scanning calorimetry, respectively. The effects of laser power on the electrochemical corrosion performances of Al–Ti–Ni coatings in 3.5% NaCl, 0.1 M H2SO4 and 0.1 M NaOH solutions were investigated using an electrochemical workstation.

Findings

The crystallization temperature of Al–Ti–Ni coatings fabricated at the laser power of 1,300 and 1,700 W is ∼520°C, whereas that fabricated at the laser power of 1,500 W is ∼310°C. The coatings display excellent corrosion resistance in 3.5% NaCl and 0.1 M NaOH solutions, while a faster dissolution rate in 0.1 M H2SO4 solution. The coatings fabricated at the laser power of 1,300 and 1,700 W present the better electrochemical corrosion resistance in 3.5% NaCl and 0.1 M NaOH solutions, whereas that fabricated at the laser power of 1,500 W exhibits the better electrochemical corrosion resistance in 0.1 M H2SO4 solution.

Originality/value

In this work, Al-wire-cored Ti–Ni powder was first on S355 steel with the laser power of 1,300, 1,500 and 1,700 W, and the effects of laser power on the electrochemical corrosion performance in 3.5% NaCl, 0.1 M H2SO4 and 0.1 M NaOH solutions were investigated using an electrochemical workstation.

Article
Publication date: 6 November 2017

Longfei Zhu, Wenming Tong, Xueyan Han and Jianguo Zhu

The specific iron losses of amorphous alloy material are extremely low compared with silicon steel material. The iron losses of motors may reduce by replacing the silicon steel…

Abstract

Purpose

The specific iron losses of amorphous alloy material are extremely low compared with silicon steel material. The iron losses of motors may reduce by replacing the silicon steel core with an amorphous alloy core. However, one drawback of amorphous alloy material is that the specific iron losses will increase a lot after the motor manufacturing process. This paper aims to study the influences of interlaminar insulator solidifying and annealing on amorphous alloy material. The iron losses of motors made of amorphous alloy and baseline silicon steel sheets are compared and discussed.

Design/methodology/approach

This paper opted for an exploratory study using the experimental analysis and loss separation methods. Two amorphous alloy cores are produced and tested. The iron losses of motors made of amorphous alloy and silicon steel sheets are calculated and compared based on the measured specific iron losses. Three wound amorphous alloy core samples are made and measured. The iron losses are separated and compared by considering the manufacturing influences.

Findings

This paper provides empirical insights about what change is brought in amorphous alloy material after manufacturing. The results have shown that, for amorphous alloy cores without the annealing process, the loss increase caused by solidifying is mainly the eddy current loss, while it is mainly the hysteresis loss component for annealed amorphous alloy cores.

Originality/value

This paper presents for the first time the measured results of manufactured amorphous alloy cores. This paper fulfils the need to manufacture amorphous alloy motors properly for the producers.

Details

COMPEL - The international journal for computation and mathematics in electrical and electronic engineering, vol. 36 no. 6
Type: Research Article
ISSN: 0332-1649

Keywords

Article
Publication date: 17 September 2021

Wang Zhizhong, Han Chao, Guosheng Huang, Han Bin and Han Bin

The deposition of particles onto a substrate during the cold spraying (CS) process relies on severe plastic deformation, so there are various micro-defects induced by insufficient…

Abstract

Purpose

The deposition of particles onto a substrate during the cold spraying (CS) process relies on severe plastic deformation, so there are various micro-defects induced by insufficient deformation and severe crushing. To solve the problems, many post-treat techniques have been used to improving the quality by eliminating the micro-defects. This paper aims to help scholars and engineers in this field a better and systematic understand of CS technology by summarizing the post-treatment technologies that have been investigated recently years.

Design/methodology/approach

This review summarizes the types of micro-defects and introduces the effect of micro-defects on the properties of CS coating/additive manufactured, illustrates the post-treatment technologies and its effect on the microstructure and performances, and finally outlooks the future development trends of post-treatments for CS.

Findings

There are significant discoveries in post-treatment technology to change the performance of cold spray deposits. There are also many limitations for post-treatment methods, including improved performance and limitations of use. Thus, there is still a strong requirement for further improvement. Hybrid post-treatment may be a more ideal method, as it can eliminate more defects than a single method. The proposed ultrasonic impact treatment could be an alternative method, as it can densify and flatten the CS deposits.

Originality/value

It is the first time to reveal the influence factors on the performances of CS deposits from the perspective of microdefects, and proposed corresponding well targeted post-treatment methods, which is more instructive for improving the performances of CS deposits.

Details

Rapid Prototyping Journal, vol. 28 no. 2
Type: Research Article
ISSN: 1355-2546

Keywords

1 – 10 of 543